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Handbook Bymat 1024 RS

Cleaning with Bymat 1024 RS

For removing oxide coatings on welded stainless steel parts, use the felt strip. Secure the cloth to an
electrode with an O-ring.

Be Careful: To avoid short circuits from the electrode to the work-piece,


be sure to change the band or cloth in time!

The stamp (electrode or marker) should be connected to the black cable, which should be connected
to the black connector on the 1024 RS. The red cable should extend from the red connector on the 1024
RS and clip on to the work-piece. Pour some electrolyte designed for this purpose into the wide-
necked container (for example, electrolyte A for light oxide coatings for very shiny surfaces or elctrolyte
B for oxide coatings and dull finishes). Dip the stamp in and stroke it over the oxide to be removed until
it is gone. For cleaning, the digital meter should show 24 volts. Use the turning knob to accomplish this.
Switch the switch to 1 (cleaning).

Be Careful: While using chemicals, an acid resistant apron, gloves, and protective
eyewear should be used.

The electrode is likely to overheat (become uncomfortable to hole) if used longer than a few minutes.
Drop it in water or be prepared with a second electrode. If the 1024 RS overheats, its thermal protection
will automatically turn the device off. Turn the voltage knob all the way down and then return ist to the
desired voltage.

Be Careful: Never exchange the stamp and cloth for cleaning with the stamp for marking.
This could cause blackening of your part.

Embossing with BYMAT 1024 RS


Use the flat marker for this purpose. Secure the marking felt with an O-ring. The stamp (electrode) should
be connected to the black cable, which should be connected to the black connector on the 1024 RS.
The red cable should extend from the red connector on the 1024 RS and clip on to the
work-piece. Pour some electrolyte designed for this purpose (for example ET or EC) into the
wide-necked container. For marking, the voltage should be adjusted to 12 Volts. The switch should be
set for 1 (marking dark) and 2 (light) are both acceptable settings.
Dip the felt into the electrolyte, position the template on the work-piece. Press the marker vertically from
the top allowing the entire surface of the marker to touch the template equally. Move the marker lightly
so that the electrolyte flows better through the template. Marking should be finished after approximately
2 to 4 seconds.

Markings appear different for every different material. For this reason, an entire palette of electrolytes
has been developed for marking many different kinds of metal. For the best results, it is important to
match the electrolyte to the metal (alloy) that is being marked. You will need to test different electrolytes
with different voltage settings.

Be Careful: The higher the voltage settings, the less time the template will last.

Bymat GmbH ∙ D - 41363 Jüchen ∙ Tel. +49 (0) 21 65 - 87 28 0 ∙ Fax: +49 (0) 21 65 - 87 28 28 Seite 1/2
Polishing Stainless Steel with BYMAT 1024 RS

To polish stainless steels, use a strip of the aramid band provided. Secure the strip to the stamp (electrode)
you have in mind with an O-ring.

Be Careful: To avoid short-circuits, the aramid band must be exchanged in time.

Use the stamp with the black cable, connected to the black connector on the machine. The red cable
must be connected from the red connector to the work-piece. Pour some electrolyte C into the
wide-necked container and dip the marker in. Stroke the marker a few times over the spot to be cleaned.
For polishing, the digital display should show 24 Volts. Set this with the smoothly rotating knob. Set the
switch to 2 (polishing).

Be Careful: While using chemicals, an acid resistant apron, gloves, and protective
eyewear should be used.

Over a period of time, the stamp could become to warm. Cool it in water or be prepared with a second
stamp. If the 1024 RS overheats, its thermal protection will automatically turn the device off. Wait a few
seconds and then press the reset switch in the upper left corner of the face of the machine back in if it
has come out.

Galvanizing with BYMAT 1024 RS

To plate with zinc, gold, chrome, etc. use a strip of the felt provided. Secure the strip to the marker you
have in mind.

Be careful: Make sure that the switch is set to 3 („Galvanizing/Plating“)


otherwise you will blacken your work-piece.

The stamp should be used with the black cable connected to the balck connector on the 1024 RS, and
the red cable should extend from the red connector to the work-piece. The switch should be set to 3
(Galvanizing/Plating). Dip the marker in the correct electrolyte (special elektrolytes should be chosen
from the price-list provided) and stroke the marker a few times over the part to be galvanized. The correct
voltage must be found on the label of the electrolyte. For example, gold uses 8 volts. Zinc uses 12-14
volts.

Be Careful: While using chemicals, an acid resistant apron, gloves, and protective
eyewear should be used.

We suggest using our handbook for electrochemical plating with safety hints and examples.

Caution: Do not use the device in wet rooms; protect it against moisture and splash water.

Bymat GmbH ∙ D - 41363 Jüchen ∙ Tel. +49 (0) 21 65 - 87 28 0 ∙ Fax: +49 (0) 21 65 - 87 28 28 Seite 2/2
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt A
Material no.: 2030 DH / 2035 DH

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier: Elektrolyt A


1.2 Relevant identified uses of the substance or mixture and uses advised against:
Relevant uses: Cleaner. For professional use only.
Uses advised against: All uses not specified in this section or in section 7.3
1.3 Details of the supplier of the safety data sheet: Bymat GmbH
Neusser Strasse 106
D – 41363 Jüchen / Germany
Tel.: +49 21 65 / 87 28 -0
Email: info@bymat.de
1.4 Emergency telephone number: +49 21 65 / 87 28 0

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture:


Directive 67/548/EC and Directive 1999/45/EC:
In accordance with Directive 67/548/EC and Directive 1999/45/EC, the product is not classified as dangerous.
CLP Regulation (EC) nº 1272/2008:
The product is not classified as dangerous according to CLP Regulation (EC) nº 1272/2008.
2.2 Label elements:
CLP Regulation (EC) nº 1272/2008:
Hazard statements:
Non-applicable
Precautionary statements:
Non-applicable
Supplementary information:
EUH210: Safety data sheet available on request
2.3 Other hazards:
Non-applicable

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Chemical description: Mixture composed of chemical products


Components:
In accordance with Annex II of Regulation (EC) nº1907/2006 (point 3), the product contains:
Identification Chemical name/Classification Concentration

CAS: 7664-38-2 Phosphoric Acid ATP CLP00


EC:
231-633-2 Directive 67/548/EC C: R34 2,5 - <10 %
Index:
015-011-00-6
REAC Regulation 1272/2008 Skin Corr. 1B: H314 - Danger
01-2119485924-24-XXXX
H:
To obtain more information on the risk of the substances consult sections 8, 11, 12 and 16.

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures:


The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for direct
exposure to the chemical product or persistent discomfort, showing the MSDS of this product.
By inhalation:
This product does not contain substances classified as dangerous for inhalation, however, in case of symptoms of intoxication
remove the person affected from the exposure area and provide with fresh air. Seek medical attention if the symptoms get worse or
persist.
By skin contact:

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Date of compilation: 2014-09-07 Version: 1 Page 1/8
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt A
Material no.: 2030 DH / 2035 DH

SECTION 4: FIRST AID MEASURES (continue)

This product is not classified as dangerous when in contact with the skin. However, in case of skin contact it is recommended to
remove contaminated clothes and shoes, rinse the skin or shower the person affected if necessary thoroughly with cold water and
neutral soap. In case of serious reaction consult a doctor.
By eye contact:
Rinse eyes thoroughly with water for at least 15 minutes. If the injured person uses contact lenses, these should be removed unless
they are stuck to the eyes, as this could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as
possible with the MSDS of the product.
By consumption:
Do not induce vomiting, but if it does happen keep the head up to avoid inhalation. Keep the person affected at rest. Rinse out the
mouth and throat, as they may have been affected during ingestion.
4.2 Most important symptoms and effects, both acute and delayed:
Acute and delayed effects are indicated in sections 2 and 11.
4.3 Indication of any immediate medical attention and special treatment needed:
Non-applicable

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media:


Product is non-flammable under normal conditions of storage, manipulation and use. In the case of inflammation as a result of
improper manipulation, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the
Regulation on fire protection systems. IT IS NOT RECOMMENDED to use tap water as an extinguishing agent.
5.2 Special hazards arising from the substance or mixture:
As a result of combustion or thermal decomposition reactive subproducts are created that can become highly toxic and, consequently,
can present a serious health risk.
5.3 Advice for firefighters:
Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment.
Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) in accordance with Directive
89/654/EC.
Additional provisions:
Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other
emergencies. Destroy any source of ignition. In case of fire, refrigerate the storage containers and tanks for products susceptible to
inflamation, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an
aqueous medium.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:


Isolate leaks provided that there is no additional risk for the people performing this task. Personal protection equipment must be used
against potential contact with the spilt product (See section 8). Evacuate the area and keep out those who do not have protection.

6.2 Environmental precautions:


This product is not classified as dangerous to the environment. Keep product away from drains, surface and underground water.
6.3 Methods and material for containment and cleaning up:
It is recommended:
Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible
absorbents. For any concern related to disposal consult section 13.
6.4 Reference to other sections:
See sections 8 and 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling:


A.- Precautions for safe manipulation

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Date of compilation: 2014-09-07 Version: 1 Page 2/8
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt A
Material no.: 2030 DH / 2035 DH

SECTION 7: HANDLING AND STORAGE (continue)

Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed. Control spills
and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and cleanliness
where dangerous products are used.
B.- Technical recommendations for the prevention of fires and explosions
Product is non-flammable under normal conditions of storage, manipulation and use. It is recommended to transfer at slow speeds
to avoid the generation of electrostatic charges that can affect flammable products. Consult section 10 for information on
conditions and materials that should be avoided.
C.- Technical recommendations to prevent ergonomic and toxicological risks
Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.
D.- Technical recommendations to prevent environmental risks
It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3)
7.2 Conditions for safe storage, including any incompatibilities:
A.- Technical measures for storage
Minimum Temp.: 5 ºC
Maximum Temp.: 25 ºC
Maximum time: 12 Months
B.- General conditions for storage
Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5
7.3 Specific end use(s):
Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this
product.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:


Substances whose occupational exposure limits have to be monitored in the work environment
Identification Environmental limits
Phosphoric Acid IOELV (8h) 1 mg/m³
CAS: 7664-38-2 IOELV (STEL) 2 mg/m³
EC: 231-633-2 Year 2014

DNEL (Workers):
Short exposure Long exposure

Identification Systemic Local Systemic Local

Phosphoric Acid Oral Non-applicable Non-applicable Non-applicable Non-applicable


CAS: 7664-38-2 Dermal Non-applicable Non-applicable Non-applicable Non-applicable
EC: 231-633-2 Inhalation Non-applicable 2 mg/m³ Non-applicable 1 mg/m³

DNEL (Population):
Short exposure Long exposure

Identification Systemic Local Systemic Local

Phosphoric Acid Oral Non-applicable Non-applicable Non-applicable Non-applicable


CAS: 7664-38-2 Dermal Non-applicable Non-applicable Non-applicable Non-applicable
EC: 231-633-2 Inhalation Non-applicable Non-applicable Non-applicable 0,73 mg/m³

PNEC:
Non-applicable
8.2 Exposure controls:
A.- General security and hygiene measures in the work place
As a preventative measure it is recommended to use basic Personal Protection Equipment, with the corresponding ""CE marking""
in accordance with Directive 89/686/EC. For more information on Personal Protection Equipment (storage, use, cleaning,
maintenance, class of protection,…) consult the information leaflet provided by the manufacturer. For more infomation see
subsection 7.1.
All information contained herein is a recommendation which needs some specification from the labour risk prevention services as
it is not known whether the company has additional measures at its disposal.

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Date of compilation: 2014-09-07 Version: 1 Page 3/8
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt A
Material no.: 2030 DH / 2035 DH

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continue)

B.- Respiratory protection


The use of protection equipment will be necessary if a mist forms or if the professional exposure limits are exceeded.
C.- Specific protection for the hands
Non-applicable
D.- Ocular and facial protection
Non-applicable
E.- Bodily protection
Non-applicable
F.- Additional emergency measures
It is not necessary to take additional emergency measures.

Environmental exposure controls:


In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage
of both the product and its container. For additional information see subsection 7.1.D

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties:


Appearance:
Physical state at 20 ºC: Liquid
Appearance: Characteristic
Color: Colourless
Odor: Characteristic
Volatility:
Boiling point at atmospheric pressure: Non-applicable *
Vapour pressure at 20 ºC: Non-applicable *
Vapour pressure at 50 ºC: Non-applicable *
Evaporation rate at 20 ºC: Non-applicable *
Product description:
Density at 20 ºC: Non-applicable *
Relative density at 20 ºC: 1,042-1,047
Dynamic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 40 ºC: Non-applicable *
Concentration: Non-applicable *
pH: Non-applicable *
Vapour density at 20 ºC: Non-applicable *
Partition coefficient n-octanol/water 20 ºC: Non-applicable *
Solubility in water at 20 ºC: Non-applicable *
Solubility property: Non-applicable *
Decomposition temperature: Non-applicable *
Melting point/freezing point: Non-applicable *
Flammability:
Flash Point: Non Flammable (>60 ºC)
Autoignition temperature: Non-applicable *
Lower flammability limit: Non-applicable *
*Not relevant due to the nature of the product, not providing information property of its hazards.

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Date of compilation: 2014-09-07 Version: 1 Page 4/8
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt A
Material no.: 2030 DH / 2035 DH

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continue)

Upper flammability limit: Non-applicable *


9.2 Other information:
Surface tension at 20 ºC: Non-applicable *
Refraction index: Non-applicable *
*Not relevant due to the nature of the product, not providing information property of its hazards.

