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Dehydration Unit Y{]M|uYÁµÂu¹mÄ¿YÂ»

Ê»Ã{Z¨fYÊa{Êa½ÂfÁ{YÃ|»Md{Ä]ÉZÅZ³Â¸z»½Á{{{ÂmÂ»[M[~mÂÀ»Ä]Ä¸u»¾ËY{
ÁÃ|[~m\Ì¯e½Á{{ {ÂmÂ»[MÄ¼ÅTEGµÂ°ËÔ³¾¸ÌeYÉe[}Zm®¼¯Ä]µÁY½Âf{Ä¯ºÌËZ¼¿
{ÂÊ»Ã{Y{d³]À¯YÁÂf¯Yd¼Ä]ÁÃ|Y|mµÂ°ËÔ³Y[M¹Á{½Âf{b
|Z]Ê»ÄmÂe¶]Z«Äf°¿Á{z]¾ËY{
|ÀZ]Ê»µÂ¸v»Ì£µÂ°ËÔ³{{YÂ»ËZÁ{ÂÊ»[~mµÂ°ËÔ³Âe[MZÆÀe,[~mk]{
ºfÌY[MZ]Â¸z»cÂÄ]Ê/§»µÂ°ËÔ³Y¹³Â¸Ì¯ ½YÌ»Ä]dZÅ{Ä¯Zn¿MY
1
|ËZ¼¿Ê»½Y^mY{Â^¼¯Y|¬»¾ËY, µÂ°ËÔ³Ê°¼¯½ZËm®Ë,{ÂÊ»kZy

Heavies Removal Column¹Âk]µÂu¹mÄ¿YÂ»

-|ËMÊ»d{Ä]|ÌY®Ì¿ÂÌaÁa YÂyÄÌ·ÁYÊ·ZyZ¿ÉZY|mZ],|ÀËM§Ê¸YµÂv»,k]¾ËY{
kZyk/]ÉÓZ]YcZfY¶Ìf»ÃY¼ÅÄ] Ê^Ë¬e Â¸yZ]Ê¸YµÂv»Ák]¾ÌËZaY|ÌY®Ì¿ÂÌaÁa
{ÂÊ»
1 Glycol Rectifying Stream

¶°{Ã|ÉY~³d»ÔÉZÅ½ZËmcZ^Ì¯eÃ|ÀÀ¯z»-ZÅÃ{Y{µÁ|m
Data base for process
Stream 1 :
component Mole flow (Kmol/h)
CO 1000
Stream 2 :
CH3OH 900
CH4 50
Propionic Acid 50
Stream 3 :
Methyl Iodide 850
H2O 10
Stream 4 :
Catalyst 850
Stream 5 :
Acetic Acid 841.5
Methyl acetate 8.5
CO 10
CO2 20
H2O 10
CH4 10
CH3OH 10
H2 20
Propionic Acid 50
Methyl Iodide 850
Catalyst 850
Stream 6 :
CO 40
CO2 80
CH4 40
H2 80
CH3OH 40
Stream 7 :
Catalyst 637.5
Stream 8 :
Acetic Acid 841.5
Methyl acetate 8.5
CO 10
CO2 20
H2O 10
CH4 10
CH3OH 10
H2 20
Propionic Acid 50
Methyl Iodide 850
Catalyst 212.5
Stream 9 :
Catalyst 212.5
Stream 10 :
Acetic Acid 841.5
Methyl acetate 8.5
Propionic Acid 50
H2O 10
Stream 11 :
CO 10
CO2 20
H2 20
CH4 10
CH3OH 10
Stream 12 :
Methyl Iodide 850
Stream 13 :
H2O 10
Stream 14 :
Acetic Acid 841.5
Methyl acetate 8.5
Propionic Acid 50
Stream 15 :
Propionic Acid 50
Stream 16 :
Acetic Acid 841.5
Methyl acetate 8.5

Energy Balance

Ã|¹Zn¿YÉ¿YÄ¿YÂ»{cZÌ§
dY|»ZmdÌ·ZeZ¯dYÃ|¿¥À¯YÁ{Ã{Z¨fY{Â»dÌ·ZeZ¯Êb·Zf¿MY ϭ
dYÃ|Äf§³¿{ϭ͘ϱ]Y]ZÅk]ÄÌ¸¯Êf³Z]d^¿½YÌ» Ϯ
|ÀÀ¯Ê»Z¯d]ZiZ§{ZÅk] ϯ

