RT (Main) SET - A

FIITJEE - JEE (Mains)
PHYSICS, CHEMISTRY & MATHEMATICS

SET - A
Time Allotted: 3 Hours QP Code: 100115 Maximum Marks: 360
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JEE MAINS 2
SECTION - 1
PHYSICS
1. A wide vessel with small hole in the bottom is filled with water and kerosene. Neglecting viscosity,
the velocity of water flow v, if the thickness of water layer is h 1 and that of kerosene layer is h 2 is
(density of water r1 gm/cc and that of kerosene is r2 gm/cc.
2g h1  h2  2g h1r1  h2r2 
(A) v = (B) v =
  r   r  
(C) v = 2gh1  h2  2  (D) 2gh1 1   h2 
 
  r1    r2  
2. A small ball of lead is falling freely in a viscous liquid. The velocity of the ball
(A) goes on increasing
(B) goes on decreasing
(C) remains uniform all along
(D) increases to a certain value and subsequently the ball continues to fall with this velocity.
3. The linear density of rod is given by  = Bx2 where B is a constant. The rod is placed along x-axis
with one end at origin. Then the co-ordinates of centre of mass are (Thickness of rod negligible)
 3L   3L 
(A)  ,0  (B)  0, 
 4   4 
 4L   0, 4L 
(C)  ,0  (D)  
 3   3 
4. A uniform rod of mass m and length h L can freely rotated in a vertical. The
angular velocity of the rod, When it falls from position P to P¢ through an angle
a, is (point 0 is fixed)
6g 6g a 6g a
(A) sina (B) sin (C) cos (D)
5L L 2 L 2
6g
sina
L
5. A cubical block of mass M and edge a slides down a rough inclined plane of inclination  with a
uniform velocity. The torque of the normal force on the block about its centre has a magnitude :
a
(A) zero (B) Mga (C) Mg sin  (D) Mga cos 
2
6. Incline planes P & Q are smooth but plane surface

from A to B is rough. Find number of times block of
mass 2 kg will climb on Q. If released from P at a
height 50 m
(a) 45 (b) 41
(c) 42 (d) 40
JEE MAINS 3
The system of springs and masses are in equilibrium. If the spring 2 is cut
then the initial acceleration of block B will be.
7
(a) g downward (b) 2g downward
2
7
(c) 2g upward (d) g upward
2
8. A piece of stone is thrown from the top of a tower with a horizontal speed of 10 3 m/s. It is found
that at a point P along the path, the velocity vector of the stone makes an angle of 30° with the
2
horizontal. The point P is reached in time t which is given by (g = 10m/s )
(a) 1 sec (b) 3 sec (c) 2 sec (d) 2 3 sec
r r r r
9. Given A = 4i� 2�
j and B = 3i� 4 �
j . Find magnitude of component of A along B .
(a) 4 (b) 20 (c) 2 (d) 3
10. S-t graph of a particle moving in straight line with u = -8 m/s, a = 4 m/s 2 and S = -1 m at t = 0 is
(a) (b)
(c) (d)
11. A block X slides down upon a friction less X Y
inclined plane when released from the top of the

inclined plane while another block falls freely h
h
from the same point then

(A) block X will strike the ground first
(B) block Y will strike the ground first
(C) both block will strike the ground
simultaneously.
(D) none.
12. A simple pendulum has a bob of mass m and swings with an angular amplitude f . The tension
in the thread is T. At a certain time, the string makes an angle  with the vertical (  �f ). Then
which one of the following is not correct?
(a) T = mgcos , for all values of  (b) T = mgcos , only for  = f
1
-1 � �
(c) T = mg, for  = cos � (2cos f  1) � (d) T will be larger for smaller values of 
3
� �
JEE MAINS 4
13. The dimensional formula for latent heat is

