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Waxes For Engineering Thermoplastics
Waxes For Engineering Thermoplastics
Waxes For Engineering Thermoplastics
ENGINEERING
THERMOPLASTICS
2 Waxes for engineering thermoplastics
Waxes for
ENGINEERING THERMOPLASTICS
Safety information 22
3
Processing of
ENGINEERING THERMOPLASTICS
The quality assurance system was certified by the Deutsche Gesellschaft zur Zertifizierung
von Qualitätssicherungssystemen mbH (German Association for the Certification of Quality
Assurances Systems, DQS) in November 1992. Thus the requirements of DIN ISO 9001
are fulfilled.
5
Product
DESCRIPTION
Licowax, Licolub, Licocene and Licomont can be divided into Amide wax
three groups with regard to their chemical structure: Licowax C is an amide wax of the N, N’-bisstearoylethylene-
diamine (EBS) type with increased thermo stability. Due to its
Polyethylene waxes low volatility, Licowax C is used in engineering plastics which
The PE waxes from Clariant are polymerized according to are processed at higher temperatures.
the Ziegler process, and they possess a particularly high
thermo-stability. Licowax C does not affect the transparency of any polymer and
is widely used as a typical slip- and anti-blocking agent.
Licowax PE 520 is a branched polyethylene wax of medium
molecular weight and low density. It is remarkable for its high Licolub FA 1 powder vegetable based is identical to Licowax C,
resistance to oxidation, complete freedom from specks and good but based on stearic acid of pure vegetable origin.
organoleptic properties. Licowax PE 520 is incompatible with
polar plastics and serves as an effective external lubricant.
Licolub WE 40 is a complex ester of montanic acids and serves Further information on the individual products is contained in
as a lubricant to improve the ease of flow and as a mold-releasing the relevant product data sheets.
agent in engineering plastics. On account of its polar centers and
the long non-polar chains the montanic acid esters show good
compatibility with both polar and non-polar plastics. Montan
waxes thus combine internal and external lubricating effects while
maintaining the transparency and good mold release properties
of injection molded parts. A further positive property is their low
volatility and migration tendency. This is especially important in
the processing of engineering resins, as the processing temperatures
are generally high in this case.
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Product data
OVERVIEW
Licowax E Esterwax on the basis of montanic acids ~ 81 1) ~ 18 ~ 20 * Pale yellowish
Licowax OP Partly saponified ester wax on the basis of montanic acids ~ 99 1) ~ 12 ~ 300 ** Yellowish
Ca2+
Licolub WE 4 Ester wax on the basis of montanic acids ~ 80 1) ~ 26 ~ 60 * Yellowish
n
Licolub WM 31 Montanic acid and long chain ~ 74 1) ~ 12 ~ 26 * Pale yellowish
aliphatic acid based ester wax
Licowax PED 191 Polar polyethylene wax ~ 123 1) ~ 17 ~ 1800 Almost white
Licocene PE MA 4221 Maleic anhydride grafted ~ 123 2) ~ 18 ~ 140 Almost white
metallocene PE wax
Licomont CaV 102 Ca salt of the montanic acids – ~ 10 – Pale yellowish
Ca2+ [ -
]2
* = At 100 °C, ** = at 120 °C, 1) = Drop point ISO 2176, 2) = Drop point ASTM D 3954
Licowax E
Licowax OP
Licolub WE 4
Licolub WE 40
Licolub WM 31
Licolub H 12
Licowax C
Licowax PE 520
Licocene PE MA 4221
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Waxes for
polyamides (PA)
The possibilities of polyamide modifications frequently lead to These amide waxes are also successfully used as lubricating agents
critical processing characteristics. They show a strong tendency to in the production of PA fibers and films.
adhere to hot machine parts, highly filled compounds do not flow
easily in the injection molding tool, which leads to damage of the For applications which are very color sensitive (e. g. bright white)
polymer and is apparent in the poor quality of the end product. we recommend to use our polar modified metallocene wax,
Licocene PE MA 4221 for demolding properties.
Lubricants and mold release agents
The montan waxes Licowax E and Licowax OP have a strong Figure 1 clearly shows how the demolding force depends on the
release effect when added to polyamide. We recommend concentration of the added waxes.
concentrations of 0.3 – 0.5 % in unfilled polyamide, in the
case of filled or reinforced materials, up to 1.0 %, depending Figure 2 shows the reduced demolding force of different Licowax
on the filler content. types in PA 6.
Figure 1: Licowax E in polyamide 6 – mold-release effect Figure 2: Better performance of montan wax in polyamide 6 compared
> 10000 to standard lubricants – measurement of release force
internal method internal method
3500 7000
3000
Demolding force[ n ]
Demolding force[ n ]
2500
5000
2000
1500
3000
1000
500
0 1000
Without 0.05 % 0.1 % 0.2 % 0.3 % 0.4 % 0.5 % Without Licowax E Licowax OP PETS
Nucleating agents Figure 4 illustrates the nucleating effect of Licomont CaV 102
Whereas inorganic nucleating agents such as talc and mica are in polyamide 6.6 glass fiber reinforced, which has a medium
added for normal applications, organic nucleating agents are crystallization rate without additives. In this example a cycle time
preferred when the requirements for homogeneity and mechanical reduction of 23 % is achieved, due to faster crystallization and
properties are higher. better flow of the polymer melt.
