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Ethylbenzene Production
Ethylbenzene Production
CHAPTER 1 ...................................................................................................... 2
INTRODUCTION .............................................................................................. 2
1.1 Introduction .......................................................................................... 2
1.2 Physical properties ................................................................................ 2
1.3 Chemical properties ............................................................................... 3
1.4 Supply and Demand .............................................................................. 4
1.5 Production Technologies ........................................................................ 6
CHAPTER 2 .................................................................................................... 11
MATERIAL AND ENERGY BALANCE........................................................... 11
2.1 Introduction ........................................................................................ 11
2.2 Block Flow Diagram ........................................................................... 11
2.3 Material Balance ................................................................................. 12
2.4 Energy Balance ................................................................................... 16
CHAPTER 3 .................................................................................................... 20
REACTOR SIZING CONSIDERING MAIN REACTION ................................... 20
3.1 Reactor Sizing According Algorithm ..................................................... 20
3.2 Catalyst Determination ........................................................................ 23
3.3 POLYMATH Result ............................................................................ 24
REFERENCES ................................................................................................ 28
CHAPTER 1
INTRODUCTION
1.1 Introduction
No. Properties
At 150C 0.87139 g/cm3
At 200C 0.8669 g/cm3
1 Density
At 250C 0.86262 g/cm3
2 Melting Point -94.9490C
3 Boiling Point At 101.3 KPa 136.1860C
At 200C 1.49588
4 Refractive Index
At 250C 1.49320
5 Critical Pressure 3609 KPa
6 Critical Temperature 344.020C
7 Flash Point 150C
8 Auto Ignition Temperature 4600C
lower 1.0%
9 Flammability Limit
upper -
fusion 86.3 J/gm
10 Latent Heat
vapour ization 335 J/gm
gross 429999 J/gm
11 Heating Value
net 40928 J/gm
At 37.80C 0.6428x10-6 m2/s
12 Kinematic viscosity
At98.90C 0.390x10-6 m2/s
13 Surface tension 28.48 mN/m
Ideal gas,250C 1169 J kg-1 K-1
14 Specific Heat Capacity
Liquid,250C 1752 J kg-1 K-1
Being rather volatile and having a flash point of 19-23 °C, ethylbenzene is
classified as a highly flammable substance, which in use may form flammable or
explosive vapour-air mixtures. The most important commercial reaction of
Ethylbenzene is its dehydrogenation to styrene. The reaction is carried out at high
temperature (600-6600C) usually over an iron oxide catalyst. Steam is used as
diluents. Commercially, selectivity’s to styrene range from 89 to 96% with per-pass
conversions of 65-70%.
The global demand for ethyl benzene is growing wherein the Asia Pacific
region has retained more than 47% of the market. China is the largest consumer and
producer of ethyl benzene, having a market share of 28%. It is because, the value of
Ethyl Benzene were so high that will give benefit to the industry to produce more
product that were linked to Ethyl Benzene.
This shows that the Ethyl Benzene (EB) is quite an important chemical
product that has a lot of uses to the industry. Based on analysis, The Asia-Pacific is
the biggest market of benzene consuming a significant share of the total consumption
in 2012, and it is also the second fastest growing market next to ROW. The
consumption patterns of benzene and its various derivatives are continuously showing
an upward trend which is mainly due to the shift of manufacturing industry to the
Asia-Pacific on account of increasing demand and low cost of production. China is
the leading country in the region in terms of both, production as well as consumption
of benzene and its derivatives, while the Indian market, despite being small in size, is
expected to be a market with high potential (PRNewswire , New York, June 19,
2014).
Figure 1.1 shows the consumption of Ethyl benzene in the world in 2013. The
world consume the EB about 99% to produce a lot of variety product that will
generate economy and about 1% consumed of ethylbenzene is used for other
applications.