dYÃ|Ã{Z¨fYHYSYSY§Y¹¿Y|ÀËM§{{ÂmÂ»ÉZÅ½ZËmÉZÅÊb·Zf¿MÄ^Zv»ÉY]¯~e
‫݆ܭ‬ൗ
߂‫ ܪ‬଴ ൌ െͳǤʹͶ ൈ ͳͲହ ‫݈݋݉ܭ‬
‫݆ܭ‬ൗ
݄ଵ ൌ െͳǤͳ ሺ൅ͷሻ ‫݈݋݉ܭ‬
‫݆ܭ‬ൗ
݄ଶ ൌ െʹǤͶͶ ሺ൅ͷሻ ‫݈݋݉ܭ‬
‫݆ܭ‬ൗ
݄ଷ ൌ െͲǤͶ͸ ሺ൅ͷሻ ‫݈݋݉ܭ‬
‫݆ܭ‬ൗ
݄ହ ൌ െʹǤ͵ ሺ൅ͷሻ ‫݈݋݉ܭ‬
‫݆ܭ‬ൗ
݄଺ ൌ െͳǤ͸͵ ሺ൅ͷሻ ‫݈݋݉ܭ‬
Âf¯YÄ]ÊmÁyÁÉ{ÁÁÉZÅ½ZËmµÂuÉ¿YÄ¿YÂ»

ο‫ ܪ‬଴ െͳǤʹͶ ൈ ͳͲହ ‫݆ܭ‬

ο݄ ൌ ݄௢௨௧ െ ݄௜௡ ൅ ൌ ͹ ൈ ͳͲଷ ൅ ൌ െͳǤͳ͹ ൈ ͳͲହ ൗ‫݈݋݉ܭ‬
ߛ ͳ
|Z]Ê»Ì³Z»³À¯YÁ®Ë,Âf¯Y¶yY{{Ã|¹Zn¿YÀ¯YÁÄ¯{ÂÊ»ÄnÌf¿,Ã|Ä^Zv»Êb·Zf¿MÄ]ÄmÂeZ]
µÁYk]µÂuÉ¿YÄ¿YÂ»
ࡴࢋࢇ࢜࢏ࢋ࢙ࡾࢋ࢓࢕࢜ࢇ࢒࡯࢕࢒࢛࢓࢔
‫݆ܭ‬ൗ
଼݄ ൌ െʹǤ͵ͷ ሺ൅ͷሻ ‫݈݋݉ܭ‬
‫݆ܭ‬ൗ
݄ଵ଴ ൌ െͶǤͷ͵ ሺ൅ͷሻ ‫݈݋݉ܭ‬
‫݆ܭ‬ൗ
݄ଵଵ ൌ െͳǤ͹Ͷ ሺ൅ͷሻ ‫݈݋݉ܭ‬
‫݆ܭ‬ൗ
݄ଵଶ ൌ ൅ͲǤͳ͹ͷ ሺ൅ͷሻ ‫݈݋݉ܭ‬
-----------------------------------------------------------
ܳୡ ൌ ሺ ൅ ͳሻ ൈ ‫ ܦ‬ൈ ο‫ ܪ‬௩௔௣
‫݆ܭ‬ൗ
ο‫ ܪ‬௩௔௣ ൌ ʹ͸Ͳ͹ͺ ‫݈݋݉ܭ‬
ܴ ൌ ͳǤͷ
‫݆ܭ‬ൗ
‫ ܦ‬ൌ ͺͷͲ ݄ ሺ‫ܪܥ‬ଷ ‫ܫ‬ሻ
‫݆ܭ‬ൗ
ܳୡ ൌ ͷǤͷͶ ሺ൅͹ሻ ݄
------------------------------------------------------------
ܳோ ൌ ܳ஼ ൅ ݄ଵ଴ ൅ ݄ଵଵ ൅ ݄ଵଶ െ ଼݄
‫݆ܭ‬ൗ
ܳோ ൌ ͷǤͷ ሺ൅͹ሻ ݄
Ê/ËY{]M|uYÁµÂuÉ¿YÄ¿YÂ»
ࡰࢋࢎ࢟ࢊ࢘ࢇ࢚࢏࢕࢔ࢁ࢔࢏࢚

