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 Answers & Solutions For JEE MAIN-2015
(Code-D)

Time Durations : 3 hrs. Maximum Marks: 360

(Physics, Mathematics and Chemistry)

Important Instructions :

1. The test is of 3 hours duration.

2. The Test Booklet consists of 90 questions. The maximum marks are 360.
3. There are three parts in the question paper A, B, C consisting of Physics,
Mathematics and Chemistry having 30 questions in each part of equal weightage. Each
question is allotted 4 (four) marks for each correct response.
4. Candidates will be awarded marks as stated above in Instructions No. 3 for correct response
of each question. ¼ (one-fourth) marks will be deducted for indicating incorrect response
of each question. No deduction from the total score will be made if no response is
indicated for an item in the answer sheet.
5. There is only one correct response for each question. Filling up more than one response
in each question will be treated as wrong response and marks for wrong response will be
deducted accordingly as per instruction 4 above.
6. Use Blue/Black Ball Point Pen only for writing particulars/marking responses on Side-1 and
Side-2 of the Answer Sheet. Use of pencil is strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers,
pager, mobile phone, any electronic device, etc. except the Admit Card inside the
examination room/hall.
8. The CODE for this Booklet is D. Make sure that the CODE printed on Side-2 of the
Answer Sheet and also tally the serial number of the Test Booklet and Answer Sheet are
the same as that on this booklet. In case of discrepancy, the candidate should immediately
report the matter to the Invigilator for replacement of both the Test Booklet and the Answer
Sheet.
 Study Materials
NCERT Solutions for Class 6 to 12 (Math & Science)
Revision Notes for Class 6 to 12 (Math & Science)
RD Sharma Solutions for Class 6 to 12 Mathematics
RS Aggarwal Solutions for Class 6, 7 & 10 Mathematics
Important Questions for Class 6 to 12 (Math & Science)
CBSE Sample Papers for Class 9, 10 & 12 (Math &
Science)
Important Formula for Class 6 to 12 Math
CBSE Syllabus for Class 6 to 12
Lakhmir Singh Solutions for Class 9 & 10
Previous Year Question Paper
CBSE Class 12 Previous Year Question Paper
CBSE Class 10 Previous Year Question Paper
JEE Main & Advanced Question Paper
NEET Previous Year Question Paper

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 PART–A : PHYSICS

1. Distance of the centre of mass of a solid uniform 3. A pendulum made of a uniform wire of cross-
cone from its vertex is z0. If the radius of its base is sectional area A has time period T. When an
R and its height is h then z0 is equal to additional mass M is added to its bob, the time
period changes to TM. If the Young's modulus of the
5h 3h 2
(1) (2) 1
8 8R material of the wire is Y then is equal to
Y
h2 3h (g = gravitational acceleration)
(3) (4)
4R 4 ⎡ ⎛ T ⎞2 ⎤ A
⎡ ⎛ TM ⎞ 2 ⎤ A
Answer (4) (1) ⎢1  ⎜ T ⎟ ⎥ Mg (2) ⎢1  ⎜ T ⎟ ⎥ Mg
⎢⎣ ⎝ ⎠ ⎥⎦ ⎢⎣ ⎝ M ⎠ ⎥⎦
Sol. dm  r 2 .dy.
⎡⎛ TM ⎞ 2 ⎤ A ⎡⎛ TM ⎞ 2 ⎤ Mg
(3) ⎢⎜ T ⎟  1⎥ Mg (4) ⎢⎜ T ⎟  1⎥ A
⎣⎢⎝ ⎠ ⎦⎥ ⎣⎢⎝ ⎠ ⎦⎥

y Answer (3)
r h
l
Sol. T  2  g ...(1)

l  l
TM  2  ...(2)
R g

h Fl Mgl
Y ⇒ l 
yCM 
∫ ydm  ∫ 0
r 2 dy   y
Al AY
...(3)
1 2
∫ dm 3
R h
1 A ⎡⎛ TM ⎞
2
⎤
⇒  ⎢⎜ ⎟  1⎥
Y Mg ⎢⎣⎝ T ⎠ ⎥⎦
3h
 4. For a simple pendulum, a graph is plotted between
4 its kinetic energy (KE) and potential energy (PE)
2. A red LED emits light at 0.1 watt uniformly around against its displacement d. Which one of the
it. The amplitude of the electric field of the light at following represents these correctly?
a distance of 1 m from the diode is (Graphs are schematic and not drawn to scale)
(1) 5.48 V/m (2) 7.75 V/m E KE
(3) 1.73 V/m (4) 2.45 V/m
Answer (4) d
(1)
P
Sol. I   U av  c ...(1)
4 r 2
PE
1 E
U av   0 E02 ...(2)
2

P 1 PE
⇒   0 E02  c
4 r 2 2
(2) KE
2P
⇒ E0   2.45 V/m
4r 2 0 c

2
 E 7. Two long current carrying thin wires, both with
KE current I, are held by insulating threads of length L
and are in equilibrium as shown in the figure, with
threads making an angle  with the vertical. If wires
(3) PE
have mass  per unit length then the value of I is
d
(g = gravitational acceleration)
E
PE

