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Parametros de La Cerveza
Parametros de La Cerveza
Water adjustment can make the difference between a good beer and a
great beer if it is done right.
Brewing water affects the beer in three ways: It affects the pH of the beer,
which affects how the beer flavors are expressed to your palate; it
provides “seasoning” from the sulfate-to-chloride ratio; and it can cause
off-flavors from chlorine or contaminants.
In general, brewing water should be clean and free of any odors, such as
chlorine or pond smells. Usually, good brewing water for conducting the
mash and creating the wort should be moderately hard and have low-to-
moderate alkalinity. But it depends (doesn’t it always?) on the type of
beer you want to brew and the mineral character of your water.
Basically water comes from two sources: surface water from lakes, rivers,
and streams; and groundwater, which comes from aquifers underground.
Surface water tends to be low in dissolved minerals but higher in organic
matter, such as leaves and algae, which need to be filtered and
disinfected with chlorine treatment. Groundwater is generally low in
organic matter but higher in dissolved minerals.
Good beer can be brewed with almost any water. However, water
adjustment can make the difference between a good beer and a great
beer if it is done right. But you have to understand that brewing is cooking
and that seasoning alone will not make up for poor ingredients or a poor
recipe
The common conception is that the best beer is made from mountain
springwater, and this is generally true, although probably not for the
reasons you think. Mountain springwater (i.e., a clean surface water
source) is good for brewing because it is largely mineral free, which lets
the brewers add any mineral salts they feel are necessary for the beer.
And that leads us to a quick refresher in chemistry.
Ions
Recall that an ion is an atom or a group of atoms that has a net positive
or negative charge due to the loss or gain of an electron. The ions in
brewing water are the cation (positive) and the anion (negative)
components of the minerals dissolved in the water. The principal cations
we’re interested in are calcium (Ca+2), magnesium (Mg+2), and sodium
(Na+1). The principal anions are bicarbonate (HCO3–1), sulfate (SO4–2),
and chloride (Cl–1).
The chloride anion acts to make the beer seem fuller and sweeter. It has
the opposite effect of sulfate. In fact, the sulfate-to-chloride ratio is a good
way to gauge the effect of the brewing water on the balance of the beer.
For example, a sulfate-to-chloride ratio of 2:1 or higher will tend to give
the beer a drier, more assertive hop balance, while a beer with a ratio of
1:2 will tend to have a less bitter, rounder, and maltier balance. However,
this effect is just like salting and seasoning your food; it helps accentuate
the flavors that are there but will not fix a bad recipe. Finally, you should
understand that chloride is not the same as chlorine, which is used as a
disinfectant. The concentrations of each are unrelated to the other.
And here is the problem for brewers: recall that I said earlier that good
brewing water should be moderately hard. It should have a minimum level
of total hardness of about 150 ppm as calcium carbonate (CaCO3). Water
softeners remove the hardness but leave the alkalinity behind.
Here is the bottom line: If your water is softened or highly alkaline, you
should not use it for either extract or all-grain brewing. The alkalinity of
water can be reduced by aeration and pre-boiling or by diluting it with
distilled or reverse-osmosis water.
So don’t assume that you have to use the exact water profile that you find
on the Internet for Dublin, Ireland, if you want to brew a good stout. The
water profile for a famous brewing city may be a step in the right direction,
but do your research and find out how the brewers of that region/style
actually used the water to brew their beer.
Water Report
How do you know your water’s alkalinity and hardness? Often that
information is contained in your city water report. Water reports are
primarily concerned with testing for contaminants, so you will usually find
Total Alkalinity and Total Hardness numbers in the Secondary Standards
or Aesthetic Standards section. As a brewer, you generally want to see
Total Alkalinity less than 100 ppm and preferably less than 50 ppm, but
that is not very likely. You will typically see Total Alkalinity numbers
between 50 and 150.