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity:
No hazardous reactions are expected if the following technical instructions storage of chemicals. See section 7.
10.2 Chemical stability:
Chemically stable under the conditions of storage, handling and use.
10.3 Possibility of hazardous reactions:
Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected.
10.4 Conditions to avoid:
Applicable for handling and storage at room temperature:
Shock and friction Contact with air Increase in temperature Sunlight Humidity
Not applicable Not applicable Not applicable Not applicable Not applicable

10.5 Incompatible materials:


Acids Water Combustive materials Combustible materials Others
Not applicable Not applicable Precaution Not applicable Not applicable

10.6 Hazardous decomposition products:


See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions,
complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon monoxide and other organic compounds.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects:


The experimental information related to the toxicological properties of the product itself is not available
Dangerous health implications:
In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure limits, it
may result in adverse effects on health depending on the means of exposure:
A.- Ingestion:
Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous for
consumption. For more information see section 3.
B- Inhalation:
Based on available data, the classification criteria are not met
C- Contact with the skin and the eyes:
Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous for skin
contact. For more information see section 3.
D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for the
effects mentioned. For more information see section 3.
E- Sensitizing effects:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous with
sensibilizing effects. For more information see section 3.
F- Specific target organ toxicity (STOT)-time exposure:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this
effect. For more information see section 3.
G- Specific target organ toxicity (STOT)-repeated exposure:

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Date of compilation: 2014-09-07 Version: 1 Page 5/8
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt A
Material no.: 2030 DH / 2035 DH

SECTION 11: TOXICOLOGICAL INFORMATION (continue)

Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this
effect. For more information see section 3.
H- Aspiration hazard:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this
effect. For more information see section 3.
Other information:
Non-applicable
Specific toxicology information on the substances:
Identification Acute toxicity Genus

Phosphoric Acid LD50 oral 3500 mg/kg Rat


CAS: 7664-38-2 LD50 dermal 2470 mg/kg Rabbit
EC: 231-633-2 LC50 inhalation Non-applicable

SECTION 12: ECOLOGICAL INFORMATION

The experimental information related to the ecotoxicological properties of the product itself is not available
12.1 Toxicity:
Identification Acute toxicity Specie Genus

Phosphoric Acid LC50 Non-applicable


CAS: 7664-38-2 EC50 4,6 mg/L (12 h) Daphnia magna Crustacean
EC: 231-633-2 EC50 Non-applicable

12.2 Persistence and degradability:


Not available
12.3 Bioaccumulative potential:
Not available
12.4 Mobility in soil:
Not available
12.5 Results of PBT and vPvB assessment:
Non-applicable
12.6 Other adverse effects:
Not described

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods:


Code Description Waste class (Directive 2008/98/EC)

It is not possible to assign a specific code, as it depends on the intended use by the user.

Waste management (disposal and evaluation):


Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex 2
(Directive 2008/98/EC). As under 15 01 (2000/532/EC) of the code and in case the container has been in direct contact with the
product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-dangerous residue. We do
not recommended disposal down the drain. See paragraph 6.2.
Regulations related to waste management:
In accordance with Annex II of Regulation (EC) nº1907/2006 (REACH) the community or state provisions related to waste
management are stated
Community legislation: Directive 2008/98/EC, 2000/532/EC: Commission Decision of 3 May 2000

SECTION 14: TRANSPORT INFORMATION

This product is not regulated for transport (ADR/RID,IMDG,IATA)

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Date of compilation: 2014-09-07 Version: 1 Page 6/8
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt A
Material no.: 2030 DH / 2035 DH

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
Candidate substances for authorisation under the Regulation (EC) 1907/2006 (REACH): Non-applicable
Regulation (EC) 1005/2009, about substances that deplete the ozone layer: Non-applicable
Active substances for which a decision of non-inclusion onto Annex I (Regulation (EU) No 528/2012): Non-applicable
Regulation (EC) 649/2012, in relation to the import and export of hazardous chemical products: Non-applicable
Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII, REACH):
Non-applicable
Specific provisions in terms of protecting people or the environment:
It is recommended to use the information included in this safety data sheet as data used in a risk evaluation of the local circumstances
in order to establish the necessary risk prevention measures for the manipulation, use, storage and disposal of this product.

Other legislation:
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009, 2009 No. 716
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 (CDG 2009), SI 2009 No 1348
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment (Amendment) Regulations 2011, 2011 No. 1885
Control of Substances Hazardous to Health Regulations 2002 (as amended)
EH40/2005 Workplace exposure limits
The Waste Regulations 2011, 2011 No. 988

- Regulation (EC) No 1223/2009 of the European Parliament and of the Council of 30 November 2009 on cosmetic products
- Regulation (EC) No 648/2004 of the European Parliament and of the Council of 31 March 2004 on detergents
- Commission Regulation (EC) No 907/2006 of 20 June 2006 amending Regulation (EC) No 648/2004 of the European Parliament
and of the Council on detergents, in order to adapt Annexes III and VII
- Commission Regulation (EC) No 551/2009 of 25 June 2009 amending Regulation (EC) No 648/2004 of the European Parliament
and of the Council on detergents, in order to adapt Annexes V and VI thereto (surfactant derogation)
15.2 Chemical safety assessment:
The supplier has not carried out evaluation of chemical safety.

SECTION 16: OTHER INFORMATION

Legislation related to safety data sheets:


This safety data sheet has been designed in accordance with ANNEX II-Guide to the compilation of safety data sheets of Regulation
(EC) Nº 1907/2006 (Regulation (EC) Nº 453/2010)
Modifications related to the previous security card which concerns the ways of managing risks. :
Non-applicable
Text of R-phrases considered in section 3:
The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the individual
components which appear in section 3
Directive 67/548/EC and Directive 1999/45/EC:
R34: Causes burns
CLP Regulation (EC) nº 1272/2008:
Skin Corr. 1B: H314 - Causes severe skin burns and eye damage
Advice related to training:
Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension and
interpretation of this safety data sheet, as well as the label on the product.
Principal bibliographical sources:
http://esis.jrc.ec.europa.eu
http://echa.europa.eu
http://eur-lex.europa.eu
Abbreviations and acronyms:

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Date of compilation: 2014-09-07 Version: 1 Page 7/8
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt A
Material no.: 2030 DH / 2035 DH

SECTION 16: OTHER INFORMATION (continue)

- ADR: European agreement concerning the international carriage of dangerous goods by road
-IMDG: International maritime dangerous goods code
-IATA: International Air Transport Association
-ICAO: International Civil Aviation Organisation
-COD: Chemical Oxygen Demand
-BOD5: 5-day biochemical oxygen demand
-BCF: Bioconcentration factor
-LD50: Lethal Dose 50
-CL50: Lethal Concentration 50
-EC50: Effective concentration 50
-Log-POW: Octanol–water partition coefficient
-Koc: Partition coefficient of organic carbon

The information contained in this security data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to guarantee its accuracy.
This information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and conditions for users of
this product are not within our awareness or control, and it is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements concerning the manipulation,
storage, use and disposal of chemical products. The information on this security data sheet only refers to this product, which should not be used for needs other than those specified.

- END OF SAFETY DATA SHEET -


Date of compilation: 2014-09-07 Version: 1 Page 8/8
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt B
Material no.: 2011 DB / 2015 DB

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier: Elektrolyt B


1.2 Relevant identified uses of the substance or mixture and uses advised against:
Relevant uses: Cleaner. For professional use only.
Uses advised against: All uses not specified in this section or in section 7.3
1.3 Details of the supplier of the safety data sheet: Bymat GmbH
Neusser Strasse 106
D- 41363 Jüchen / Germany
Tel.: +49 (0) 21 65 / 87 28 – 0
Email: info@bymat.de
1.4 Emergency telephone number: +49 (0) 21 65 / 87 28 - 0

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture:


Directive 67/548/EC and Directive 1999/45/EC:
In accordance with Directive 67/548/EC and Directive 1999/45/EC, the product is not classified as dangerous.
CLP Regulation (EC) nº 1272/2008:
The product is not classified as dangerous according to CLP Regulation (EC) nº 1272/2008.
2.2 Label elements:
CLP Regulation (EC) nº 1272/2008:
Hazard statements:
Non-applicable
Precautionary statements:
Non-applicable
Supplementary information:
EUH210: Safety data sheet available on request
2.3 Other hazards:
Non-applicable

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Chemical description: Mixture composed of chemical products


Components:
In accordance with Annex II of Regulation (EC) nº1907/2006 (point 3), the product contains:
Identification Chemical name/Classification Concentration

CAS: 7664-93-9 Sulphuric acid ATP CLP00


EC:
231-639-5 Directive 67/548/EC C: R35 2,5 - <10 %
Index:
016-020-00-8
REAC Regulation 1272/2008 Skin Corr. 1A: H314 - Danger
01-2119458838-20-XXXX
H:
To obtain more information on the risk of the substances consult sections 8, 11, 12 and 16.

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures:


The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for direct
exposure to the chemical product or persistent discomfort, showing the MSDS of this product.
By inhalation:
This product does not contain substances classified as dangerous for inhalation, however, in case of symptoms of intoxication
remove the person affected from the exposure area and provide with fresh air. Seek medical attention if the symptoms get worse or
persist.
By skin contact:

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Date of compilation: 2014-09-10 Version: 1 Page 1/8
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt B
Material no.: 2011 DB / 2015 DB

SECTION 4: FIRST AID MEASURES (continue)

This product is not classified as dangerous when in contact with the skin. However, in case of skin contact it is recommended to
remove contaminated clothes and shoes, rinse the skin or shower the person affected if necessary thoroughly with cold water and
neutral soap. In case of serious reaction consult a doctor.
By eye contact:
Rinse eyes thoroughly with water for at least 15 minutes. If the injured person uses contact lenses, these should be removed unless
they are stuck to the eyes, as this could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as
possible with the MSDS of the product.
By consumption:
Do not induce vomiting, but if it does happen keep the head up to avoid inhalation. Keep the person affected at rest. Rinse out the
mouth and throat, as they may have been affected during ingestion.
4.2 Most important symptoms and effects, both acute and delayed:
Acute and delayed effects are indicated in sections 2 and 11.
4.3 Indication of any immediate medical attention and special treatment needed:
Non-applicable

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media:


Product is non-flammable under normal conditions of storage, manipulation and use. In the case of inflammation as a result of
improper manipulation, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the
Regulation on fire protection systems. IT IS NOT RECOMMENDED to use tap water as an extinguishing agent.
5.2 Special hazards arising from the substance or mixture:
As a result of combustion or thermal decomposition reactive subproducts are created that can become highly toxic and, consequently,
can present a serious health risk.
5.3 Advice for firefighters:
Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment.
Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) in accordance with Directive
89/654/EC.
Additional provisions:
Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other
emergencies. Destroy any source of ignition. In case of fire, refrigerate the storage containers and tanks for products susceptible to
inflamation, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an
aqueous medium.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:


Isolate leaks provided that there is no additional risk for the people performing this task. Personal protection equipment must be used
against potential contact with the spilt product (See section 8). Evacuate the area and keep out those who do not have protection.

6.2 Environmental precautions:


This product is not classified as dangerous to the environment. Keep product away from drains, surface and underground water.
6.3 Methods and material for containment and cleaning up:
It is recommended:
Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible
absorbents. For any concern related to disposal consult section 13.
6.4 Reference to other sections:
See sections 8 and 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling:


A.- Precautions for safe manipulation

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According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt B
Material no.: 2011 DB / 2015 DB

SECTION 7: HANDLING AND STORAGE (continue)

Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed. Control spills
and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and cleanliness
where dangerous products are used.
B.- Technical recommendations for the prevention of fires and explosions
Product is non-flammable under normal conditions of storage, manipulation and use. It is recommended to transfer at slow speeds
to avoid the generation of electrostatic charges that can affect flammable products. Consult section 10 for information on
conditions and materials that should be avoided.
C.- Technical recommendations to prevent ergonomic and toxicological risks
Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.
D.- Technical recommendations to prevent environmental risks
It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3)
7.2 Conditions for safe storage, including any incompatibilities:
A.- Technical measures for storage
Minimum Temp.: 5 ºC
Maximun Temp.: 25 ºC
Maximum time: 12 Months
B.- General conditions for storage
Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5
7.3 Specific end use(s):
Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this
product.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:


Substances whose occupational exposure limits have to be monitored in the work environment
Identification Environmental limits
Sulphuric acid IOELV (8h) 0,05 mg/m³
CAS: 7664-93-9 IOELV (STEL)
EC: 231-639-5 Year 2014

DNEL (Workers):
Short exposure Long exposure

Identification Systemic Local Systemic Local

Sulphuric acid Oral Non-applicable Non-applicable Non-applicable Non-applicable


CAS: 7664-93-9 Dermal Non-applicable Non-applicable Non-applicable Non-applicable
EC: 231-639-5 Inhalation Non-applicable 0,1 mg/m³ Non-applicable 0,05 mg/m³

DNEL (Population):
Non-applicable
PNEC:
Identification

Sulphuric acid STP 8,8 mg/L Fresh water 0,0025 mg/L


CAS: 7664-93-9 Soil Non-applicable Marine water 0,00025 mg/L
EC: 231-639-5 Intermittent Non-applicable Sediment (Fresh water) 0,002 mg/kg
Oral Non-applicable Sediment (Marine water) 0,002 mg/kg

8.2 Exposure controls:


A.- General security and hygiene measures in the work place
As a preventative measure it is recommended to use basic Personal Protection Equipment, with the corresponding ""CE marking""
in accordance with Directive 89/686/EC. For more information on Personal Protection Equipment (storage, use, cleaning,
maintenance, class of protection,…) consult the information leaflet provided by the manufacturer. For more infomation see
subsection 7.1.
All information contained herein is a recommendation which needs some specification from the labour risk prevention services as
it is not known whether the company has additional measures at its disposal.

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According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt B
Material no.: 2011 DB / 2015 DB

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continue)

B.- Respiratory protection


The use of protection equipment will be necessary if a mist forms or if the professional exposure limits are exceeded.
C.- Specific protection for the hands
Non-applicable
D.- Ocular and facial protection
Non-applicable
E.- Bodily protection
Non-applicable
F.- Additional emergency measures
It is not necessary to take additional emergency measures.

Environmental exposure controls:


In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage
of both the product and its container. For additional information see subsection 7.1.D

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties:


Appearance:
Physical state at 20 ºC: Liquid
Appearance: Characteristic
Color: Colourless
Odor: Characteristic
Volatility:
Boiling point at atmospheric pressure: Non-applicable *
Vapour pressure at 20 ºC: Non-applicable *
Vapour pressure at 50 ºC: Non-applicable *
Evaporation rate at 20 ºC: Non-applicable *
Product description:
Density at 20 ºC: Non-applicable *
Relative density at 20 ºC: 1,020-1,025
Dynamic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 40 ºC: Non-applicable *
Concentration: Non-applicable *
pH: Non-applicable *
Vapour density at 20 ºC: Non-applicable *
Partition coefficient n-octanol/water 20 ºC: Non-applicable *
Solubility in water at 20 ºC: Non-applicable *
Solubility property: Non-applicable *
Decomposition temperature: Non-applicable *
Melting point/freezing point: Non-applicable *
Flammability:
Flash Point: Non Flammable (>60 ºC)
Autoignition temperature: Non-applicable *
Lower flammability limit: Non-applicable *
*Not relevant due to the nature of the product, not providing information property of its hazards.