¹Zn¿YYÊ°ËÌ§[~m¶¼®ËZÆÀe[~mk]dYÄf§ZË¶Ì°eÉZ½ZËÁ[~mk]Á{Y|uYÁ¾ËY
ÉY] Z»Y - {Ë~a Ê» cÂ cYu µZ¬f¿Y ½Á|] Ì¿ ½M Ê°ËÌ§ [~m ¶¼ Á {Y|¿ ¸ËÂ^Ë Á Â¿Y|À¯ Á |Å|Ì»
Ä¯ºÌÀ¯Ê»Ã{Z¨fY¸ËÂ^ËÁÂ¿Y|À¯ÃY¼ÅÄ]Y{ÊÀÌk]®ËYZ½ZËk]{[MYµÂ°ËÔ³ÉZY|m
|Z]Ê»ËY«Ä]k]¾ËYµÂuÉ¿YÄ¿YÂ»
‫݆ܭ‬ൗ
݄୵ୟ୲ୣ୰ୖୣୟୡ୦ୋ୪୷ୡ୭୪ ൌ െ͹Ǥ͵͸ ሺ൅ͷሻ ‫݈݋݉ܭ‬
‫݆ܭ‬ൗ
݄ଵଷ ൌ െ͵Ǥʹ ሺ൅ͷሻ ‫݈݋݉ܭ‬
‫݆ܭ‬ൗ
݄୘୉ୋୖୣୡ୷ୡ୪ୣ ൌ െ͹ǤͲͻ ሺ൅ͷሻ ‫݈݋݉ܭ‬
ܳୡ ൌ ሺ ൅ ͳሻ ൈ ‫ ܦ‬ൈ ο‫ ܪ‬௩௔௣
‫݆ܭ‬ൗ
ο‫ ܪ‬௩௔௣ ൌ ͳǤͲͻ ሺ൅ͷሻ ‫݈݋݉ܭ‬
ܴ ൌ ͳǤͷ
‫ ܦ‬ൌ ͳʹǤͷ ‫݈݋݉ܭ‬ൗ݄
‫݆ܭ‬ൗ
ܳୡ ؆ ͵ͶǤͲ͸ ሺ൅ͷሻ ݄
--------------------------------------------------------------
ܳோ ൌ ܳ஼ ൅ ݄୘୉ୋୖୣୡ୷ୡ୪ୣ ൅ ݄ଵଷ െ ݄୵ୟ୲ୣ୰ୖୣୟୡ୦ୋ୪୷ୡ୭୪
‫݆ܭ‬ൗ
ܳோ ൌ ͵ͳǤͳ͵ ሺ൅ͷሻ ݄
¹Âk]µÂuÉ¿YÄ¿YÂ»
‫݆ܭ‬ൗ
݄ଵସ ൌ െͶǤͷͷ ሺ൅ͷሻ ‫݈݋݉ܭ‬
‫݆ܭ‬ൗ
݄ଵହ ൌ െͶǤͺʹ͹ ሺ൅ͷሻ ‫݈݋݉ܭ‬
‫݆ܭ‬ൗ
݄ଵ଺ ൌ െͶǤͷ͵ ሺ൅ͷሻ ‫݈݋݉ܭ‬
ܳୡ ൌ ሺ ൅ ͳሻ ൈ ‫ ܦ‬ൈ ο‫ ܪ‬௩௔௣
‫݆ܭ‬ൗ
ο‫ ܪ‬௩௔௣ ൌ ʹʹͲͷ͹ ‫݈݋݉ܭ‬
ܴ ൌ ͳǤͷ
‫݆ܭ‬ൗ
‫ ܦ‬ൌ ͺͷͲ ݄ ሺ‫݀݅ܿܣܿ݅ݐ݁ܿܣ‬Ƭ‫ ܯ‬െ ‫݁ݐܽݐ݁ܿܣ‬ሻ
‫݆ܭ‬ൗ
ܳୡ ൌ ͶǤ͸ͻ ሺ൅͹ሻ ݄
--------------------------------------------------------------
ܳோ ൌ ܳ஼ ൅ ݄ଵ଺ ൅ ݄ଵହ െ ݄ଵସ
‫݆ܭ‬ൗ
ܳோ ൌ ͶǤ͸Ͷ ሺ൅͹ሻ ݄
Cooler :
ºÌ¿Z]૝૙ԨÉZ»{Ä]Y|ÀËM§Ê/ËZÆ¿µÂv»Ä¯ºËY{¿{
ܳ஼௢௢௟௘௥ ൌ ݊Ǥ ‫ܥ‬௉ Ǥοܶ
‫݆ܭ‬ൗ
‫ܥ‬௉ ൌ ͶͲ ‫݈݋݉ܭ‬Ǥ ‫ܭ‬
݊ ൌ ͺͷͲ ‫݈݋݉ܭ‬ൗ݄
οܶ ൌ ሺͶͲ െ ͳͲͲሻ ൌ െ͸Ͳ‫ܭ‬
‫݆ܭ‬ൗ
ܳ஼௢௢௟௘௥ ൌ െʹǤͲͶ ሺ൅͸ሻ ݄
Âf¯YÊuY
Reactor Design

cZÔYbÁÃ{Â¼¿Ã|ÅZ»YHysysÉZÄÌ^Y§Y¹¿Ä¸ÌÁÄ]Ã|¹Zn¿YÊuYYÊ¸¯ÉZ¼®ËY|f]Y 
||ÅYÂyk{½M¶Ë}{½MYÃ|kYzfY
dyY{YaºÌÅYÂyÂf¯YÊWmÉZÅf»ZaÄ^Zv»Ä]É| ]Ä¸u»{ 
dYÃ|Ã{ZnÀ³Z¯É{Zf«Y{ÁM]ºÅyM{ 
|Z]Ê»Ë\ÌeeÄ]Y§Y¹¿Ìv»{Z¯¹Zn¿Y¶uY» 