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For Total Hardness, you generally want to see a value of 150 ppm or
greater as calcium carbonate. Preferably, you would like to see a value
greater than 300, but that is not likely either. Typically, you will see total
hardness numbers in the range of 75 to 150 ppm because water
companies don’t want carbonate scale in their pipes. In fact, almost every
city’s tap water, everywhere in the world, is generally going to be higher in
alkalinity and lower in hardness than we would prefer for brewing.
You can also test your brewing water for total alkalinity and total hardness
by using a water test kit, such as the Lamotte BrewLab. These are simple
drop-test kits similar to what you would use for a swimming pool.
Once you have your water’s information, you can use the calculations in
my book, How To Brew, and/or use brewing software to calculate how
much of what to add. A common practice is to start with a low hardness,
low alkalinity water source and add brewing salts to the mash and/or
kettle.
For hoppier beer styles such as American Pale Ale or American IPA, you
can add calcium sulfate (gypsum) to the water to make the beer taste
drier and have a crisper, more assertive bitterness. For maltier styles,
such as Oktoberfest or Brown Ale, you can add calcium chloride to the
water to make the beer taste fuller and sweeter.
Generally, you don’t want to exceed 400 ppm for sulfate or 150 ppm for
chloride. Sulfate and chloride are the seasoning for your beer, and their
ratio will affect the flavor balance to a large degree. A hoppy beer will
generally have a sulfate-to-chloride ratio of 3:1 or higher, and you don’t
want both of them to be at their maximum because that will just make the
beer taste like mineral water.
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Tips For All-Grain Brewers
I have only scratched the surface of what there is to know about water
chemistry and mash pH. Read chapter 15 in How To Brew (John Palmer,
Brewers Publications, 2006) or chapter 5 in the Water book (John Palmer
and Colin Kaminski, Brewers Publications, 2013) to learn more about
both.
>> Don’t add salts to your water without an understanding of how they will
affect your mash pH.
>> Measure the pH of your mash after you’ve added water to the grain.
It is that pH that affects the activity of the mash enzymes and the
propensity for the extraction of astringent tannins from the grain husks.
Start the mash, check the pH, and then make adjustments.
>> The mash pH should be in the range of 5.2–5.6, 10–15 minutes after dough-
in, after the sample has been cooled to room temperature.
If you want to add brewing salts to enhance the flavor of the beer, use
either 1 gram of calcium sulfate per gallon (3.8 liters) of wort for bitterness
or 1 gram of calcium chloride per gallon (3.8 liters) of wort for fullness.
Don’t use both, and don’t exceed 1 gram per gallon (3.8 liters) until you
have brewed with that extract recipe and determined how it tastes.
Traducicon
Interestingly, extract brewers can use distilled water for their brewing
because all the minerals needed for brewing are already in the malt
extract. When the maltster created your malt extract he/she mashed
grains and then concentrated the wort down by removing the water, which
means the ideal set of ions for brewing are already in the concentrated
malt.
If you are an all-grain brewer with a “good” water source, the most
important thing to worry about is mash pH. The proper mash pH has a
number of positive effects on your beer—improving both the flavor and
stability of the finished beer. Mash pH is simply the pH of the mixture of
water and grains in the mash tun. You can best find it by measuring it with
a pH meter or pH test strips. Ideally, you want a mash pH of 5.2–5.6
when you mix the water and grains.
You might recall from high school chemistry class that pure distilled water
has a pH of 7.0, but most municipal water sources have a higher (slightly
alkaline) pH above 7.0, due to minerals they pick up from ground and
surface sources.
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Grains, in contrast, are acidic, meaning they will lower the pH of the
water/grain mixture. Dark roast malts are very acidic and will have the
largest effect, while pale malts are only slightly acidic.
So when we mix our slightly alkaline water with our acidic grains, we get a
pH that is often in the range of 5.0–7.0. That will depend on how alkaline
the water was to start with, how much acid the water itself can absorb
(which is measured by the water’s residual alkalinity), and how much dark
vs. light malt we use.
