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Unit 2 Chemistry (ABE)

Exam 2012
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Multiple-Choice Answer Sheet

VCAA Number: ________________________________

Circle the correct answer.


If you make a mistake, cross out your answer clearly and circle the correct response.
There is one mark per question.
No marks will be deducted for incorrect answers.
No marks will be given if more than one answer is selected.

Question 1 A B C D

Question 2 A B C D

Question 3 A B C D

Question 4 A B C D

Question 5 A B C D

Question 6 A B C D

Question 7 A B C D

Question 8 A B C D

Question 9 A B C D

Question 10 A B C D

Question 11 A B C D

Question 12 A B C D

Question 13 A B C D

Question 14 A B C D

Question 15 A B C D

Question 16 A B C D

Question 17 A B C D

Question 18 A B C D

Question 19 A B C D

Question 20 A B C D
Unit 2 Chemistry (ABE)
Exam 2012
-----------------------------------------------------------------------------------------------------------------------------------------------------------------

Marking Sheet: 2013 Chemistry Unit 2 Exam

Name: ________________________________

Section / Question Available Marks Marks Attained

Multiple Choice 20

1 8

2 8

3 4

4 4

5 6

6 4

7 5

8 5

9 2

10 5

11 6

12 10

Total Marks Available: 87

Marks Attained:

Comments:
When a piece of metal, X, is placed into a solution of YCl2, the green colour of the solution fades and the
SECTION A: MULTIPLE-CHOICE
metal becomes QUESTIONS
coated in a dark-coloured deposit.
Which of the following conclusions is consistent with2for
Unit
Instructions the observations
Chemistry
Section (ABE)
A made?
2+ 2+ Exam 2012
A.Answer X all ions are moreinreadily
questions pencil reduced than Ysheet
on the answer ions
provided for multiple-choice questions.
-----------------------------------------------------------------------------------------------------------------------------------------------------------------
B.Choose metaltheYresponse
is more reactive than metal
that is correct X best answers the question.
or that
C. metal X is oxidised more readily than metal Y
A correct answer
– scores 1, an incorrect answer Multiplescores Choice
0. Section
D. the Cl ion is more readily oxidised than metal X
Marks will not be deducted for incorrect answers.
AllNoanswers
marks will MUST BEifMARKED
be given more than one on answer
the Answer Sheet.forAnswers
is completed any question.given in the question booklet WILL
Question
NOT BE MARKED.5
Which of the following conditions is most likely to produce photochemical smog?
Question
A. 11:
temperature
Question inversion, ozone, cool weather, hydrocarbons, nitrogen oxides
B. strong light, temperature
The pH of some household inversion,
liquids at 25°Chydrocarbons, nitrogen
is shown on the oxides, oxygen gas
scale below.
C. hot weather, ozone, nitrogen oxides, carbondistilled
dioxide gas, ultraviolet light
D. mild temperatures, still air, oxygen gas, nitrogen
watermonoxide gas, carbon monoxide gas
cola milk soap bleach

VCE Chemistry
Question 6 Unit0 2 Trial Examination Question and Answer Booklet
1 2 3 4 5 6 7 8 9 10 11 12 13 14
A sample of argon gas occupies 48 L at 15°C and 720 mmHg.
Which of the following statements concerning these liquids is incorrect?
If the sample is heated to 30°C and the8 volume
Questions dropstotothe
and 9 relate 24following
L, the newinformation.
pressure (in kPa) will be closest to
A. The hydrogen ion concentration in cola is 0.001 M.
A. 200 + –
B.
B. In
300the soapGassolution, > H 3 O @ Solubility
> OH @ . in water (mL of gas per 100 mL of water)
6
C. Milk
2000 is 10 times more acidic than 0 qCbleach. 20 qC 40 qC
+ –7
D. 3000
In distilled
Nitrogen water, > H 3 O @ is 10 2.4 M at any temperature.1.6 1.3
Oxygen 4.8 3.3 2.5
Question
Question 7 2:
Question 2Carbon dioxide 171 92.3 56.6
Which of the
Under which of following graphsconditions
the following does not represent the behaviour
of temperature of an do
and pressure ideal
realgas?
gases behave most like an
Sulfur dioxide 7980 4250 2170
Note:gas?
ideal V = volume (L); T = temperature (°C); p = pressure (atm); n = number of mole (mol)
A. high
p
temperature and low pressure B. p
B. high8temperature and high pressure
Question
C.
Whichlow temperature
of the followingand high
is not pressure conclusion concerning the data presented?
a reasonable
D.
A. low
Smalltemperature
non-polar and low pressure
molecules seem to have low solubility in water.
B. The solubility of gases in water decreases with increasing temperature.
Question
C. The3higher solubility of sulfur dioxide is due only to its higher molar mass.
D. range
The Oxygen
of processes whichVout
gas will come of solution
occur in boiling
in the nitrogen water
cycle n
and be seen as bubbles.
include
C. I lightning discharges producing nitrogen(II) D. oxide
V gas
pV
QuestionII 9 ammonium ions produced by certain soil-borne bacteria
When III sulfur nitrogen
dioxide and
gas carbon
returneddioxide are by
to the air dissolved in water,
microbial decay it is likely that
A. both
IV solutions formed from the gases will be basic.
production of man-made nitrogenous fertilisers
B. only carbon dioxide will form an acidic solution.
In which of these processes does nitrogen fixation occur?
C. both solutions formed from the gases will be acidic.
A. II and III only
D. only sulfur dioxide willp form an acidic solution. T
B. I, II and III only
C. II, III and IV only
Question
Question
D. I, II 10
3: IV only
and
Which of the following solutions contains the smallest amount (in mol) of hydronium ions?
A. 10.0 mL of 0.3 M HNO3
B. 10.0 mL of 0.3 M H2SO4
Copyright30.0
C. mL
© 2010 of 0.1 M HCl
Neap TEVCHEMU2_QA_2010.FM !
D. 30.0 mL of 0.1 M CH3COOH
! TEVCHEMU2_QA_2010.FM Copyright © 2010 Neap

