komponen Tc,K Pc Omega R T (k) P Tr (T/Tc)

etilen 282.4 50.4 0.085 83.14 298 12 1.0552407932

van der waals Redlich/Kwong

27 R 2 TC
2 RT a (T )
RT a a 3 RTC P 
P  2 64 PC VC  V  b V ( V  b)
Vb V 1 RTC
8 PC a (T)
b b
8 PC
a 4614266.5527 PC VC 3 v Trial
b 58.2309920635 Vc 174.693 ZC   sisi kanan (P)
v trial 1929.6069201 z 0.375 R TC 8 12
sisi kanan (P) sisi kiri
12 12.0000394949

Peng-Robinson

(Tr , )  1  (0.37464  1.54226   0.26992 2 )  (1  Tr )
1/ 2
 2

RT a (T ) R 2 TC
2
R 2 TC
2
P  a (T)    (Tr , )   0.45724  (Tr , ) 
V  b V ( V  b) PC PC
RTC RT
alpa(Tr,ω) 1.2558187095 b  0.07779 C
PC PC
a(T) 6280439.7511
b 36.238310981
V Trial 182.34306976
sisi kanan (P) sisi kiri
12 11.999924996
gas ideal
pv=RT
P=RT/V
V trial 2064.6332747
sisi kiri sisi kanan
12 12.0000584626
 Pr (P/Pc)
0.2380952381

2 2
R 2TC 1 R 2 TC
RT a (T ) a (T)     (Tr )  0.42748  Tr 2 
 PC PC
V  b V ( V  b) RTC RTC
b  0.08664 saturated vapor
PC PC
4551545.656843
40.361065219 Vc
1915.121268607 Zc
sisi kiri saturated liquid Pr
12.0000368697   
Tr
3
ZRT cm
V  
beta 0.019549 P mol
q vdw 4.578651
q RK 4.639482
a PR 4.96247

Z VAN DER WALLS VAPOR z redlich kwon

Z Kiri z kanan z kiri z kanan
0.9345957672 0.927703 0.92758 0.925808