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FACTSHEET

TASTE AND ODOR

Environmental Contaminant Treatment

Taste and Odor -Causing Compounds in Drinking Water


The primary sources of taste and odor problems common name “blue-green algae” has remained. Man-Made Chemicals
in drinking water are algae and bacteria. However, Cyanobacteria are photosynthetic bacteria. In Man-made chemicals are another source of
other anthropogenic sources such as wastewater addition to the blue-green color of many inferred taste and odor-causing chemicals in drinking
discharges and chemical spills also act as sources by the name, other species can be red, brown, or water. For example, methyl tertiary butyl ether
of chemicals that cause off tastes and odors. yellow. Cyanobacteria are most commonly found (MTBE), a gasoline additive persistent in
Such chemicals can affect both groundwater and in eutrophic waters (waters with high levels of groundwater and recreational surface waters,
surface water. nutrients) and shallow reservoirs, and can occur has an odor threshold as low as 5 parts per
as surface scum, benthic (bottom) mats, and on billion. Dissolved in water, it smells oily and like
TYPES OF TASTE AND aquatic weeds (Hoehn, 2002). In the 1960’s turpentine. Industrial phenols can create odor
and 1970’s, it was discovered that cyanobacteria problems. Hydrocarbons and volatile organic
ODOR PROBLEMS produce geosmin and MIB as intracellular by- compounds such as fuels and solvents produce
products. As a bloom progresses, bacteria die, oily, paint-like, and medicinal odors.
There are four basic taste types: sour, sweet, salty
releasing these odorous chemicals into the water.
and bitter. There are also a variety of odor types
including earthy, musty, chemical, and chlorinous. ALGAE AND BACTERIA
Actinomycetes
The table on the reverse side lists several taste
Actinomycetes are spore-forming bacteria that
BLOOM PATTERNS
and odor types and their potential causes.
grow as branching filaments in water. Closely
A bloom occurs in a surface water body when
related to cyanobacteria, they have simple cells.
THE CAUSES OF TASTE AND light, temperature, and nutrient conditions are
Actinomycetes also live in soil. In fact, it is the
favorable for one type of algae or bacteria over
ODOR PROBLEMS geosmin-producing soil variety that causes soil to
another. This combination allows one organism to
smell “earthy.” Other species produce antibiotics.
become dominant. It is an ecological imbalance
Some species of algae and bacteria naturally Aquatic actinomycetes grow in aerobic mud, on
often triggered by pollution. Nitrates, organic
produce odorous chemicals inside their cells. decaying vegetation, and in the excrement
phosphorus and ammonia are discharged into the
Geosmin (trans-1, 10-dimethyl-trans-9-decalol) of zebra mussels. The bacteria help to degrade
water body from water treatment plants or are
and MIB (2-methylisoborneol) are common cellulose and other plant parts, and for this
carried in by watershed runoff (including runoff
odorous chemicals. The earthy and musty odors reason thrive as a result of an algae bloom
from pig and cattle feed lots and fertilizer from
generated by geosmin and MIB are detectable by (Hoehn, 2002). Actinomycetes, like cyanobacteria,
agricultural fields). The conditions favorable to
many people at concentrations of 5 to 10 parts produce geosmin and MIB.
blooms are seasonal. Spring and winter conditions
per trillion. When large numbers of algae and
favor golden brown algae and fishy, cucumber
bacteria flourish in a water body (an “algae bloom”), Other Algal and Natural Sources
odors. Summer and fall conditions favor geosmin
taste and odor-compound concentrations increase Green algae blooms in a reservoir can produce
and MIB-producing bacteria and earthy and musty
to levels above this threshold and cause taste a grassy or fishy odor. Golden-brown algae,
odors. Generally, the most common bloom month
and odor problems. particularly the species Synura, can produce a
is September.
cucumber, melon, or fishy odor. Biological activity
Cyanobacteria (Blue-Green Algae) in surface waters can produce 2,4-heptadienal
Cyanobacteria are known by several names, and decadienal, which have a fishy, rancid odor. MEASUREMENT AND
including “blue-green algae”, “blue greens”, In addition, dissolved metals such as zinc, REGULATION OF TASTE AND
and “cyanophyta”. To the biologist, they are not manganese, copper, and iron can produce a ODOR QUALITY
technically algae (a multi-celled plant), but metallic taste.
bacteria. This was not known until the advent There are several methods of taste and odor
of high-powered microscopes, however, the quality measurement and very few regulations.
TASTE OR ODOR SOURCE

FACTSHEET Earthy Geosmin


Musty MIB, isopropylmethoxypyrazine (IPMP), isobutylmethoxypyrazine (IBMP)
Turpentine, oily Methyl tertiary butyl ether (MTBE)
Fishy/rancid 2,4-Heptadienal, decandienal, octanal