For instance, global demand for ethyl benzene amounted to 28,567,852 tons
in 2014 (BGI research, 2012). The global EB market was dominated by the Asia-
Pacific region, with the domestic markets in developing economies expanding
exponentially (Global Chemical Price, 2013). The increasing standard of living and
increased styrene capacities across the globe increased the usage of EB in a number of
countries. With demand recovery expected in developed markets and increasing
demand expected from developing economies, overall global EB demand is expected
to have reached 34,667,874 tons by 2020 (GBI Research, 2012). Figure 1.2 shows
global demand trends for EB in volume terms from 2000 to 2020.
Figure 1. 2: Global Demand Trends for EB in volume terms from 2000 to 2020 by
GBI Research (2012)
Vapour-phase alkylation has been practiced since the early 1940s, but at that
time processes were unable to compete with liquid-phase aluminum chloride based
technology. The alkar process developed by UOP, based on boron trifluoride catalyst,
had modest success in the 1960s, but fell from favour because of high maintenance
costs resulting from the severe corrosion caused by small quantities of water.
Nevertheless, some Ethylbenzene units continue to use this process. The Mobil –
badger Ethylbenzene process represents the latest and most successful vapour phase
technology to be introduced. The process was developed in the 1970’s around.
The CDTECH process is based on mixed liquid-vapour phase alkylation reactor section. The design of commercial plant is similar to the
liquid phase technologies except for the design of the alkylation reactor which combines catalytic reaction with distillation into a single
operation.
Table 1.2: The Comparison for Production Technology of Ethylbenzene. (Shenglin Liu, March 2009)
Liquid Phase Aluminium Vapour-phase Zeolite Liquid phase Zeolite Mixed Liquid-vapour phase
Properties
Chloride Alkylation Alkylation Alkylation Zeolite Alkylation
Operating
400-450 C 450° to 600° C.
Temperature
Operating
2-3 MPa (20-30 bars).
Pressure
Conversion 99% 100% 100% 100%
Three phase are present ; The high-activity catalyst allows
Aromatic liquid, ethylene transalkylation and alkylation to The alkylation reactor is
Phase Mixed liquid-vapour phase
gas, and a liquid catalyst occur simultaneously in a single maintained in liquid phase
complex phase reactor
Aluminium Chloride
Catalyst Zeolite Catalyst Zeolite Catalyst Zeolite Catalyst
catalyst complex
i. The aluminium i. Use of zeolite catalyst i. The liquid phase i. Combines catalyst
chloride present in that eliminated issues associated zeolite catalyst process reaction with distillation into
alkylation reactor effluent with corrosion and waste operates at substantially single operation
Advantages
catalyst trans alkylation disposal of aluminium chloride lower temperature decreased ii. The exothermic heat
reaction. ii. The original vapour side reactions dramatically of reaction creates
ii. Reaction is very phase design accomplished the resulting in ultra-high purity vaporisation necessary to
fast in presence of alkylation and trans alkylation EB product effect distillation
Aluminum chloride reactions in single reactor ii. The plant achieve iii. Capable of using
&produces almost iii. The third generation high on stream efficiency dilute ethylene feed e.g. Off
stoichiometric yields of technology is capable of often greater than 99% which gas from a fluid catalytic
Ethylbenzene. achieving EB yield greater than results in low turnaround & cracking plant or dilute
iii. Essentially 100% 99% maintenance cost ethylene from steam cracker
of ethylene is converted iv. The third generation iii. EBZ-500 catalyst has iv. In general ethylene
technology offered significant operating length of more than feed streams containing
benefits in purity ,capital cost 8year without catalyst significant amounts of
regeneration hydrogen, methane or ethane
iv. The regeneration is do not require some pre-
mild carbon burn procedure treatment. (David Netzer,