Since we want to get the mash pH down to 5.2–5.6, we often need to use
additional acid to drive it down further. This is particularly true for light
beers, which don’t have enough acidic dark malts to reach the desired
range. For a homebrewer, this means adding small amounts of lactic
acid, phosphoric acid, or acidulated malt to the mash until you get the pH
down to the range you need. Lactic acid is probably the most easily found
in an average homebrew store.
Twenty-five years ago, Prof. Dr. Anton Piendl of the Technical University
of Munich’s renowned Brewing Science and Beverage Technology
program at Weihenstephan observed, “Malt is the soul, hops the spice,
yeast the spirit, and water the body of beer.” Maltless beer would be an
astringent, one-dimensional shell of itself. To study malt, then, is to peer
deeply into beer’s very being.
What Is Malt?
Malt is simply a cereal seed that has been tricked into thinking it is about
to grow into a plant and then abruptly denied the opportunity to do so.
Mother Nature packs raw grains full of all the nutrients and enzymes a
newborn plant needs before it grows old enough to photosynthesize its
own food. Malting makes those nutrients and enzymes available to
brewers. Just about any cereal grain can be malted, but some are better
suited to brewing than others.
Barley
If malt is the soul of beer, then barley must surely be the élan vital,
the qi, the aura. More than any other grain, barley means beer. Barley’s
morphology and biochemical constitution make it the ideal brewer’s grain.
The tough outer husks that surround barley kernels protect the
grains during malting, and they collectively form an effective filter
during lautering (wort runoff).
Barley is rich in diastatic enzymes, which convert starches to
sugars during mashing. In fact, barley is so rich in these enzymes
that it can even convert the starches of other grains as it converts
its own.
Barley’s low protein content enhances beer clarity and promotes
easy lautering in the brewery.
Barley is low in lipids (fats) that can degrade head retention in the
finished beer.
Without barley, there would be no beer. Sure, we would certainly brew
other grain-based fermented beverages such as sake and chicha (Homo
sapiens possesses an unquenchable thirst to turn things into alcohol), but
we wouldn’t have beer as we know it.
Barley may take center position on the Olympic podium of malt, but wheat
and rye flank it on the left and right. Wheat has long enjoyed celebrity
status in Bavarian Weißbier, Berliner Weisse, Belgian wit, and American
wheat ale. Rye has recently gained prominence in American craft ales
and lagers alike.
Malted wheat and rye are high in protein and lack outer husks, promoting
gumminess (think oatmeal) in the mash, difficulty in lautering, and haze in
the final beer. They follow their own malting schedules and require a deft
hand in the brewhouse. But the rewards are great for those who choose
to work with them.
Almost any cereal grain can be malted: oats, maize (corn), spelt, millet,
triticale, and even buckwheat. But for diastatic purposes (a malt’s ability
to convert starches to sugars), barley, wheat, and rye reign supreme.
With the notable exception of gluten-free beers, other cereal grains are
almost always combined with barley.
Malt Preparation
The conversion of raw grain to malt is achieved in stages. Every malt
house has its own unique process, but the general idea is the same
across the board.
Kilning halts germination with a combination of heat and air. Hot air is
drawn through the green malt to evaporate moisture and preserve the
diastatic enzymes, which are crucial to starch conversion when the
brewer conducts a mash. When the moisture content of the malt has
fallen to acceptable levels, the maltster increases the temperature of the
hot air to cure the malt. Different curing temperatures yield different kinds
of malt.
When the malt has reached the desired color and moisture level, kilning
ends, and the basic malting process is complete. But maltsters have other
tricks up their sleeves to create the myriad malt varieties available to
today’s brewers.
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Malt Classification
Malts are generally categorized according to their color and function. In
the United States, color is measured in degrees Lovibond (°L). The darker
the malt, the higher the Lovibond rating.
Malts are also classified according to the roles they play. Base malts,
caramel and crystal malts, and roasted malts offer brewers unlimited
ways in which to build up a wort.
Base Malts
Base malts form the canvas upon which brewers paint the malt character
of a beer. Some base malts are neutral, while others supply their own
distinctive flavors and aromas. Base malts must be mashed and, in fact,
they supply the enzymes necessary to convert mash starches to
fermentable sugars. All beer recipes are built on a foundation of base
malt.