The most frequently used measuring system is Chlorinous Chlorine


the Total Odor Number (TON), a method based Medicinal Chlorophenols, iodoform
on the persistence of an odor after dilution. Oily, gas-like, paint Hydrocarbons, volatile organic compounds (VOCs)
Other methods include Flavor Profile Analysis Metallic Iron, copper, zinc, manganese
and analytical measurement of chemical
Grassy Green algae
concentrations. Regulatory limits are few. The
United States Environmental Protection Agency
(USEPA) has issued a secondary maximum
concentration limit (MCL) limiting the TON to 3. larger utilities. Chlorine is widely used for the For over 30 years, Trojan has specialized in UV
Iron, manganese, copper, and zinc have USEPA oxidation of taste and odor-causing chemicals, applications for water treatment and wastewater
MCLs ranging from 0.5 to 5 parts per million. but itself can produce chlorinous odors and disinfection. Over 6,500 Trojan UV systems are
However, the primary regulator with respect to disinfection by-products such as THMs and HAAs. treating municipal wastewater in more than 80
taste and odor is the consumer. Ozonation is also used, but is expensive, complex countries around the world. Tens of thousands
to operate, and can form bromate, a harmful by- of industrial and residential Trojan UV treatment
ALGAL TOXINS product. However, UV-photolysis and UV-oxidation systems are in operation in industries and
using UV light and hydrogen peroxide is a cost- households worldwide. Now, Trojan offers the
In addition to producing chemicals that impact effective alternative for treating a wide variety of industry standard in Environmental Contaminant
the aesthetic quality of water, certain species taste and odor problems. MIB, geosmin, MTBE, Treatment (ECT). Trojan’s UV-photolysis and UV-
of cyanobacteria produce toxins (“cyanotoxins”) phenols, VOCs, and many others contaminants oxidation systems are capable of cost-effectively
that can cause harm to animals and humans. can be treated with UV-oxidation. This technology removing environmental contaminants from a
Toxic cyanobacteria are indistinguishable from requires the photolysis of hydrogen peroxide variety of water streams. With its optimized
non-toxic cyanobacteria under a microscope and with UV light to generate hydroxyl radicals. The technology, Trojan is the leader in ECT, offering
both types may be present in a bloom. Multiple hydroxyl radical is one of the most powerful the most cost effective, highest quality UV
classes of cyanotoxins exist, including microcystin, oxidizing agents known and reacts rapidly with solutions available.
cylindrospermopsin, and anatoxin-a. Cyanotoxins organic constituents in the water, including taste
can be present wherever blooms occur and as a and odor compounds, breaking them down into
result, several regulating agencies worldwide have their elemental, non-odorous components. Trojan’s
issued guidance regulations. Research in the U.S. UV-oxidation reactors provide a reliable barrier
and Canada has shown that a high percentage of to taste and odor compounds and do not form
raw water taken from water supplies undergoing bromate. In addition, the same UV system used
a cyanobacteria bloom contained cyanotoxins, for taste and odor control simultaneously performs
in addition to other taste and odor-causing disinfection. This reduces or eliminates the source
chemicals (Carmichael, 2001). In the U.S., the of unpleasant chlorinous odors resulting from the
USEPA has listed freshwater cyanobacteria and use of chlorine as a primary disinfectant.
their toxins on the Contaminant Candidate List.
In addition, New Zealand, Germany, and the World TREATING MULTIPLE
Health Organization (WHO) have established CONTAMINANTS WITH ONE
microcystin guidelines of 1.0 ppb, while Canada Cyanobacteria Bloom in Lake Manatee, Florida
has established a 1.5 ppb guideline.
UV SYSTEM (Photo courtesy of Bruce MacLeod)

As a further benefit to taste and odor control and


TREATMENT ALTERNATIVES – microbial disinfection, the Trojan UV system will References:
UV LIGHT A KEY disinfect Cryptosporidium and Giardia. The process Hoehn, R.C. 2002. Odor Production by Algae. Conference
will also treat many other dissolved organic Workshop Presentation: Understanding and Controlling
Many utilities use powdered activated carbon compounds present in the water, including the Taste and Odor of Drinking Water. AWWA Annual
endocrine disruptors, N-nitrosodimethylamine Conference, New Orleans. June 16, 2002.
(PAC) to treat taste and odor problems. However,
Carmichael, W. W. 2001. Assessment of Blue-Green
large doses of PAC are required to treat geosmin (NDMA), pesticides, and algal toxins. Algal Toxins in Raw and Finished Drinking Water. AWWA
and MIB, making it impractical, especially for Research Foundation, Denver. 179 pgs.

North America T. 519.457.3400 F. 519.457.3030 www.trojanuv.com


Europe (please contact our UK office) T. +44 (1905) 771117 F. +44 (1905) 772270

©Copyright 2010. Trojan Technologies, London, Ontario, Canada.


No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means
without the written permission of Trojan Technologies. ECT-1110

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