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Elektrolyt B
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continue)

Upper flammability limit: Non-applicable *


9.2 Other information:
Surface tension at 20 ºC: Non-applicable *
Refraction index: Non-applicable *
*Not relevant due to the nature of the product, not providing information property of its hazards.

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity:
No hazardous reactions are expected if the following technical instructions storage of chemicals. See section 7.
10.2 Chemical stability:
Chemically stable under the conditions of storage, handling and use.
10.3 Possibility of hazardous reactions:
Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected.
10.4 Conditions to avoid:
Applicable for handling and storage at room temperature:
Shock and friction Contact with air Increase in temperature Sunlight Humidity
Not applicable Not applicable Not applicable Not applicable Not applicable

10.5 Incompatible materials:


Acids Water Combustive materials Combustible materials Others
Not applicable Not applicable Precaution Not applicable Not applicable

10.6 Hazardous decomposition products:


See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions,
complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon monoxide and other organic compounds.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects:


The experimental information related to the toxicological properties of the product itself is not available
Dangerous health implications:
In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure limits, it
may result in adverse effects on health depending on the means of exposure:
A.- Ingestion:
Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous for
consumption. For more information see section 3.
B- Inhalation:
Based on available data, the classification criteria are not met
C- Contact with the skin and the eyes:
Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous for skin
contact. For more information see section 3.
D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for the
effects mentioned. For more information see section 3.
E- Sensitizing effects:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous with
sensibilizing effects. For more information see section 3.
F- Specific target organ toxicity (STOT)-time exposure:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this
effect. For more information see section 3.
G- Specific target organ toxicity (STOT)-repeated exposure:

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Elektrolyt B
Material no.: 2011 DB / 2015 DB

SECTION 11: TOXICOLOGICAL INFORMATION (continue)

Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this
effect. For more information see section 3.
H- Aspiration hazard:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this
effect. For more information see section 3.
Other information:
Non-applicable
Specific toxicology information on the substances:
Identification Acute toxicity Genus

Sulphuric acid LD50 oral 2140 mg/kg Rat


CAS: 7664-93-9 LD50 dermal Non-applicable
EC: 231-639-5 LC50 inhalation 510 mg/L (4 h) Rat

SECTION 12: ECOLOGICAL INFORMATION

The experimental information related to the ecotoxicological properties of the product itself is not available
12.1 Toxicity:
Not available
12.2 Persistence and degradability:
Not available
12.3 Bioaccumulative potential:
Not available
12.4 Mobility in soil:
Not available
12.5 Results of PBT and vPvB assessment:
Non-applicable
12.6 Other adverse effects:
Not described

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods:


Code Description Waste class (Directive 2008/98/EC)

It is not possible to assign a specific code, as it depends on the intended use by the user.
Waste management (disposal and evaluation):
Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex 2
(Directive 2008/98/EC). As under 15 01 (2000/532/EC) of the code and in case the container has been in direct contact with the
product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-dangerous residue. We do
not recommended disposal down the drain. See paragraph 6.2.
Regulations related to waste management:
In accordance with Annex II of Regulation (EC) nº1907/2006 (REACH) the community or state provisions related to waste
management are stated
Community legislation: Directive 2008/98/EC, 2000/532/EC: Commission Decision of 3 May 2000

SECTION 14: TRANSPORT INFORMATION

This product is not regulated for transport (ADR/RID,IMDG,IATA)

SECTION 15: REGULATORY INFORMATION

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Elektrolyt B
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SECTION 15: REGULATORY INFORMATION (continue)

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
Candidate substances for authorisation under the Regulation (EC) 1907/2006 (REACH): Non-applicable
Regulation (EC) 1005/2009, about substances that deplete the ozone layer: Non-applicable
Active substances for which a decision of non-inclusion onto Annex I (Regulation (EU) No 528/2012): Non-applicable
Regulation (EC) 649/2012, in relation to the import and export of hazardous chemical products: Non-applicable
Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII, REACH):
Non-applicable
Specific provisions in terms of protecting people or the environment:
It is recommended to use the information included in this safety data sheet as data used in a risk evaluation of the local circumstances
in order to establish the necessary risk prevention measures for the manipulation, use, storage and disposal of this product.

Other legislation:
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009, 2009 No. 716
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 (CDG 2009), SI 2009 No 1348
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment (Amendment) Regulations 2011, 2011 No. 1885
Control of Substances Hazardous to Health Regulations 2002 (as amended)
EH40/2005 Workplace exposure limits
The Waste Regulations 2011, 2011 No. 988

- Regulation (EC) No 1223/2009 of the European Parliament and of the Council of 30 November 2009 on cosmetic products
- Regulation (EC) No 648/2004 of the European Parliament and of the Council of 31 March 2004 on detergents
- Commission Regulation (EC) No 907/2006 of 20 June 2006 amending Regulation (EC) No 648/2004 of the European Parliament
and of the Council on detergents, in order to adapt Annexes III and VII
- Commission Regulation (EC) No 551/2009 of 25 June 2009 amending Regulation (EC) No 648/2004 of the European Parliament
and of the Council on detergents, in order to adapt Annexes V and VI thereto (surfactant derogation)
15.2 Chemical safety assessment:
The supplier has not carried out evaluation of chemical safety.

SECTION 16: OTHER INFORMATION

Legislation related to safety data sheets:


This safety data sheet has been designed in accordance with ANNEX II-Guide to the compilation of safety data sheets of Regulation
(EC) Nº 1907/2006 (Regulation (EC) Nº 453/2010)
Modifications related to the previous security card which concerns the ways of managing risks. :
Non-applicable
Text of R-phrases considered in section 3:
The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the individual
components which appear in section 3
Directive 67/548/EC and Directive 1999/45/EC:
R35: Causes severe burns
CLP Regulation (EC) nº 1272/2008:
Skin Corr. 1A: H314 - Causes severe skin burns and eye damage
Advice related to training:
Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension and
interpretation of this safety data sheet, as well as the label on the product.
Principal bibliographical sources:
http://esis.jrc.ec.europa.eu
http://echa.europa.eu
http://eur-lex.europa.eu
Abbreviations and acronyms:

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Elektrolyt B
Material no.: 2011 DB / 2015 DB

SECTION 16: OTHER INFORMATION (continue)

- ADR: European agreement concerning the international carriage of dangerous goods by road
-IMDG: International maritime dangerous goods code
-IATA: International Air Transport Association
-ICAO: International Civil Aviation Organisation
-COD: Chemical Oxygen Demand
-BOD5: 5-day biochemical oxygen demand
-BCF: Bioconcentration factor
-LD50: Lethal Dose 50
-CL50: Lethal Concentration 50
-EC50: Effective concentration 50
-Log-POW: Octanol–water partition coefficient
-Koc: Partition coefficient of organic carbon

The information contained in this security data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to guarantee its accuracy.
This information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and conditions for users of
this product are not within our awareness or control, and it is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements concerning the manipulation,
storage, use and disposal of chemical products. The information on this security data sheet only refers to this product, which should not be used for needs other than those specified.

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According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt C
Material no.: 2020 DC / 2021 DC / 2025 DC

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier: Elektrolyt C


1.2 Relevant identified uses of the substance or mixture and uses advised against:
Relevant uses: Cleaner. For professional use only.
Uses advised against: All uses not specified in this section or in section 7.3
1.3 Details of the supplier of the safety data sheet: Bymat GmbH
Neusser Strasse 106
D -41363 Jüchen Germany
Tel.: +49 (0) 21 65 / 87 28 0
Email: info@bymat.de
1.4 Emergency telephone number: +49 (0) 21 65 / 87 28 0

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture:


Directive 67/548/EC and Directive 1999/45/EC:
This product was classified in accordance with Directive 67/548/EC and Directive 1999/45/EC, adapting the requirements to
Regulation (EC) nº1907/2006 (REACH regulation).
C: R34 - Causes burns
CLP Regulation (EC) nº 1272/2008:
Classification of this product has been carried out in accordance with CLP Regulation (EC) nº 1272/2008.
Eye Dam. 1: Serious eye damage, Category 1
Skin Corr. 1B: Skin corrosion, Category 1B
2.2 Label elements:
CLP Regulation (EC) nº 1272/2008:
Danger

Hazard statements:
Skin Corr. 1B: H314 - Causes severe skin burns and eye damage
Precautionary statements:
P280: Wear protective gloves/protective clothing/eye protection/face protection
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing
P310: Immediately call a POISON CENTER or doctor/physician
Supplementary information:
Non-applicable
Substances that contribute to the classification
Phosphoric Acid
2.3 Other hazards:
Non-applicable

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Chemical description: Mixture composed of chemical products


Components:
In accordance with Annex II of Regulation (EC) nº1907/2006 (point 3), the product contains:

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Elektrolyt C
Material no.: 2020 DC / 2021 DC / 2025 DC

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS (continue)

Identification Chemical name/Classification Concentration


CAS: Phosphoric Acid ATP CLP00
7664-38-2
EC:
231-633-2 Directive 67/548/EC C: R34 25 - <50 %
Index:
015-011-00-6
REAC Regulation 1272/2008 Skin Corr. 1B: H314 - Danger
01-2119485924-24-XXXX
H:
To obtain more information on the risk of the substances consult sections 8, 11, 12 and 16.

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures:


Request medical assistance immediately, showing the MSDS of this product.
By inhalation:
This product does not contain substances classified as dangerous for inhalation, however, in case of symptoms of intoxication
remove the person affected from the exposure area and provide with fresh air. Seek medical attention if the symptoms get worse or
persist.
By skin contact:
Remove contaminated clothing and footwear, rinse skin or shower the person affected if appropriate with plenty of cold water and
neutral soap. In serious cases see a doctor. If the product causes burns or freezing, clothing should not be removed as this could
worsen the injury caused if it is stuck to the skin. If blisters form on the skin, these should never be burst as this will increase the risk
of infection.
By eye contact:
Rinse eyes thoroughly with luke warm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes. If the
injured person uses contact lenses, these should be removed unless they are stuck to the eyes, as this could cause further damage.
In all cases, after cleaning, a doctor should be consulted as quickly as possible with the MSDS of the product.
By consumption:
Request immediate medical assistance, showing the MSDS of this product. Do not induce vomiting, because its expulsion from the
stomach can be hazardous to the mucus of the main digestive tract, and its inhalation, to the respiratory system. Rinse out the mouth
and throat, as they may have been affected during ingestion. In the case of loss of consciousness do not administrate anything orally
unless supervised by a doctor. Keep the person affected at rest.
4.2 Most important symptoms and effects, both acute and delayed:
Acute and delayed effects are indicated in sections 2 and 11.
4.3 Indication of any immediate medical attention and special treatment needed:
Non-applicable

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media:


Product is non-flammable under normal conditions of storage, manipulation and use. In the case of inflammation as a result of
improper manipulation, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the
Regulation on fire protection systems. IT IS NOT RECOMMENDED to use tap water as an extinguishing agent.
5.2 Special hazards arising from the substance or mixture:
As a result of combustion or thermal decomposition reactive subproducts are created that can become highly toxic and, consequently,
can present a serious health risk.
5.3 Advice for firefighters:
Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment.
Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) in accordance with Directive
89/654/EC.
Additional provisions:
Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other
emergencies. Destroy any source of ignition. In case of fire, refrigerate the storage containers and tanks for products susceptible to
inflamation, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an
aqueous medium.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:

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Elektrolyt C
Material no.: 2020 DC / 2021 DC / 2025 DC

SECTION 6: ACCIDENTAL RELEASE MEASURES (continue)

Isolate leaks provided that there is no additional risk for the people performing this task. Personal protection equipment must be used
against potential contact with the spilt product (See section 8). Evacuate the area and keep out those who do not have protection.

6.2 Environmental precautions:


This product is not classified as dangerous to the environment. Keep product away from drains, surface and underground water.
6.3 Methods and material for containment and cleaning up:
It is recommended:
Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible
absorbents. For any concern related to disposal consult section 13.
6.4 Reference to other sections:
See sections 8 and 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling:


A.- Precautions for safe manipulation
Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed. Control spills
and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and cleanliness
where dangerous products are used.
B.- Technical recommendations for the prevention of fires and explosions
Product is non-flammable under normal conditions of storage, manipulation and use. It is recommended to transfer at slow speeds
to avoid the generation of electrostatic charges that can affect flammable products. Consult section 10 for information on
conditions and materials that should be avoided.
C.- Technical recommendations to prevent ergonomic and toxicological risks
Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.
D.- Technical recommendations to prevent environmental risks
It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3)
7.2 Conditions for safe storage, including any incompatibilities:
A.- Technical measures for storage
Minimum Temp.: 5 ºC
Maximun Temp.: 25 ºC
Maximum time: 12 Months
B.- General conditions for storage
Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5
7.3 Specific end use(s):
Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this
product.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:


Substances whose occupational exposure limits have to be monitored in the work environment
Identification Environmental limits
Phosphoric Acid IOELV (8h) 1 mg/m³
CAS: 7664-38-2 IOELV (STEL) 2 mg/m³
EC: 231-633-2 Year 2014
DNEL (Workers):
Short exposure Long exposure

Identification Systemic Local Systemic Local

Phosphoric Acid Oral Non-applicable Non-applicable Non-applicable Non-applicable


CAS: 7664-38-2 Dermal Non-applicable Non-applicable Non-applicable Non-applicable
EC: 231-633-2 Inhalation Non-applicable 2 mg/m³ Non-applicable 1 mg/m³

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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continue)

DNEL (Population):
Short exposure Long exposure

Identification Systemic Local Systemic Local

Phosphoric Acid Oral Non-applicable Non-applicable Non-applicable Non-applicable


CAS: 7664-38-2 Dermal Non-applicable Non-applicable Non-applicable Non-applicable
EC: 231-633-2 Inhalation Non-applicable Non-applicable Non-applicable 0,73 mg/m³

PNEC:
Non-applicable
8.2 Exposure controls:
A.- General security and hygiene measures in the work place
As a preventative measure it is recommended to use basic Personal Protection Equipment, with the corresponding ""CE marking""
in accordance with Directive 89/686/EC. For more information on Personal Protection Equipment (storage, use, cleaning,
maintenance, class of protection,…) consult the information leaflet provided by the manufacturer. For more infomation see
subsection 7.1.
All information contained herein is a recommendation which needs some specification from the labour risk prevention services as
it is not known whether the company has additional measures at its disposal.
B.- Respiratory protection
The use of protection equipment will be necessary if a mist forms or if the professional exposure limits are exceeded.
C.- Specific protection for the hands
Pictogram PPE Labelling CEN Standard Remarks

Chemical protective gloves EN 374-1:2003 Replace the gloves at any sign of deterioration.
EN 374-3:2003/AC:2006
EN 420:2003+A1:2009

Mandatory hand
protection
D.- Ocular and facial protection
Pictogram PPE Labelling CEN Standard Remarks

Panoramic glasses against EN 166:2001 Clean daily and disinfect periodically according to the
liquid splash EN 172:1994/A1:2000 manufacturer´s instructions. Use if there is a risk of
EN 172:1994/A2:2001 splashing.
EN ISO 4007:2012
Mandatory face
protection
E.- Bodily protection
Pictogram PPE Labelling CEN Standard Remarks

Work clothing EN ISO 13688:2013 For professional use only.