(a) M0L2 T -2 (b) MLT -2 (c) ML2 T -2 (d) ML2 T -1
14. Two wires of the same material and length are stretched by the same force. Their masses are in
the ratio 3 : 2, their elongations are in the ratio :
(a) 1 : 2 (b) 2 : 3 (c) 2 : 1 (d) 3 : 2
15. A liquid of density r and surface tension T rises to a height h in a capillary tube of radius r. The
potential energy of the liquid in the capillary is :
pT 2 2 pT 2 p 2T2 4p 2 T 2
(a) (b) (c) (d)
rg rg rg rg
16. A wave equation which gives the displacement along the y direction is given by
y = 10-4 sin (60t + 2x), where x and y are in meters and t is time in seconds. This represents a
wave
(A) travelling with a velocity of 60 ms-1 in the negative x direction.
(B) of wavelength 2p m
(C) of frequency 60/p Hz
(D) of amplitude 10-4 m travelling along the negative x direction
17. Two waves of intensities I and 4I produce interference. Then the intensity at constructive and
destructive interference respectively is
(A) 3I, 5I (B) 5I, 3I
(C) I, 9I (D) 9I, I
18. An open pipe is suddenly closed at one end as a result of which the frequency of the second
harmonic of the closed pipe is found to be higher by 100 Hz than the fundamental frequency of
the open pipe is
(A) 200 Hz (B) 300 Hz (C) 240 Hz (D) 480 Hz
19. P and Q are two small loud speakers which emit sound waves of the same amplitude but with a
phase difference of p. A small receiver R moves along the perpendicular bisector of PQ in the
direction away from P and Q. The intensity of the sound recorded in the receiver is :
(A) continuously decreasing tending to zero at a very large distance
(B) alternates between a constant maximum and zero minimum
(C) alternates between diminishing maximum and increasing minimum
(D) remains constant equal to zero.
20. A railway engine whistle at a constant frequency moves with a constant speed. It goes past a
stationary observer standing beside the railway track. The frequency n of the sound heard by the
observer is plotted against time t. Which of the following best represents the resulting curve?
(A) (B) (C) (D)
n n n n
t t t
t
21. Find the pressure at which temperature attains its maximum value if the relation between
pressure and volume for an ideal is P = P0  (1 - a )V 2 ;x > 1
2P0 P0 4P0
(a) (b) (c) P0 (d)
3 3 3
JEE MAINS 5
22. Three rods made of the same material and having the same cross-
section have been joined as shown in the figure. Each rod is of the
same length. The left and right ends are kept at 0ºC and 90ºC
respectively. The temperature of junction of the three rods will be :
(a) 45ºC (b) 60ºC
(c) 30ºC (d) 20ºC
23. Two bodies of masses m1 and m2 are initially at rest placed infinite distance apart. They
are then allowed to move towards each other under mutual gravitational attraction. Their
relative velocity when they are r distance apart is :
2G(m1  m2 ) 2Gm1m2 G(m1  m2 ) Gm1m2
(a) (b) (c) (d)
r (m1  m2 )r r (m1  m2 )r
24. A spherical black body of radius 12 cm radiates 450W at 500 K. If the radius is halved and
temperature doubles. The radiated power is watts will be
(A) 225 (B) 450 (D) 900 (D) 1800
25. Two rods of lengths 1 and 2 are made of material whose coefficients of linear expansions are a1
and a2. If the difference between two lengths is independent of temperature
l 1 a1 l 1 a2 a 12 a 22
(A) = (B) = (C) 21 a1 = 22 a2 (D) =
l 2 a2 l 2 a1 1 2
26. In order to calculate the speed of sound in nitrogen gas at 300 K, you are given that the gas is
diatomic. You will also need to know only the
(A) density of the gas at 300 K, and the mass of one mole of the nitrogen
(B) pressure of the gas at 300 K
(C) molecular weight of nitrogen and the universal gas constant
(D) characteristic gas constant for nitrogen
27. A horizontal tube, open at both ends, contains a column of

liquid. The length of this liquid column does not change
with temperature. Let  = coefficient of volume expansion of
the liquid and a = coefficient of linear expansion of the
material of the tube t1
(A)  = a (B)  = 2a L1
L2 t2
(C)  = 3a (D)  = 0
28. Two identical plates of metal are welded end

to end as shown in figure (A), 20 cal of heat
flows through it in 4 minutes. If the plates are
welded as shown in figure (B) the same
amount of heat will flow through the plates in: A B
(A) 1 minute (B) 2 minute
(C) 4 minute (D) 16 minute
29. A cylindrical tube of cross-section area A fitted with two

frictionless pistons. The pistons are connected to each
other by a metallic wire. Initially the temperature of gas is
T0 and its pressure is P0 which equal to atmospheric
pressure. Calculate tension in wire.
(A) P0A (B) 2P0A
P0 A
(C) zero (D)
2
JEE MAINS 6
30. A disc of radius R/2 is cut from a uniform disc of radius R as X