that is relatively inexpensive 1999)
i. Handling and i. The significant extent of
disposal of aluminium isomerisation reactions and
chloride catalyst and waste catalyst deactivation by
has become increasingly deposition of carbonaceous
more costly and material are most important
complicated because of problems associated with high
environmental temperature
considerations ii. The length of time
Disadvantages Do not have disadvantage
ii. Equipment and between regeneration can vary
piping corrosion and from as little as 2 months to
fouling along with related slightly more than 1 year
environmental issues led depending on specific plant
to development of EB design and operating conditions
process based on solid iii. Because the reactors
acid heterogeneous must be taken off line for
catalysts regeneration ,on-stream
iii. Major equipment efficiency can be low resulting
pieces needed to replace in high operating costs for
on regular schedule vapour phase plant
because of corrosion iv. Additional equipment
which results in extensive may be required for regeneration
turnarounds poor plant on- procedure depending on specific
stream efficiency and thus plant design which adds capital
are primary contributors to cost to plant
the high operating costs
associated with aluminium
chloride
From above advantages & disadvantages for different processes we select Vapour Phase Zeolite Catalyst process (UOP). Since it has
more advantages over other existing manufacturing process for Ethylbenzene. Not only that, it also have long catalyst run-length with excellent
stability which can minimizes plant downtime, and It has highly selective reaction that are insignificant amount of xylenes are produced,
providing a highest product quality. Also it requires less pure benzene & ethylene. Less harm full to environment also. (technology, 2012)
CHAPTER 2
2.1 Introduction
This chapter will focus on calculation of material and energy balance for
production of 40,000 MT of Ethylbenzene. The reaction kinetics of EB production is
as follows. The production of ethylbenzene (C6H5C2H5) takes place with the direct
addition reaction between ethylene (C2H4) and benzene (C6H6).
However, there is another inevitable reaction takes place at the same time as
reaction (1) which is to produce diethylbenzene (C6H4(C2H5)2), an unwanted product.
As this is mini project for Chemical Reaction Engineering II, we will consider
the material balance in the reactor only. Analysis of material balance follows the
extent of reaction method. The symbols ξ1 and ξ2 are used to denote the extents of
reaction for the first and second reaction, Equation (1) and Equation (2) respectively.
The material balances of all chemical species are generally computed using
the correlation as follows:
ṅi = ṅ0 + vi ξ1 -----(3)
where ṅi is molar flow rate of the species i and vi is the stoichiometric coefficient. The
summary of using extent of reaction is as in Table 2.1.
----- (4)
From Equation (4), 5000 kg of Ethylbenzene will be produced per hour. The
assumption of calculation are listed as follows;
Ethylene
= FFE/X
= PEB/YX
= 47.09/0.99 (0.9)
n2 = 52.85 kmol/hour
Ethylene outlet from the reactor, FE = FFE + (1-X)
= PEB/YX * (1-X)
n3 = 5.29 kmol/hour
Benzene
For PEB,
= PEB/Y+FE (3 – X)
n1 = 158.55 kmol/hour
= PEB/YX (3-X)
= 47.09/0.99(0.9) * (3-0.90)
n4 = 110.99 kmol/hour
Diethylbenzene
n6 = 0.53 kmol/hour
The results of calculations are tabulated as in Table 2.3. It is shown from total
of mass balance, the calculation is considered balanced.
In this part, only energy balance in the packed bed reactor will be calculated
accordingly. Figure 2.2 shows input-output structure of temperature in the said reactor, where
temperature feed is at 298K, while the temperature outlet is 573K. The reactor operates at
573K and 5000 kPa.
As both ethylene and benzene enter in gas phase at 298K (Smith, 1925), no heat of
vaporization is required. To aid the calculation, thermodynamic properties is tabulated as in
Table 2.4.