Question 11
A significant chemical reaction in the rusting of iron is shown in the equation:
2+ –
2Fe(s) + O2(aq) + 2H2O(l) o 2Fe (aq) + 4OH (aq)
It can be deduced from this equation that
A. both hydrogen and oxygen are reduced.
A. 10.0 mL of 0.3 M HNO3
B. 10.0 mL of 0.3 M H2SO4
VCE
C.
VCE Chemistry
30.0 2007 Year
mL of 0.1 M HCl
Chemistry 2007 Year 11 Trial
11 Trial Exam Unit
Unit 2 Chemistry
Exam Unit
(ABE) 2
2
D. 30.0 mL of 0.1 M CH3COOH
Exam 2012
-----------------------------------------------------------------------------------------------------------------------------------------------------------------
SECTION A
SECTION A -- [[ 24
24 marks,
marks, 3030 minutes
minutes ]]
Question
Question 4:11
This
This section chemical
section
A significant contains reaction
contains 24 multiple
24 multiple choice
in thechoice questions.
rustingquestions.
of iron is shown in the equation:
For each question choose the response
For each question choose the response that is that is correct
correct or
or 2+
best answers
best answers– the
the question.
question.
Indicate your
your answer
answer on 2Fe(s)
on the +
the answer O (aq)
answer2 sheet + 2H O(l)
sheet provided.
provided. o 2Fe (aq) + 4OH (aq)
Indicate 2
(Choose
(Choose only one
only onefrom
It can be deduced answer
answer for each question.)
for eachthat
this equation question.)
A. both hydrogen and oxygen are reduced.
Question
Question
B. 11 causes reduction and undergoes oxidation.
oxygen
Which
Which one of the
one of the following
following combinations of of aqueous solutions would not produce a
C. hydrogen is oxidised andcombinations
iron is reduced. aqueous solutions would not produce a
precipitate
VCE Chemistry
precipitate when mixed?
Unit mixed?
2 Trial Examination Question and Answer Booklet
D. iron iswhen
A. the reductant
Copper(II) and undergoes
nitrate and sodiumoxidation.
sodium hydroxide.
A. Copper(II) nitrate and hydroxide.
B. Barium
B. Barium nitrate
nitrate and
and sodium
sodium sulfate.
sulfate.
Question
C.
Question 16 Copper(II)
5: nitrate and sodium sulfate.
C. Copper(II) nitrate and sodium sulfate.
D. Silver
This question
D. Silver nitrate
nitrate and
concerns the and sodium
sodium hydroxide.
following hydroxide.
chemical equation:
3P + 2Q o 5R
Question
Question
The minimum 22 amount (in mol) of P which must be added to 1.50 mol of Q in order to produce exactly
When
When fuels
fuels
3.00 mol containing
of Rcontaining
is sulfur impurities
sulfur impurities are are burnt
burnt toto produce
produce energy
energy they they also
also produce
produce sulfur
sulfur
dioxide,
dioxide,
A. 1.65
SO22.. The
SO The main
main impactimpact ofof this
this gas
gas onon the
the environment
environment is is
A.
A. the depletion of ozone in the stratosphere.
!B. 1.80 the depletion of ozone in the stratosphere.
B. the formation of photochemical smog. TEVCHEMU2_QA_2010.FM Copyright © 2010 Neap
C. B. 2.25 the formation of photochemical smog.
C. 5 the
Question the formation of of ozone
ozone in in the
the lower
lower atmosphere.
atmosphere.
D. C. 2.40 the formation
D. formation of acid rain.
The latent
D. heat of vaporisation
the formation of acidis rain.
the energy required to turn a liquid into a gas at its boiling
temperature. The latent heat of vaporisation for water is significantly higher than many other
Question
substances
Question
Question 17
Question 336:with similar molecular masses. The best explanation for this observation is
Which
Which
Samples one
A.one of
of
of three the
thethe following
forces
following
acids, holding
of chemical
thevolume
chemical
the same atoms equations
together
equations
and best
best represents
in water
represents
concentration, are the ionisation
molecules
the ionisation
neutralised arewith of the
stronger
of
0.050the ethanoate
than thosesolution.
M ethanoate
NaOH
-
ion,
ion, CH
Two CH COO
3COO
3 acids
of the - (aq),
present
(aq), a
in weak
other
a -weakacids,
are strong base, in
substances.
base,Hin water?
water?
2SO 4 and HCl, and the other is a weak -
acid, HCOOH. The volume of
NaOHA.A.
B.
solution CH
the COO
forces
3COO (aq)
CHrequired
3 -(aq)
between+ H O(l)
the
+ H2O(l)
2
to neutralise water
HCl U U CH
molecules
CH
is 10.0 COOH(aq)
are +
stronger OH
3COOH(aq) + OH (aq)
3
mL. than-(aq)
those present in other
substances. - - 2-
B.of theCH
WhichB.
CH 3COO (aq) +
3COO-(aq)
following
- + OH
shows the
OH - (aq) (in
(aq)
volume
omL)
o CHof33COOH(aq)
CH COOH(aq)
NaOH solution
+ O
+ O 2- (aq) to neutralise the other
(aq)
required
C. CH
C. water has
COO - a relatively
(aq) + H high
O(l) boiling
o CH temperature.
COOH(aq) + OH -
-
(aq)
C. CH33COO-(aq) + H22O(l) o CH33COOH(aq)
two acids? + OH (aq)
D. CH
D. the forces
COO-(aq) between
(aq) + HHthe water molecules involve
2O(l) U CH2COO2-(aq) + H3O+(aq)
2- strong covalent
+ interactions
D. CH33COO + 2O(l) U CH2COO (aq) + H3O (aq)
whereasVolume theof molecules
NaOH required in othertosubstances are only held to each other by weak
Question 447: forces. neutralise the acid
Question
Question
When the
When the volume
volume H2SO of 4aa gas
of gas sample
sample in in aaHCOOH
piston is
piston is doubled
doubled without
without changing
changing the the temperature,
temperature,
Question
the pressure 6 exerted by the gas will
the
A. pressure
The pH exerted
of aincrease
10020.0 mLby the gas
sample will
ofthe
0.0100 M aqueous
10.0 solution of potassium hydroxide is
A.
A. increase to
to double
double the original
original pressure.
pressure.
B. A. be
B. 11the same as
20.0 as the
the original
original lesspressure.
than 10.0
B.
B. be
12the same pressure.
C. C. C. decrease
decrease to half the original
10.0 to half the original 10.0 pressure.
pressure.
C.
D. depend 13
depend on the actual gas sample. sample.
D. D. D. 10 10.0on the actual gasless than 10.0