shown in the figure. The mass of the disc (with cavity) is M.
The moment of inertia of this disc about an axis XX¢ which
passes through the center O of the disc and is in the plane 45o
of the disc will be
7 MR 2 13MR 2
(a) (b) O
12 24
13MR 2 11MR 2
(c) (d)
48 36 X¢
SECTION – 2
CHEMISTRY
1. A balloon filled with N2O is pricked with a sharper point and quickly plunged into a tank of
CO2 under the same temperature and pressure. The balloon will
(A) be enlarged (B) be shrink
(C) remains unchanged in size (D) collapse completely
2. If the total energy of an electron in a hydrogen like atom in excited state is –3.4 eV, then
the de Broglie wavelength of the electron is
(A) 6.6 ´ 10–10 m (B) 3 ´ 10–10 m(C) 5 ´ 109 m (D) 9.3 ´ 10–12 m
3. The correct order of the increasing s-character of the orbital of B which overlaps with the
orbital of F to form B – F bonds in BF2+, BF3 and BF4- is
(A) BF2+ < BF3 < BF4- (B) BF3 < BF2+ < BF4-
+ -
(C) BF2 < BF4 < BF3 (D) BF4- < BF3 < BF2+
4. The reaction of HBr to give major product is :
CH3O
OH
will give
Br
CH 3O CH 3O
(A) (B)
OH OH
Br
Br
Br
CH3O
(C) CH 3O (D)
OH
OH
5. Solubility product constant (Ksp) of salts of types MX, MX2 and M3X at temperature ‘T’
are 4.0 ´ 10-8, 3.2 ´ 10-14 and 2.7 ´ 10-15, respectively. Solubilities (mole dm-3) of the
salts at temperature ‘T’ are in the order
(A) MX > MX2 > M3X (B) M3X > MX2 > MX
(C) MX2 > M3X > MX (D) MX > M3X > MX2
6. 0.1 M CH3COOH is titrated against 0.1 M NaOH solution. Find the difference in pH
�1 � � 1�
1- �
between � �th and � th stages of neutralization.
�n � � n�
JEE MAINS 7
(A) log (n - 1) (B) log (2n - 1) (C) 2log (n - 1) (D) log (2n - 2)
7. Predict the hybridization of boron and nitrogen atoms in the following molecule:
H
B
H N N H
H B B H
N
H
(A) sp2, sp2 (B) sp2, sp3 (C) sp, sp2 (D) sp, sp
8. The first emission line of Balmer series in H spectrum has the wave number equal to
9RH 7RH 3RH 5RH
(A) cm-1 (B) cm-1 (C) cm-1 (D) cm-1
400 144 4 36
9. The approach of the following equilibrium was observed kinetically from both directions
PtCl24-  H2 O � Pt  H2O  Cl3-  Cl-
d
- PtCl24- �
�
dt �
 -3 -1
�= 500 �10 s � � 
PtCl24- � -1 -1
�- 25 Lmol s � 
� 
Pt  H2 O  Cl3- �Cl- �
��
� �
What is the value of equilibrium constant when fourth [Cl-] is complexed?
(A) 2 × 10-2 (B) 5 × 10-3 (C) 50 (D) Data insufficient
10. Which is not aromatic?
O NH2
(A) N (B) N
N O N O
O N
(C) N (D)
N O N
11. The solubility of calomel(Hg2Cl2(s)) in water at 25oC is x moles/litre. Its solubility product
is
(A) 4x3 (B) 12x3 (C) 108x3 (D) x2
� 1 �dv ��
12. Which of the following graphs correctly represents the variation of b �
= - � ��with pressure
� v �dp �
T�
for an ideal gas at constant temperature
(a) (b) (c) (d)
b b b
b
P P P
P
13. If the value of Avogadro number (NA) be taken as 1.2 × 1023 mol-1, then the molar mass of O2 will
become
JEE MAINS 8
(a) 5 × 32 g mol-1 (b) 32 g mol-1 (c) 32 ×1.2 × 1023 g mol-1 (d) 32 ×

1.2 g mol-1
14. Correct order of dipole moment is :

OH Cl Cl
NO2 Cl
(I) (II) (III) Cl
(a) I = II = III (b) I < II < III (c) I > II > III (d) II < III < I
15. Following graph shows the variation of Ionisation Ne

potential with atomic number in second period
F
(Li ��Ne) . The value of ionization potential of Na (Z = N
11) will be : C
(a) Above Ne (b) below Ne but above O Be O
(c) Below Li (d) between N and O I.P . Li
B
3 4 5 6 7 8 9 10
Z
16. Which will give maximum yeild of Friedel Craft methylation product on the following
compound
NO 2 NH2 OH CH 3
(a) (b) (c) (d)
17. Carbon atoms in C2(CN)4 are :

(a) sp-hybridized (b) sp2-hybridized
(c) sp and sp2 hybridized (d) sp3, sp and sp2 hybridized
18. Ammonium sulphate, a common fertilizer used by gardeners is produced commercially by

passing gaseous ammonia into an aqueous solution, that is 65% H 2SO4 by mass and has density
of 1.55 gm/ml. The volume of sulphuric acid required to convert 1.00 kg NH 3 to (NH4)2SO4 is
(a) 6.8 L (b) 2.9 L (c) 6.3 L (d) 3.5 L
19. The distribution of molecular speeds for CO 2 at different temperature is given C1

Fraction of molecule
below, which of the following statement is incorrect ?

(a) It represent Maxwell’s distribution curve. C2
(b) Temperature of C2 graph is more than that of C1
(c) The average velocity of molecules in C2 graph is more than C1
1 Molecular speed
(d) Velocity � , therefore molecular mass of molecules in C1 > C2
M
20. Neelotpal is comparing Vander Waals equation with Viral equation for one mol of real gas.
� a � x y
Vander Waals equation � p 2 � (V - b) = RT Virial equation Z = 1   2  .....
� v � V V
In terms of Vander Waals constants, second coefficient of Virial equation is
8a a a
(a) (b) b - (c) (d) 3b
27Rb RT 27b2
21. Stability of trivalent and monovalent cation of group III A (boron family) will be order :
(a) Ga3+ < In3+ < Tl3+ (b) Ga3+ > In3+ > Tl3+ (c) Ga+ > In+ > Tl+ (d) None of these
JEE MAINS 9
22. Denver is trying to find heat of the following reaction H2O �� - OH  H DH = ? . Its value
will be :
(a) -13.7 kJ/mol (b) 57.5 kcal / mol (c) 13.7 kcal / mol (d) Can not be find
23. Si3O96- (having three tetrahedral) is represented as :
(a) (b)
(c) Both (A) and (B) (d) None of these
24. DH - DU for the formation of CO from its element at 298 K is :

(a) – 1238.78 J mol-1 (b) 1238.78 J mol-1 (c) – 2477.57 J mol-1 (d) 2477.57 J mol-1
25. Consider the following carbocation