General Information about this reactor:
ÃaÄ]Â]»cZ^Zv»
|Z]Ê»Ä¤ÌeZ]ÃY¼ÅÊ°Ë{¾Ì]ÂeÂ¿YÃa
ࡾࢋࢇࢉ࢚࢕࢘ࢂ࢕࢒࢛࢓ࢋ ൌ ૚૙࢓૜
ࡰ ൌ ૛Ǥ ૙૚૞࢓®¿Ze«
ࡴ ൌ ૜Ǥ ૙૛૜࢓®¿ZeZëY
ࡿ࢚ࢇ࢔ࢊࢇ࢘ࢊࢀ࢛࢘࢈࢏࢔ࢋ ‫׷‬
Ãa«
૚
۲ࢇ ൌ ൈ ۲ ൌ ૙Ǥ ૟ૠ࢓
૜
½z»¦¯YÃaÄ¸Z§
૚
ࡱ ൌ ൈ ࡰ ൌ ૙Ǥ ૟ૠ࢓
૜
Ä¤ÌeµÂ
૚
ࡸ ൌ ൈ ࡰࢇ ൌ ૙Ǥ ૞࢓
૝
Ä¤Ìe
૚
ࢃ ൌ ൈ ࡰࢇ ൌ ૙Ǥ ૝࢓
૞
ࡼ࢘࢕࢖ࢋ࢚࢘࢏ࢋ࢙࢏࢔࢚ࢇ࢔࢑ ‫׷‬
ࡷࢍ
࣋ ൌ ૞૞૛ ൗ ૜
࢓
ࣆ ൌ ૙Ǥ ૙૙૙૚૛ࡼࢇǤ ࢙
࡭࢙࢙࢛࢓ࢋ ‫ ࡺ ׷‬ൌ ૚૜૙࢘࢖࢓࢏࢙ࢋ࢔࢕࢛ࢍࢎࢌ࢕࢚࢘ࢎ࢏࢙࢘ࢋࢇࢉ࢚࢏࢕࢔
ࡺ ൌ ૛Ǥ ૚ૠ࢘࢖࢙
ࡰࢇǤ ࡺǤ ࣋
ࡾࢋ ൌ ൌ ૝Ǥ ૞ ൈ ૚૙૞
ࣆ
We have:
{ from Reference 1 , Chapter 9 & Fig 9-13 }
ࡺ࢖ ൌ ૟ Power Number
ࡼ ൌ ࡺ࢖ ൈ ࣋ ൈ ࡰ૞ࢇ ൈ ࡺ૜ ൌ ૝Ǥ ૞ૠࡷ࢝
ࣁ ൌ ૞૙Ψ
ࡼ࢕࢝ࢋ࢘࢕ࢌ࢓࢕࢚࢕࢘ ‫ૢ ׷‬Ǥ ૚૝ࡷ࢝
Âf¯Y½{¯®ÀyÉY]ZÌ¿{Â»[MÄ]Â]»cZ^Zv»
ࡲ࢘࢕࢓ࡴ࢙࢙࢟࢟࢝ࢋࢎࢇ࢜ࢋǣ
ࡽ ൌ ૚Ǥ ૛૝ ൈ ૚૙૞ ࡷ࢝
࡭࢙࢙࢛࢓ࢋ ‫׷‬
ࡲ࢕࢘࢝ࢇ࢚ࢋ࢘ǣࢀ࢏࢔ ൌ ૛૙Ǐ࡯Ƭࢀ࢕࢛࢚ ൌ ૛૞Ǐ࡯
ࡽ ൌ ࢓ ൈ ࡯࢖ ൈ ࢤࢀ ՜ ૚૛૝૙૙૙ࡷ࢝ ൌ ࢓ ൈ ૝Ǥ ૛ ൈ ૞
ࡷࢍൗ ࡷࢍ
࢓ ൌ ૞ૢ૙૙ ࢎ ൌ ૚૝૚૟૙૙ ൗࡰࢇ࢟

Âf¯YÄ]Â]»É{Zf«Y{ÁM]
Ã|kYzfYÉZÅÃ{Y{
{ form Reference 2 , Chapter 6 }
Cost of Equipment & water in 1990 :
Jacketed stirred tank Reactor :
Volume : 1300 gal = 4.9 m3
Cost : 58400 $
Pump (centrifugal) for pumping cooling water to jacket of reactor:
Material: carbon steel
Size: 45 gpm (up to 150 psi)
Cost: 1600 $
Water :
Cost of Cooling water = 10 $ / 1000gal
year Marshal Index