∫ ( ) [ ]
The total heat of reaction of benzene, ethylene, ethylbenzene from 298 K to 573 K
= 11729.63 J/mol
To find the total heat of reaction
= -105520 +11729.63
Mechanism,
Adsorption:
Surface area:
Desorption:
Rate law,
Adsorption: [ ]
[ ]
Surface area: [ ]
Desorption: [ ]
( )
( )
( )
[ ] ( )
Site balance,
[ ]
( )
[ ]
substitute (1),(2),(3)and (5) into (4)
[ ]
[ ]
[ ]
[ ],
[ ]
[ ]
Stoichiometry
Rearranging Pressure
( )( ) ( )
( )( ) ( )
( )( ) ( )
Where
4
6.344 X 10
k1 [kmol/m3 cat/h/atm2 ] 0.69 10 6 exp
RT
162 ,730
K A [atm -1 ] 1.2328 10 17 exp
RT
35,368
K B [atm -1 ] 2.0850 10 4 exp
RT
4
3.933X 10
K A [atm-1 ] 1.5202 10 2 exp
RT
Design Equation
( )
Rate law
[ ]
Stoichiometry
( )
( )
Combine
[ ]
It is chosen that zeolite is the catalyst for this Ethylbenzene production. And its
properties is evaluated as below;
Therefore,
( ) ( )
[ ]
( )( ) ( )( )( )
[ ( )]
( )( )( )( ) ( )
( )
( )( )
( )( )( )( )
In order to find the weight of catalyst, the simulation is ran by using Polymath
software as shown below,
POLYMATH Report No Title
Ordinary Differential Equations 30-Dec-2014
Differential equations
1 d(X)/d(W) = -rT/Fao
design equation for packed bed reactor
2 d(y)/d(W) = - A * (1+(E*X))/(2*y)
Explicit equations
1 Fao = 158.55
2 Pao = 5000
3 E = -1/6
4 R = 8.314
5 T = 573
6 k1 = 0.69 *10^(6)* exp(-6.344*10^4/(R*T))
7 Ka = 1.2328 *10^(-17) * exp (162730/(R*T))
8 Kb = 2.085*10^(-4) * exp(35368/(R*T))
9 Kc = -1.5202 *10^(-2) * exp(-3.933*10^4/(R*T))
10 Pa = Pao * y*(1-X) /(1+E*X)
11 Pb = Pao *y* (5 - X)/(1+E*X)
12 Pc = Pao *y* (X)/(1+E*X)
13 r1 = -k1 * Pa * Pb / (1 + Ka * Pa + Kb * Pb + Kc * Pc)^2
14 A = 3.482*10^(-6)
alpha
15 rT = r1
General
Total number of equations 17
Number of differential equations 2
Number of explicit equations 15
Elapsed time 0.000 sec
Solution method RKF_45
Step size guess. h 0.000001
Truncation error tolerance. eps 0.000001
From Table 3.1, at approximately 90% conversion the weight of catalyst required is
172.55 kg. Hence, analyzing the reactor sizing,
( )
( )( )
= 106.60 m
= 17.76 m
It is determined that the length of the reactor is 106.6 m while its diameter is 17.76 m
REFERENCES
David Netzer, 1. H. (1999). "Mixed Phase Ethylene Process for Manufacturing Ethylbenene".
U.S.Patent, 977,423.
ICIS. (2011, August). Retrieved from Ethylbenzene (EB) Prices and Pricing Information:
http://www.icis.com/resources/news/2007/11/02/9075692/ethylbenzene-eb-prices-
and-pricing-information/
Klaewkla, R., Arend, M., & Hoelderich, W. F. (2011). A Review of Mass Transfer
Controlling the Reaction Rate in Heterogeneous Catalytic Systems. InTech.
Smith, J. M., Van Ness, H. C., & Abbott, M. M. (2005). Introduction to Chemical
Engineering Thermodynamics. New York: Mc Graw Hill Education.
technology, w. (2012, - -). Ethylbenzene/Styrene Monomer. Retrieved oktober 14, 2014, from
Ethylbenzene/Styrene Monomer.
Turton, R., Bailie, R. C., Whiting, W. B., Shaeiwitz, J. A., & Bhattacharya, D. (2013).
Analysis, Synthesis, and Design of Chemical Processes (Fourth ed.). United States:
Pearson Education.