Pale malt, often simply called 2-row, forms the basis for most American
and British beer styles. U.S. pale malt is frequently (but certainly not
always) very mild in flavor, while British pale malts often contribute nutty
or toast-like flavors. Typical color is 2–5°L.
Pilsner malt is the lightest malt available and serves as the backbone for
most beer styles of Continental European origin. Pilsner malt lends
delicate grainy or bready notes to light-colored beers and serves the
same role as pale malt in most German, Czech, and Belgian styles.
Typical color is 1–2°L.
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Munich and Vienna malts are highly kilned malts that offer intense, chewy
malty flavors. Some of these may be used for up to 100 percent of a
beer’s malt bill, but extended kilning reduces the diastatic potential of
darker varieties, which are more commonly combined with other base
malts. Look for them in Oktoberfest, Bock, and other malty German
styles. Color can range from 4–20°L.
Six-row malt has been the grain of choice for mass-market lager brewers
and has rarely been used in craft beer. You may come across 6-row in
recipes for a pre-Prohibition pilsner or light American lager, but it has
been otherwise fairly obscure until very recently (see “Craft Malt: Taking
Beer Back to Its Historical Roots” for one craft malthouse that is
successfully making 6-row barley its main product). Six-row malt has a
rough, husky quality and high diastatic power, which is why it is often cut
with adjuncts such as rice and maize. Six-row is similar in color to Pilsner
malt, less than 2°L.
In the roaster, the malt is heated to mash temperatures, and alpha- and
beta-amylase enzymes convert the starchy endosperms to sugars—
essentially pre-mashing the malt within its husk. The longer the malt is
heated, the darker and more intensely these sugars caramelize, yielding
the wide range of caramel malts available to today’s brewers.
Maltsters can also roast malt, much as one might roast coffee. Roasted
malts go through the entire process, all the way through kilning, but these
malts are then further kilned at a high temperature or for longer periods of
time to yield roasted qualities. These can range from the subtle to the
severe.
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Black malt, also called black patent malt, is an exceedingly dark malt that
contributes burnt-coffee notes. Used sparingly, it lends bitterness. Used
with abandon, it can make a beer undrinkable. Black malt is 500°L or
darker.
Debittered black malt has had the husk removed, which eliminates much
of the acrid and astringent flavors associated with black malt. Debittered
black malts are also 500°L or darker.
Chocolate malt contains no chocolate whatsoever, but its flavor and color
are reminiscent of dark baker’s chocolate, hence the name. It’s available
in a range of colors from 180–450°L.
Roasted barley isn’t malt at all but rather raw barley that has been
roasted. It supplies the signature roast flavor of Irish stouts such as
Guinness and Murphy’s. When the English taxed beer according to the
amount of malt it contained, the Irish got around it by using roasted raw
barley for flavor.
The world of malt is varied, complex, and sometimes confusing. But it’s
always interesting and always flavorful. Great malt in the hands of a
skilled brewer can make ordinary beer sing.
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From Pilsner to pale and crystal to chocolate, good malt makes good
beer. And that is most certainly good for the soul.
More Resources
Brewing With Wheat, 1st Edition, by Stan Hieronymus. (Brewers
Publications, 2010).
https://www.google.com/search?q=industria+acido+fosforico&rlz=1C1PRFI_enPE783PE783&s
xsrf=ACYBGNQfmy0fS5IEKLJMhMM9zAhDEv_ALA:1571422313523&source=lnms&tbm=isch&s
a=X&ved=0ahUKEwjInqimtKblAhXRrVkKHeqyBlAQ_AUIEigB&biw=1093&bih=526#imgrc=7TMc
Sjakzk4IkM:
https://beerandbrewing.com/water-and-mash-ph/
https://www.chimicamo.org/chimica-generale/acido-fosforico-produzione.html
https://ppqujap.files.wordpress.com/2016/05/proceso-de-c3a1cido-fosfc3b3rico.pdf