Narayana Sri Chaitanya IIT Academy

Sri Sarvani Educational Society

COMMON CENTRAL OFFICE_MADHAPUR_HYD
JR. IPL CO JEE ADVANCED DATE : 23-06-14
TIME : 3:00 2010_P1 MODEL MAX MARKS : 252
KEY & SOLUTIONS

CHEMISTRY
01) D 02) D 03) C 04) D 05) B 06) C 07) B
08) C 09) A,B,D 10) B,D 11) B,D 12) B,C,D 13) A,B 14) A
15) C 16) B 17) B 18) A 19) 2 20) 5 21) 4
22) 3 23) 5 24) 0 25) 3 26) 2 27) 8 28)9

MATHEMATICS
29) A 30) C 31) C 32) D 33) C 34) A 35) D
36) C 37) A,C 38) A,B,D 39) A,B,C 40) B,C,D 41) A,B,C,D 42) D
43) A 44) B 45) A 46) B 47) 1 48) 1 49) 1
50) 4 51) 3 52) 7 53) 6 54) 4 55) 4 56) 1

PHYSICS
57) B 58) D 59) C 60) B 61) A 62) A 63) B
64) C 65) A,B,C,D 66) A,C 67) A,B 68) B,C 69) C 70) A
71) B 72) C 73) D 74) A 75) 4 76) 6 77) 5

78) 4 79) 5 80) 4 81) 3 82) 4 83) 2 84) 2

CHEMISTRY - HINTS

 H 
1. CP'   
 T  P

2. At STP, 16g O2 or 1/ 2 mole O2 occupy 11.2 l . Volume is doubled.

V2  V1   22.4 11.2  11.2l

111.2  2
W  P V2  V1   111.2 l atm   272.84 kcal
0.082

4. Smx  R  n1l n x1  n2l n x2 

nO  1, nN  4, X O  0.2, X N  0.8
2 2 2 2

Sm  R l n 0.2  4 l n 0.8

Narayana Sri Chaitanya IIT Academy 23-06-14_Jr. IPL CO (ADV 2010_P1 Model)_Solutions

 2.5 R  20.8 JK 1mol 1

 25.8 
400 K 400 K
5. S 0    Cp / T  dT    T  0.012  dT
300 K 300 K

400
 25.8 l n  0.012  400  300 
300

 7.42  1.20  8.62 JK 1mol 1

6. N  N 00 H H

8. dU  TdS  PdV

 U   U 
   T,    P
 S V  V S

9. mass is extensive property

10. dH  TdS  VdP

 H   H 
   T,   V
 S  P  P S

11. A and C are not correct because they are not for one mole of the compound.
12. Combustion of C2 H 5OH is exothermic.

13. (C) is not for 1 mole. (D) is not from the constituent elements.
14. H  E  RT  ng 

25
C8 H18  l   O2  g   8 CO2  g   9 H 2O  l 
2

 25 
H  E   8   RT
 2 

9
H  E   RT
2

15. E  w for adiabatic process. So it is wrong.

16. At constant volume PV  0, q  u  500 J

17,18

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Narayana Sri Chaitanya IIT Academy 23-06-14_Jr. IPL CO (ADV 2010_P1 Model)_Solutions

H f  BE for formation of bonds + BE data for dissociation of bonds.

  3  C  C   3  C  C   6  C  H    6 Cs  g  3  H  H  

  3 340  3 620  6  490  6  716.8  3 436.2

 208.5 KJ mol 1

Resonance energy   H f exp t   H f calcd

 358.5   208.5

 150 KJ mol 1

19. CP  CV  R  2Cal

H v 540
20. Sv  
TBP 373

H fusion 80
DS f  
TMP 273

Sv 546.5 273

  5
S f 373 80

HVap
21. SVap. 
TBP

30 1000
75 
TBP

30 1000
TBP   400 K , x  4
75

3R
22. He is monoatomic
2

23. Energy available for muscular work by 1 mole of glucose = 2880  26.04
 750 KJ
100

180g glucose supply = 750 KJ

120
120g of glucose = 750   500 KJ
180

With 100 kJ the distance covered is 1 km

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Narayana Sri Chaitanya IIT Academy 23-06-14_Jr. IPL CO (ADV 2010_P1 Model)_Solutions