Anti-slip work shoes EN ISO 20347:2012 None


EN ISO 20344:2011

F.- Additional emergency measures


Emergency measure Standards Emergency measure Standards

ANSI Z358-1 DIN 12 899


ISO 3864-1:2002 ISO 3864-1:2002

Emergency shower Eyewash stations

Environmental exposure controls:


In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage
of both the product and its container. For additional information see subsection 7.1.D

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Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt C
Material no.: 2020 DC / 2021 DC / 2025 DC

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties:


Appearance:
Physical state at 20 ºC: Liquid
Appearance: Characteristic
Color: Colourless
Odor: Characteristic
Volatility:
Boiling point at atmospheric pressure: 100 ºC
Vapour pressure at 20 ºC: Non-applicable *
Vapour pressure at 50 ºC: Non-applicable *
Evaporation rate at 20 ºC: Non-applicable *
Product description:
Density at 20 ºC: Non-applicable *
Relative density at 20 ºC: 1,290 - 1,295
Dynamic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 40 ºC: Non-applicable *
Concentration: Non-applicable *
pH: Non-applicable *
Vapour density at 20 ºC: Non-applicable *
Partition coefficient n-octanol/water 20 ºC: Non-applicable *
Solubility in water at 20 ºC: Non-applicable *
Solubility property: Non-applicable *
Decomposition temperature: Non-applicable *
Melting point/freezing point: Non-applicable *
Flammability:
Flash Point: Non Flammable (>60 ºC)
Autoignition temperature: Non-applicable *
Lower flammability limit: Non-applicable *
Upper flammability limit: Non-applicable *
9.2 Other information:
Surface tension at 20 ºC: Non-applicable *
Refraction index: Non-applicable *
*Not relevant due to the nature of the product, not providing information property of its hazards.

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity:
No hazardous reactions are expected if the following technical instructions storage of chemicals. See section 7.
10.2 Chemical stability:
Chemically stable under the conditions of storage, handling and use.
10.3 Possibility of hazardous reactions:
Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected.
10.4 Conditions to avoid:
Applicable for handling and storage at room temperature:
Shock and friction Contact with air Increase in temperature Sunlight Humidity
Not applicable Not applicable Not applicable Not applicable Not applicable

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According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt C
Material no.: 2020 DC / 2021 DC / 2025 DC

SECTION 10: STABILITY AND REACTIVITY (continue)

10.5 Incompatible materials:


Acids Water Combustive materials Combustible materials Others
Not applicable Not applicable Precaution Not applicable Not applicable

10.6 Hazardous decomposition products:


See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions,
complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon monoxide and other organic compounds.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects:


No experimental information is available on the product itself in relation to the toxicological properties. When performing the danger
classification on corrosive or irritant effects the recommendations included in section 3.2.5 of Annex VI of Directive 67/548/EC, in
paragraphs b) and c) of section 3 of article 6 of Directive 1999/45/EC and in section 3.2.3.3.5. of Annex I of CLP Regulation were
taken into account.
Dangerous health implications:
In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure limits, it
may result in adverse effects on health depending on the means of exposure:
A.- Ingestion:
Corrosive product, its consumption causes burns destroying the full thickness of fabrics. For more information on the secondary
effects of contact with the skin see section 2.
B- Inhalation:
Prolonged inhalation of the product is corrosive to mucous membranes and the upper respiratory tract
C- Contact with the skin and the eyes:
Above all, skin contact may occur as fabrics of all thicknesses can be destroyed, resulting in burns. For more information on the
secondary effects see section 2.
D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for the
effects mentioned. For more information see section 3.
E- Sensitizing effects:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous with
sensibilizing effects. For more information see section 3.
F- Specific target organ toxicity (STOT)-time exposure:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this
effect. For more information see section 3.
G- Specific target organ toxicity (STOT)-repeated exposure:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this
effect. For more information see section 3.
H- Aspiration hazard:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this
effect. For more information see section 3.
Other information:
Non-applicable
Specific toxicology information on the substances:
Identification Acute toxicity Genus

Phosphoric Acid LD50 oral 3500 mg/kg Rat


CAS: 7664-38-2 LD50 dermal 2470 mg/kg Rabbit
EC: 231-633-2 LC50 inhalation Non-applicable

SECTION 12: ECOLOGICAL INFORMATION

The experimental information related to the ecotoxicological properties of the product itself is not available
12.1 Toxicity:

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According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt C
Material no.: 2020 DC / 2021 DC / 2025 DC

SECTION 12: ECOLOGICAL INFORMATION (continue)

Identification Acute toxicity Specie Genus

Phosphoric Acid LC50 Non-applicable


CAS: 7664-38-2 EC50 4,6 mg/L (12 h) Daphnia magna Crustacean
EC: 231-633-2 EC50 Non-applicable

12.2 Persistence and degradability:


Not available
12.3 Bioaccumulative potential:
Not available
12.4 Mobility in soil:
Not available
12.5 Results of PBT and vPvB assessment:
Non-applicable
12.6 Other adverse effects:
Not described

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods:


Code Description Waste class (Directive 2008/98/EC)

It is not possible to assign a specific code, as it depends on the intended use by the user.
Waste management (disposal and evaluation):
Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex 2
(Directive 2008/98/EC). As under 15 01 (2000/532/EC) of the code and in case the container has been in direct contact with the
product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-dangerous residue. We do
not recommended disposal down the drain. See paragraph 6.2.
Regulations related to waste management:
In accordance with Annex II of Regulation (EC) nº1907/2006 (REACH) the community or state provisions related to waste
management are stated
Community legislation: Directive 2008/98/EC, 2000/532/EC: Commission Decision of 3 May 2000

SECTION 14: TRANSPORT INFORMATION

Transport of dangerous goods by land:


With regard to ADR 2013 and RID 2013:
14.1 UN number: UN1805
14.2 UN proper shipping name: PHOSPHORIC ACID, SOLUTION
14.3 Transport hazard class(es): 8
Labels: 8
14.4 Packing group: III
14.5 Dangerous for the environment: No

14.6 Special precautions for user


Special regulations: Non-applicable
Tunnel restriction code: E
Physico-Chemical properties: see section 9
Limited quantities: 5L
14.7 Transport in bulk according to Non-applicable
Annex II of MARPOL 73/78 and
the IBC Code:
Transport of dangerous goods by sea:
With regard to IMDG 36-12:

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According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt C
Material no.: 2020 DC / 2021 DC / 2025 DC

SECTION 14: TRANSPORT INFORMATION (continue)

14.1 UN number: UN1805


14.2 UN proper shipping name: PHOSPHORIC ACID, SOLUTION
14.3 Transport hazard class(es): 8
Labels: 8
14.4 Packing group: III
14.5 Dangerous for the environment: No

14.6 Special precautions for user


Special regulations: 223
EmS Codes: F-A, S-B
Physico-Chemical properties: see section 9
Limited quantities: 5L
14.7 Transport in bulk according to Non-applicable
Annex II of MARPOL 73/78 and
the IBC Code:
Transport of dangerous goods by air:
With regard to IATA/ICAO 2014:
14.1 UN number: UN1805
14.2 UN proper shipping name: PHOSPHORIC ACID, SOLUTION
14.3 Transport hazard class(es): 8
Labels: 8
14.4 Packing group: III
14.5 Dangerous for the environment: No

14.6 Special precautions for user


Physico-Chemical properties: see section 9
14.7 Transport in bulk according to Non-applicable
Annex II of MARPOL 73/78 and
the IBC Code:

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
Candidate substances for authorisation under the Regulation (EC) 1907/2006 (REACH): Non-applicable
Regulation (EC) 1005/2009, about substances that deplete the ozone layer: Non-applicable
Active substances for which a decision of non-inclusion onto Annex I (Regulation (EU) No 528/2012): Non-applicable
Regulation (EC) 649/2012, in relation to the import and export of hazardous chemical products: Non-applicable
Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII, REACH):
Non-applicable
Specific provisions in terms of protecting people or the environment:
It is recommended to use the information included in this safety data sheet as data used in a risk evaluation of the local circumstances
in order to establish the necessary risk prevention measures for the manipulation, use, storage and disposal of this product.

Other legislation:
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009, 2009 No. 716
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 (CDG 2009), SI 2009 No 1348
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment (Amendment) Regulations 2011, 2011 No. 1885
Control of Substances Hazardous to Health Regulations 2002 (as amended)
EH40/2005 Workplace exposure limits
The Waste Regulations 2011, 2011 No. 988

- Regulation (EC) No 1223/2009 of the European Parliament and of the Council of 30 November 2009 on cosmetic products
- Regulation (EC) No 648/2004 of the European Parliament and of the Council of 31 March 2004 on detergents
- Commission Regulation (EC) No 907/2006 of 20 June 2006 amending Regulation (EC) No 648/2004 of the European Parliament
and of the Council on detergents, in order to adapt Annexes III and VII
- Commission Regulation (EC) No 551/2009 of 25 June 2009 amending Regulation (EC) No 648/2004 of the European Parliament
and of the Council on detergents, in order to adapt Annexes V and VI thereto (surfactant derogation)

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Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

Elektrolyt C
Material no.: 2020 DC / 2021 DC / 2025 DC

SECTION 15: REGULATORY INFORMATION (continue)

15.2 Chemical safety assessment:


The supplier has not carried out evaluation of chemical safety.

SECTION 16: OTHER INFORMATION

Legislation related to safety data sheets:


This safety data sheet has been designed in accordance with ANNEX II-Guide to the compilation of safety data sheets of Regulation
(EC) Nº 1907/2006 (Regulation (EC) Nº 453/2010)
Modifications related to the previous security card which concerns the ways of managing risks. :
Non-applicable
Text of R-phrases considered in section 3:
The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the individual
components which appear in section 3
Directive 67/548/EC and Directive 1999/45/EC:
R34: Causes burns
CLP Regulation (EC) nº 1272/2008:
Skin Corr. 1B: H314 - Causes severe skin burns and eye damage
Advice related to training:
Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension and
interpretation of this safety data sheet, as well as the label on the product.
Principal bibliographical sources:
http://esis.jrc.ec.europa.eu
http://echa.europa.eu
http://eur-lex.europa.eu
Abbreviations and acronyms:
- ADR: European agreement concerning the international carriage of dangerous goods by road
-IMDG: International maritime dangerous goods code
-IATA: International Air Transport Association
-ICAO: International Civil Aviation Organisation
-COD: Chemical Oxygen Demand
-BOD5: 5-day biochemical oxygen demand
-BCF: Bioconcentration factor
-LD50: Lethal Dose 50
-CL50: Lethal Concentration 50
-EC50: Effective concentration 50
-Log-POW: Octanol–water partition coefficient
-Koc: Partition coefficient of organic carbon

The information contained in this security data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to guarantee its accuracy.
This information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and conditions for users of
this product are not within our awareness or control, and it is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements concerning the manipulation,
storage, use and disposal of chemical products. The information on this security data sheet only refers to this product, which should not be used for needs other than those specified.

- END OF SAFETY DATA SHEET -


Date of compilation: 2014-11-19 Version: 1 Page 9/9
SAFETY DATA SHEET Revision date: 10/12/2014
Version: 4
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 8/6/2015

Electrolyte EN
Material number 2170 EN / 2175 EN / 2171 EN / 2185 EN Page: 1 of 7

SECTION 1: Identification of the substance/mixture and of the


company/undertaking
1.1 Product identifier
Trade name: Electrolyte EN

1.2 Relevant identified uses of the substance or mixture and uses advised against
General use: Electrolytic/electrochemical metal inscription
For industrial purposes only

1.3 Details of the supplier of the safety data sheet


Company name: Bymat GmbH

Street/POB-No.: Neusser Straße 106


Postal Code, city: 41363 Jüchen
Germany
WWW: www.bymat.com
E-mail: info@bymat.de
Telephone: +49 (0) 21 65 / 87 28 - 0
Telefax: +49 (0) 21 65 / 87 28 28
Dept. responsible for information:
Michael Byhahn,
Telephone: +49 (0) 21 65 / 87 28 0, Email: info@bymat.de

1.4 Emergency telephone number


Michael Byhahn, Telephone: +49 (0) 21 65 / 87 28 0

SECTION 2: Hazards identification


2.1 Classification of the substance or mixture
Classification according to EC regulation 1272/2008 (CLP)
This mixture is classified as not hazardous.

Classification according to Directive 67/548/EEC or 1999/45/EC


This preparation is classified as not hazardous.

2.2 Label elements


Labelling (CLP)

Hazard statements: not applicable


Precautionary statements: not applicable

Labelling (67/548/EEC or 1999/45/EC)


R phrase(s): not applicable
S phrase(s): not applicable

Page 1/7
SAFETY DATA SHEET Revision date: 10/12/2014
Version: 4
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
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Electrolyte EN
Material number 2170 EN / 2175 EN / 2171 EN / 2185 EN Page: 2 of 7

2.3 Other hazards


Electrolytic vapours may form during signature processes under direct current voltage.
May be harmful if inhaled.

