Hint & Solution Chemistry: NH NH CL

HINT & SOLUTION
CHEMISTRY
SECTION – I
Part – A
1. Buffer solution=>AcOH + AcONa

=> AcONa + HCl (limited)
 NH3  NH4Cl
2. ( A) S  Ksp  105 mol / lt

(B) S  105 mol / lt, not affected by non-common ion
(C ) AgCl (s) Ag  Cl 
s2 s
10 10   s  2  s
2  s  s  5  10 11 mol / L

(D ) AgCl (s)  2NH3  Ag  NH3 2   Cl 
2  2s s s
2
 s  10
K  K sp  K f     10  10
8
 2  2s 
 s  0.166 mol / lt
3. It is simultaneously both isothermal and adiabatic.

Q=0, T2  T1
P2V2Y  P1 V1Y for adiabatic reversible process
T2 P P
 S   nCp ln  nR ln 1  nR ln 1
T1 P2 P2
sin ce q  0  Ssurr .  0  Stotal  Ssys.
4. In case of weak acid, Hneut .  57.3 KJ / eq.

HA is stronger acid, i.e. Hionization of HB is higher
5.
B OH 4  H 

H3 BO3  H2O
weak, monobasic, Lewis acid
Ethylene glycol makes complex with B OH 4 leads to forward reaction.

H3BO3  s  is a planar due to H-bonding.
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2
Ai TS – 3 ( XI ) | SET – A | APT – 1 | Page |2
6.
R R R R
H2O Condensation
Cl Si Cl HO Si OH - O Si O Si -----
-H2O
R R (by several units) R R
used as electrical insulator due to inertness of –Si-O-Si- bonds.
7.
A
Z X ZA1 Y  
23
11 Na 12 H 12
24
Mg 10 n
7
3 Li 11 H 24 He  24 He
(p) ()
A 4
A
ZX YZ2
{X and Y have same isotopic no. (A-2Z)}
8.
dN
N
T 2>T 1
T1
du du u
Area under curve remain same, but area for finite du decreases
9.
r.p.f
r
For dZ 2 , ml  0
→ two conical nodes, no nodal plane
→ no. of radial nodes = n-l-1
= 4-2-1=1
10. X should be non-metal (P)

Z should be s-block element (Na)
Y should be in between X and Z
Part – C
11. H2S 2H   S 2  K  K1  K2  1.2  1020

S 2  required to start precipitation of MS
min
6  1021
  1.2  1019
0.05
2 2
H   S 2  20
H   1.2  1019 
K  1.2  10 
 H 2S   0.1
1
 1.2 2
H   

 102   0.1
 1.2 
pH  1
2
12.
pH  pK a   log
KA
HA
4.3   4  log2   log
KA  KA  4
HA HA
13. ∆U=q+w
  1 
 100  1 1    1  bar  m3
  2 
 

3
 100   102  KJ
2 

1 bar  m3  100 KJ 
  50 KJ
1.435  1000
14. Tmp   275 K  2 c
5.22
15.
 lattice  charge
1

   r 
r 
CaCl2 , LiF, MgO, Al2O3 , TiO2
16.
H
H H
B B
H
H
H
17.
F
F F
I
F F
IF5  sp d hybridisation
3 2
 5   bond  1 lp
 due to lp  bp repulsion, all eight bond angles are less than 90
18. H2S2O8  2H2O  2H2SO4  H2O2
19.
BrO3  5Br   6H   3Br2  3H2O
m mol of Br2  3  m mol of BrO3
 3  10  0.2   6
20.

Al  C   Al 4C3 
H2O
 Al OH 3  CH4
White ppt.  gas 
2
MATHEMATICS
SECTION – II
Part – A
x2 y 2
1. Let equation of ellipse is  1
a2 b2
16 1
as it passes through (4, -1), so, 2  2  1........(i )
a b
Also, x  4y  10  0 is a tangent
Any Tangent to the Ellipse is y  mx  a2 m2  b2
Rewrite the tangent line mx  y  a2m2  b2  0
Both tangent are identical,
m 4 10
So,  
1 1 a m2  b2
2
10 5
m  4, and a2m2  b2  
4 2
25
or , a 2 m 2  b 2 
4
25
or , 16a 2  b 2  .........( ii )
4
Solve (i) & (ii), and get a2 and b2
2. Take any point as  

