Phenol and Photocatalysis

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200 64.

146
400 100.083 Calibration plot of Absorbance vs Concentration in ppm
600 156.37
350
800 207.415
1000 326.441 300
0 0 f(x) = 0.2904806364x
250 R² = 0.9865343366

200

150

100

50

0
0 200 400 600 800 1000 1200

30 0.053
20 0.04
10 0.023
5 0.016

time abs value rate ln(rate) ln(value)


60 0.011 1.666667 0.1682 -1.7826 0.510826
45 0.016 5 0.2852 -1.25456 1.609438
30 0.0248 10.86667 0.4022 -0.91081 2.3857
15 0.0326 16.06667 0.5192 -0.65547 2.776747
10 0.04 21 0.5582 -0.58304 3.044522
5 0.0426 22.73333 0.5972 -0.5155 3.123832
n 2.0663
Plot of ln(rate) vs ln(time)
k 67.05412 3.

f(x) = 2.0662738483x + 4.2054859173


R² = 0.9977121494
2.

ln(rate)
1.

0.

-2 -1.8 -1.6 -1.4 -1.2 -1 -0.8 -0.6


ln(time)

8 0.0269 12.26667 -0.73568 0.73568


15 0.0186 6.733333 -0.54115 0.54115
30 0.0119 2.266667 -0.2134 0.2134
75 0.0116 2.066667 -0.1547 0.1547
90 0.0114 1.933333 -0.1174 0.1174

n 0.9293
k 0.080082

Plot of ln(rate) vs ln(time)


0
0.5 1 1.5 2 2.5 3
f(x) = 0.9292585852x - 2.5246725561
-0.5 R² = 0.9477119049

-1
ln(rate)

-1.5

-2

-2.5

ln(time)
-1.5

l
-2

-2.5

ln(time)

0 0
200 58.765
400 88.2346 Chart Title
600 119.598 200
800 160.327 180 f(x) = 0.1905542x
R² = 0.9876436639
1000 172.152 160
140
120
100
80
60
40
20
0
0 200 400 600 800

P H conc P conc H rate ln(rate)


2 48.38 28.6 166.5404 150.0525 -7.5781 7.5781
5 46.73 30.12 160.8606 158.0273 -7.0345 7.0345
9 44.25 30.23 152.3236 158.6044 -6.3097 6.3097
15 34.57 27.86 119.0017 146.17 -5.2225 5.2225
20 12.52 16.6 43.09811 87.09339 -4.3165 4.3165
40 8.144 14.27 28.03442 74.86884 -0.6925 0.6925

Chart Title
8

7 f(x) = 0.037356736x + 1.0216765446


R² = 0.838369497
6

0
20 40 60 80 100 120 140 160 180

n 0.0374
k 2.777913

Chart Title
3
f(x) = - 0.0315791316x + 5.0416950231
2 R² = 0.349626374

0
70 80 90 100 110 120 130 140

-1

-2

-3
Concentration in ppm

800 1000 1200

Calibration plot of Absorbance vs Concentration in ppm

0.06

0.05 f(x) = 0.0015050847x + 0.0085423729


R² = 0.9968043364

0.04
Absorbance

0.03

0.02

0.01

0
0 5 10 15 20 25 30 35

Concentration in (ppm)

Plot of Concentration(ppm) vs time(min)


25

f(x) = 0.0038512934x^2 - 0.6361536104x + 25.9701728577


20 R² = 0.9922522167
Concentration (ppm)

15

10

0
0 10 20 30 40 50 60 70
20 R² = 0.9922522167

Concentration (ppm)
15

10

vs ln(time) 0
0 10 20 30 40 50 60 70
3.5
Time (min)
54859173 3

2.5

1.5

0.5

0
.2 -1 -0.8 -0.6 -0.4
time)

Plot of Concentration(ppm) vs time(min)


-0.30696 2.506886
-0.61406 1.90707
14
-1.54459 0.81831
-1.86627 0.725937 12
-2.14217 0.659246 f(x) = - 8.92510729411127E-05x^3 + 0.0169512135x^2 - 0.9903508471x + 18.7652558853
R² = 0.990462386
10
Concentration (ppm)

0
0 10 20 30 40 50 60 70 80 90 100

e) Time (min)

2.5 3
Chart Title

400 600 800 1000 1200

Chart Title
180
rate value f(x) = 0.0906097854x^2 - 7.9404573333x + 196.8111053988
160 R² = 0.89233146
3.2 -1.81037
140
3.1165 -1.4158
120
100
80
60
180
f(x) = 0.0906097854x^2 - 7.9404573333x + 196.8111053988
160 R² = 0.89233146

140

-2.2707 1.726881 120


-7.1655 2.350144 100
-8.324 2.444238 80
-8.879 2.48705 60
40
20
0
0 5 10 15 20 25 30 35 40 45

Chart Title
180
160 f(x) = 0.0176827511x^3 - 1.0451414044x^2 + 12.2402081619x + 125.5471182009
R² = 0.9623803181
140
120
100
80
60
40
20
0
0 5 10 15 20 25 30 35 40 45

Chart Title

316x + 5.0416950231

00 110 120 130 140 150 160 170


in ppm

30 35

60 70
60 70

me(min)

9903508471x + 18.7652558853

70 80 90 100
8111053988
8111053988

30 35 40 45

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