SECTION 3: Composition / information on ingredients


3.1 Substances: not applicable

3.2 Mixtures
Chemical characterisation: Mixtureof water/mineral salt and complexing agent
Additional information: Preparation does not contain dangerous substances above limits that need to be
mentioned in this section according to applicable EU-legislation.

SECTION 4: First aid measures


4.1 Description of first aid measures
In case of inhalation: Provide fresh air. Seek medical treatment in case of troubles.
Following skin contact: Remove residues with water. In case of skin irritation, consult a physician.
After eye contact: With eyelids open, wash out eyes for several minutes under flowing water. In case of
troubles or persistent symptoms, consult an opthalmologist.
After swallowing: Rinse mouth thoroughly with water. If you feel unwell, seek medical advice.

4.2 Most important symptoms and effects, both acute and delayed

no data available

4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures


5.1 Extinguishing media
Suitable extinguishing media:
Product is non-combustible. Extinguishing materials should therefore be selected
according to surroundings.
5.2 Special hazards arising from the substance or mixture
Fires in the immediate vicinity may cause the development of dangerous vapours.
5.3 Advice for firefighters
Special protective equipment for firefighters:
Wear self-contained breathing apparatus.
Additional information: Hazchem-Code: -
Do not allow water used to extinguish fire to enter drains, ground or waterways. Treat
runoff as hazardous.

Page 2/7
SAFETY DATA SHEET Revision date: 10/12/2014
Version: 4
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 8/6/2015

Electrolyte EN
Material number 2170 EN / 2175 EN / 2171 EN / 2185 EN Page: 3 of 7

SECTION 6: Accidental release measures


6.1 Personal precautions, protective equipment and emergency procedures
Avoid contact with skin and eyes. Provide adequate ventilation.
6.2 Environmental precautions
Do not allow to penetrate into soil, waterbodies or drains.
6.3 Methods and material for containment and cleaning up
Wipe up with absorbent material (eg. cloth, fleece).
6.4 Reference to other sections
Refer additionally to section 8 and 13.

SECTION 7: Handling and storage


7.1 Precautions for safe handling
Advices on safe handling: Wear protective equipment. Do not breathe vapour/aerosol.
Avoid contact with skin and eyes.
Provide adequate ventilation, and local exhaust as needed.
Do not mix with other chemicals.

7.2 Conditions for safe storage, including any incompatibilities


Requirements for storerooms and containers:
Keep container tightly closed.
Storage class: 12 = Non-combustible liquids
7.3 Specific end use(s)
No information available.

SECTION 8: Exposure controls/personal protection


8.1 Control parameters
Additional information: Contains no substances with occupational exposure limit values.

8.2 Exposure controls


Provide adequate ventilation.

Personal protection equipment


Occupational exposure controls
Respiratory protection: Use a breathing protection against vapours/aerosol.
Hand protection: Recommendation: Protective gloves according to EN 374.
Glove material: Nitrile rubber
Observe glove manufacturer's instructions concerning penetrability and breakthrough time.
Eye protection: Recommendation: Tightly sealed goggles according to EN 166.
Body protection: Wear suitable protective clothing.

Page 3/7
SAFETY DATA SHEET Revision date: 10/12/2014
Version: 4
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 8/6/2015

Electrolyte EN
Material number 2170 EN / 2175 EN / 2171 EN / 2185 EN Page: 4 of 7

General protection and hygiene measures:


Avoid contact with skin and eyes.
Change contaminated clothing. Do not breathe vapour/aerosol.
Wash hands before breaks and after work.
When using do not eat, drink or smoke.

SECTION 9: Physical and chemical properties


9.1 Information on basic physical and chemical properties
Appearance: Form: liquid
Colour: colourless
Odour: characteristic
Odour threshold: no data available
pH value: neutral
Melting point/freezing point: no data available
Initial boiling point and boiling range: no data available
Flash point/flash point range: not combustible
Evaporation rate: no data available
Flammability: no data available
Explosion limits: no data available
Vapour pressure: no data available
Vapour density: no data available
Density: at 20 °C: 1.03 g/mL
Water solubility: at 20 °C: completely miscible
Partition coefficient: n-octanol/water: no data available
Auto-ignition temperature: no data available
Thermal decomposition: no data available
Viscosity, dynamic: no data available
Explosive properties: no data available
Oxidizing characteristics: no data available

9.2 Other information


Additional information: no data available

SECTION 10: Stability and reactivity


10.1 Reactivity
Refer to 10.3

10.2 Chemical stability


Product is stable under normal storage conditions.

10.3 Possibility of hazardous reactions


No hazardous reaction when handled and stored according to provisions.

Page 4/7
SAFETY DATA SHEET Revision date: 10/12/2014
Version: 4
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 8/6/2015

Electrolyte EN
Material number 2170 EN / 2175 EN / 2171 EN / 2185 EN Page: 5 of 7

10.4 Conditions to avoid


Do not mix with other chemicals.

10.5 Incompatible materials


Strong acids and alkalis

10.6 Hazardous decomposition products


Fires in the immediate vicinity may cause the development of dangerous vapours.
Thermal decomposition: no data available

SECTION 11: Toxicological information


11.1 Information on toxicological effects
Toxicological effects: Acute toxicity (oral): Lack of data.
Acute toxicity (dermal): Lack of data.
Acute toxicity (inhalative): Lack of data.
Skin corrosion/irritation: Lack of data.
Eye damage/irritation: Based on available data, the classification criteria are not met.
mild irritant
Sensitisation to the respiratory tract: Lack of data.
Skin sensitisation: Lack of data.
Germ cell mutagenicity/Genotoxicity: Lack of data.
Carcinogenicity: Lack of data.
Reproductive toxicity: Lack of data.
Effects on or via lactation: Lack of data.
Specific target organ toxicity (single exposure): Lack of data.
Specific target organ toxicity (repeated exposure): Lack of data.
Aspiration hazard: Lack of data.

SECTION 12: Ecological information


12.1 Toxicity
Further details: no data available

12.2. Persistence and degradability


Further details: no data available

12.3 Bioaccumulative potential


Partition coefficient: n-octanol/water:
no data available

12.4 Mobility in soil


no data available

Page 5/7
SAFETY DATA SHEET Revision date: 10/12/2014
Version: 4
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 8/6/2015

Electrolyte EN
Material number 2170 EN / 2175 EN / 2171 EN / 2185 EN Page: 6 of 7

12.5 Results of PBT and vPvB assessment


no data available

12.6 Other adverse effects


General information: Do not allow to enter into ground-water, surface water or drains.

SECTION 13: Disposal considerations


13.1 Waste treatment methods
Product
Waste key number: 11 01 99 = Wastes from chemical surface treatment and coating of metals and other
materials (eg. galvanic processes, zinc coating processes, pickling
processes, etching, phosphatising, alkaline degreasing, anodising)
Recommendation: Smaller amounts: Product can be released into the sewage system.

Contaminated packaging
Waste key number: 15 01 02 = Plastic packaging
Recommendation: Dispose of waste according to applicable legislation.
Non-contaminated packages may be recycled.

SECTION 14: Transport information


14.1 UN number
ADR/RID, IMDG, IATA-DGR:
not applicable

14.2 UN proper shipping name


ADR/RID, IMDG, IATA-DGR:
Not restricted

14.3 Transport hazard class(es)


ADR/RID, IMDG, IATA-DGR:
not applicable

14.4 Packing group


ADR/RID, IMDG, IATA-DGR:
not applicable

14.5 Environmental hazards


Marine pollutant: No

14.6 Special precautions for user


No dangerous good in sense of these transport regulations.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
no data available

Page 6/7
SAFETY DATA SHEET Revision date: 10/12/2014
Version: 4
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 8/6/2015

Electrolyte EN
Material number 2170 EN / 2175 EN / 2171 EN / 2185 EN Page: 7 of 7

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance
or mixture
National regulations - Great Britain
Hazchem-Code: -
15.2 Chemical Safety Assessment
For this mixture a chemical safety assessment is not required.

SECTION 16: Other information


Further information
Reason of change: General revision
Date of first version: 20/6/2008
Department issuing data sheet
Contact person: see section 1: Dept. responsible for information

For abbreviations and acronyms, see: ECHA Guidance on information requirements and chemical safety
assessment, chapter R.20 (Table of terms and abbreviations).
The information in this data sheet has been established to our best knowledge and was up-to-date at time of
revision. It does not represent a guarantee for the properties of the product described in terms of the legal
warranty regulations.

Page 7/7
SAFETY DATA SHEET Revision date: 10/12/2014
Version: 5
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 4/5/2015

Electrolyte ET
Material number 2101 ET / 2105 ET / 2111 ET / 2115 ET Page: 1 of 7

SECTION 1: Identification of the substance/mixture and of the


company/undertaking
1.1 Product identifier
Trade name: Electrolyte ET

1.2 Relevant identified uses of the substance or mixture and uses advised against
General use: Electrolytic/electrochemical metal inscription
For industrial purposes only

1.3 Details of the supplier of the safety data sheet


Company name: Bymat GmbH

Street/POB-No.: Neusser Straße 106


Postal Code, city: 41363 Jüchen
Germany
WWW: www.bymat.com
E-mail: info@bymat.de
Telephone: +49 (0)21 65 / 87 28 0
Telefax: +49 (0)21 65 / 87 28 28
Dept. responsible for information:
Michael Byhahn,
Telephone: +49 (0)21 65 87 28 0, Email: info@bymat.de

1.4 Emergency telephone number


Michael Byhahn, Telephone: +49 (0)21 65 / 87 28 0

SECTION 2: Hazards identification


2.1 Classification of the substance or mixture
Classification according to EC regulation 1272/2008 (CLP)
This mixture is classified as not hazardous.

Classification according to Directive 67/548/EEC or 1999/45/EC


This preparation is classified as not hazardous.

2.2 Label elements


Labelling (CLP)

Hazard statements: not applicable


Precautionary statements: not applicable

Labelling (67/548/EEC or 1999/45/EC)


R phrase(s): not applicable
S phrase(s): not applicable
SAFETY DATA SHEET Revision date: 10/12/2014
Version: 5
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 4/5/2015

Electrolyte ET
Material number 2101 ET / 20105 ET / 2111 ET / 2115 ET Page: 2 of 7

2.3 Other hazards


Electrolytic vapours may form during signature processes under direct current voltage.
May be harmful if inhaled.

SECTION 3: Composition / information on ingredients


3.1 Substances: not applicable

3.2 Mixtures
Chemical characterisation: Aqueous solution of anorganic salts and organic compounds.
Hazardous ingredients:

Ingredient Designation Content Classification


EC No. 233-826-7 Magnesium nitrate < 10 % DSD/DPD: O, Xi; R 8, 36/38
CAS 10377-60-3 CLP: Ox. Sol. 3; H272. Skin Irrit. 2; H315.
Eye Irrit. 2; H319.

SECTION 4: First aid measures


4.1 Description of first aid measures
In case of inhalation: Provide fresh air. Seek medical treatment in case of troubles.
Following skin contact: Change contaminated clothing.
After contact with skin, wash immediately with soap and plenty of water.
In case of skin reactions, consult a physician.
After eye contact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids
apart. Subsequently consult an ophthalmologist.
After swallowing: Rinse mouth with water.
Never give an unconscious person anything through the mouth.
Do not induce vomiting.
If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
no data available
4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures


5.1 Extinguishing media
Suitable extinguishing media:
Use extinguishing material as appropriate for the surrounding area.
5.2 Special hazards arising from the substance or mixture
Fires in the immediate vicinity may cause the development of dangerous vapours.
In case of fire may be liberated: Chlorine decomposition products, nitrogen oxides (NOx).
SAFETY DATA SHEET Revision date: 10/12/2014
Version: 5
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 4/5/2015

Electrolyte ET
Material number 2101 ET / 2105 ET / 2111 ET / 2115 ET Page: 3 of 7

5.3 Advice for firefighters


Special protective equipment for firefighters:
Wear self-contained breathing apparatus.
Additional information: Hazchem-Code: -
Do not allow fire water to penetrate into surface or ground water.

SECTION 6: Accidental release measures


6.1 Personal precautions, protective equipment and emergency procedures
Do not breathe vapour/aerosol.
Avoid contact with skin and eyes.
Wear suitable protective clothing.
Provide adequate ventilation.
6.2 Environmental precautions
Do not allow to penetrate into soil, waterbodies or drains.
6.3 Methods and material for containment and cleaning up
Soak up with absorbent materials such as sand, siliceus earth, acid- or universal binder.
Store in special closed containers and dispose of according to ordinance. Final cleaning.
Do not allow to dry.
6.4 Reference to other sections
Refer additionally to section 8 and 13.

SECTION 7: Handling and storage


7.1 Precautions for safe handling
Advices on safe handling: Provide adequate ventilation, and local exhaust as needed.
Wear protective equipment.
Avoid contact with skin and eyes. Do not breathe vapour/aerosol.

7.2 Conditions for safe storage, including any incompatibilities


Requirements for storerooms and containers:
Keep container tightly closed.
Storage class: 12 = Non-combustible liquids
7.3 Specific end use(s)
No information available.

SECTION 8: Exposure controls/personal protection


8.1 Control parameters
Additional information: Contains no substances with occupational exposure limit values.

8.2 Exposure controls


Provide good ventilation and/or an exhaust system in the work area.
SAFETY DATA SHEET Revision date: 10/12/2014
Version: 5
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 4/5/2015

Electrolyte ET
Material number 2101 ET / 2105 ET / 2111 ET / 2115 ET Page: 4 of 7

Personal protection equipment


Occupational exposure controls
Respiratory protection: Use a breathing protection against vapours/aerosol.
Hand protection: Protective gloves according to EN 374.
Glove material: Butyl caoutchouc (butyl rubber)
Observe glove manufacturer's instructions concerning penetrability and breakthrough time.
Eye protection: Tightly sealed goggles according to EN 166.
Body protection: Wear suitable protective clothing.
General protection and hygiene measures:
Change contaminated clothing. Do not breathe vapour/aerosol.
Avoid contact with skin and eyes.
When using do not eat, drink or smoke.
Wash hands before breaks and after work.