1990 904
2009 1585 (assume 3% average Inflation)
Cost of Equipment & water in 2009 :
Stirred tank Reactor:
Volume: 10 m3
૚૙ ૙Ǥ૞૝ ૚૞ૡ૞
ࡼ࢘ࢋ࢙ࢋ࢔࢚࡯࢕࢙࢚ ൌ ૞ૡ૝૙૙ ൈ ሺ ሻ ൈሺ ሻ ൌ ૚૞૙૞૙૙̈́
૝Ǥ ૢ ૢ૙૝
Pump :
૚૞ૡ૞
ࡼ࢘ࢋ࢙ࢋ࢔࢚࡯࢕࢙࢚ ൌ ૚૟૙૙ ൈ ሺ ሻ ൌ ૛ૡ૙૙̈́
ૢ૙૝
Cooling water :
૚૞ૡ૞ ̈́
ࡼ࢘ࢋ࢙ࢋ࢔࢚࡯࢕࢙࢚ ൌ ૚૙ ൈ ൬ ൰ ൌ ૚ૡ
ૢ૙૝ ૚૙૙૙ࢍࢇ࢒
Cost of Purchased equipment: 150500 + 2800 = 153300 $
Items proportion Cost ($)

Direct Costs ( D )
Purchased equipment (E) E 153300
Purchased-equipment installation 0.47 E 72000
Instrumentation and controls 0.18 E 27600
Piping (installed) 0.66 E 101200
Electrical (installed) 0.11 E 16900
Buildings (including services) 0.18 E 72000
Yard improvements 0.1 E 15300
Service facilities (installed) 0.7 E 107300
Indirect Costs ( I )
Engineering and supervision 0.33 E 50600
Construction expenses 0.41 E 62800
D+I 679000
Contractor’s fee 0.05 (D+I) 33900
Contingency 0.42 (D+I) 258200
Fixed-capital investment 998100
Working capital 0.15 T.C.I 176100
Total capital investment F.C.I /0.85 1174200
Ê§»Ã|ÀÀ¯®Ày[MÄ¿YÁÄÀËÅ

ࡷࢍൗ ࡷࢍ
࢓ ൌ ૞ૢ૙૙ ࢎ ൌ ૚૝૚૟૙૙ ൗࢊࢇ࢟
ࡷࢍ
࣋࢝ࢇ࢚ࢋ࢘ ൌ ૚૙૙૙ ൗ ૜
࢓
૚૝૚૟૙૙ ࢍࢇ࢒
ࢂ ቀÊ§»[MÊ¼nuÊ]{ቁ ൌ ൌ ૚૝૚Ǥ ૟ ࢓૜ൗࢊࢇ࢟ ൌ ૜ૠ૝૙ૠ ൗࢊࢇ࢟
૚૙૙૙
̈́
࡯࢕࢙࢚࢕ࢌࢉ࢕࢕࢒࢏࢔ࢍ࢝ࢇ࢚ࢋ࢘ ൌ ૜ૠ૝૙ૠࢍࢇ࢒ ൈ ૚ૡ ൌ ૟ૠ૜̈́
૚૙૙૙ࢍࢇ࢒

ÊËY{[M|uYÁ[~mk]ÊuY
Dehydration Unit Design

Z½ZËk]®ËÁÃ|ÀÀ¯[~mk]®ËYÊËZ¼¿

{Zz]ÁËZ»¾Ì]¹mµZ¬f¿YÌ¬e|ÀËM§{|ÀZ]Ê»Ì¬e|ÀËM§Ä]Z»ÉZ½ZËÁ[~mÉZÅ|ÀËM§
Å{ËZ»Z§ÁZ³Z§®Ë¾Ì]¹mµZ¬f¿Y,ÉZ½ZËÁ[~m{{ÂÊ»¹Zn¿Y½Âf¶yY{{Ä¸u»Å
Y,{Â[~mdYY«Ä¯ÊWmZË,Ã|¶uÃ{Z»,[~m|ÀËM§{{Ë~aÊ»cÂ½ÂfZe{Ä¸u»
wZ³Z§Ä]ËZ»Z§YµZ¬f¿YÊÀ Ë-dY©{Z½M°,ÉZ½ZË{Z»Y{ÂÊ»¶¬fÀ»ËZ»Z§Ä]Z³Z§
|Å{Ê»
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dYÃ|»MËµÁ|m

Surface Void
Diameter×Height×Thichness
Number Area Fraction
Type Size
/ m3
(mm)
(m2/m3) %
16 16 × 16 × 0.4 235000 371 0.933
25 25 × 25 × 0.5 53000 267 0.940
Pall
38 38 × 38 × 0.6 14800 129 0.946
Ring
50 50 × 50 × 0.8 6500 112 0.950
76 76 × 76 × 1.0 1930 72 0.961

