1

6.- En la reacción SO2 (g) + O2 (g) = SO3 (g) Ka = 6.55 a 900°K. Hallar
2
∆𝐹° de la reacción a esta temperatura.

∆𝐹 = −𝑅𝑇𝑙𝑛𝐾𝑎

𝑎𝑡𝑚. 𝑙𝑡𝑠
∆𝐹 = − (0.082 ) (900°𝐾) ln(6.55)
𝑚𝑜𝑙⁄
°𝐾
𝑎𝑡𝑚. 𝑙𝑡𝑠
∆𝐹 = −138.7045
𝑚𝑜𝑙
7.- Calcular la relación Kp / Kc a 300°K en cada una de las reacciones
dadas en el problema 2.

𝑎) 𝐶2 𝐻6 ↔ 𝐶2 𝐻4 + 𝐻2
[𝐶2 𝐻4 ][𝐻2 ] [1][1]
𝐾𝑝 = = =1
[𝐶2 𝐻6 ] [1]

𝐾𝑝 = 𝐾𝑐 (𝑅𝑇)∆𝑛𝑔

𝐾𝑝 1
𝐾𝑐 = = = 0.0406
(𝑅𝑇)1 (0.082)(300)
𝐾𝑝
⁄𝐾 = 1⁄0.0406 = 24.6305
𝑐

𝑏)2𝑁𝑂 + 𝑂2 ↔ 2𝑁𝑂2

[𝑁𝑂2 ]2 [1]2
𝐾𝑝 = = =1
[𝑁𝑂]2 [𝑂2 ] [1]2 [1]

𝐾𝑝 = 𝐾𝑐 (𝑅𝑇)∆𝑛𝑔

𝐾𝑝 1
𝐾𝑐 = = = 24.6
(𝑅𝑇)−1 (0.082)(300)−1
𝐾𝑝
⁄𝐾 = 1⁄24.6 = 0.0406
𝑐

𝑐) 𝑁𝑂2 + 𝑆𝑂2 ↔ 𝑆𝑂3 + 𝑁𝑂

 [𝑆𝑂3 ][𝑁𝑂]
𝐾𝑝 = = 1
[𝑁𝑂2 ][𝑆𝑂2 ]

𝐾𝑝 = 𝐾𝑐 (𝑅𝑇)∆𝑛𝑔

𝐾𝑝 1
𝐾𝑐 = = =1
(𝑅𝑇)0 (0.082)(300)0
𝐾𝑝
⁄𝐾 = 1
𝑐

𝑑) 3𝑂2 ↔ 2𝑂3

[𝑂3 ]2
𝐾𝑝 = = 1
[𝑂2 ]3

𝐾𝑝 = 𝐾𝑐 (𝑅𝑇)∆𝑛𝑔

𝐾𝑝 1
𝐾𝑐 = = = 24.6
(𝑅𝑇)−1 (0.082)(300)−1
𝐾𝑝
⁄𝐾 = 0.0406
𝑐