With 600 kJ the distancee covered is 6 km

H H
24. CP    , H 2 O  l  H 2O  s 
T 0

1
0
CP

25. Net reaction is Ca 2  aq   CO32  aq   CaCO3  s 

H   0f CaCO3  H 0f Ca 2  H 0f CO3 

2

 288.45   129.80  161.65  3 kcal

26. Heat of dissociation is endothermic

11.7   13.7   2.0 kcal

R
27. CP  Cv 
M

2
0.125  0.075 
M

M  40, x  8

28. CuSO4  s   H 2O  CuSO4  aq   15.5

CuSO4 .5H2O  H2O  CuSO4  aq   2.5

CuSO4  5H2O  CuSO4 .5H2O  18.0

H  18 kcal

x 9

MATHEMATICS - HINTS

29. sin 2/3  sin 2/3  cos2/3  cos2/3  cos2/3  sin2/3   a

sin  cos2/ 3   sin 2/ 3   cos2/ 3  

1/ 2
2/ 3
a

sin   cos2/ 3  
3/ 2
2/ 3
a

 sin 2 / 3   cos 2 / 3   a 2 / 3

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Narayana Sri Chaitanya IIT Academy 23-06-14_Jr. IPL CO (ADV 2010_P1 Model)_Solutions

x 2 sec2   1  y 2  tan 2   2 y  tan 

x 2 sec2   5  y 2 tan 2 
30.
______________________________
0  4  2 y tan   tan   2 / y

 x 2 1  tan 2    5  y 2 tan 2 

 4 
x 2 1  2   5  4  9
 y 

cos 2  sin 2 
31. x ,y
sin  cos 

 x y   xy 2 
2/ 3 2/ 3
2
 sin 2   cos 2   1

Sin  2 A  B  5
32. 
SinB 1

Sin  2 A  B   SinB 6

Sin  2 A  B   SinB 4


2sin  A  B  cos A  3 / 2
2 cos  A  B  sin A

Tan  A  B  3

TanA 2

33. cos 2 B  3sin 2 A

3
sin 2 B  sin 2 A
2

cos  A  2B   cos A cos 2B  sin A sin 2B

3
 3cos A sin 2 A  sin 2 A sin A
2

 3cos A sin 2 A  3cos A sin 2 A

0

 A  2 B  900

34. A is involuntary. Hence, A2  I  A  A1

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Narayana Sri Chaitanya IIT Academy 23-06-14_Jr. IPL CO (ADV 2010_P1 Model)_Solutions

1
Also,  kA    A 
1 1

k
1
1 
  A   2  A  2 A
1

2 

        2  
35. 2 cos   cos    2 cos 1  3 / 2
 2   2  2

        2  
4 cos   cos    4 cos 1
 2   2  2

     
4 cos 2  4 cos cos 1  0
2 2 2

     2   
2
 
 2 cos  cos   sin  0
 2 2   2 

         
 2 cos    cos   , sin 0
 2   2  2

   0

 

 2 cos   1

1
cos  
2

  /3  

36. If A  B  450 then 1  tan A1  tan A  2


 1  tan10 1  tan 440  1  tan 2 1  tan 43 ......1  tan 22 1  tan 23  1  tan 45 
0 0 0 0 0

 2  2  2  ......  2  2  223

 n  23

37. 0    / 2

 sin  cos   cos

 sin   

cos  sin    cos

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Narayana Sri Chaitanya IIT Academy 23-06-14_Jr. IPL CO (ADV 2010_P1 Model)_Solutions

sin  cos   cos  sin  

Here (A) is correct.