 
(A) CH - CHCl - CH - CH (B) CH Cl - CH - CH - CH
3 2 2 2 2 2 2
 
(C) CH - CH - CH - CHCl (D) CH - CH - CHCl - CH
3 2 2 3 2 2
Arrange these carbocation in increasing order of stability :
(a) C < D < A < B (b) B < C < A < D (c) D < A < B < C (d) A < B < C < D
26. Arrange the following compound in there increasing acidity order :

OH OH OH OH
(A) (B) (C) (D)
F Cl Br I
(a) D < C < B < A (b) C < B < A < D (c) B < A < D < C (d) A < D < C < B
27. Identify the statement that is incorrect as far as structure of diborane is concerned
(a) There are two bridging hydrogen atoms in diborane
(b) Each boron atom forms four bonds in diborane
(c) All the hydrogen atoms are not in the same plane in diborane
(d) all b-H bonds in diborane are similar
28. Which of the following structures most closely represents an intermediate in the electrophilic
bromination of para-xylene ?
(a) (b) (c) (d)
H 3C H C H CH 3 CH 3
3 H H
Br Br Br Br
H
+ + + +
C H 3
H H 3C CH 3 CH 3
29. Basic lead carbonate is :

(a) Pb(OH)2.2PbCO3 (b) Pb(OH)2.Pb(CH3COO)2
(c) PbCO3 (d) PbCO3.Pb(OH)2
30. Graphite conducts electricity because of :
(a) weak van der Waal’s forces between layers
(b) covalent bonding between carbon atoms of layers
(c) delocalized electrons in each layer
(d) sp2 – hybridization of carbon atoms in each layer
10
JEE MAINS
SECTION – 3
MATHS
1. Maximum distance of any point on the curve 2013x2 – 4008xy + 2013y2 = 1 from origin is
(a) 2013 (b) 9 (c) 3 (d) 1/3
2. The relation R on the set A = {1, 2, 3 4, 5, 6} defined by R = {(x, y) | x, y �A and y = 2x + 1} is

(a) Reflexive (b) Symmetric (c) Transitive (d) Equivalence
�1 1 � �8 8 �
If a chord of the circle x  y - 4x - 2y - c = 0 is trisected at the points � , �and � , �, then
2 2
3.
�3 3 � �3 3 �
‘c’ equals to
(a) 10 (b) 20 (c) 40 (d) None of these
4. The expression tan55º.tan65º.tan75º simplifies to cot xº where x �(0, 90) , then x equals to :
(a) 8 (b) 10 (c) 5 (d) 9
4
� p 2p 4p 8p �
5. The value of the expression log 2 log1/ 4 �
cos .cos .cos .cos � is
� 17 17 17 17 �
(a) 17 (b) 13 (c) 8 (d) 6
tan 3 x
6. If lim = |k – 1|, then k equals to
sin 7 x
x 0
10 4 3 4 4 8 3
(A) , (B) , (C) , (D)
7 7 7 7 7 7 7
The coefficient of t50 in (1  t ) (1  t )(1  t )(1  t )(1  t ) is

2 25 25 40 45 47
7.
(A) 1 + 25C5 (B) 1 + 25C5 + 25C7 (C) 1 + 25C7 (D) none of these
  - 
7 7
8. The expression P(x) = x5 - 1  x x5 - 1 - x is polynomial of degree
(A) 16 (B) 18 (C) 20 (D) 27
9. A 1.5 m tall boy is standing at some distance from a 30 m tall building. The angle of elevation
from his eyes to the top of the building increases from 30º to 60º as he walks towards the
building, then the distance he walked towards the building is
(A) 19 m (B) 19 3 m (C) 17 m (D) 17 3 m
p p
10. - < x < and the sum to infinite number of terms of the series
2 2
2 4
cos x  cos x sin2 x  cos x sin4 x  ........ is finite, then x lies in the set
3 9
p p p p p p p
(A) - < x < (B) - < x < (C) <x< (D) 0 < x <
2 2 6 6 6 2 2
11. In a D ABC, a, b, A are given and c1, c 2 are two values of the third side c .The sum of
the areas of two triangles with sides a, b, c1 and a, b, c 2 is
1 2 1 2
(A) b sin 2A (B) a sin 2A (C) b2 sin 2A (D) none of these.
2 2
JEE MAINS 11
12. If P is any general point on x + y = 2 and A and B are respectively at (3, 5) and (6, 11), then
maximum possible value of |PA – PB| is
(a) 2 5 (b) 3 5 (c) 5 2 (d) None of these
2013
� 2 pK 2 pK �
13. The value of ��
sin
� 2014
- icos
2014 �
�
=
K =1
(a) 1 (b) – 1 (c) i (d) – i
2013 2
�n 1 �
14. If x2 + x + 1 = 0, then � �x  n �
n =1 � x �
=
(a) 0 (b) 2013 (c) 4026 (d) None of these
15. If normals drawn to y2 = 4x at (1, 2), (9, -6) and (a, b) are concurrent then a b =
(a) 0 (b) 4 (c) 8 (d) 16
16. For the hyperbola xy + 4 = 4x + 2y which of the following is not true ?

