FIITJEE KVPY (QUESTION BANK) CHEMISTRY 1 (MODULE - 2)

CHEMISTRY
STATES OF MATTER
LEVEL 1 OBJECTIVE TYPE QUESTIONS
1. A gas mixture contains 20% by weight of H2 and 80% by weight of O2. The total
pressure is 1 atm. What is partial pressure of H2?
(a) 0.5 atm (b) 0 .67 atm
(c) 0.75 atm (d) 0 .80 cm

2. In a closed vessel, a gas is heated from 300K to 600 K , the kinetic energy
becomes/remains
(a) half (b) double
(c) same (d) four times

3. A closed vessel contains equal number of nitrogen and oxygen molecules at a pressure of
P mm. If nitrogen is removed from the system, then the pressure will be
(a) P (b) 2P
(c) P/2 (d) P2

4. Dalton's law of partial pressure will apply for

(a) H2 and Cl2 (b) CO and Cl2
(c) O2 and SO2 (d) CO2 and H2

5. In a closed room of 1000 m3, a perfume bottle is opened up. The whole room develops
smell. This is due to which property of gases.
(a) Viscosity (b) Density
(c) Diffusion (d) None

6. A gas occupies 300 ml at 27°C and 730 mm pressure. What would be its volume at
S.T.P.?
(a) 321.2 ml (b) 298.5 ml
(c) 262.2 ml (d) 213.2 ml

7. A gas at –20°C occupies the volume 140 ml. Calculate the temperature at which the
volume of gas becomes 65 ml. Assume P is constant:
(a) –345.21°C (b) 55.04°C
(c) 126.45°C (d) –155.54°C

8. A gaseous mixture contains 56 g of N2, 44 g of CO2 and 16 g of CH4. The total pressure
of the mixture is 7209 mm of Hg. The partial pressure of CH4 is (m, m hg):
(a) 180 (b) 360
(c) 540 (d) 720

FIITJEE BANGALORE CENTRE, #19, 13TH CROSS, 6TH SECTOR, HSR LAYOUT, BENGALURU-560102
www.fiitjee.com, 080-49149900
FIITJEE KVPY (QUESTION BANK) CHEMISTRY 2 (MODULE - 2)

9. When a balloon filled with N2O is pierced with a needle and dropped immediately into a
cylinder of CO2 at the same pressure the size of the balloon:
(a) increase (b) decrease
(c) does not change (d) cannot be predicted

10. An open flask contains air at 27°C and one atm pressure. The flask is heated to 127°C at
the same pressure. The fraction of original air remaining in the flask will be:
1 2
(a) (b)
5 5
1 3
(c) (d)
2 4

11. 3.7 g of gas at 25°C occupies the same volume as 0.184 g of H2 at 17°C and same
pressure. What is molecular weight of gas?
(a) 23.651 (b) 45.123
(c) 66.987 (d) 41.326

12. A gas behaves most like an ideal gas under conditions of

(a) High pressure and low temperature
(b) High temperature and high pressure
(c) Low pressure and high temperature
(d) Low pressure and low temperature

13. Ideal gas equation in terms of KE per unit volume, E is :

3 2
(a) RT (b) E
2 3
2 3
(c) RT (d) E
3 2

14. Two vessels of volume 2V and 3V contains two gases A and B separately at 1.5 and 4
atm respectively. If the vessels are at constant temperature connected through a tube
(negligible volume). The total pressure of gaseous mixture is
15
(a) 3 atm (b) atm
2
(c) 5 atm (d) 6 atm

15. 380 ml of a gas at 27C, 800 mm of Hg weighs 0.455 g. The mol. wt. of gas is
(a) 27 (b) 28
(c) 29 (d) 30

FIITJEE BANGALORE CENTRE, #19, 13TH CROSS, 6TH SECTOR, HSR LAYOUT, BENGALURU-560102
www.fiitjee.com, 080-49149900
FIITJEE KVPY (QUESTION BANK) CHEMISTRY 3 (MODULE - 2)

16. If a gas is expanded at constant temperature

(a) Number of Molecules of gas decreases
(b) KE of the molecules decreases
(c) KE of the molecules remain the same
(d) KE of the molecule increases