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οܲ ൌ ͳͲͲͲ ܲܽൗ݉ ൌ ͲǤͲͳ ܽ‫݉ݐ‬ൗ݉
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‫ܮ‬Ǥ ‫ܯ‬௅ ߩ௏ ଴Ǥହ

൬ ൰൤ ൨ ൌ ͳǤʹ ൈ ͳͲିଶ
ܸǤ ‫ܯ‬௏ ߩ௅ െ ߩ௏
‫ ܩ‬ଶ Ǥ ‫ܨ‬௣ Ǥߤ௅଴Ǥଵ

ൌ ͲǤͷͷ͹
ߩ௏ ሺߩ௅ െ ߩ௏ ሻ
‫݃ܭ‬ൗ
‫ ܩ‬ൌ ͸ǤͶ ݉ଶ Ǥ ‫ݏ‬
‫ܣ‬௖ ൌ ʹǤͶ݉ଶ
ࡰ ൌ ૚Ǥ ૠ૞࢓

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ࡴࢋࢇ࢜࢟ࡾࢋ࢓࢕࢜ࢇ࢒ࢉ࢕࢒࢛࢓࢔ࡰࢋ࢙࢏ࢍ࢔
: ½YÂf¿MÄ]Y
Antoine Equation is used To determine the Vapor Pressure of the Components as Shown
Below :
࡮
ࡸ࢕ࢍࡼ‫ כ‬ൌ ࡭Ȃ൤ ൨ǡ ࡼ‫ כ‬ሺ࢓࢓ࡴࢍሻǡ ࢀሺǑ࡯ሻ
ࢀ൅࡯
࡭ǡ ࡮ǡ ࡯ ൌ ࡯࢕࢔࢙࢚ࢇ࢔࢚࢙࢕ࢌ࡭࢔࢚࢕࢏࢔ࢋࡱ࢛ࢗࢇ࢚࢏࢕࢔
̷ࡼ ൌ ૚ࢇ࢚࢓ǡ ࢀ ൌ ૚૚૙Ǒ࡯
ࡼ‫ כ‬ሺ࡭ࢉࢋ࢚࢏ࢉ࡭ࢉ࢏ࢊሻ ൌ ૞ૠ૛Ǥ ૠૠ࢓࢓ࡴࢍ
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ࡼ‫ כ‬ሺࡼ࢘࢕࢖࢏࢕࢔࢏ࢉ࡭ࢉ࢏ࢊሻ ൌ ૠ૟ૠǤ ૛࢓࢓ࡴࢍ

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ࡷ࢜ࢇ࢒࢛ࢋ ሺࡹࢋ࢚ࢎ࢟࢒࡭ࢉࢋ࢚ࢇ࢚ࢋሻ ൌ ૞
ࡷ࢜ࢇ࢒࢛ࢋ ሺࡼ࢘࢕࢖࢏࢕࢔࢏ࢉ࡭ࢉ࢏ࢊሻ ൌ ૚
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࡯࢕࢒࢛࢓࢔ࡰ࢏ࢇ࢓ࢋ࢚ࢋ࢘ െ ࢀ࢘ࢇ࢟
ࢀ࢘ࢇ࢚࢟࢟࢖ࢋ ‫ࢋ࢜ࢋ࢏ࡿ ׷‬
࡭૙
૙Ǥ ૚ ൏ ൏ͳ
࡭ࢇ
࢖࢏࢚ࢉࢎ ൌ ૚૚Ǥ ૛૞࢓࢓
ࢀ࢘ࢇ࢙࢟࢖ࢇࢉ࢏࢔ࢍ ‫׷‬
࢚ ൌ ૙Ǥ ૞࢓
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ࢻ ൌ ૙Ǥ ૙ૠ૝૝࢚ ൅ ૙Ǥ ૙૙૚૚ૠ૜
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૚ ࣌ ૙Ǥ૛
࡯ࡲ ൌ ൦ࢻǤ ࢒࢕ࢍ ൅ ࢼ൪ ൈ ቂ ቃ
ࡸ ࣋ ૛૙
ቀࡳቁ ቀ ࣋ࡳ ቁ
ࡸ
ࢻ ൌ ૙Ǥ ૙૞૟૜ૠࢼ ൌ ૙Ǥ ૙૜૜૛૝
ࡷࢍ ࡷࢍ
࣋ࡸ ൌ ૚૙૟૝Ǥ ૟ ൗ ૜ ࣋ࡳ ൌ ૚૙૞ૢ ൗ ૜
࢓ ࢓
ࡸ ൌ ૟૙૙Ǥ ૠ ࡷ࢓࢕࢒ൗࢎ ࡳ ൌ ૜૙ૢǤ ૜ ࡷ࢓࢕࢒ൗࢎ
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ࢂ࢔ ൌ ૙Ǥ ૠ૞ ൈ ࢂࡲ ൌ ૚Ǥ ૜࢓Ȁ࢙
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ࡹࢉ࡯ࢇ࢈ࢋࡹࢋ࢚ࢎ࢕ࢊ
ࡺ࢛࢓࢈ࢋ࢘࢕ࢌࢀࢎ࢕࢘ࢋ࢚࢏ࢉࢇ࢒ࢀ࢘ࢇ࢙࢟ ൌ ૚ૢǤ ૟
࡯࢕࢒࢛࢓࢔ࡱࢌࢌ࢏ࢉ࢏ࢋ࢔ࢉ࢟ ൌ ૙Ǥ ૟
ࡺ࢛࢓࢈ࢋ࢘࢕ࢌࢀࢎ࢕࢘ࢋ࢚࢏ࢉࢇ࢒ࢀ࢘ࢇ࢙࢟ ૚ૢǤ ૟
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Acetic Acid