6 cos , 2 sin  on the ellipse
Then 6cos2   2sin2   2 and solve
3. Convent the hyp in the form of

 x  h y  k 
2 2
 1
a2 b2
X  x  h { Shift the hyp
then put X2 Y2
Y  y k {  1
a2 b2
and then compare.
4. Take any point on hyp. (2secθ, 2tanθ). Write the equation of normal and proceed.
5. Write the given equation as a quadratic in x, we get

x 2  4 x  3  9y 2  0
as x  R, D  0
Get the interval of x. Also write the equation as a quadratic in y, we get
9y 2  x 2  4 x  3  0
as y  R, D  0;
get the interval of x.
2x  1 2x  1
6.  0

x 2x  3 x  1
2
 x  2x  1 x  1
using Wavy Curve method, get the solution.
2
7.
16a 2  25b 2  40ab  c 2
 4a  5b   c 2  0
2
 4a  5b  c  4a  5b  c   0
i .e. 4a  5b  c  0.........( i )
or 4a  5b  c  0
i .e.  4a  5b  c  0.........( ii )
from (i) & (ii), it is clear ax+by+c=0 passes through the point (4, -5) and (-4, 5).
8.
 x 2  y 2  2x  6y  6  0
C
Tangent line
P 3 x  4y  k  0
use CP=r
9. Focus of Parabola is (4, 0)

Equation of focal chord is y  m  x  4 .........(i )
C
 y  m  x  4
P use CP  radius
Find m.
10.
5  4 sin  3cos  5
as  a2  b2  a cos  b sin  a2  b2
Part – C
x2 y 2 x2 y 2
11. Given Ellipse   1 intersect the director circle of Ellipse   1 at four points
50 20 16 9
12. Write the equation of Ellipse at any point 9cos , 5sin . Find the distance of normal at the origin
l  f  
dl
 0 for max imum or min imum
d
13. Eliminating the parameter ‘a’

Given 2 3 x  ea  e a ........(i )
2y  ea  e a ............(ii )
Square and substract, i.e. (i )2  (ii )2 , get the equation of hyperbola.
14.

3x 2  6x  4  0

use
  2
4
 
3
2
15. Given hyperbola,

x2 y 2
 1
9 1
Equation of any Tangent is y  mx  9m2  1
It passes through the point (3, 2)
So, 2  3m  9m  1
2
Solve we get two value of m. Hence two Tangents.

Equation of chord of contact is
3 x 2y
 1
9 1
x
or ,  2y  1
3
Now after getting equation of required ∆. Find Area.
16. Given
2 1
x  2  23  23
cube both sides and get the result.
17.
A
M x-y-4=0
o
O 60
(0, 0) B
Pair of straight line passes through origin. In ∆OBM, find OM. So, side of equilateral ∆.
18. Given circle touches each other externally. So, number of common tangent=3.
19. Equation of normal to y 2  4 x is y  mx  2am  am3

Let point P(h, k) as normal passes through ……. (h, k)
k  mh  2am  am3
m1
or , am3   2a  h  m  k  0 m2 (i)
m3
k
Now , m1m2 m3 
a
as m1m2  
k
So, m3 
a
as m3 is the root of (i)
3
 k  k
so, a     2a  h  k  0
 a  a
Simplify, to get the locus and compare with y 2  4 x
20.
cos x  cos 4 x  cos2x  cos3 x  0
C  D  C  D 
use cosC cosD  2cos    cos  2 
 2   
And solve the trigonometric equation
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2
PHYSICS
SECTION – III
Part – A
1. A, B and C are orthogonal
V
2. Va.v.  
2  2
V
 
v 2  v 2  2vv cos 600 3V 2
aa.v  
2  2
V
 
3. For block C For block B

 1 
T2 cos 2  mg T1 cos 1  mg  2mg  
 2
T2 sin 2  mg T1 sin 1  mg
1
 tan 2  1  tan 1 
2
& T2  2 mg & T1  5 mg
4.
2m/s
m1  m2  5 kg 2m2

v11' kg v  v 1 kg 5 kg
m1  m2  1 m1  m2  2
 1 5 
2    v1  0
 1 5 
 v1  3m / s
 m  m1   2m1 
v '2   2  v2    v1
 m1  m2   m1  m2 
 2  1
v '2  0    3
 6 
 v '2  1 m / s
PCM  Pi  m1v1  3 kg m / s
P5'  m2 v '2  5 kg m / s
2
PCM 9
K CM    0.75 J
2  m1  m2  2  6
1
K total  m1v12  4.5 J
2
5. Magnitude of angular momentum about the point of suspension is mv , which is constant but direction is
continuously changing.
Torque of mg about point of suspension is non – zero. Which is responsible for change in direction of angular
momentum.
6. When disc comes, at the point where string leaves contact with the disc is point of instantaneous rest, thus
string does no work.
1  mR2   v 
2
1 2
 