SECTION 9: Physical and chemical properties


9.1 Information on basic physical and chemical properties
Appearance: Form: liquid
Colour: colourless, clear
Odour: odourless
Odour threshold: no data available
pH value: 5.5 - 6.5
Melting point/freezing point: no data available
Initial boiling point and boiling range: no data available
Flash point/flash point range: no data available
Evaporation rate: no data available
Flammability: no data available
Explosion limits: no data available
Vapour pressure: no data available
Vapour density: no data available
Density: 1.03 g/mL
Water solubility: completely miscible
Partition coefficient: n-octanol/water: no data available
Auto-ignition temperature: not self-igniting
Thermal decomposition: no data available
Viscosity, dynamic: no data available
Explosive properties: Product is not explosive.
Oxidizing characteristics: no data available

9.2 Other information


Additional information: no data available
SAFETY DATA SHEET Revision date: 10/12/2014
Version: 5
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 4/5/2015

Electrolyte ET
Material number 2101 ET / 2105 ET / 2111 ET / 2115 ET Page: 5 of 7

SECTION 10: Stability and reactivity


10.1 Reactivity
Refer to 10.3

10.2 Chemical stability


Product is stable under normal storage conditions.

10.3 Possibility of hazardous reactions


No hazardous reaction when handled and stored according to provisions.

10.4 Conditions to avoid


no data available

10.5 Incompatible materials


Strong acids and alkalis

10.6 Hazardous decomposition products


Fires in the immediate vicinity may cause the development of dangerous vapours.
In case of fire may be liberated: Chlorine decomposition products, nitrogen oxides (NOx).
Thermal decomposition: no data available

SECTION 11: Toxicological information


11.1 Information on toxicological effects
Toxicological effects: Acute toxicity (oral): Lack of data.
Acute toxicity (dermal): Lack of data.
Acute toxicity (inhalative): Lack of data.
Skin corrosion/irritation: Lack of data.
Eye damage/irritation: Lack of data.
Sensitisation to the respiratory tract: Lack of data.
Skin sensitisation: Lack of data.
Germ cell mutagenicity/Genotoxicity: Lack of data.
Carcinogenicity: Lack of data.
Reproductive toxicity: Lack of data.
Effects on or via lactation: Lack of data.
Specific target organ toxicity (single exposure): Lack of data.
Specific target organ toxicity (repeated exposure): Lack of data.
Aspiration hazard: Lack of data.

SECTION 12: Ecological information


12.1 Toxicity
Further details: no data available
SAFETY DATA SHEET Revision date: 10/12/2014
Version: 5
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 4/5/2015

Electrolyte ET
Material number 2101 ET / 2105 ET / 2111 ET / 2115 ET Page: 6 of 7

12.2. Persistence and degradability


Further details: no data available

12.3 Bioaccumulative potential


Partition coefficient: n-octanol/water:
no data available

12.4 Mobility in soil


no data available

12.5 Results of PBT and vPvB assessment


no data available

12.6 Other adverse effects


General information: Do not allow to enter into ground-water, surface water or drains.

SECTION 13: Disposal considerations


13.1 Waste treatment methods
Product
Waste key number: 11 01 99 = Wastes from chemical surface treatment and coating of metals and other
materials (eg. galvanic processes, zinc coating processes, pickling
processes, etching, phosphatising, alkaline degreasing, anodising)
Recommendation: Dispose of waste according to applicable legislation.

Contaminated packaging
Waste key number: 15 01 02 = Plastic packaging.
Recommendation: Dispose of waste according to applicable legislation.
Non-contaminated packages may be recycled.

SECTION 14: Transport information


14.1 UN number
ADR/RID, IMDG, IATA: not applicable

14.2 UN proper shipping name


ADR/RID, IMDG, IATA: Not restricted

14.3 Transport hazard class(es)


ADR/RID, IMDG, IATA: not applicable

14.4 Packing group


ADR/RID, IMDG, IATA: not applicable

14.5 Environmental hazards


Marine pollutant: No
SAFETY DATA SHEET Revision date: 10/12/2014
Version: 5
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 4/5/2015

Electrolyte ET
Material number 2101 ET / 2105 ET / 2111 ET / 2115 ET Page: 7 of 7

14.6 Special precautions for user


No dangerous good in sense of these transport regulations.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
no data available

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance
or mixture
National regulations - Great Britain
Hazchem-Code: -
15.2 Chemical Safety Assessment
For this mixture a chemical safety assessment is not required.

SECTION 16: Other information


Further information
Wording of the H-phrases under paragraph 2 and 3:
H272 = May intensify fire; oxidiser.
H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
Wording of the R-phrases under section 2 and 3:
R 8 = Contact with combustible material may cause fire.
R 36/38 = Irritating to eyes and skin.
Reason of change:General revision
10/11/2008
Date of first version:

Department issuing data sheet


Contact person: see section 1: Dept. responsible for information

For abbreviations and acronyms, see: ECHA Guidance on information requirements and chemical safety
assessment, chapter R.20 (Table of terms and abbreviations).
The information in this data sheet has been established to our best knowledge and was up-to-date at time of
revision. It does not represent a guarantee for the properties of the product described in terms of the legal
warranty regulations.
SAFETY DATA SHEET Revision date: 11/11/2013
Version: 4
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 4/5/2015

Neutralizer
Material number 2210 NT / 2215 NT / 2211 NT / 2250 NT Page: 1 of 7

SECTION 1: Identification of the substance/mixture and of the


company/undertaking
1.1 Product identifier
Trade name: Neutralizer

1.2 Relevant identified uses of the substance or mixture and uses advised against
General use: Electrolytic/electrochemical metal inscription:
Cleaning agent/Neutralizing agent

1.3 Details of the supplier of the safety data sheet


Company name: Bymat GmbH

Street/POB-No.: Neusser Strasse 106


Postal Code, city: 41363 Jüchen
Germany
WWW: www.bymat.com
E-mail: info@bymat.de
Telephone: +49 (0) 21 65 / 87 28 - 0
Telefax: +49 (0) 21 65 / 87 28 28
Dept. responsible for information:
Michael Byhahn,
Telephone: +49 (0)21 65 / 87 28 - 0, Email: info@bymat.de

1.4 Emergency telephone number


Michael Byhahn, Telephone: +49 (0) 21 65 / 87 28 - 0

SECTION 2: Hazards identification


2.1 Classification of the substance or mixture
Classification according to EC regulation 1272/2008 (CLP)
This mixture is classified as not hazardous.

Classification according to Directive 67/548/EEC or 1999/45/EC


This preparation is classified as not hazardous.

2.2 Label elements


Labelling (CLP)
Hazard statements: not applicable
Precautionary statements: not applicable

Labelling (67/548/EEC or 1999/45/EC)


R phrase(s): not applicable
S phrase(s): not applicable
2.3 Other hazards

Due to its pH value (see section 9), irritation of the skin and eyes cannot be ruled out.

Page 1/7
SAFETY DATA SHEET Revision date: 11/11/2013
Version: 4
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 4/5/2015

Neutralizer
Material number 2210 NT / 2215 NT / 2211 NT / 2250 NT Page: 2 of 7

SECTION 3: Composition / information on ingredients


3.1 Substances: not applicable

3.2 Mixtures
Chemical characterisation: Aqueous solution
Hazardous ingredients:

Ingredient Designation Content Classification


EC No. 207-838-8 Sodium 1-5% DSD/DPD: Xi; R36.
CAS 6132-02-1 carbonate-10-hydrate CLP: Eye Irrit. 2; H319.

SECTION 4: First aid measures


4.1 Description of first aid measures
In case of inhalation: Provide fresh air. Seek medical treatment in case of troubles.
Following skin contact: Remove residues with water. In case of skin irritation, consult a physician.
After eye contact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids
apart. In case of troubles or persistent symptoms, consult an opthalmologist.
After swallowing: Rinse mouth thoroughly with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed

After contact with skin: May cause irritations.


After eye contact: May cause irritations.

4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures


5.1 Extinguishing media
Suitable extinguishing media:
Product is non-combustible. Extinguishing materials should therefore be selected
according to surroundings.
5.2 Special hazards arising from the substance or mixture
Fires in the immediate vicinity may cause the development of dangerous vapours.
5.3 Advice for firefighters
Special protective equipment for firefighters:
Wear self-contained breathing apparatus.
Additional information: Hazchem-Code: -
Do not allow water used to extinguish fire to enter drains, ground or waterways. Treat
runoff as hazardous.

Page 2/7
SAFETY DATA SHEET Revision date: 11/11/2013
Version: 4
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 4/5/2015

Neutralizer
Material number 2210 NT / 2215 NT / 2211 NT / 2250 NT Page: 3 of 7

SECTION 6: Accidental release measures


6.1 Personal precautions, protective equipment and emergency procedures
Avoid contact with skin and eyes. Wear suitable protective clothing. Provide adequate
ventilation.
6.2 Environmental precautions
Do not allow to penetrate into soil, waterbodies or drains.
6.3 Methods and material for containment and cleaning up
Soak up with absorbent materials such as sand, siliceus earth, acid- or universal binder.
Store in special closed containers and dispose of according to ordinance. Final cleaning.
6.4 Reference to other sections
Refer additionally to section 8 and 13.

SECTION 7: Handling and storage


7.1 Precautions for safe handling
Advices on safe handling: Avoid contact with skin and eyes.
Provide adequate ventilation, and local exhaust as needed.
Do not mix with other chemicals.

7.2 Conditions for safe storage, including any incompatibilities


Requirements for storerooms and containers:
Keep container tightly closed.
Storage class: 12 = Non-combustible liquids
7.3 Specific end use(s)
No information available.

SECTION 8: Exposure controls/personal protection


8.1 Control parameters
Additional information: Contains no substances with occupational exposure limit values.

8.2 Exposure controls


Provide adequate ventilation, and local exhaust as needed.

Personal protection equipment


Occupational exposure controls
Hand protection: Recommendation: protective gloves according to EN 374.
Glove material: Nitrile rubber
Observe glove manufacturer's instructions concerning penetrability and breakthrough time.
Eye protection: Tightly sealed goggles according to EN 166.
Body protection: Wear suitable protective clothing.

Page 3/7
SAFETY DATA SHEET Revision date: 11/11/2013
Version: 4
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 4/5/2015

Neutralizer
Material number 2210 NT / 2215 NT / 2211 NT / 2250 NT Page: 4 of 7

General protection and hygiene measures:


Avoid contact with skin and eyes.
Change contaminated clothing.
Wash hands before breaks and after work.
When using do not eat, drink or smoke.

SECTION 9: Physical and chemical properties


9.1 Information on basic physical and chemical properties
Appearance: Form: liquid
Colour: colourless
Odour: characteristic
Odour threshold: no data available
pH value: 10 - 11.5
Melting point/freezing point: no data available
Initial boiling point and boiling range: no data available
Flash point/flash point range: not combustible
Evaporation rate: no data available
Flammability: no data available
Explosion limits: no data available
Vapour pressure: no data available
Vapour density: no data available
Density: at 20 °C: 1.03 g/mL
Water solubility: at 20 °C: completely miscible
Partition coefficient: n-octanol/water: no data available
Auto-ignition temperature: no data available
Thermal decomposition: no data available
Viscosity, dynamic: no data available
Explosive properties: no data available
Oxidizing characteristics: no data available

9.2 Other information


Additional information: no data available

SECTION 10: Stability and reactivity


10.1 Reactivity
Refer to 10.3

10.2 Chemical stability


Product is stable under normal storage conditions.

10.3 Possibility of hazardous reactions


No hazardous reaction when handled and stored according to provisions.

Page 4/7
SAFETY DATA SHEET Revision date: 11/11/2013
Version: 4
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 4/5/2015

Neutralizer
Material number 2210 NT / 2215 NT / 2211 NT / 2250 NT Page: 5 of 7

10.4 Conditions to avoid


Do not mix with other chemicals.

10.5 Incompatible materials


Strong acids and alkalis

10.6 Hazardous decomposition products


Fires in the immediate vicinity may cause the development of dangerous vapours.
Thermal decomposition: no data available

SECTION 11: Toxicological information


11.1 Information on toxicological effects
Toxicological effects: Acute toxicity (oral): Lack of data.
Acute toxicity (dermal): Lack of data.
Acute toxicity (inhalative): Lack of data.
Skin corrosion/irritation: Based on available data, the classification criteria are not met.
Product can cause skin irritation because of the pH-value.
Eye damage/irritation: Based on available data, the classification criteria are not met.
Product can cause eye irritation because of the pH-value.
Sensitisation to the respiratory tract: Lack of data.
Skin sensitisation: Lack of data.
Germ cell mutagenicity/Genotoxicity: Lack of data.
Carcinogenicity: Lack of data.
Reproductive toxicity: Lack of data.
Effects on or via lactation: Lack of data.
Specific target organ toxicity (single exposure): Lack of data.
Specific target organ toxicity (repeated exposure): Lack of data.
Aspiration hazard: Lack of data.

Symptoms
After contact with skin: May cause irritations.
After eye contact: May cause irritations.

SECTION 12: Ecological information


12.1 Toxicity
Aquatic toxicity: In case of spills of large quantities: Harmful effects on water organisms by modification of
pH-value.

12.2. Persistence and degradability


Further details: no data available

Page 5/7
SAFETY DATA SHEET Revision date: 11/11/2013
Version: 4
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 4/5/2015

Neutralizer
Material number 2210 NT / 2215 NT / 2211 NT / 2250 NT Page: 6 of 7

12.3 Bioaccumulative potential


Partition coefficient: n-octanol/water:
no data available

12.4 Mobility in soil


no data available

12.5 Results of PBT and vPvB assessment


no data available

12.6 Other adverse effects


General information: Do not allow to enter undiluted resp. in large quantities into surface water or into drains.

SECTION 13: Disposal considerations


13.1 Waste treatment methods
Product
Waste key number: 20 01 30 = Detergents other than those mentioned in 20 01 29
Recommendation: Special waste. Dispose of waste according to applicable legislation.

Contaminated packaging
Waste key number: 15 01 02 = Plastic packaging
Recommendation: Dispose of waste according to applicable legislation.
Non-contaminated packages may be recycled.