(a) x = 2 is an asymptote
(b) y = 4 is an asymptote
(c) xy + 16 = 4x + 2y is the equation of the conjugate hyperbola
(d) xy + 12 =4x + 2y is the equation of the conjugate hyperbola
17. If z �C the eccentricity of | z - (1  2i) |  | z - ( -1  2i) | = 4 is

1
(a) (b) 1 (c) 2 (d) None of these
2
18. The length of latusrectum of the parabola 25 � � (x - 1)2  (y - 4)2 �
�= (3x  4y - 4) is
2
(a) 3/5 (b) 3 (c) 6 (d) 15
19. The equation of the line

passing through the centre and bisecting the chord
x2 y2
2013x + y – 1 = 0 of the ellipse  = 1 is
1 2013
(a) x = y (b) x = 2013y (c) 2013x = y (d) x + 2013y = 0
x2 y2
20. The locus of the feet of perpendiculars from the foci on any tangent of the ellipse  = 1 is
9 4
(a) x  y = 4 (b) x  y = 9 (c) x  y = 13
2 2 2 2 2 2
(d) None of these
21. If PSQ is the focal chord of the parabola y 2 = 8x such that SP = 6. Then the length of
SQ is
(a) 6 (b) 4
(c) 3 (d) none of these
22. The equation of the circle passing through the point of intersection of the curves
(2x+3y+19) (9x+6y-17) = 0 and xy = 0 is
(a) x 2  y 2  137  63y - 303 = 0 (b) 4x 2  4y 2  137x  63y - 323 = 0
(c) 18x 2  18y 2  137x  63y - 323 = 0 (d) None of these
2
( y - 2) 2
23. The length of the common chord of the ellipse ( x - 1)  = 1 and the circle
9 4
 x - 1   y - 2  = 1.
2 2
(a) 2 (b) 3
(c) 4 (d) None of these
12
JEE MAINS
24. Eccentricity of the hyperbola whose asymptotes are given by 3x + 2y – 5 = 0 and 2x – 3y

– 5 = 0 is
3
(a) 2 (b)
2
(c) 2 (d) None of these
If all the real solutions of the equation 4 -  a - 3  2   a - 4  = 0 are non positive,

x x
25.
then
(a) 4 < a £ 5 (b) 0 < a< 4
(c) a> 4 (d) a< 3
26. If the centroid of a triangle lies at the origin and the coordinate of its two vertices are (–8,
7) and (9, 4) the area of the triangle is
95 285
(a) (b)
6 2
190
(c) (d) 285
3
27. The number of ordered triplets (a, b, c), a, b, c Î N, such that a + b + c £ 20 is

(A) less than 100 (B) less than 1000
(C) equal to 1000 (D) more than 1000
28. In a hockey tournament, a total of 153 matches were played. If each team played one
match with every other team, the total number of teams that participated in the
tournament were
(A) 20 (B) 18
(C) 16 (D) 14
29. If x = 9 is the chord of contact of the hyperbola x 2 - y 2 = 9 , then the equation of the
corresponding pair of tangent is
(A) 9x 2 - 8y 2  18x - 9 = 0 (B) 9x 2 - 8y 2 - 18x  9 = 0
(C) 9x 2 - 8y 2 - 18x - 9 = 0 (D) 9x 2 - 8y 2  18x  9 = 0
x2 y2
30. If tangent at a point on the hyperbola - = 1 cuts the axis at A and B and rectangle
a2 b 2
OAPB is completed, then locus of point P is given by (when O is the centre of the
hyperbola)
a2 b2 a2 b2
(A) 2 - 2 = 1 (B) 2  2 = 1
x y y x
a2 b2 x2 y2
(C) 2 - 2 = 1 (D)  =1
y x a 1 - b2 b 1 - a2
ANSWERS SET - A
Que. PHYSICS CHEMISTRY MATHS

No. C.Code Answer C.Code Answer C.Code Answer
1 P111010 C C111208 C M111404 D
13
JEE MAINS
2 P111012 D C110106 A C
3 P110602 A C110305 D M110804 B
4 P110717 B C111804 B M111412 C
5 P110802 C C110501 D M111416 D
6 P110502 C C110502 C M110603 A
7 P110413 A C110507 A M110410 A
8 P110310 A C110104 D M110414 A
9 P110205 A C110402 C M111311 B
10 P110301 B C111801 C M110503 A
11 P110321 C C110501 A M111502 A
12 P110505 A C111201 A M110701 B
13 P110108 A C110202 B M110307/8 C
14 P111101 B C110304 C M110307 C
15 P111029 B C110703 C M110915 D
16 P111302 D C111102 D M111123/4 C
17 P111306 D C110305 C M111001 A
18 P111309 A C111101 B M110902 C
19 P111304 D C111206 D M111010 A
20 P111313 D C111204 B M111007 B
21 P111205 A C111501 B M110910 C
22 P111221 B C111909 C M110803 C
23 P110901 A C111608 C M111024 D
24 P111222 D C111903 B M111128 A
25 P111203 B C111303 C M110109 A
26 P111303 C C111302 D M110708 B
27 P111204 C C111506 D M111218 D
28 P111221 A C111804 C M111210 B
29 P111209 C C111610 A M111110 B
30 P110707 C C111602 C M111106 A
SOLUTIONS :
PHYSICS
1. C
Apply Bernaullies theorem
14
JEE MAINS
1 2
P  r.gh  rv = const
2
2. D
acquire terminal velocity
3. A
L
�B.x .x.dx = 3L
2
x cm = 0
L
�Bx .dx 4
2
0
4. B
l 1 ml 2 2
mg (1 - fsa ) = .w
2 2 3
5. C
tN = t mg
a
mgsin . = tN
2
6. (C)
WET = w a  w f = DK - e
mgh - mmgx = 0
h 50
x= = = 250m
m 0.2
\ 250 = 41 �6  3  1
7. (A)
For C 5mg – 3kx3 = 0 � 3kx 3 = 5mg
For B 3kx 3  2mg = 2k.x 2 � 2kx 2 = 7mg
For A 2kx 2  3mg = kx1