(B)  cos  1
 loge cos   loge 1  0


If e 2   
2
 
  log e   log e  / 2 
2 2


 log e  
2

 log e  is in 4 th or 1st quadrant

cos  loge    0

 B  is correct

(C)  C is correct from following graph

38. (A) Area of ABCD = 2  Area of le ABD

1
2   AB  P1
2

P2
  P1
sin 

P1 P2

sin 

 (A) is correct.
(B) le ABD and le ABE are similar

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Narayana Sri Chaitanya IIT Academy 23-06-14_Jr. IPL CO (ADV 2010_P1 Model)_Solutions

P1 AD
 
P2 AB

Now P1  P2  AD  AB  all sides equal

  900  ABCD is a square Hence (B) is correct.

AE
In le ABE  sin 
AB

P2
AB 
sin 

(C) P1  P2  all sides are equal

But   900 is not necessary for ABCD to be rhombus.
Hence C is not correct.
(D)If   900 ABCD is a reactangle.
Hence (D) is correct.
39. Given that A and B commute, we have
AB  BA  A and B are symmetric

Also,
AT  A, BT  B

 A B  BT  A1   BA1
1 T T

 if A is symmetric, A1 is also symmetric 

Also from Eq.(1),

ABA1  B

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Narayana Sri Chaitanya IIT Academy 23-06-14_Jr. IPL CO (ADV 2010_P1 Model)_Solutions

 A1 ABA1  A1B

 IBA1  A1B

 BA1  A1B

Hence, from Eq.(2),

 A B
1 T
 A1B

Thus, A1B is symmetric. Similarly, AB 1 is also symmetric. Also, BA  AB

  BA   AB 
1 1

 A1B 1  B 1 A1

  A1B 1    B 1 A1 
T T

  A1  B 
T 1 T

 A1 B 1

Hence, A1B 1 is symmetric.

40. Graph sin x  Cosx in [0,  )

From graph it is observed that (A), (B), (C), (D) are correct.
Sin2 81
41. 81   30
81
Sin2

Sin2
Let  81 t

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Narayana Sri Chaitanya IIT Academy 23-06-14_Jr. IPL CO (ADV 2010_P1 Model)_Solutions

81
t  30
t

t 2  30t  81  0

t  27 t  3  0
t  27 t 3
 
 33  31
2 2
34sin 34sin

4 sin 2   3 4sin 2   1

sin 2   3 / 4 sin 2   1/ 2

3 1
sin   sin  
2 2

  600 or 1200    300 or 1500

42,43,44
1  Tan  3tan   tan 3  
 3 
1  Tan  1  3tan  
2

Put tan   t

1  t 3  3t  t 
3


1  t 1  3t 2 

 3t 4  6t 2  8t  1  0

Its roots are tan  , tan  , tan  , tan 

 (1)  tan   0
1
(2)  tan  
3

1
(3)  Tan  8
45,46
a
Cos 
l

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Narayana Sri Chaitanya IIT Academy 23-06-14_Jr. IPL CO (ADV 2010_P1 Model)_Solutions

1 a
Cos 120   
l

1 a
Cos120 cos   sin120sin  
l

1 a 3 a2 1  a
.  . 1 2 
2 l 2 l l

3 2 a
l  a2  1  a 
2 2
2
 a

3 2
4
l  a 2   1  
 2

4  a 2  4a
3 2
4
 l  a2  
4

3l 2  3a 2  4  a 2  4a

4  a 2  a  1
l 
2

3
2
l a2  a  1
3

47. Tan2  Sin .Cos

Sin2
 Sin .Cos
Cos 2

Sin  Cos 3

Sin2  1  sin 2  
3

Sin 2  1  3sin 4   3sin 2   sin 6 

1  4sin 2   3sin 4   sin 6   0

 2  4sin 2   3sin 4   sin 6   1

48. 2 cot   1  cot 2   cot 

 1  cot    cot 
2

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Narayana Sri Chaitanya IIT Academy 23-06-14_Jr. IPL CO (ADV 2010_P1 Model)_Solutions

 1  cot   cot 

 1  1

49. Dividing given expression with tan 2  tan 2  tan 2 

2  cot 2   cot 2   cot 2   cot 2  cot 2  cot 2 

2  cos ec 2  1  cos ec 2   1  cos ec  1   cos ec 2  1 cos ec 2   1 cos ec 2  1

 cos ec2 cos ec2   cos ec2  cos ec2  cos ec2 cos ec2  cos ec2 cos ec2  cos ec2

1 1 1
   1
cos ec  cos ec  cos ec 2
2 2

sin 2   sin   sin 2   1

a b 
50.  c 1  a  is an idempotent matrix.
 