(4) KE L
d

Answer (4)
1 I I
Sol. KE  m2 ( A2  d 2 )
2 gL gL
1 (1) 2 tan  (2) tan 
PE  m2 d 2 0 0
2
At d = ± A,
gL gL
PE = maximum while KE = 0. (3) sin   cos  (4) 2 sin   cos 
0 0
5. A train is moving on a straight track with speed
20 ms–1. It is blowing its whistle at the frequency of Answer (4)
1000 Hz. The percentage change in the frequency
heard by a person standing near the track as the
train passes him is (speed of sound = 320 ms–1) 
close to
(1) 18% (2) 24% T
(3) 6% (4) 12%
Sol.
Answer (4) F

⎡ v ⎤ ⎡ 320 ⎤ 320
Sol. f 1  f ⎢ v  v ⎥  f ⎢ 320  20 ⎥  f  300 Hz (l)g
⎣ s ⎦ ⎣ ⎦
T cos = gl …(1)
⎡ v ⎤ 320
f2  f ⎢ ⎥ f Hz 0 I  Il
⎣ v  vs ⎦ 340 T sin = . …
2   2 L sin  
⎛f ⎞ ⎛ f  f1 ⎞
100  ⎜ 2  1 ⎟  ⎜ 2 ⎟  100
f
⎝ 1 ⎠ ⎝ f1 ⎠ gL
⇒ I  2 sin 
⎡ 300 ⎤  0 cos 
 100 ⎢  1⎥  12%
⎣ 340 ⎦
8. In the circuit shown, the current in the 1  resistor
6. When 5 V potential difference is applied across a
is
wire of length 0.1 m, the drift speed of electrons is
2.5 × 10–4 ms–1. If the electron density in the wire is 6V 2
P
8 × 1028 m–3, the resistivity of the material is close to
(1) 1.6 × 10–6 m (2) 1.6 × 10–5 m
(3) 1.6 × 10 m
–8 (4) 1.6 × 10–7 m 1 9V
Answer (2)
l 3 3
Sol. V  IR  I 
A
Q
VA VA V
⇒    (1) 0.13 A, from Q to P
Il ln eA  d l n  e  d
(2) 0.13 A, from P to Q
5
⇒ (3) 1.3 A, from P to Q
0.1  2.5  10  1.6  10 19  8  10 28
19

= 1.6 × 10–5 m (4) 0 A

3
Answer (1) t
 L
Sol. I  I 0 e  ,  
Sol. From KVL, R

9 = 6I1 – I2 …(1) 1103

15  1/5103
 e  0.67 mA
6 = 4I2 – I1 …(2) 150
Solving, I1 – I2 = –0.13 A
11. An LCR circuit is equivalent to a damped
6V pendulum. In an LCR circuit the capacitor is
I2 P 2
I1 charged to Q0 and then connected to the L and R as
shown below :
I1–I2
3 R L
1 9V

Q
3
9. Assuming human pupil to have a radius of 0.25 cm
and a comfortable viewing distance of 25 cm, the C
minimum separation between two objects that
human eye can resolve at 500 nm wavelength is If a student plots graphs of the square of maximum
(1) 100 m (2) 300 m charge QMax
2
 on the capacitor with time (t) for two
(3) 1 m (4) 30 m different values L1 and L2 (L1 > L2) of L then which
of the following represents this graph correctly?
Answer (4) (Plots are schematic and not drawn to scale)

1.22  1.22  (500  10 9 m) 2

QMax
Sol. RP   L1
2 sin  ⎛ 1 ⎞
2  1 ⎜ ⎟
⎝ 100 ⎠ (1)
L2
 t
0.25 cm

25 cm
2
= 3.05 × 10–5 m QMax
Q0 (For both L1 and L2)
= 30 m
(2)
10. An inductor (L = 0.03 H) and a resistor (R = 0.15
k) are connected in series to a battery of 15 V EMF t
in a circuit shown below. The key K1 has been kept
closed for a long time. Then at t = 0, K1 is opened
and key K 2 is closed simultaneously. At 2
QMax
t = 1 ms, the current in the circuit will be ( e 5  150) L1
0.03 H 0.15 k (3)
L2
t
K2

2
QMax
K1 L2
15 V
(1) 6.7 mA (2) 0.67 mA (4)
L1
(3) 100 mA (4) 67 mA t
Answer (2)

4
Answer (3) Answer (4)

Sol. For a damped pendulum, A = A0e–bt/2m 3C

Sol. C aq = ...(i)
3C
⎛ 3C ⎞
Total charges q  ⎜
R ⎞
⎛⎜ ⎟t ⎟E ...(ii)
 A  A0 e ⎝ 2L ⎠ ⎝ 3C ⎠
Charge upon capacitor 2 F,