If spring 2 is cut kx2 = 0
2mg + 3kx3 = 2maB
7 mg = 2maB
7
aB = g(�)
2
8. (A)
9. (A)
10. (B)
1 2
S = -1 - 8t  ut
2
And v = 0 at t = 2
And S = -9 at t = 2
11. (B)
12. (A)
13. (A)
14. (B)
Mass = Volume × density
M = cross-sectional area × length × density
Both the wires are of same material and same length
Therefore their
Mass � cross-sectional area.
15
JEE MAINS
AYDL
Now F=
L
F.L ( DL)1 A 2 m2 2
Or DL = Thus, = = =
A.Y ( DL)2 A1 m1 3
15. (B)
h
Potential energy must be U = mg
2
Now mass of liquid in the capillary is m = pr hr
2
2T
And from capillary rise method, we have h = …..(i)
rrg
mgh pr 2h2rg
Thus, potential energy must be U = =
2 2
Substituting the value of h from eq. (i), we get
pr 2h2rg �4T 2 � 2pT 2
U= �2 2 2 �=
2 r r g � rg
�
16. A
17. D
18. A
19. D
20. D
21. A
22. B
23. A
24. D
25. B
26. C
27. C
28. A
29. C
30. C
CHEMISTRY
1. C
Molar mass of N2O and CO2 are same.
2. A
6.626 �10 -34 �2
= = 6.6 �10 -10 m
9.9 �10 -31 �2.16 �10 6
3. D
s-charactor depends on hybridisation
4. B
OH- is more electron releasing group.
5. D
Mx3 is most soluble
6. C
1
n
pH1 = pK + log
1
1-
n
16
JEE MAINS
1
1-
pH2 = pKa  log n
1
n
pH1 – pH2 = 2log (n - 1)
7. A
Since molecule is planar
8. D
1 �1 1 � 5RH
= v = RH � - �= cm -1
 �4 9 � 36
9. C
50
K eq = = 50
500 �10 -3
10. C
No cyclic delocalisation
11. A
��
Hg2Cl2 (s) ��
�Hg2 Cl2 (aq) ��
�
2
�Hg2 (aq)  2Cl
�
-
Ksp = 4x3
12. A
13. B
Molar mass will remains same
14. C
1
Dipole moment �

15. C
Down the group ionisation potential decreases
16. D
17. C
N C C N
C C
N C C N
18. B
58.58
= 10.8 �v, v = 2.9L
2
19. D
High molar mass decreases the most probable velocity
20. B
a
Second viral coefficient = b -
RT
21. B
22. C
Enthalpy of neutralisation = -13.7 K Cal/mol
23. C
6-
With Si3 O9 , silicates can be chain or cyclic
24. B
DH - DB = DngRT
1
= �8.314 �298
2
= 1238.78 J/mol
17
JEE MAINS
25. C
Electron withdrawing groups decreases the stability of cation, but in option (c), chlorine atom
stabilises the positive charge.
26. D
Electron withdrawing group increases the acidic strength
27. D
Out of six hybdrogen atoms only 4 H-atoms are in one plane.
28. C
C H 3
H
Br
+
C H 3
29. A
30. C
MATHS
1. (D)
Put x = r cos , y = r sin 
� 2013r 2 - 2004.r 2 sin2 = 1
1
� r2 =
2013 - 2004 sin2
r is maximum, when 2013 - 2004 sin 2 is minimum.
1 1
2013 - 2004 sin2 |min. = 9 � r 2 |max = � r |max =
9 3
2. (C)
R = {(1, 3), (2, 5)}
Obviously, R is not reflexive or symmetric
R is trivially transitive.
3. B
Hint : Find a point on the circle satisfy the circle.
4. C
tan55º.tan65º.tan75º
tan75�
= tan5�
.tan(60 �-5�
).tan(60 �5�).
tan5�
tan15 � -15 �
.tan(90 � )
= = cot 5�
tan5�
\ x=5
5. D
sin 2n 
By using formula cos .cos2.cos 4.....cos 2n-1 = we get
2n sin 
4
�1 �
log 2 log1/ 4 � 2 � = log 2 8 = 6
�4 �
6. Answer A.
7. (A)
As we are interested in coefficient of t 50, we shall ignore all the term with exponent more than 50.
Thus, we can write given equation as
18
JEE MAINS
(1  25 C1t 2  .....  25 C25 t 50 ) �(1  t 25  t 40  t 45  t 47 )