Question 78:
Question
Which one of the following samples of gases would have the smallest volume at SLC?
A. 2!1023 helium atoms.
B. 22 g of carbon dioxide.
C. 0.50 mol of argon atoms.
D. 30 g of chlorine gas.

Question 8
The current drought in Australia has seen a great deal of interest focused on desalination of
sea Lisachem
water to Materials
provide VCE
waterChemistry
supplies2007
suitable forTrial
Year 11
11 domestic use.2 One process that can be used to1
Exam Unit
Unit
Lisachem Materials VCE Chemistry 2007 Year Trial Exam 2 1
achieve this is reverse osmosis. In this process
A. water molecules pass through a membrane under reduced pressure leaving the
dissolved ions behind.
B. the water is converted into gas to separate it from the dissolved ions.
C. water molecules are forced through a semipermeable membrane under high
pressures leaving the dissolved solids behind.
dissolved ions behind.
3 ZnCO (s) + o ZnO(s) + CO2(g)
VCE Chemistry Unit 2 Trial Examination Question and Answer Booklet
8.621 B. g of zinc carbonate
the water is convertedwas placedintoingas
a crucible withit afrom
to separate masstheof dissolved
24.915 g. ions.
What would be
the massC. of waterthe crucible
moleculesand are
its contents after thea semipermeable
forced through completion of the reaction?under high
membrane
Unit 2 Chemistry (ABE)
A. 27.94
SECTION A: pressures g.
MULTIPLE-CHOICEleaving the dissolved solids behind.
QUESTIONS Exam 2012
B.
D. 30.51
the sea g.water passes through a bed of resin that removes the dissolved ions.
-----------------------------------------------------------------------------------------------------------------------------------------------------------------
C. 33.54 g. Instructions for Section A
Answer
Question
Question D. all questions
99:38.20 g. in pencil on the answer sheet provided for multiple-choice questions.
The complete
Choose
Question the combustion
21response that isof butaneorcan
correct thatbe represented
best answers the byquestion.
the chemical equation
Question
The reaction
A correct 12 between
answer scores2C 1,4Han
iron and(g)superheated
+ 13O
10incorrect answer o can
2(g)steam
scores8CO
0. be2(g) + 10H2by
described O(l)the chemical equation,
A
Whatsample
Marks volumeof
will not
nitrogen
ofbe carbongas
deducted
placed
dioxide
3Fe(s) in a sealed
is+ produced
4H2O(g)
for incorrect
vessel
o Fe
when
answers.
at 18 °C
1.53OL4(s) had
of butane a
+ 4H2is pressure
(g)burnt andof 240thekPa.
reaction
Assuming
mixture
What mass that
brought
of the
iron volume
back
mustto the of
react the
same
to vessel does
temperature
produce 835 not
and
mL change
pressure
of when
hydrogen that heated,
gastheat what
butane
SLC? is
was the pressure
initially
No marks will be given if more than one answer is completed for any question.
exerted
measured A.byat? the
1.43 nitrogen
g. when the temperature is 180 °C?
A.
A.
B. 6.0 370 kPa.
2.54Lg.
B.
B. 2400
C. 1 1.91 L
12.0 kPa.
g.
Question
C.
C.
D. 1.5 1500
1.17Lg. kPa.
WhichD. of the400 following
kPa. shows the relationship between an acid (A) and its conjugate base (B)?
D. +15.0 L
A. A+H →B
Question 22 +
B.
Question
The B+H
presence 13 → ofA+which of the following ions in a water supply is least likely to cause the
Question
Question 10
10:
When
C.
water + B → chloride,
Alithium H hard? LiCl, dissolves in water the ionic bonds between the lithium and
A basetoisbecome
best described as a substance that
chloride
D. A ions
A.+ B will→ H2broken
are
Calcium O ions. and
A.
2 Lisachem neutralise
Materials an acid.2007 Year 11 Trial Exam Unit 2
VCE Chemistry
A.
B. can the ions ions.
Iron(II) form hydrogen bonds with the water molecules.
B. accept a proton.
B.
C. 2 willcovalent
Magnesium bonds are formed between the ions and the water molecules.
Question C. turn red ions.
litmus indicator blue,
C.
D. the
Sodium ions form
ions. new ionic bonds with the water molecules.
Consider D. a can
gas donate
contained ainproton.
the arrangement shown
D. the ions form ion-dipole bonds withbelow.
the water molecules.
Question 11
Question 23 A B
Question
Question
Which 14
11:
one of the following gases
Zinc carbonate decomposes when would
heated be andleast
this likely to contribute
reaction to the depletion
can be described of ozone
by the chemical
In
in a redox
the reaction
stratosphere?
equation tap
A.
A. CCl the reductant
3F.
200gains
mL electrons and is oxidised. 600 mL
B. the oxidant 2.0 atmZnCO
loses electrons + o
3(s) and is ZnO(s) + CO2(g)
reduced. 1.2 atm
8.621 C.B. NO.carbonate20˚C
g of zinc was placed in a crucible with a mass of 24.915
20˚Cg. What would be
C. the 4reductant
CH . gains electrons and is reduced.
the massD. of the
the cruciblegains and its contentsand after the completion of the reaction?
CBroxidant
D. 27.94
A. 2ClF.
g.
electrons is reduced.

