UNIQUE COLLEGE FOR GIRLS

99-A, New Muslim Town, Wahdat Road Lahore

Subject: Chemistry (Ch #12) Class: 2nd Year
Total marks: 20 (Group A) Time: 45Min
Prof. Riaz Hussain Date: 09-01-12

Q.1: Encircle the correct answers: 6x1=6

1. Ether is formed when alkyl halide is treated with:

(a) Na metal (b) Aquous NaOH (c) Silver nitrate (d) Silver oxide

2. Crotonaldehyde formed from an aldol, which is formed by condensation of:

(a) Ethanal (b) Propanal (c) Methanal (d) Propanone

3. Compound A when treated with Benedicts solution, no brick red ppt. the compound A is:

(a) CH3CHO (b) CH3COCH3 (c) CH3CH2CHO (d) CH2O

4. In reaction CH3COCH3+HCN  Cyanohydrin, it involves:

(a) Electrophilic addition (b) Electrophilic substitution

(c) Nucleophilic substitution (d) Nucleophilic addition

5. Compound ‘X’ is treated with NaBH 4 forms product B and B is used in denaturing of ethanol, the

compound ‘X’ is:

(a) H2C=CH2 (b) HCHO (c) CH3CHO (d) CH3COCH3

6. Acetaldehyde is formed by dry distillation of:

(a) Ca-acetate + Ca-formate (b) Ca-formate + Ca-oxalate

(c) Ca-acetate (d) Ca-formate

SUBJECTIVE
Q.2:Answer the Short questions. 5x2=10
1. How will you bring the conversion: (a) Ethanal into propanone (b) Ethene into ethanal
2. Write the mechanism of cannizaro reaction.
3. How will you distinguish between acetone and ethyl alcohol?
4. What is silver mirror test?
5. Write two reactions by adding sodium borohydride to an aqueous solution of an aldehyde or ketone.
Q.3: Define and discuss aldol Condensation reactions with mechanism. 04
 UNIQUE COLLEGE FOR GIRLS
99-A, New Muslim Town, Wahdat Road Lahore
Subject: Chemistry (Ch #12) Class: 2nd Year
Total marks: 20 (Group B) Time: 45Min
Prof. Riaz Hussain Date: 09-01-12

Q.1: Encircle the correct answers: 6x1=6

1. Compound ‘X’ is treated with NaBH 4 forms product B and B is used in denaturing of ethanol, the

compound ‘X’ is:

(a) H2C=CH2 (b) HCHO (c) CH3CHO (d) CH3COCH3

2. Acetaldehyde is formed by dry distillation of:

(a) Ca-acetate + Ca-formate (b) Ca-formate + Ca-oxalate

(c) Ca-acetate (d) Ca-formate

3. Crotonaldehyde formed from an aldol, which is formed by condensation of:

(a) Ethanal (b) Propanal (c) Methanal (d) Propanone

4. Compound A when treated with Benedicts solution, no brick red ppt. the compound A is:

(a) CH3CHO (b) CH3COCH3 (c) CH3CH2CHO (d) CH2O

5. Ether is formed when alkyl halide is treated with:

(a) Na metal (b) Aquous NaOH (c) Silver nitrate (d) Silver oxide

6. In reaction CH3COCH3+HCN  Cyanohydrin, it involves:

(a) Electrophilic addition (b) Electrophilic substitution

(c) Nucleophilic substitution (d) Nucleophilic addition

SUBJECTIVE
Q.2:Answer the Short questions. 5x2=10
1. How will you bring the conversion: (a) Ethanal into propanone (b) Ethene into ethanal
2. Write the mechanism of cannizaro reaction.
3. How will you distinguish between acetone and ethyl alcohol?
4. What is silver mirror test?
5. Write two reactions by adding sodium borohydride to an aqueous solution of an aldehyde or ketone.
Q.3: Define and discuss aldol Condensation reactions with mechanism. 04