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Acetic Acid

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࡯ࡴ૜ ࡻࡴ ൅ ࡴࡵ ՜ ࡯ࡴ૜ ࡵ ൅ ࡴ૛ ࡻ

࡯ࡴ૜ ࡵ ൅ ࡯ࡻ ՜ ࡯ࡴ૜ ࡯ࡻࡵ

࡯ࡴ૜ ࡯ࡻࡵ ൅ ࡴ૛ ࡻ ՜ ࡯ࡴ૜ ࡯ࡻࡻࡴ ൅ ࡴࡵ

 Dehydration Unit Y{]M|uYÁµÂu¹mÄ¿YÂ»

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Heavies Removal Column¹Âk]µÂu¹mÄ¿YÂ»

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1 Glycol Rectifying Stream

Data base for process

ο‫ ܪ‬଴ െͳǤʹͶ ൈ ͳͲହ ‫݆ܭ‬

ܳୡ ൌ ሺ ൅ ͳሻ ൈ ‫ ܦ‬ൈ ο‫ ܪ‬௩௔௣

ܳோ ൌ ܳ஼ ൅ ݄ଵ଴ ൅ ݄ଵଵ ൅ ݄ଵଶ െ ଼݄

ܳୡ ൌ ሺ ൅ ͳሻ ൈ ‫ ܦ‬ൈ ο‫ ܪ‬௩௔௣

‫ ܦ‬ൌ ͳʹǤͷ ‫݈݋݉ܭ‬ൗ݄

ܳோ ൌ ܳ஼ ൅ ݄୘୉ୋୖୣୡ୷ୡ୪ୣ ൅ ݄ଵଷ െ ݄୵ୟ୲ୣ୰ୖୣୟୡ୦ୋ୪୷ୡ୭୪

ܳୡ ൌ ሺ ൅ ͳሻ ൈ ‫ ܦ‬ൈ ο‫ ܪ‬௩௔௣

ܳோ ൌ ܳ஼ ൅ ݄ଵ଺ ൅ ݄ଵହ െ ݄ଵସ

ܳ஼௢௢௟௘௥ ൌ ݊Ǥ ‫ܥ‬௉ Ǥοܶ

οܶ ൌ ሺͶͲ െ ͳͲͲሻ ൌ െ͸Ͳ‫ܭ‬

࡭࢙࢙࢛࢓ࢋ ‫ ࡺ ׷‬ൌ ૚૜૙࢘࢖࢓࢏࢙ࢋ࢔࢕࢛ࢍࢎࢌ࢕࢚࢘ࢎ࢏࢙࢘ࢋࢇࢉ࢚࢏࢕࢔

{ from Reference 1 , Chapter 9 & Fig 9-13 }

ࡺ࢖ ൌ ૟ Power Number

ࡼ ൌ ࡺ࢖ ൈ ࣋ ൈ ࡰ૞ࢇ ൈ ࡺ૜ ൌ ૝Ǥ ૞ૠࡷ࢝

ࡼ࢕࢝ࢋ࢘࢕ࢌ࢓࢕࢚࢕࢘ ‫ૢ ׷‬Ǥ ૚૝ࡷ࢝

ࡽ ൌ ૚Ǥ ૛૝ ൈ ૚૙૞ ࡷ࢝

ࡲ࢕࢘࢝ࢇ࢚ࢋ࢘ǣࢀ࢏࢔ ൌ ૛૙Ǐ࡯Ƭࢀ࢕࢛࢚ ൌ ૛૞Ǐ࡯

ࡽ ൌ ࢓ ൈ ࡯࢖ ൈ ࢤࢀ ՜ ૚૛૝૙૙૙ࡷ࢝ ൌ ࢓ ൈ ૝Ǥ ૛ ൈ ૞

{ form Reference 2 , Chapter 6 }

Cost of Equipment & water in 1990 :