If B. 1530.51
the gaseous
Question g. of vessel B were forced into vessel A, the total pressure in vessel A at 20°C
contents
Question
Question
would C. 24
become12:
33.54 g.
Small samples
An amphiprotic ofsubstance
oxygen gas are that
is one best prepared in the laboratory by
A. D.
1.2
A. atm38.20 g.
A. distilling
will donate it from
moreliquid
than one air.proton.
B. 2.0
B. atmadding an aqueous solution of hydrogen peroxide to some solid manganese(IV)
QuestionB. 12can either accept or donate protons.
C. 3.6
C. atm oxide.
will acceptgas more thaninone proton.
A sampleC. of nitrogen placed a sealed vessel at 18 °C had a pressure of 240 kPa.
D. 5.6
D. atmthe
will electrolysis
neither of pure
accept or water.
donate protons.
AssumingD. by thermally decomposing water not
that the volume of the vessel does change
in the whenofheated,
presence what is the pressure
a catalyst.
exerted by the nitrogen when the temperature is 180 °C?
QuestionA. 313:370 kPa.
Question
A beakerB. contains
2400 akPa.
saturated solution of copper(II) sulfate, together with some undissolved
Lisachem Materials VCE Chemistry 2007 Year 11 Trial Exam Unit 2 3
C. sulfate.
copper(II) 1500 kPa.
WhichD. of the400 kPa. procedures would increase the concentration of the saturated solution?
following
End of Section A
A. heating the mixture
Question
B. 13 stirring the mixture
vigorously
When lithium chloride, LiCl, dissolves in water the ionic bonds between the lithium and
C. adding more CuSO (s) to the mixture
chloride ions are broken4 and VCE Chemistry Unit 2 Trial Examination Question and Answer Booklet
D. adding
A. the water
ionsto form
the mixture
hydrogen bonds with the water molecules.
B. covalent bonds are formed between the ions and the water molecules.
Question
QuestionC. 414:the ions form new ionic bonds with the water molecules.
In whichD. of the
thefollowing
ions formreactions
ion-dipoleis thebonds with
gaseous the water
product molecules.
different from that of the other three reactions?
A. thermal decomposition of potassium chlorate (KClO4)
Question
B. 14
photosynthesis
In
C. a redox reaction of hydrogen peroxide in the presence of a MnO catalyst
decomposition 2
A. the reductant gains electrons and is oxidised.
D. incomplete combustion of methane
!
B. the oxidant loses electrons and is reduced. TEVCHEMU2_QA_07.FM Copyright © 2007 Neap
C. the reductant gains electrons and is reduced.
Question
D. 5 the oxidant gains electrons and is reduced.
Lisachem
A 0.50 Materials
mol sample VCE Chemistry
of nitrogen dioxide2007
(NOYear 11 Trial Exam Unit 2
2) has a volume of 7.0 L at a pressure of 3.0 atm.
5
Question 15
The temperature of the NO2 sample is
C. thermal
A. 512°C decomposition of potassium chlorate (KClO4)
D.
B. 785°C
photosynthesis
C. decomposition of hydrogen peroxide in theUnit
presence of a MnO
2 Chemistry 2 catalyst
(ABE)
D. incomplete
Question 6 combustion of methane Exam 2012
-----------------------------------------------------------------------------------------------------------------------------------------------------------------
Ethene burns in oxygen according to the equation
Question5 15:
Question C2H4(g) + 3O2(g) → 2CO2(g) + 2H2O(g)
A 0.50 mol sample of nitrogen dioxide (NO2) has a volume of 7.0 L at a pressure of 3.0 atm.
When
The 0.20 mol of
temperature 2HNO
ofCthe 4 burns in 0.40
sample is mol of O2, the amount of CO2 expected to form would be
2
A.
A. 0.20 mol
5.0°C
B.
B. 0.27 mol
239°C
C.
C. 0.40 mol
512°C
D.
D. 0.80 mol
785°C