SECTION 14: Transport information


14.1 UN number
ADR/RID, IMDG, IATA: not applicable

14.2 UN proper shipping name


ADR/RID, IMDG, IATA: Not restricted

14.3 Transport hazard class(es)


ADR/RID, IMDG, IATA: not applicable

14.4 Packing group


ADR/RID, IMDG, IATA: not applicable

14.5 Environmental hazards


Marine pollutant: No

14.6 Special precautions for user


No dangerous good in sense of these transport regulations.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
no data available

Page 6/7
SAFETY DATA SHEET Revision date: 11/11/2013
Version: 4
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) Language: en-GB,IE
No 453/2010 Date of print: 4/5/2015

Neutralizer
Material number 2210 NT / 2215 NT / 2211 NT / 2250 NT Page: 7 of 7

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance
or mixture
National regulations - Great Britain
Hazchem-Code: -
15.2 Chemical Safety Assessment
For this mixture a chemical safety assessment is not required.

SECTION 16: Other information


Further information
Wording of the H-phrases under paragraph 2 and 3:
H319 = Causes serious eye irritation.
Wording of the R-phrases under section 2 and 3:
R 36 = Irritating to eyes.
Reason of change: Changes in section 4, 5, 6, 8: General revision
Changes in section 15: National regulations USA
General revision
Date of first version: 7/4/2008
Department issuing data sheet
Contact person: see section 1: Dept. responsible for information

For abbreviations and acronyms, see: ECHA Guidance on information requirements and chemical safety
assessment, chapter R.20 (Table of terms and abbreviations).
The information in this data sheet has been established to our best knowledge and was up-to-date at time of
revision. It does not represent a guarantee for the properties of the product described in terms of the legal
warranty regulations.

Page 7/7
EC Safety data sheet
in accordance with Regulation (EC) No. 1907/2006

Preservative
Print date: 10.06.2015 Material number: 2310 KO / 2315 KO / 2311 KO Page 1 of 7

SECTION 1: Description of the substance or the mixture and the company

1.1. Product identifier


Preservative
REACH Registration number: 01-2119487078-27-
CAS-No.: 8042-47-5
EC No.: 232-455-8
1.2. Relevant identified uses of the substance or mixture and uses advised against
Usage of substance/mixture
Care product for metal surfaces; only for industrial consumers.
1.3. Details of the supplier who provides the safety data sheet
Company name: Bymat GmbH
Street: Neusser Straße 106
City: D-41363 Jüchen, Germany

Address: Neusser Straße 106


D-41363 Jüchen, Germany
Phone: +49 (0) 21 65 / 87 28 - 0 Fax: +49 (0) 21 65 / 87 28 28
E-mail: info@bymat.de
Internet: www.bymat.de
Information from: Mr Michael Byhahn

1.4. Emergency number: +49 (0) 21 65 / 87 28 - 0

SECTION 2: Possible risks

2.1. Classification of the substance or mixture

Classification in accordance with Directive 67/548/EEC or 1999/45/EC


In accordance with Directive 67/548/EEC, this substance has been classified as non-hazardous.
Classification in accordance with Regulation (EC) No. 1272/2008 [CLP]
Hazard categories:
Aspiration hazard: Asp. 1
Hazard notes:
Can be lethal if swallowed and allowed to penetrate the respiratory tracts.
2.2. Labelling elements
Hazard-determining component(s) for labelling
White mineral oil (petroleum)
Signal word: Hazard
Pictograms: GHS08

Hazard notes
H304 Can be lethal if swallowed and allowed to penetrate the respiratory tracts.
Safety instructions
P102 Must be kept out of the reach of children.
P301+P310 FOLLOWING INGESTION: Call POISONS INFORMATION CENTRE/doctor immediately.
P331 DO NOT induce vomiting.
Revision No.: 1,00 D - DE Revised on: 10.06.2015
EC Safety data sheet
in accordance with Regulation (EC) No. 1907/2006
Preservative

Print date: 10.06.2015 Material number: 2310 KO / 2315 KO / 2311 KO Page 2 of 7


P405 Store under lock and key.
P501 Only add fully emptied containers to recyclable waste collection.
2.3. Other hazards
No information available.
SECTION 3: Composition /Details of components
3.1. Substances
Hazardous ingredients
EC No. Description Part
CAS No. Classification in accordance with Directive 67/548/EEC
Index No. Classification in accordance with Regulation (EC) No. 1272/2008 [CLP]
232-455-8 White mineral oil (petroleum) 30 -100 %
8042-47-5
Asp. Tox. 1; H304

Wording of R, H, and EU H phrases: see section 16.


Labelling of ingredients in accordance with Regulation (EC) No. 648/2004
>= 30 % aliphatic hydrocarbons.
SECTION 4: First-aid measures
4.1. Description of first-aid measures
Following skin contact
Rinse off with plenty of water. Change contaminated clothing immediately. Medical attention is
required.
Following eye contact
Immediately rinse carefully but thoroughly with eye wash or with water. Following eye irritation
contact an ophthalmologist.
Following ingestion
DO NOT induce vomiting. Pay attention to aspiration hazard following vomiting. Medical
attention is required.
4.2. The most important occurring acute and delayed symptoms and effects
No information available.
4.3. Instructions for immediate medical attention or special treatment
Symptomatic treatment.
SECTION 5: Measures for fire fighting
5.1. Extinguishing agents
Suitable extinguishing agents
Co-ordinate the extinguishing measures to the environment.
5.2. Special hazards emanating from substance or mixture
Non-combustible.
5.3. Notes on fire fighting
In case of fire: Wear self-contained breathing apparatus.
Additional notes
Precipitate gases/vapours/mists with water spray jet. Separately collect contaminated extinguishing
water. Do not allow the product to enter sewage systems or waters.
SECTION 6: Measures in the event of unintentional release

Revision No.: 1,00 D - DE Revised on: 10.06.2015


EC Safety data sheet
in accordance with Regulation (EC) No. 1907/2006
Preservative
Print date: 10.06.2015 Material number: 2310 KO / 2315 KO / 2311 KO Page 3 of 7

6.1. Personal precautions, protective equipment and procedures to be used in emergencies


Ensure sufficient ventilation. Do not inhale gas/smoke/vapour/aerosol. Avoid contact with skin,
eyes and clothing. Use personal protective equipment.
6.2. Environmental measures
Do not allow the product to enter sewage systems or waters.
6.3. Methods and material for retention and cleaning
Take up with liquid binding material (sand, diatomaceous earth, acid binder, universal binder).
Handle the taken up material in accordance with the section on disposal.
6.4. Reference to other sections
Safe handling: see section 7
Personal protective equipment: see section 8
Disposal: see section 13
SECTION 7: Handling and storage

7.1. Protective measures for secure handling


Advice on safe handling
For open handling, devices with local removal by suction must be used. Do not
inhale gas/smoke/vapour/aerosol.
Advice on fire and explosion protection
No special fire protection measures are necessary.
7.2. Conditions for safe storage while observing incompatibilities
Requirements for storage areas and containers
Keep containers tightly sealed. Store under lock and key. Store in a location only accessible to
authorized persons. Ensure sufficient ventilation and point removal by suction at critical points.
Advice on co-storage
No special precautions are necessary.
Storage class in accordance with TRGS 510: 10 (Combustible liquids which are not allocated to any of the
previously stated storage classes)
7.3. Specific end uses
Care product for metal surfaces; only for industrial consumers.
SECTION 8: Restriction and monitoring of exposure/ personal protective equipment
8.1. Parameters to be monitored
8.2. Restriction and monitoring of exposure
Suitable technical control systems
For open handling, devices with local removal by suction must be used. Do not
inhale gas/smoke/vapour/aerosol.
Protective and hygiene measures
Immediately remove soiled or drenched clothing. Prepare and heed skin protection plan! Thoroughly
wash your hands and face, or take a shower as necessary, before taking breaks and after completing
work. Do not eat and drink during work.
Eye/Face protection
Wear eye/face protection.
Hand protection
When handling chemical agents, wear only chemical protection gloves with CE mark including four-
digit inspection number. The type of chemical protection gloves must be selected according to
hazardous substance concentration and quantity
Revision No.: 1,00 D - DE Revised on: 10.06.2015
EC Safety data sheet
in accordance with Regulation (EC) No. 1907/2006

Preservative
Print date: 10.06.2015 Material number: 2310 KO / 2315 KO / 2311 KO Page 4 of 7

and specific to the workplace. It is recommended to clarify the chemical resistance of the above-stated protection
gloves for special applications with the glove manufacturer.
Body protection
Wear suitable protective clothing at work.
Respiratory protection
For insufficient ventilation wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1. Information to basic physical and chemical properties


State of aggregation: Liquid
Colour: Colourless
Odour: Characteristic
Test standard
pH value: Not determined
Changes of state
Melting point: Not determined
Initial boiling point and boiling range: 218°C
Pour point: approx. -15°C
Flash point: > 110°C
Flammability
Solid matter: Not applicable
Gas: Not applicable
Lower explosion range: Not determined
Upper explosion range: Not determined
Spontaneous ignition temperature
Solid matter: Not applicable
Gas: Not applicable
Decomposition temperature: Not determined
Oxidizing properties
Non-oxidizing.
Vapour pressure: < 0.1 hPa
(at 20°C)
Density (at 20°C): 0.816 g/cm3
Water solubility: Slightly soluble
Solubility in other solvents
Not determined
Distribution coefficient: Not determined
Kin. viscosity: approx. 3.8 mm2/s
(at 40°C)
Vapour density: Not determined
Evaporation rate: Not determined
9.2. Other information
Solids content: Not determined

SECTION 10: Stability and reactivity

Revision No.: 1,00 D - DE Revised on: 10.06.2015


EC Safety data sheet
in accordance with Regulation (EC) No. 1907/2006

Preservative
Print date: 10.06.2015 Material number: 2310 KO / 2315 KO / 2311 KO Page 5 of 7

10.1. Reactivity
If handled and stored as intended, there are no dangerous reactions.
10.2. Chemical stability
The product is stable when stored at normal ambient temperatures.
10.3. Possibility of dangerous reactions
There are no known dangerous reactions.
10.4. Conditions to avoid
none
10.5. Incompatible materials
No information available.
10.6. Dangerous decomposition products
There are no known dangerous decomposition products.
SECTION 11: Toxicological information

11.1. Information to toxicological effects


Acute toxicity
CAS No. Description
Routes of exposure Method Dosage Species Source
8042-47-5 White mineral oil (petroleum)
oral LD50 >5000 mg/kg Rat
dermal LD50 >2000 mg/kg Rabbit
inhalation (4 h) Aerosol LC50 >5000 mg/l Rat

Other information to tests


Substance information: properties hazardous to health, special hazards emanating from
substance or mixture, classification in accordance with Regulation (EC) No. 1272/2008 [CLP]
SECTION 12: Environment-related information
12.1. Toxicity
The product is not: Ecotoxic.
CAS No. Description
Aquatic toxicity Method
Method Dosage
Dosage [h][h]
| [d][d] Species
Species Source
Source
8042-47-5 White mineral oil (petroleum)
Acute fish toxicity LC50 > 1000 mg/l 96 h Leuciscus idus (Orfe) OECD
Acute algae toxicity ErC50 >= 100 mg/l 72 h Pseudokirchneriella 203
OECD 201
subcapitata
Acute crustacean toxicity EC50 >100 mg/l 48 h Daphnia magna (water OECD 202
flea)

12.2. Persistence and degradability


The product was not tested.
12.3. Bioaccumulation potential
The product was not tested.
12.4. Mobility in the ground
The product was not tested.
12.5. Results of the PBT and vPvB assessment
The product was not tested.
Revision No.: 1,00 D - DE Revised on: 10.06.2015
EC Safety data sheet
in accordance with Regulation (EC) No. 1907/2006
Preservative
Print date: 10.06.2015 Material number: 2310 KO / 2315 KO / 2311 KO Page 6 of 7

12.6. Other harmful effects


No information available.
Further notes
Avoid releasing to the environment.
SECTION 13: Advice on disposal

13.1. Procedure of waste treatment


Recommendation
Do not allow the product to enter sewage systems or waters. Disposal in accordance with
official regulations.
Disposal of uncleaned packaging and recommended cleansing agents
This product and its container must be disposed of as hazardous waste. Contaminated
packaging must be treated in the same manner as the substance.
SECTION 14: Transport information

14.6. Special precautions for the user


No information available.
14.7. Bulk goods transport in accordance with Appendix II of the MARPOL Convention 73/78 and as per IBC
Code
Not applicable
SECTION 15: Legal specifications
15.1. Specifications on safety, health and environmental protection/Specific legal specifications for the
substance or the mixture
EU regulations
Additional notes
To be observed: 850/2004/EC, 79/117/EEC, 689/2008/EC
Regulation (EC) No. 648/2004 concerning detergents
National regulations
Employment restrictions: Observe the employment restrictions for youths (§22
JArbSchG - German Youth Employment Protection Act). Observe the
restrictions for pregnant and breastfeeding mothers (§§4 and 5
MuSchRiV - German Maternity Protection Guideline Regulation).
Water endangering class: 1 - low hazard to water
Status: Rule of mixtures in accordance with VwVwS Appendix 4, No. 3
15.2. Chemical safety assessment
No chemical safety assessment was implemented for this substance.

SECTION 16: Other information

Abbreviations and acronyms


ADR: Accord européen sur le transport des marchandises dangereuses par Route
(European Agreement concerning the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service
LC50: Lethal concentration, 50%
LD50: Lethal dose, 50%
Revision No.: 1,00 D - DE Revised on: 10.06.2015
EC Safety data sheet
in accordance with Regulation (EC) No. 1907/2006

Preservative
Print date: 10.06.2015 Material number: 2310 KO / 2315 KO / 2311 KO Page 7 of 7

Wording of H and EUH phrases (number and full text)


H304 Can be lethal if swallowed and allowed to penetrate the respiratory tracts.
Additional details
To the best of our knowledge, the information in this safety data sheet complies with our findings at
the time of print. The information should provide you with references to safely handle the product
specified in this safety data sheet concerning storage, processing, transport and disposal. The
information cannot be transferred to other products. In as far as the product is combined, mixed or
processed with other materials, or is subjected to processing, the information in this safety data
sheet cannot be transferred to the new material produced in this manner, unless expressly stated
otherwise.