17. A thin balloon filled with air at 47C has a volume of 3.0 litre. If on placing it in a cooled
room, its volume become 2.7 litre, the temperature of room is
(a) 42C (b) 30C
(c) 15C (d) 0C

18. Which relation holds good for Graham’s law of diffusion

r1 M2
(a)  (at same P and T)
r2 M1

r1 l2
(b)  (at same P and T)
r2 l1

r1 M 2 P1
(c)   (at same T)
r2 M 1 P2
(d) All

19. A flask is of a capacity of one litre. What volume of air will escape out from it on heating
from 27 to 37C? (Assume pressure to be constant)
(a) 1.033 Litre (b) 33.3 ml
(c) 33.3 Litre (d) None

20. A gaseous mixture contains 1 g of H2, 4g of He, 7g of N2 and 8g of O2. The gas having
the highest partial pressure is
(a) H2 (b) O2
(c) He (d) N2

FIITJEE BANGALORE CENTRE, #19, 13TH CROSS, 6TH SECTOR, HSR LAYOUT, BENGALURU-560102
www.fiitjee.com, 080-49149900
FIITJEE KVPY (QUESTION BANK) CHEMISTRY 4 (MODULE - 2)

LEVEL 2
1. Gas AB2 dissociates as
AB2(g) AB(g) + B(g)
Initially, the pressure of AB2 is 400 mm. What is the pressure of the gaseous mixture if
AB2 dissociates up to 25%
(a) 500 mm (b) 400 mm
(c) 800 mm (d) 600 mm

2. A mixture of H2 and He in 1:1 mass ratio is allowed to diffuse through a porous pot. The
mole ratio of H2 to He in the initially effused mixture will be
(a) 2 : 2 (b) 2 2 : 1
(c) 1:2 (d) None of these

3. The temperature of a sample of gas is raised from 127C to 527C. The average K.E per
molecules of the gas
(a) will remain unchanged
(b) will be doubled
(c) will be halved
(d) can’t be calculated

4. 1 mole of a real gas enclosed in a container of x L capacity excess a pressure of 10 atm at

27C. The compressibility factor of the gas under this condition is 0.86. Hence x is
nearly
(a) 13 (b) 8
(c) 10 (d) None

5. One litre of gaseous mixture is effused in 5 min 11 sec, while 1 litre of oxygen takes 10
mins, the gaseous mixture contains methane and hydrogen. Calculate the vapour density
of the gaseous mixture.
(a) 5.269 (b) 4.298
(c) 9.567 (d) 0.410

6. The density of Neon is maximum at

(a) STP
(b) 0°C, 2atm
(c) 273°C, 1 atm
(d) 273°C, 2 atm
7. Equal weights of methane and hydrogen are mixed in an empty container at 25°C. The
fraction of the total pressure exerted by hydrogen is
(a) 1/2 (b) 8/9
1
(c) 6/17 (d)
9

FIITJEE BANGALORE CENTRE, #19, 13TH CROSS, 6TH SECTOR, HSR LAYOUT, BENGALURU-560102
www.fiitjee.com, 080-49149900
FIITJEE KVPY (QUESTION BANK) CHEMISTRY 5 (MODULE - 2)

8. 50 ml of hydrogen diffuses through small hole from vessel in 20 minutes time. The time
taken for 40 ml of oxygen to diffuse out under similar condition will be
(a) 12 min (b) 64 min
(c) 8 min (d) 32 min

9. X mL of H2 gas effuse through a hole in a container in 5 seconds. The time taken for the
effusion of the same volume of the gas specified below under ideal condition is :
(a) 10 seconds : He (b) 20 seconds : O2
(c) 25 seconds : CO (d)55 seconds : CO2

10. The density of a gaseous substance at 1 atm pressure and 750 K is 0.30 g/litre. If the
molecular weight of the substance is 27, the forces existing among gas molecules is
(a) Attractive (b) Repulsive
(c) Both (d) None

11. A mixture of 50.0 mL of NH3 and 60.0 mL of O2 gas reacts as :

4NH3 (g)  5O2 (g)  4NO  6H2O(g)
If all the gases are at the same temperature and pressure and the reaction continues until
one of the gases is completely consumed, what volume of water vapour is produced:
(a) 48 mL (b) 60 mL
(c) 72 mL (d) 75 mL