Question 6716:
Question
Question
An orange-coloured
Ethene solution
burns in oxygen was prepared
according by dissolving 14.5 g of potassium dichromate (K2Cr2O7) in
to the equation
water and making up the volume to 100.0 mL with distilled water. This solution (solution I) was used to
prepare three further solutions asCoutlined 3O2(g) → 2CO2(g) + 2H2O(g)
2H4(g) +below.
solution II: 10 mL of solution I added to 30 mL of water
When 0.20 mol of C2H4 burns in 0.40 mol of O2, the amount of CO2 expected to form would be
solution III: 20 mL of solution I made up to 50 mL with water
A. 0.20 mol
solution IV: 40 mL of solution I added to 30 mL of water
B. 0.27 mol
The concentrations
C. 0.40 mol of these three solutions increase in the order
A. 0.80
D. II, III, IV.
mol
B. III, II, IV.
C. II, IV, III.
VCE Chemistry
Question 7 Unit 2 Trial Examination Question and Answer Booklet
D. IV, III, II.
An orange-coloured solution was prepared by dissolving 14.5 g of potassium dichromate (K2Cr2O7) in
water and making
Question up the volume to 100.0 mL with distilled water. This solution (solution I) was used to
Question
Question
prepare 8917:
three further solutions as outlined below.
Which of
Which of the
the following is unit conversions incorrect? processes of flash distillation and reverse osmosis?
isdesalination
solution II: 10following
mL of solution3 common to to
I added the30 mL of water
A.
A. 3.0 atm = 2.3
movement of × 10 by
water mmHg
diffusion
solution
B. 64III:
m 20
3 mL of solution
= on
6.4the
× 10
4
L I made up to 50 mL with water
B. reliance difference in boiling points of water and dissolved salts
solution
C. IV: 40= mL
–32°C 241 of
K solution I added to 30 mL of water
C. conditions of reduced pressure
The
D. concentrations
620 mmHg =of83these
Pa three solutions increase in the order
D. both are endothermic processes
A. II, III, IV.
B. III, II, IV.
Questions 10 and 11 refer to the following information.
C. II, IV, III.
Copyright © 2007 Neap
8.55 gIV,of Ba(OH) !
III, II. 2 was completely dissolved in water so that the final volume of the solution was 250.0 mL.
TEVCHEMU2_QA_07.FM
D.

Question 810
Question
The concentration
Which of theisBa(OH)
of the following common 2 solution was
to the desalination processes of flash distillation and reverse osmosis?
A.
A. movement
0.150 M of water by diffusion
B.
B. reliance
0.200 Mon the difference in boiling points of water and dissolved salts
C.
C. conditions
0.250 M of reduced pressure
D.
D. both
0.300are
Mendothermic processes

Question 11
Copyright © 2007 Neap !
At 25°C, the pH of the solution would be
TEVCHEMU2_QA_07.FM

A. 12.3
B. 12.6
C. 13.3
D. 13.6

Question 12
A particular brand of vodka has an ethanol content of 40.0% v/v.
Unit 2 Chemistry (ABE)
Exam 2012
VCE Chemistry Unit 2 Trial Examination Question and Answer Booklet
-----------------------------------------------------------------------------------------------------------------------------------------------------------------

Question 18-20:
Questions 18 to 20 relate to the following information.
Two experiments were conducted using three metals identified by the symbols X, Y and Z. 1.0 M solutions
of XCl2, YCl2 and ZCl2 were placed in each of three beakers. A strip of each metal was placed in the
appropriate beaker to construct a half-cell. Half-cells were connected via wires, a voltmeter and a salt bridge
containing KNO3(aq). Three cells were constructed as shown below. For cells 1 and 2, the direction of
electron flow and the cell voltage were recorded. Cell voltage provides an indication of the extent of reaction
occurring. Results are shown below.
Cell Direction of
Cell structure Cell voltage
number electron flow

X V Z

1 from X to Z 0.31 V
2+ 2+
X Z

Y V Z

2 from Y to Z 0.10 V
2+ 2+
Y Z

Y V X

3 ? ?
2+ 2+
Y X

Question 18
In cell number 1, electrode Z is the
A. positively charged cathode
B. positively charged anode
C. negatively charged cathode
D. negatively charged anode.

Question 19
Which of the following represents the expected reaction occurring at the negative electrode in cell 3?
2+
A. X (aq) + 2e oX(s)
2+
B. Y (aq) + 2e oY(s)
2+
C. X(s) oX (aq) + 2e
2+
D. Y(s) oY (aq) + 2e

Question 20
If metal X is identified as iron, and Z is identified as lead, then, with the aid of the electrochemical series,
metal Y is possibly
A. copper
B. nickel
C. calcium
D. unable to be determined from the data provided

Copyright © 2010 Neap TEVCHEMU2_QA_2010.FM !


• give simplified answers with an appropriate number of significant figures to all numerical questions;
unsimplified answers will not be given full marks.
• show all working in your answers to numerical Unit 2questions.
ChemistryNo credit will be given for an incorrect
(ABE)
answer unless it is accompanied by details of the working. Exam 2012
-----------------------------------------------------------------------------------------------------------------------------------------------------------------
• make sure chemical equations are balanced and that the formulas for individual substances include an
indication of state, for example H2(g); NaCl(s).
Short-Answer Questions:

Question 11: 8 marks


Question
A 5.25 g sample of hydrogen gas is held in a container at STP.
a. Calculate the volume of the container.

________________________________________________________________________________

________________________________________________________________________________

________________________________________________________________________________

________________________________________________________________________________
2 marks
b. All of the hydrogen gas is pumped into another container of volume 25 L which already contains
0.301 mol of oxygen gas. The temperature of this container is raised to 250°C and held at this
temperature throughout the experiment.
i. Calculate the total gas pressure in the 25 L container.

___________________________________________________________________________

___________________________________________________________________________

___________________________________________________________________________

___________________________________________________________________________
ii. The gas mixture is ignited.
Write the balanced equation for the chemical reaction which occurs.

___________________________________________________________________________
iii. Calculate the number of mole of gas in the mixture resulting from the reaction.

___________________________________________________________________________

___________________________________________________________________________

___________________________________________________________________________

___________________________________________________________________________
2 + 1 + 3 = 6 marks

! TEVCHEMU2_QA_2010.FM Copyright © 2010 Neap


_________________________________________________________________________________

_________________________________________________________________________________
Unit 2 Chemistry (ABE) 2 marks
Exam 2012 Total 10 marks
-----------------------------------------------------------------------------------------------------------------------------------------------------------------
Question 22: 8 marks
Question
A student conducted electrical conductivity and pH tests on a range of aqueous solutions and pure water.
The results are displayed in the table below.
Electrical
Substance pH at 25°C
conductivity
pure water very low 7.0

1.0 M HCl(aq) high 0

1.0 M CH3COOH(aq) low 2.7

1.0 M NH3(aq) low 11.6

a. Explain the very low electrical conductivity of pure water.