Revision No.: 1,00 D - DE Revised on: 10.06.2015


EC Safety data sheet
in accordance with Regulation (EC) No. 1907/2006

Trade name: Zinc acidic Revised on: 15.04.2013


Product number: 2410 GZ, 2450 GZ Print date: 15.04.2013

Page 1 of 8

1. Description of the substance / the mixture and the company

1.1 Product identifier


Trade name: Zinc acidic
Article number: 2410 GZ, 2450 GZ

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses: Industrial use

1.3. Details of the supplier who provides the safety data sheet

Supplier: Bymat GmbH


Neusser Str. 106
D - 41363 Jüchen, Germany
Phone: +49 2165 / 87 28 -0
Fax: +49 2165 / 87 28 28
Email: info@bymat.de

1.4. Emergency number

+49 (0) 21 173 - 53 75 366 (Michael Byhahn)


2. Possible risks

2.1. Classification of the substance or mixture Classification in

accordance with Regulation (EC) No. 1272/2008

GHS09 environment
Aquatic Chronic 2 H411 - Poisonous to water organisms, long-term effect

GHS07
Exe irrit. 2 H319 Causes severe eye irritation

Classification (1999/45/EEC) Xi; Irritant, R 36 Irritates the eyes


N; Environmentally dangerous

The product acts as an irritant to eyes and skin.

2.2 Labelling elements

Contains Zinc sulphate

Labelling

Risk phrases: R phrases: R 36 irritates the eyes


EC Safety data sheet
in accordance with Regulation (EC) No. 1907/2006

Trade name: Zinc acidic Revised on: 15.04.2013


Product number: 2410 GZ, 2450 GZ Print date: 15.04.2013

Page 2 of 8

R 51/53 Poisonous to water organisms, can have a longer-term


harmful effect in waterbodies.
Safety phrases:
S phrases:

S 26 Upon contact, immediately flush eyes thoroughly with water


and consult a doctor.
S 24/25 Avoid contact with eyes and skin.
S 36/3739 Wear suitable protective clothing, gloves and
glasses/face mask during work.
S45 In case of accident or if feeling unwell, consult a doctor immediately. (If
possible, show this label.)
S 53 Avoid exposure — obtain special instructions before use.
- Only for the professional user -
S 60 This product and its container must be disposed of as hazardous waste.

2.3 Other hazards

3. Composition / details of components

3.1 Substances
This product is a mixture.

3.2 Mixtures
galvanic preparation for tampon plating, contains zinc sulphate in aqueous solution

Zinc sulphate EC No.: 231-793-3; CAS No.: 7446-20-0 Part: 5 -10 %

Classification in accordance with


EC 1272/2008:

H411 Poisonous to water organisms, long-term effect


H319 Causes severe eye irritation

Classification in accordance with Directive 67/548/EEC)

Xi; R36 Irritates the eyes


R 51/53 Poisonous to water organisms, can have a longer-term harmful effect in waterbodies.
(Refer to section 16 for the wording of the listed hazard notes)
4. First-aid measures

4.1 Description of first-aid measures

General advice:

Following inhalation: Provide warmth and fresh air and stay calm.

Following skin contact: Wash off with water, replace drenched clothing immediately.
EC Safety data sheet
in accordance with Regulation (EC) No. 1907/2006

Trade name: Zinc acidic Revised on: 15.04.2013


Product number: 2410 GZ, 2450 GZ Print date: 15.04.2013

Page 3 of 8

Following eye contact: Immediately flush with plenty of water for 10 minutes, consult a doctor.

Following ingestion: Rinse with water


Do not induce vomiting! Drink plenty of water.

4.2 The most important occurring acute and delayed symptoms and effects

Eye contact
Strong irritation to eyes and mucous membranes including burning and tears.

4.3 Instructions for immediate medical attention or special treatment


For unconsciousness or if in doubt, alert the emergency doctor.

5. Measures for fire fighting

5.1 Extinguishing agents

Suitable extinguishing agents


Suitable: Water spray jet, foam (alcohol-resistant), carbon dioxide, powder, spray (water).
5.2 Special hazards emanating from substance or mixture
The product is not combustible. If heated, caustic vapours/gases can develop.

5.3 Notes on fire fighting


Remain in the hazardous area only with breathing apparatus with independent circulation.
Precipitate vapours with water.
Avoid skin contact by wearing suitable protective clothing and maintaining a safety distance.

6. Measures in the event of unintentional release

6.1 Personal precautions, protective equipment and procedures to be used in emergencies


Note for personnel not trained for emergencies: Avoid product contact and inhaling solvent vapours. Avoid
skin contact by maintaining a safety distance or by wearing suitable protective clothing.

6.2 Environmental protection measures


Prevent the product from penetrating the ground and large quantities of polluted wash water from
accessing bodies of water. Cover the sewage systems to prevent the product from penetrating the
sewage system.

6.3 Methods and material for retention and cleaning

Soak up leaked material with a chemisorption agent, diatomaceous earth or sawdust, wipe down wet and
dispose of as special waste.

Contaminated extinguishing water must not access the sewage system

6.4 Reference to other sections

Observe protective measures in section 8.


EC Safety data sheet
in accordance with Regulation (EC) No. 1907/2006

Trade name: Zinc acidic Revised on: 15.04.2013


Product number: 2410 GZ, 2450 GZ Print date: 15.04.2013

Page 4 of 8
7. Handling and storage

7.1 Protective measures for secure handling

Do not leave vessels open.

General hygienic measures:


 Do not eat, drink or smoke in working areas
 Wash hands after use
 Take off contaminated clothing and protective equipment before entering areas where food is
being eaten.
7.2 Conditions for safe storage while observing incompatibilities
Requirements towards storage rooms and containers
Store in an area with solvent-resistant floor or in a drip pan so that the ground water is protected in
case of leaks.
Always store in containers that comply with the original drum.
7.3 Specific end uses
Please refer to our Technical Data Sheet for additional notes.
8. Restriction and monitoring of exposure/personal protective equipment

8.1 Parameters to be monitored

The product does not contain any relevant quantities of substances subject to workplace-related
limiting values.

8.2 Restriction and monitoring of exposure

Personal protective equipment

Technical measures

Ensure good ventilation. This can be achieved through local removal by suction or general outgoing air.
Personal protective equipment
The type of personal protective equipment must be selected according to hazardous substance concentration
and quantity and specific to workplace.
Respiratory protection
When the workplace limit value is exceeded, suitable respiratory protection must be worn:
comply with the rules for the use of breathing apparatus as well as wearing time
restriction in accordance with trade association Rule 2 (BGR) 190.
Hand protection
Wear chemical-resistant protective gloves.
Eye protection
Use protective glasses with side guard in accordance with EN 166:2001.

General protection and hygiene measures


Ensure good ventilation, switch on outlet or fan, avoid skin contact, do not eat or drink during work, wash
your hands with soap after completing work.

9. Physical and chemical properties

9.1 Information to basic physical and chemical properties


EC Safety data sheet
in accordance with Regulation (EC) No. 1907/2006

Trade name: Zinc acidic Revised on: 15.04.2013


Product number: 2410 GZ, 2450 GZ Print date: 15.04.2013

Page 5 of 8

Appearance

State of aggregation: Liquid


Colour: yellowish
Odour: Weakly acidic
Density: ( 20°C ) 1.23 g/cm3
pH value ( 20°C) 4
Flash point:
Ignition temperature: Not determined
Water solubility: ( 20°C ) completely soluble

9.2 Other information


Further physical-chemical data were not found.

10. Stability and reactivity

10.1 Reactivity
There are no specific reactivity hazards that can be associated with this product.

10.2 Chemical stability


The product is chemically stable under normal ambient conditions (room temperature).

10.3 Possibility of dangerous reactions


If used as intended, no dangerous reactions are to be expected.

10.4 Conditions to avoid


Avoid excessive heat over a longer period.

10.5 Incompatible materials


No information

10.6 Dangerous decomposition products


Not known.
1 1 . T o x i c ol o g i c a l i n f o r m a t i o n

1 1 . 1 I n f or m a t i o n t o t ox i c o l o g i c a l e f f e c t

Inhalation: Can irritate respiratory tract. Vapours irritate the respiratory tract and can cause throat inflammation and
breathing difficulties.
Ingestion: Can cause nausea or vomiting.
Skin contact: Slight irritations.

Eye contact: Irritation.

12. Environment-related information

12.1 Toxicity
No data available
Fish toxicity
7446-20-0 Zinc sulphate-Heptahydrate
LC50 0.1 mg/I/96 h (Onchorhynchus mykiss)
EC Safety data sheet
in accordance with Regulation (EC) No. 1907/2006

Trade name: Zinc acidic Revised on: 15.04.2013


Product number: 2410 GZ, 2450 GZ Print date:15.04.2013

Page 6 of 8

Algae toxicity

7446-20-0 Zinc sulphate-Heptahydrate


IC50 0.52 mg/I (Scenedesmus quadricauda)
12.2 Persistence and degradability

Degradability
No data available

12.3 Bioaccumulation potential


Bioaccumulation potential
The product does not contain any substances that are bioaccumulative as expected.

12.4 Mobility on ground


Mobility:
The product is water soluble.

12.5 Results of PBT and vPBT/vPvB classified.


In accordance with current EU criteria, not classified as PBT/vPvB.

12.6 Other harmful effects


Not determined.

13. Advice on disposal

13.1 Procedure of waste treatment

Dispose of waste and residues in compliance with local official guidelines.

14. Information on transportation

14.1 UN Number

UN No. (ADR/RID/ADN) 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Zinc


sulphate – heptahydrate)
UN No. (IMDG) 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Zinc
UN No. (ICAO) sulphate heptahydrate)
3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Zinc
sulphate heptahydrate)

14.2 Proper UN shipping name


Correct shipping name: Environmentally hazardous substance, liquid, N.O.S. (zinc sulphate-heptahydrate)

14.3 Transport hazard classes

ADR/RID/ADN Class Class 9 Various hazardous substances and objects


ADR Label No. 9
IMDG Class 9
ICAO Class/Sub-class 9
ICAO Subsidiary hazard
EC Safety data sheet
in accordance with Regulation (EC) No. 1907/2006

Trade name: Zinc acidic Revised on: 15.04.2013


Product number: 2410 GZ, 2450 GZ Print date: 15.04.2013

Page 7 of 8

Transport designation

14.4 Packaging group

ADR/RID/ADN Packaging group III

IMDG Packaging group III

ICAO Packaging group III

Additional transport information ADR


Limited quantity 5 L
Transport category 3

14.5 Environmental hazards

Environmentally hazardous substance/marine pollutant: Yes


The product contains environmentally harmful substances: Zinc sulphate-heptahydrate

14.6 Special precautions for the user

EMS F-A, S-B


Hazard Code 2R
Hazard No. (ADR) 90
Tunnel restriction code (E)

14.7 Bulk goods transport in accordance with Appendix II of the MARPOL Convention
73/78 and as per IBC Code
No information required

15. Legal specifications

15.1 Specifications on safety, health and environmental protection/Specific legal specifications for
the substance or the mixture

EU legal specifications

REGULATION (EC) No. 1907/2006 OF THE EUROPEAN PARLIAMENT AND COUNCIL


dated 18 December 2006 on the registration, evaluation, authorisation and restriction of chemical substances
(REACH), on the creation of a European Agency for chemical substances, on the modification of the Directive
1999/45/EC and on the repeal of the Regulation (EEC) No. 793/93 of the Council, the Regulation (EC) No.
1488/94 of the Committee, the Directive 76/769/EEC of the Council as well as the Directives 91/155/EEC,
93/67/EEC, 93/105/EC and 2000/21/EC of the Committee

15.2 Chemical safety assessment


The mixture was not subjected to a safety assessment
EC Safety data sheet
in accordance with Regulation (EC) No. 1907/2006

Trade name: Zinc acidic Revised on: 15.04.2013


Product number: 2410 GZ, 2450 GZ Print date: 15.04.2013

Page 8 of 8

16. Other Information

Risk phrases:
R phrases: R 22 Harmful to health on ingestion.
R41 Risk of serious eye damage.
R 51/53 Poisonous to water organisms, can have a longer-term harmful effect in
waterbodies.

Complete hazard notes


H phrases:
H302 Harmful to health on ingestion
H314 Causes severe caustic burns to skin and severe eye damage
H400 Very poisonous to water organisms.
H410 Very poisonous to water organisms with long-term effect.

Bibliography and data sources


Regulations
Preparations directive (1999/45/EC), last changed by the Regulation (EC) No. 1907/2006. Substance directive
(67/548/EEC), last changed by the Directive 2009/2/EC.
REACH Regulation (EC) No. 1907/2006, last changed by the Regulation (EU) No. 412/2012.
CLP regulation (EC) No. 1272/2008, last changed by the Regulation (EU) No. 286/2011.

Methods used as per Article 9 of the Regulation (EC) No. 1272/2008 on the assessment of information for the
purpose of classification:
Classification in accordance with Regulation (EC) No. 1272/2008, Appendix VII (conversion table)

Legend
ADR European convention on the international transport of hazardous goods by road
(BlmSchV) Regulation for the implementation of the Federal Immission Control Act
CAS Chemical Abstracts Service
DIN Standard of the German Institute for Standardization (Deutsches Institut für Normung)
EC Effective Concentration
EC European Community
EN European Standard
IATA-DGR International Air Transport Association-Dangerous Goods Regulations ICAO-TI
International Civil Aviation Organization-Technical Instructions
IMDG-Code International Maritime Code for Dangerous Goods
ISO International Standards Organization
IUCLID International Uniform Chemical Information Database
LC Lethal Concentration
LD Lethal Dosage
MARPOL Maritime Pollution Convention = convention on prevention of maritime pollution through ships
OECD Organisation for Economic Co-operation and Development PBT
Persistent, bioaccumulative, toxic
RID Regulation for international railway transport of hazardous goods
TRGS Technical Rules for Hazardous substances
UN United Nations
VOC Volatile Organic Compounds vPvB very persistent and very bioaccumulative
VwVwS German Regulation on Substances Hazardous to Water
WGK Water hazard class

Exclusion of liability

According to our state of knowledge, the information contained herein is correct. However, the manufacturer shall not be held
liable in terms of correctness or completeness of the specified information. All materials can contain unknown risks and must
therefore be applied with caution.

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