12. 4.4g of CO2 and 2.24 L of H2 at STP are mixed in a container. The total number of
molecules present in the container will be
(a) 6.0221023 (b) 1.20441023
(c) 2 (d) 6.0231024

13. The density of oxygen gas at 25C is 1.458 mg/litre at 1 atm pressure. At what pressure
will oxygen have the density twice the value
(a) 0.5 atm/25C (b) 2 atm/25C
(c) 4 atm/25C (d) None

14. The RMS speed of H2 molecules at room temperature is 2400 ms-1. At room temperature
the RMS speed of O2 molecules would be
(a) 400 ms–1 (b) 300 ms–1
(c) 600 ms–1 (d) 1600 ms–1

15. The V.D. of a gas in 11.3. Volume occupied by 11.2g of the gas at NTP is
(a) 1 litre (b) 11.2 litre
(c) 22.4 litre (d) 4.8 litre

FIITJEE BANGALORE CENTRE, #19, 13TH CROSS, 6TH SECTOR, HSR LAYOUT, BENGALURU-560102
www.fiitjee.com, 080-49149900
FIITJEE KVPY (QUESTION BANK) CHEMISTRY 6 (MODULE - 2)

16. P versus T curves at constant pressure P1 and P2 for an ideal gas are shown in Fig. Which
is correct,
P1

P2

(a) P1 > P2 (b) P1 < P2

(c) P1 = P2 (d) All

17. O2 gas is collected by downward displacement of water in a jar. The level of water inside
the jar is adjusted to the height of water outside the jar. When the adjustment is made, the
pressure exerted by the O2 is
(a) Equal to atmospheric pressure
(b) Equal to the vapour pressure of O2 at that temperature
(c) Equal to atmospheric pressure plus aqueous tension at that temperature.
(d) Equal to atmospheric pressure minus aqueous tension at that temperature.

18. O2 gas is collected by downward displacement of water in a jar. The level of water inside
the jar is adjusted to the height of water outside the jar. When the adjustment is made, the
pressure exerted by the O2 is
(a) Equal to atmospheric pressure
(b) Equal to the vapour pressure of O2 at that temperature.
(c) Equal to atmospheric pressure plus aqueous tension at that temperature.
(d) Equal to atmospheric pressure minus aqueous tension at that temperature.

19. Air circulation of blood in human body supplies O2 and releases CO2. The concentration
of O2 and CO2 is variable but on the average, 100 ml blood contains 0.02 g of O2 and
0.08 g CO2. The volume of O2 and CO2 at 1atm and body temperature 37C, assuming
10 litre blood in human body is,
(a) 2 litre, 4 litre (b) 1.5 litre, 4.5 litre
(c) 1.59 litre, 4.62 litre (d) 3.82 litre, 4.62 litre

20. 22 g solid CO2 or dry ice is enclosed in a bottle of one litre properly closed. If
temperature of bottle is raised to 25C to evaporate all CO2, the pressure in the bottle
would be,
(a) 13.23 atm (b) 12.23 atm
(c) 11.23 atm (d) 14.23 atm

FIITJEE BANGALORE CENTRE, #19, 13TH CROSS, 6TH SECTOR, HSR LAYOUT, BENGALURU-560102
www.fiitjee.com, 080-49149900
FIITJEE KVPY (QUESTION BANK) CHEMISTRY 7 (MODULE - 2)

ANSWER KEY: LEVEL: 1

1. D 2. B 3. C 4. D 5. C
6. C 7. D 8. A 9. C 10. D
11. D 12. C 13. A 14. A 15. B
16. C 17. C 18. D 19. A 20. C

ANSWER KEY: LEVEL: 2

1. A 2. A 3. B 4. D 5. B
6. B 7. B 8. B 9. B 10. B
11. C 12. B 13. B 14. C 15. B
16. B 17. C 18. C 19. C 20. B

FIITJEE BANGALORE CENTRE, #19, 13TH CROSS, 6TH SECTOR, HSR LAYOUT, BENGALURU-560102
www.fiitjee.com, 080-49149900