Jacketed stirred tank Reactor :

Volume : 1300 gal = 4.9 m3

Pump (centrifugal) for pumping cooling water to jacket of reactor:

Material: carbon steel

Size: 45 gpm (up to 150 psi)

Cost of Cooling water = 10 $ / 1000gal

year Marshal Index

Cost of Equipment & water in 2009 :

Stirred tank Reactor:

Items proportion Cost ($)

Dehydration Unit Design

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16 16 × 16 × 0.4 235000 371 0.933

25 25 × 25 × 0.5 53000 267 0.940

50 50 × 50 × 0.8 6500 112 0.950

76 76 × 76 × 1.0 1930 72 0.961

ܸ ൌ ͻͳͲ ‫݈݋݉ܭ‬ൗ݄ ൌ ͲǤʹͷ͵ ‫݈݋݉ܭ‬ൗ‫ݏ‬

‫ ܮ‬ൌ ͳͲͲ ‫݈݋݉ܭ‬ൗ݄ ൌ ͲǤͲʹ͹ ‫݈݋݉ܭ‬ൗ‫ݏ‬

ߤ௅ ൌ ͲǤʹͶܿܲ ൌ ʹǤͶ ൈ ͳͲିସ ܲܽǤ ‫ݏ‬

οܲ ൌ ͳͲͲͲ ܲܽൗ݉ ൌ ͲǤͲͳ ܽ‫݉ݐ‬ൗ݉

‫ܮ‬Ǥ ‫ܯ‬௅ ߩ௏ ଴Ǥହ

‫ ܩ‬ଶ Ǥ ‫ܨ‬௣ Ǥߤ௅଴Ǥଵ

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|ÌY®ÌfYÄrzËZe

ZË|¿M, ºÅ{¿Z½«{ |Ê»ÄÌÆeÉ¸§ÉZÅ

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Y|{ ZÆÀeÊËZËf¯Z]ÁÃÁ»Y {ÂÊ»|Ì·Âe,

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Dehydration Unit Y{]M|uYÁµÂu¹mÄ¿YÂ»

ºfÌY[MZ]Â¸z»cÂÄ]Ê/§»µÂ°ËÔ³Y¹³Â¸Ì¯ ½YÌ»Ä]dZÅ{Ä¯Zn¿MY

Heavies Removal Column¹Âk]µÂu¹mÄ¿YÂ»

-|ËMÊ»d{Ä]|ÌY®Ì¿ÂÌaÁa YÂyÄÌ·ÁYÊ·ZyZ¿ÉZY|mZ],|ÀËM§Ê¸YµÂv»,k]¾ËY{

kZyk/]ÉÓZ]YcZfY¶Ìf»ÃY¼ÅÄ] Ê^Ë¬e Â¸yZ]Ê¸YµÂv»Ák]¾ÌËZaY|ÌY®Ì¿ÂÌaÁa

ܳୡ ൌ ሺ ൅ ͳሻ ൈ ‫ ܦ‬ൈ ο‫ ܪ‬௩௔௣

ܳୡ ൌ ሺ ൅ ͳሻ ൈ ‫ ܦ‬ൈ ο‫ ܪ‬௩௔௣

ܳୡ ൌ ሺ ൅ ͳሻ ൈ ‫ ܦ‬ൈ ο‫ ܪ‬௩௔௣

Ä]ÉZÌ¿Ä¯cÁZ¨e¾ËYZ] dYÌ¬ecYÌÆne Ä]ÄÌ^ZÌ]ÉZ½ZËÁ[~mÉY]Ã{Z¨fY{Â»cYÌÆne

¾ËY|ÀÀ¯Ê»Z¯Ìv»ÉZ»{Ä] ®Ë{¿ÉZ»{ÁÌv»Z§YeÓZ]ÉZ§{ZÅÃ|ÀÀ¯[~mfÌ]ÓÂ¼ »

Ϭ͘ϰZ^Ë¬e HETP ®ËÂXe|uYÁ®ËÉY]µ{Z »Z¨eY,f»Ê¸Ì» ϮϱµZaÊ°ÌfÔaÄ¬¸uÉZÅÄÀ¯MÉY]

ࢂk] ൌ ࢎ ൈ ࡭ ൌ ૚૞Ǥ ૟࢓૜

dyZÉÄÀËÅ{ÁM]ÉY]½Z´ËZf¯{Ä¼me,fÌa,Ä¿ZyZ¯{Zf«YÁs[Zf¯ ϭϲ± ϭϱ¶°®¼¯Ä]