2
a b  a b 
   
c 1 a c 1 a

a b  a b  a b 
     
c 1 a c 1 a c 1 a

 a 2  bc b  a b 
 2
 
 c bc  1  a    c 1  a 

 a 2  bc  a

a  a 2  bc  1/ 4 (given)
f  a   1/ 4

51. tan 3  200   3

3tan 20  tan 3 20
 3
1  3tan 2 20

Squaring or both sides we get the answer.

 2 cos A  9 cos D    6 cos B  7 cos C 

2 2
52.

 2sin A  9SinD    6sin B  7 sin C 

2 2

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Adding:
36 cos  A  D   84 cos  B  C 

cos  A  D  84
  7/3
cos  B  C  36

cos  A  D 
3 7
cos  B  C 

1 1 1
53.   
cos80 cos 40 cos 20

cos 40 cos 20  cos80 cos 20  cos 40 cos80


cos 20 cos 40 cos80

 8cos 20  cos 40  cos80  cos 40cos80

4 2 cos 2 20  2 cos 40 cos80

 41  cos 40  cos120  cos 40

 4  3/ 2  6

2sin 40 cos 30  2sin 40 cos10

54.
cos10 cos 20 sin 40

cos 30  cos10 2cos 20.cos10

2 2 4
cos10.cos 20 cos 20.cos10

55. Let    /16  8   tan13   cot 5
2

tan9   cot 

tan   tan5  tan9  tan13 tan 5  tan 8  3   cot 3

  tan   cot     tan 5  cot 5 

sin 2   cos2  cos 2 3  sin 2 3

 
sin  cos  sin 3 cos 3

 cos 6 cos 2 
2  
 sin 6 sin 2 

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Narayana Sri Chaitanya IIT Academy 23-06-14_Jr. IPL CO (ADV 2010_P1 Model)_Solutions

 sin 4 
 2  
 sin 2 sin 6 

sin 4
 2   
  4
 sin 2 cos 2 

 absolute value is 4.
sin  / 2  2cos 2  / 2 2cos 2  2sin 2 2 
56. f n     . . .....
cos  / 2  cos  cos 2 cos 4 

 tan  2n  

     
f5    tan  32.  1
 128   128 

PHYSICS - HINTS
57. Force exerted on B by A in magnitude is equal to force exerted on A by B.
59. Area under force – time graph is Impulse, i.e., change in momentum.
61. 2F   M  m g

20sin 530  10sin 370

63. a m / s2
3
10
 m / s2
3

64. (B)
Conceptual

65. (A),(B),(C),(D)
In equilibrium, net force on each block is zero.
66. (A), (C)
Conceptual
67. (A), (B)

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The impulse given to the particle is equal to area under f – t graph = 0.07 kgm/s = 2x
initial momentum of the particle. Hence the particle will reverse in direction and move
with its initial speed.
68. (B),(C)
In the frame of refference of the box, effective acceleration due to gravity is g cos  along
perpendicular to the incline plane.
69. (C)
Reading of the weighing machine is equal to Normal force, which is equal to vector sum
of true weight and Pseudo force.
70. (A)
Conceptual
71. (B)
Conceptual
72. (C)
Conceptual

73. (D)
Conceptual
74. (A)
75. (4)
76. (6)
77. (5)
78. (4)
Plot speed – time graph. The area under the curve gives distance.

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79. (5)
80. (4)
81. (3)
82. (4)
83. (2)
84. (2)

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