I  2 2   R 
 
KR 2 C 1
 
KT 1 1 2
mv 2 mv 2
2 2
7. Applying energy conservation
2
2
1  gRE  GMEm 1 GMEm
m
    mv 2 
2  2  RE 2  5RE 
 4 
 
Applying angular momentum conservation about centre of Earth
 gRE   5R 
m
  RE sin   mv  E 
 2   4 
On solving both equations, we get v & .
8. Applying energy conservation for ‘m’

KEi  PEi  KE f  PE f
1  GMm 
mv 2  2   00
2  L 
GM
v2
L
9.   2gh a
10. For sphere of density '  '

4 3 4
R g  kx  R3  2  g
3 3
For sphere of density '3 '
4 3 4
R  3  g  R3  2  g  kx
3 3
4R3 g
On solving we get x =
3k
Part – C
m
11. 
r 2L
  m 2r L 
  100      100
  m r L 
 Percentage error in density = 4%
12. For circular tube

2Ncos   Mg
For small sphere
mv 2
N  mgcos   Force equation
R
1
MgR 1  cos    mv 2 Energy conservation 
2
m
On solving above three equations, we get 2
M
13. In reference frame of hemisphere
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2
2
1  2gR 
maR sin   mgR 1  cos    m   ........ i 
2  n 
 work  Energy theorem  
2
 2gR 
m  
n 
mgcos   ma sin    ......  ii 
R
Netwon' s 2nd law 
On solving both equations,
we get n  3
14. Applying Energy conservation

1 1
3mg  mg  m  2v    2m  v 2 i 
2
m
2 2 2v
For mass ' 2m'
 3v 
2
T  2mg   2m  ..... ii 
 from reference frame of mass 'm' 

Solving  i  &  ii  , we get T  12 mg
For mass 'm' v PE = 0
N  mg  T  N  13 mg 2m
15. Applying angular momentum conservation about centre of mass of rod
m 2
P  
2 12

6P 2
 
m t
m
t
12P
16. m  2kg, a  0.3 m / s2 

r  0.5 m
2  f  ma ....  i 
fr  2r  mr 2  ..... ii  N
2N
a  r ......  iii  a
from  i  ,  ii  &  iii  2
  0.4 f
mg
4 
G  R3  
g'  2   2 
GM 3
17.
R R
g'
 g' R  R

Now, v e  2g'R
 v e  g'R
g'
 ve

2
Ai TS – 3 ( XI ) | SET – A | APT – 1 | P a g e | 10
6
v e  planet 
11
g 
  
v e Earth   2  g
 3 
 
 v e  planet   3 km / s
2
 R 
  mg   R
2
18. mg 
 R  3 
 6   2R 
 mg  1    mg 1  
 R  g 
4
19.     
V1 1.5  103 g  V2 2.5  103 g   V1  V2  2  103 g 
 V1  V2
V1 1
 
V1  V2 2
h
20. V1  2g  Apply Bernoulli's equation 
2
V2  2gh
2
V 
 2 2
 V1 

Hint & Solution Chemistry: NH NH CL

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HINT & SOLUTION

1. Buffer solution=>AcOH + AcONa

2. ( A) S  Ksp  105 mol / lt

3. It is simultaneously both isothermal and adiabatic.

4. In case of weak acid, Hneut .  57.3 KJ / eq.

H3BO3  s  is a planar due to H-bonding.

{X and Y have same isotopic no. (A-2Z)}

10. X should be non-metal (P)

11. H2S 2H   S 2  K  K1  K2  1.2  1020

18. H2S2O8  2H2O  2H2SO4  H2O2

2. Take any point as  

Then 6cos2   2sin2   2 and solve

3. Convent the hyp in the form of

5. Write the given equation as a quadratic in x, we get

9. Focus of Parabola is (4, 0)

13. Eliminating the parameter ‘a’

15. Given hyperbola,

Solve we get two value of m. Hence two Tangents.

19. Equation of normal to y 2  4 x is y  mx  2am  am3

1. A, B and C are orthogonal

3. For block C For block B

7. Applying energy conservation

8. Applying energy conservation for ‘m’

10. For sphere of density '  '

12. For circular tube

13. In reference frame of hemisphere

14. Applying Energy conservation

T  2mg   2m  ..... ii 

 from reference frame of mass 'm' 

16. m  2kg, a  0.3 m / s2 

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