_________________________________________________________________________________

_________________________________________________________________________________
1 mark
b. Explain why the two acids in the table conduct electricity to different extents.

_________________________________________________________________________________

_________________________________________________________________________________

_________________________________________________________________________________

_________________________________________________________________________________
2 marks
c. Calculate the amount (in mol) of hydroxide ions in 250 mL of the 1.0 M NH3 solution.

_________________________________________________________________________________

_________________________________________________________________________________

_________________________________________________________________________________

VCE Chemistry Unit 2 Trial Examination Question and Answer Booklet


_________________________________________________________________________________
3 marks
d. The water molecule is amphiprotic.

Using chemical equations, show that H2PO4 (aq) is also amphiprotic.

________________________________________________________________________________
Copyright © 2010 Neap TEVCHEMU2_QA_2010.FM !
________________________________________________________________________________
2 marks
e. When the HCl solution was being made, 75 mL of concentrated (10 M) HCl was accidentally spilt on
the bench.
i. Calculate the minimum mass (in g) of solid sodium hydrogen carbonate which could be used to
neutralise the spilt acid if reaction occurs according to the equation:
NaHCO3(s) + HCl(aq) o NaCl(aq) + H2O(l) + CO2(g)

___________________________________________________________________________

___________________________________________________________________________

___________________________________________________________________________
___________________________________________________________________________

___________________________________________________________________________
Unit 2 Chemistry (ABE) 2 + 1 = 3 marks
Exam 2012 Total 7 marks
-----------------------------------------------------------------------------------------------------------------------------------------------------------------
2 marks
Question 43: 4 marks
Question
iv. When the saturated solution from iii. above was cooled from 85 °C to 50 °C no
a. A 2.0 gsolid
sample
hadofcrystallised
magnesiumfromwas added to a beaker of water. The mixture was warmed and reaction
the solution.
occurred according to the equation:
At 50 °C the solution was (circle the correct term)
Mg(s) + 2H2O(l) o Mg(OH)2(aq) + H2(g)
In thisunsaturated saturated
reaction, is the water acting as an acid, a base, an oxidant supersaturated
or a reductant?
Explain your choice.
1 mark
b. Thermal power stations use large volumes of water for cooling purposes. This
________________________________________________________________________________ water is
often taken from rivers and then discharged back into the river down stream. When the
rivers have low stream flow, due to poor rainfall, this could lead to a significant increase
________________________________________________________________________________
in the temperature of the river water in the areas below the discharge point.
________________________________________________________________________________
i. What effect would an increase in the water temperature have on the amount of
dissolved oxygen in the water available to aquatic life?
________________________________________________________________________________
2 marks
b. A 2.0 g sample of copper was added to a beaker of aqueous silver nitrate solution.
i. What observations, if any, would you expect to make?

___________________________________________________________________________
1 mark
ii. What effect would an increase in the water temperature have on the amount of
___________________________________________________________________________
ii. dissolved solidschemical
Write a balanced in the water?
equation to account for the expected observations, or explain why no
reaction would occur.

___________________________________________________________________________

___________________________________________________________________________
1 +11mark
= 2 marks
Total 4 marks
Question 24:- 4[ 8marks
Question marks, 10 minutes ]
a. Sulfurous acid, H2SO3, is a weak diprotic acid. Write two appropriate chemical
!" Copyright © 2010 Neap
TEVCHEMU2_QA_2010.FM
equations to describe the ionisation of this acid in aqueous solutions.

2 marks
b. The pH of a 2 L sample of an aqueous solution is 4. What are the respective
concentrations of the H3O+(aq) and OH-(aq) ions in this solution?
Lisachem Materials VCE Chemistry 2007 Year 11 Trial Exam Unit 2 7

2 marks
c. Write an appropriate chemical equations to describe the reaction that would occur when
an aqueous solution of 1 M nitric acid was added to some solid barium oxide, BaO.
Unit 2 Chemistry (ABE)
Exam 2012
1 mark
-----------------------------------------------------------------------------------------------------------------------------------------------------------------

Question 45:- 6[ 7marks


Question marks, 9 minutes ]
a. A piece of copper wire is placed in an aqueous solution of silver nitrate.
i. Write the chemical half-equation for the reduction reaction that takes place.

1 mark
ii. Write the chemical half-equation for the oxidation reaction that takes place.

1 mark
iii. Write the overall chemical equation for the reaction that takes place.

1 mark
b. In an investigation of corrosion processes a group of students constructed a cell as
shown in the diagram, using an iron nail for one electrode and different materials for the
other electrode (labelled A). Complete the table below (circling the correct answer) to
give the results that the students would be expected to obtain.

Electrode A Electrode at which oxidation occurs


i. Carbon Iron nail Carbon (Electrode A)

ii. Zinc Iron nail Zinc (Electrode A)

iii. Copper Iron nail Copper (Electrode A)

3 marks

10 Lisachem Materials VCE Chemistry 2007 Year 11 Trial Exam Unit 2


Unit 2 Chemistry (ABE)
Exam 2012
-----------------------------------------------------------------------------------------------------------------------------------------------------------------
1 mark
Question 6: 4 marks
a. Question 6 - [ 8 marks, 10 minutes ]
a. A 4.85 g sample of a gas occupied a volume of 1.74 L at 351 K and 127 kPa.
i. How many mol of gas are present in this sample?

1 mark
ii. What is the molar mass for this gas?