As all the terms in the first expression have even exponent we can ignore t 25, t45 and t47 too. Thus,
coefficient of t50
= 25 C25  25 C5 = 1  25 C5
8. (A)
Using (a + b)7 – (a - b)7
= 2[ 7 C1a6b  7 C3 a 4b3  7 C5a2b5  7 C7b7 ],
We get P(x) = 7 C1(x 5 - 1)3 x  7 C2 (x 5 - 1)2 x 3  7 C3 (x5 - 1)x 5  7 C7 x 7
Which is a polynomial of degree 16.
9. B
We are given the height of tower (AF) = 30 m

The height of boy (BD) = 1.5 m
Therefore, AC = AF - BD = 30 -1.5 = 28.5 m
We want to find distance he walked towards the tower which is BG.
In △AGC, we have GCAC=cot60∘

⇒GC=28.5×1/√ 3/
⇒GC=9.5√ 3 m
BC
In △ABC, we have =cot30∘
AC
⇒BC=28.5×√ 3=28.5√ 3 m
BG=BC-GC =28.5√ 3−9.5√ 3=19√ 3m
Therefore, he walks 19√3 m towards the tower.
10. A
-p p
Hint: <x<
2 2
2 4
Solution: cos x  cos x sin2 x  cos x sin4 x  ......... is finite
3 9
cos x
2
1 - sin2 x
3
3 cos x
3 - 2 sin2 x
3 cos x

1  2 1 - sin2 x 
3 cos x
1  cos2 x
19
JEE MAINS
2 2
-1 < sin x < 1
3
-3 < 2 sin2 x < 3
3 3
- < sin2 x <
2 2
3
0 < sin2 x <
2
3 3
- < sin x <
2 2
always possible
p p
\ - <x<
2 2
Answer A.
11. A
1 1 1
S1  S2 = bc1 sin A  bc 2 sin A = b sin A  c1  c 2 
2 2 2
a  c1 - b
2 2 2
a  c 2 - b2
2 2
Hint : cosB = =
2ac1 2ac 2
We get c1c 2 = b - a
2 2
b2  c12 - a2 c1  c1  c 2 
cos A = = = cos A
2bc1 2bc1
 c1  c 2  = 2b cos A
1 1
D= �2b2 sin A cos A = b2 sin 2A
2 2
Answer A.
Alternate:
b 2  c 2 - a2
cos A =
2bc
C2 – 2bc cos A + b2 – a2 = 0
Quadratic in C where roots give 2 possible values of C
C1 + C2 = 2b cos A
1
Sum of areas = b sin A  C1  C2 
2
1
= b2 sin 2A
2
Answer A.
12. (B)
For any point P,PA �PA  AB �
��| PA - PB |�AB
Also, PB �PA  AB �
Equality holds if P, A and B are collinear AB = 3 5
13. (C)
2013
2pK 2013
2pK
�sin 2014 = 0 = �cos 2014
K =0 K =0
2 pK
2013
� �cos = -1
K =1 2014
20
JEE MAINS
14. (C)
If x2 + x + 1 = 0, then x = w or w 2
1 � 2, if n = 3K
xn  n = �
x �-1, if n = 3K  1, 3K  2
2
�n 1 � �4, if n = 3K
�x  n�= �
� x � �,
1 if n = 3K  1, 3K  2
15. (D)
2
If (t i ,2t i ) , i = 1, 2, 3 are conormal points, then,
t1  t 2  t 3 = 0
Here t1 = 1, t2 = -3 � t3 = 2
� a = 4, b = 4
16. (C)
(x - 2)(y - 4) = 4 is the given hyperbola
� (x - 2)(y - 4) = 0 is the equation of pair of asymptotes
� (x -2)(y - 4) = -4 is the equation of the conjugate hyperbola
17. (A)
Given is equation of an ellipse with foci at (1, 2) and (-1, 2) and length of major axis being 4.
1
� 2ae = 2 and 2a = 4 � e =
2
18. (C)
(1, 4) is the focus of the parabola, and 3x + 4y = 4 is the directrix
| 3.1  4.4 - 4 |
� 2a = = 3 � 4a = 6
5
19. (A)
If (h, k) is the mid point of 2013x + y – 1 = 0
hx ky h2 k2
�  = 
1 2013 1 2013
and 2013x + y = 1 represents the same straight line.
h k
� = �h =k
2013 2013
� Equation of line joining (0, 0) and (h, k) is x =
20. (B)
Auxiliary circle of the given ellipse is x2 + y2 = 9
21. (C)
Parabola y = 8x, SP = 6
2
a=2
1 1 2
\  =
SP SQ 2a
1 1 1
 =
6 SQ 2
\ SQ = 3
22. (C)
Any curve through the intersection of given curves is
(2x + 3y + 19) (9x + 6y – 17) + xy = 0.
For this curve to represent a circle coefficient of x 2 = coefficient of y 2 and coefficient of xy term =
0
21
JEE MAINS
� 12  27   = 0 �  = -39
\ Equation of required circle is
(2x + 3y + 19) (9x + 6y – 17) – 39xy = 0
� 18 x 2  12 xy - 34 x  27 xy  18y 2 - 51y  171x  114 y - 323 - 39 xy = 0
� 18 x 2  18 y 2  137 x  63 y - 323 = 0
23. (D)
 x - 1  y - 2
2 2
Given ellipse  = 1 and the circle

9 4
 x - 1   y - 2  = 1 both have
2 2
centre (1, 2).