Figure 3: Better performance of montan wax in polyamide 6.6 compared Figure 4: Nucleating effect of Licomont CaV 102 –
to standard lubricants – measurement of release force injection molding of polyamide 6.6 GF (30 % glass fibers)
internal method internal method
28 30
MFR [ g / 10 min ]
26 25
Cycle time [s]
- 23 %
24 20
22 15
Without Licowax E Licowax OP Licowax WE 4 Without + 0.5 % Licomont CaV 102
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Waxes for
polyesters (Pet/PBt)
Lubricants and release agents in Pet/PBt Furthermore the polar modified metallocene wax Licocene
Montan waxes like Licowax E, Licowax OP, Licolub WE 4 and PE MA 4221 can be used for this purpose as an alternative to
Licolub WE 40 are mainly used in polyester compounds for montan waxes, if the slight yellowish color of the montan waxes
injection molding and extrusion applications. is an obstacle, especially in natural colored polyester compounds.
For applications like bottles and films, which are produced by The increased flow ability and the favorable demolding
calandaring and blow molding, we recommend the use of amide characteristics as a result of the use of our products in polyester
waxes like Licowax C or Licolub FA 1 powder vegetable based are demonstrated in the following diagrams by determination of
as they act as excellent slip- and anti-blocking agents. Usual the MFR and the demolding force (Figures 10 – 14).
concentrations are about 0.1 – 0.5 %.
Figure 10: Lubricants in polyester (PET) – measurement of the demolding force Figure 11: L
ubricants in polyester (PET) – improvement of flow
6000
Demolding force [ n ]
40
4000
20
2000
0 0
Without Licowax E Licowax OP Licolub Licolub Without Licowax E Licowax OP Licolub Licomont
WE 4 WE 40 WE 4 CaV 102
Formulation: pet + 0.3 % Test product Formulation: pET + 0.3 % Test product
5000 26
3000 24
1000 22
Without Licowax E Licowax OP PETS Without Licowax E Licowax OP Licowax WE 4
Formulation: PBT + 0.3 % Test product Formulation: PBT + 0,3 % Test product
6
Release force [ N ]
800
400
2
0 0
Without Licowax E Licocene Without Licowax E Licocene
PE MA 4221 PE MA 4221
Formulation: pBt + 0.3 % Test product Formulation: pbT + 0.3 % Test product
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Waxes for
polyesters (Pet/PBt)
Nucleation
The sodium salt of long-chain aliphatic carboxylic acid, such
as contained in our Licomont NaV 101, has proved to be a
25
suitable nucleating agents in PET and PBT. Due to the high
molecular weight, it has a low volatility and favorable migration
characteristic in the finished product.
15
In addition to the excellent nucleation effect of the Licomont Without 0.1 % 0.2 % 0.4 %
NaV 101, this product also has outstanding lubrication and Formulation: PET + x % Licomont NaV 101
mold-releasing effects. Licomont NaV 101 is effective in a
concentration of 0.1 – 0.4 % in polyester. In the case of film
extrusion this leads to improved stretch characteristics and
higher mechanical strength.
■ Transparency [ % ]
75
they have almost no adverse effect on the transparency of PC.
2500
carbonate using Licowax E and Licowax PED 191 in comparison Formulation: PC + 0.3 % Test product
to the use of PETS.
Figure 17: L
ubricants in polycarbonate – measurement of demolding force
Figure 17 illustrates the reduction of the release force of the
internal method
polycarbonate with different montan waxes compared to standard 5000
lubricants.
4000
Demolding force [ n ]
Dispersion
We recommend the addition of Licowax E, Licowax OP or 3000
Licolub WE 40 in concentrations of 0.1 – 1.0 % as a dispersing
agent for homogeneous distribution of filling and reinforcing 2000
materials or pigments in polycarbonate.
1000
0
Without Calcium- PETS Licowax Licowax Licolub
stearat E OP WE 4
17
Waxes for
thermoplastic polyurethanes (tPU)
20
6
15
4
10
2
5
0 0
Without Licowax E Licowax OP Without Licowax E Licowax OP Licolub We 4 Licowax C
Formulation: TPU + 0.5 % Test product Formulation: TPU + 0.5 % Test product
Figure 7: Sticking behavior of aromatic polyether-based thermoplastic polyurethane compounds (Two Roll Mill)
internal method
30
25
20
Glue power
15
10
0
0 200 400 600 800 1000 1200 1400 1600 1800 2000
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Waxes for
polyacetals (PoM)
Lubricants and mold release agents Figure 8: Lubricants in POM – improvement of flow
in polyacetal
internal method
The main application fields for our lubricants for POM are in 50
based from the Clariant range can be added in concentrations of Formulation: pom + 0.2 % Test product
2500
Demolding force [ n ]
2000
1500
1000
500
0
Without Licowax E Licowax OP Licolub Licomont
WE 4 CaV 102
Formulation: pom + 0.3 % Test product
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Safety
Information
www.additives.clariant.com
www.clariant.com
This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express or
implied, as to the information’s accuracy, adequacy, sufficiency or freedom from defect and assumes
no liability in connection with any use of this information. Any user of this product is responsible for
determining the suitability of Clariant’s products for its particular application. * Nothing included in this
information waives any of Clariant’s General Terms and Conditions of Sale, which control unless it agrees
DA 8289 E | 09.2013
otherwise in writing. Any existing intellectual/industrial property rights must be observed. Due to possible
changes in our products and applicable national and international regulations and laws, the status of our
products could change. Material Safety Data Sheets providing safety precautions, that should be observed
when handling or storing Clariant products, are available upon request and are provided in compliance
with applicable law. You should obtain and review the applicable Material Safety Data Sheet information
before handling any of these products. For additional information, please contact Clariant.
* For sales to customers located within the United States and Canada the following applies in addition:
NO EXPRESS OR IMPLIED WARRANTY IS MADE OF THE MERCHANTABILITY, SUITABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE OF ANY PRODUCT OR SERVICE.