1 mark
b. Lithium hydroxide will react with carbon dioxide as described by the chemical equation
below and can be used to 'scrub' carbon dioxide from gas mixtures.
b. c. The diagram below represents three containers of equal volume at the same
LiOH(s) + CO2(g) o LiHCO3(s)
temperature.
What is the minimum mass of lithium hydroxide required to completely react with all of
the carbon dioxide present in a 500 L gas sample, at SLC, that has a carbon dioxide
concentration of 8.0 % v/v?

Containers A and B each hold different gases. The number of moles of gas in each
container is the same.
Container C contains the combined contents of containers A and B.
i. What is the pressure of the gas in container B if the pressure of the gas in
container A is 108 kPa?

3 marks
1 mark
ii. What is the pressure of the gases in container C?

12 Lisachem Materials VCE Chemistry 2007 Year 11 Trial Exam Unit 2 1 mark
iii. Explain the answer given in ii. above using the kinetic molecular theory.

1 mark
VCE Chemistry Unit 2 Trial Examination Question and Unit 2 Chemistry
Answer Booklet (ABE)
Exam 2012
-----------------------------------------------------------------------------------------------------------------------------------------------------------------
Question 2
Question 7: 5 marks 2+ +
A galvanic cell is formed by the combination of two half-cells: X (aq)/X(s) and Ag (aq)/Ag(s). When the
cell is operating, the electron flow is as shown.

flow of e
V

X(s) salt bridge Ag(s)

2+ +
X (aq) Ag (aq)

a. i. Write a balanced ionic equation for the reaction occurring in the cell.

___________________________________________________________________________
ii. Which electrode (X or Ag) is the anode?

___________________________________________________________________________
iii. Which electrode (X or Ag) carries a positive charge?

___________________________________________________________________________
iv. In which direction (towards X or towards Ag) do cations move through the salt bridge?

___________________________________________________________________________
v. Give the formula for a substance that would be suitable for use in the salt bridge of this cell.

___________________________________________________________________________
1 + 1 + 1 + 1 + 1 = 5 marks
b. After some time the change in mass at the Ag electrode was found to be 2.10 g, while the change at
electrode X was 2.02 g.
Identify metal X. Show your working.

________________________________________________________________________________

________________________________________________________________________________

________________________________________________________________________________

________________________________________________________________________________
4 marks
Total 9 marks

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VCE Chemistry Unit 2 Trial Examination Question and Answer Booklet
Unit 2 Chemistry (ABE)
VCE Chemistry Unit 2 Trial Examination Question and Answer Booklet
Exam 2012
-----------------------------------------------------------------------------------------------------------------------------------------------------------------
Question 3
Question
a. The3table
Question 8: 5 below
marksshows the relationship between properties of various samples of compounds or
a. elements.
The Complete
table below thethe
shows table by indicating
relationship whether
between the quantity
properties in thesamples
of various first column is greater than
of compounds or (>),
less than (<) or equal to (=) the quantity in the second column. The first entry is completed
elements. Complete the table by indicating whether the quantity in the first column is greater than as an (>),
example.
less than (<) or equal to (=) the quantity in the second column. The first entry is completed as an
example. Quantity 1 >, < or = Quantity 2
Quantity
number of atoms 1 1.0 mol of He
of He in >, < =or = Quantity
number of atoms 2 1.0 mol of Ne
of Ne in
number
pH of
ofatoms ofM
an 0.10 HeHCl
in 1.0 mol of He
solution = number of atoms
pH of an 0.10 MofCH
Ne COOH
in 1.0 mol of Ne
solution
3
pH of
volume of 0.20
an 0.10 M HCl(asolution
M HNO pH of anof0.10
0.20MMCH 3COOH solution
3 strong acid) volume HCN (a weak acid)
volume of 0.20 M HNO3 (areact
required to completely with
strong acid) required to completely react
volume of 0.20 M HCN (a weak acid) with
20.0 mL of 0.20 M KOH solution
required to completely react with 20.0 mL to
required of completely
0.20 M KOH solution
react with
20.0 mL
number of 0.20 M of
of molecules KOH N2 solution
in 3.0 L of 20.0 mL of 0.20 M KOH solution
number of molecules of O2 in 4.0 L of
N gas at 2.0 atm and 20°C
number2of molecules of N2 in 3.0 L of O2ofgas
number at 1.5 atm
molecules ofand 20°C
O2 in 4.0 L of
N2 gas at 2.0 atm and 20°C O2 gas at 1.5 atm and 20°C
3 marks
b. With the aid of the relevant calculations, explain the answer you gave in the last row of the 3 marks
b. table the
With above.
aid of the relevant calculations, explain the answer you gave in the last row of the
table above.
_________________________________________________________________________________
_________________________________________________________________________________
_________________________________________________________________________________
_________________________________________________________________________________
_________________________________________________________________________________
_________________________________________________________________________________ 2 marks
Total 25 marks
marks
Total 5 marks
Question 49: 2 marks
Question
Question 4
The label shown below is taken from a bottle of a carbonated apple drink.
The label shown below is taken from a bottle of a carbonated apple drink.
Ingredients
Carbonated water, apple juice, sugar, glucose syrup, malic acid, preservative, artificial sweetener.
Ingredients
Carbonated water, apple juice, sugar, glucose syrup, malic acid, preservative, artificial sweetener.
a. Malic acid (C4H6O5) is added to improve the apple flavour of the drink. Malic acid is a weak,
a. Malic acid
diprotic (C4H6O5) is added to improve the apple flavour of the drink. Malic acid is a weak,
acid.
diprotic
Explain acid.
what is meant by the term
Explain
i. whatacid’.
‘weak is meant by the term
i. ‘weak acid’.
____________________________________________________________________________
____________________________________________________________________________
____________________________________________________________________________
ii. ____________________________________________________________________________
‘diprotic acid’.
ii. ‘diprotic acid’.
____________________________________________________________________________
____________________________________________________________________________
____________________________________________________________________________
____________________________________________________________________________
1 + 1 = 2 marks
1 + 1 = 2 marks

Copyright © 2007 Neap TEVCHEMU2_QA_07.FM !