It is clear that they do not intersect in real points.
\ There is no common chord.
24. (A)
3x + 2y = 5 and 2x – 3y = 5 are perpendicular each other.
So eccentricity = 2
25. (A)
4 x -  a - 3  2x   a - 4  = 0
x £ 0, Let y = 2
x
y2 -  a - 3  y   a - 4  = 0
The roots of Quadratic must lie b/w (0, 1]
 a - 3 - 4  a - 4  �0
2
(a)
a2  9 - 6a - 4a  16 �0
a2 - 10a  25 �0
aÎR
a-3
(b) 0<
�1
2
0 < a - 3 �2
0 < a �5
(c) f(0) = a – 4 > 0 a> 4
(d) f(1) = 1 – a + 3 + a – 4  0 a Î (4, 5]
26. (B)
-8  h  9 7 4k
=0 � h = -1, =0 � k = -11
3 3
-8 7 1
1 1
D= 9 4 1= � -8  4  11 - 7  9  1  1 -99  4  �
2 2� �
-1 -11 1
1
=  -15 �70 - 95 
2
1 285
=  -120 - 165  = .
2 2
27. (D)
22
JEE MAINS
a + b + c £ 20
Þ a + b + c + d = 20, a, b, c  1, d  0
Þ a1 + b1 + c1 + d = 17, a1, b1, c1, d  0
No. of solutions = 17 + 4 - 1C4-1 = 20C3 = 1140
28. (B)
Given nC2 = 153
Þ n2 – n – 306 = 0Þ n = 18.
29. Equation of chord of contact

xh + yk – 9 = 0 ….(1)
x–9=0 …..(2)
h = 1 and k = 0
pair of tangent
SS ' = T 2
x 2

- y 2 - 9  -8  =  x - 9 
2
9x 2 - 8y 2 - 18x  9 = 0
Answer B.
30. Equation of tangent
x y
sec  - tan  = 1
a b
x = 0, y = - bcot 
y = 0, x = acos 
locus of point p
a2 b 2
- =1
x2 y2
Answer A.

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FIITJEE - JEE (Mains)

PHYSICS, CHEMISTRY & MATHEMATICS

3. The test is of 3 hours duration.

Name of the Candidate (in Capital Letters) :_____________________________________

Enrolment Number :_________________________________________________________

Batch :________________________ Date of Examination : ________________________

6. Incline planes P & Q are smooth but plane surface

11. A block X slides down upon a friction less X Y

inclined plane when released from the top of the

13. The dimensional formula for latent heat is

27. A horizontal tube, open at both ends, contains a column of

28. Two identical plates of metal are welded end

29. A cylindrical tube of cross-section area A fitted with two

30. A disc of radius R/2 is cut from a uniform disc of radius R as X

4. The reaction of HBr to give major product is :

(a) (b) (c) (d)

(a) 5 × 32 g mol-1 (b) 32 g mol-1 (c) 32 ×1.2 × 1023 g mol-1 (d) 32 ×

14. Correct order of dipole moment is :

(I) (II) (III) Cl

15. Following graph shows the variation of Ionisation Ne

(a) (b) (c) (d)

17. Carbon atoms in C2(CN)4 are :

18. Ammonium sulphate, a common fertilizer used by gardeners is produced commercially by

19. The distribution of molecular speeds for CO 2 at different temperature is given C1

below, which of the following statement is incorrect ?

23. Si3O96- (having three tetrahedral) is represented as :

(c) Both (A) and (B) (d) None of these

24. DH - DU for the formation of CO from its element at 298 K is :

25. Consider the following carbocation

26. Arrange the following compound in there increasing acidity order :

(A) (B) (C) (D)

29. Basic lead carbonate is :

2. The relation R on the set A = {1, 2, 3 4, 5, 6} defined by R = {(x, y) | x, y �A and y = 2x + 1} is

The coefficient of t50 in (1  t ) (1  t )(1  t )(1  t )(1  t ) is

(a) 1 (b) – 1 (c) i (d) – i

(a) 0 (b) 2013 (c) 4026 (d) None of these

16. For the hyperbola xy + 4 = 4x + 2y which of the following is not true ?

17. If z �C the eccentricity of | z - (1  2i) |  | z - ( -1  2i) | = 4 is

(a) 3/5 (b) 3 (c) 6 (d) 15

19. The equation of the line

24. Eccentricity of the hyperbola whose asymptotes are given by 3x + 2y – 5 = 0 and 2x – 3y

If all the real solutions of the equation 4 -  a - 3  2   a - 4  = 0 are non positive,

27. The number of ordered triplets (a, b, c), a, b, c Î N, such that a + b + c £ 20 is

Que. PHYSICS CHEMISTRY MATHS

For A 2kx 2  3mg = kx1

Hint : Find a point on the circle satisfy the circle.

(1  25 C1t 2  .....  25 C25 t 50 ) �(1  t 25  t 40  t 45  t 47 )

We are given the height of tower (AF) = 30 m

We want to find distance he walked towards the tower which is BG.

In △AGC, we have GCAC=cot60∘

BG=BC-GC =28.5√ 3−9.5√ 3=19√ 3m

Therefore, he walks 19√3 m towards the tower.

Given ellipse  = 1 and the circle

centre (1, 2).

29. Equation of chord of contact

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Batch : Date of Examination :