Copyright © 2007 Neap TEVCHEMU2_QA_07.FM !
Unit 2 Chemistry (ABE)
VCE Chemistry
Exam Unit2012
2 Trial Examination Question and Answer Booklet
-----------------------------------------------------------------------------------------------------------------------------------------------------------------

Question 510: 5 marks


Question
2.5 g (an excess) of iron (Fe) was added to 50.0 mL of 0.50 M sulfuric acid solution (H2SO4). When the
reaction was complete and all the hydrogen gas had bubbled out of the solution, the mixture of iron sulfate
and unreacted iron was filtered to obtain the iron. When dried, the unreacted iron had a mass of 1.1 g.

a. Determine
i. the mass of iron that reacted with the sulfuric acid.

____________________________________________________________________________
ii. the amount (in mol) of iron that reacted with the sulfuric acid.

____________________________________________________________________________
iii. the amount (in mol) of sulfuric acid that reacted.

____________________________________________________________________________
1 + 1 + 1 = 3 marks
b. Using the values obtained in part a, write the balanced equation for the reaction. Hence determine the
formula of the iron sulfate formed.

_________________________________________________________________________________

_________________________________________________________________________________

_________________________________________________________________________________
2 marks
Total 5 marks

Question 6
Emissions from motor vehicles are a major contributor to air pollution. These emissions may include CO2,
CO, NOx, H2O and unburnt hydrocarbons.

a. Write a balanced equation to show how


i. CO may be produced in an engine using octane (C8H18) as fuel.

____________________________________________________________________________
ii. NO may be produced in a car engine.

____________________________________________________________________________
1 + 1 = 2 marks
b. Uncontrolled emissions of NOx may contribute to acid rain.
i. What is meant by the term ‘acid rain’?

____________________________________________________________________________
ii. State one problem caused by acid rain.

____________________________________________________________________________
1 + 1 = 2 marks

Copyright © 2007 Neap TEVCHEMU2_QA_07.FM !!


a) Calculate the percentage, by mass, of nitrogen in ammonium dichromate.
STAV Publishing Pty Ltd 2005 10 Chemistry Unit 2 Examination
__________________________________________________________________________
Unit 2 Chemistry (ABE)
__________________________________________________________________________
Exam 2012
-----------------------------------------------------------------------------------------------------------------------------------------------------------------
__________________________________________________________________________
Question 2
Question 11: 6 marks
A 0.630 g sample of ammonium dichromate, (NH4)2Cr2O7, is decomposed by heating strongly.
b) Calculate the mass of water vapour formed when this sample of ammonium dichromate is
a) Calculate The
decomposed. the percentage, by mass,
chemical equation forofthe
nitrogen in ammonium
decomposition is dichromate.

(NH4)2Cr2O7(s) o N2(g) + Cr2O3(s) + 4H2O(g)


__________________________________________________________________________
__________________________________________________________________________
__________________________________________________________________________
__________________________________________________________________________
__________________________________________________________________________
__________________________________________________________________________
b) Calculate the mass of water vapour formed when this sample of ammonium dichromate is
__________________________________________________________________________
decomposed. The chemical equation for the decomposition is
__________________________________________________________________________
(NH4)2Cr2O7(s) o N2(g) + Cr2O3(s) + 4H2O(g)

c) The__________________________________________________________________________
gas released from the decomposition is collected in a 250 mL syringe at 25 qC. Calculate
the pressure (in kPa) of the collected gas.
__________________________________________________________________________
__________________________________________________________________________
__________________________________________________________________________
__________________________________________________________________________
__________________________________________________________________________
__________________________________________________________________________
__________________________________________________________________________
__________________________________________________________________________
__________________________________________________________________________
c) The gas released from the decomposition is collected in a 250 mL syringe at 25 qC. Calculate
the pressure (in kPa) of the collected gas.
__________________________________________________________________________

! __________________________________________________________________________
! ! ! ! ! ! ! ! ! (2 +3 4++34==610marks!
marks) !
__________________________________________________________________________
(Suggested time: 9 minutes)
__________________________________________________________________________
__________________________________________________________________________
__________________________________________________________________________
__________________________________________________________________________

(2 + 4 + 4 = 10 marks)
(Suggested time: 9 minutes)
Reproduced by Roxburgh College, under licence from STAV Publishing 2008

Reproduced by Roxburgh College, under licence from STAV Publishing 2008


STAV Publishing Pty Ltd 2005 15 Chemistry Unit 2 Examination
Unit 2 Chemistry (ABE)
Exam 2012
-----------------------------------------------------------------------------------------------------------------------------------------------------------------
Question 7
Question 12: 10 marks
a) Complete the diagram below to clearly show a galvanic cell that could be constructed from
half cells containing the conjugate redox pairs Cu2+ /Cu and Pb2+ /Pb.

Clearly indicate the anode, the cathode, the polarity of the electrodes, the direction of flow of
the electrons, the salt bridge, and the direction of flow of anions.

Copper Lead

1 M Cu2+ 1 M Pb2+

b) Suggest a suitable solution for the salt bridge. ______________________

c) Write ionic half equations and the overall equation for the reactions occurring in the
galvanic cell.

Oxidation: _____________________________________________________________

Reduction: _____________________________________________________________

Overall: _____________________________________________________________

d) Write the chemical formula of the oxidant in the galvanic cell. ____________________

(5 + 1 + 3 + 1 = 10 marks)
(Suggested time: 9 minutes)

Reproduced by Roxburgh College, under licence from STAV Publishing 2008

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