(Since L plays the same role as m) 2 3CE 2CE 2E

q'    
3 (3  C ) 3  C 1  3
12. In the given circuit, charge Q2 on the 2 F capacitor C
changes as C is varied from 1 F to 3 F. Q2 as a
function of C is given properly by : (Figures are dQ dQ 2
Now,  0, 2  0
dC dC
drawn schematically and are not to scale)
13. From a solid sphere of mass M and radius R a cube
of maximum possible volume is cut. Moment of
1 F inertia of cube about an axis passing through its
C center and perpendicular to one of its faces is
2 F 4 MR 2 4 MR 2
(1) (2)
9 3 3 3
MR 2 MR 2
(3) (4)
E 32 2  16 2 
Charge Answer (1)

Q2 Sol. d  2 R  a 3

(1)
C
1 F 3 F

Charge

Q2
(2)
2
C  a R
1 F 3 F 3

Charge 4 3
R
M 3
 3  
Q2 M ⎛ 2 ⎞ 3
2
⎜ R⎟
(3) ⎝ 3 ⎠
C
1 F 3 F 2M
 M' 
3
Charge
M ' a2 2 M 4 2 1
Q2 I   R 
6 3 3 6
(4)
C 4 MR 2
1 F 3 F I
9 3

5
14. The period of oscillation of a simple pendulum is Answer (1)
L Sol. Frequencies of resultant signal are
T  2
g . Measured value of L is 20.0 cm known fe + fm, fe and fe – fm
to 1 mm accuracy and time for 100 oscillations of (2000 + 5) kHz, 2000 kHz, (2000 – 5) kHz,
the pendulum is found to be 90 s using a wrist 2005 kHz, 2000 kHz, 1995 kHz
watch of 1 s resolution. The accuracy in the
determination of g is 17. A solid body of constant heat capacity 1 J/°C is
being heated by keeping it in contact with reservoirs
(1) 1% (2) 5% in two ways :
(3) 2% (4) 3% (i) Sequentially keeping in contact with 2
Answer (4) reservoirs such that each reservoir supplies
same amount of heat.
2 l
Sol. g  4  . (ii) Sequentially keeping in contact with 8
T2 reservoirs such that each reservoir supplies
g l T same amount of heat.
  100   100  2  100 In both the cases body is brought from initial
g l T
temperature 100°C to final temperature 200°C.
l t Entropy change of the body in the two cases
=  100  2.  100
l t respectively is
0.1 1 (1) ln 2, 2ln 2 (2) 2ln 2, 8ln 2
=  100  2   100
20.0 90 (3) ln 2, 4ln 2 (4) ln 2, ln 2
100 200 1 20 Answer (None)
=     3%
200 90 2 9 dQ dT
15. On a hot summer night, the refractive index of air is Sol. ds   ms
T T
smallest near the ground and increases with height
form the ground. When a light beam is directed dT T 473
horizontally, the Huygen's principle leads us to s  ∫ ds  ms ∫ 1log e 2  log e
T T1 373
conclude that as it travels, the light beam
18. Consider a spherical shell of radius R at
(1) Bends downwards
temperature T. The black body radiation inside it
(2) Bends upwards can be considered as an ideal gas of photons with
(3) Becomes narrower U
internal energy per unit volume u   T 4 and
(4) Goes horizontally without any deflection V
Answer (2) 1 U
pressure P  ⎛⎜ ⎞⎟ . If the shell now undergoes an
Sol. Consider a plane wavefront travelling horizontally. 3⎝V ⎠
As it moves, its different parts move with different adiabatic expansion the relation between T and R is
speeds. So, its shape will change as shown
1
 Light bends upward (1) T  1 (2) T 
R R3
(3) T  e–R (4) T  e–3R
Answer (1)

1⎛U ⎞ 1 4
Sol. P  ⎜ ⎟  kT ...(i)
3⎝V ⎠ 3
16. A signal of 5 kHz frequency is amplitude modulated
on a carrier wave of frequency 2 MHz. The PV = RT ...(ii)
frequencies of the resultant signal is/are RT 1 4
 kT
(1) 2005 kHz, 2000 kHz and 1995 kHz V 3
(2) 2000 kHz and 1995 kHz  V  T–3
(3) 2 MHz only 1
R
(4) 2005 kHz and 1995 kHz T

6
19. Two stones are thrown up simultaneously from the (1) R1 = 0 and R2 < (R4 – R3)
edge of a cliff 240 m high with initial speed of
(2) 2R < R4
10 m/s and 40 m/s respectively. Which of the
following graph best represents the time variation of (3) R1 = 0 and R2 > (R4 – R3)
relative position of the second stone with respect to
(4) R1  0 and (R2 – R1) > (R4 – R3)
the first?
(Assume stones do not rebound after hitting the Answer (1, 2)
ground and neglect air resistance, take g = 10 m/s2)
Q
(The figures are schematic and not drawn to scale) Sol. V0  k ...(i)
R

(y2 – y1) m kQ
240
VI   3R 2  r 2 
2 R3

3
V  V0 R1 = 0
(1) 2
t (s) 5 kQ  2 2
8 12  kQ 3R 3 r
4 R 2R

(y2 – y1) m R
 R2 
240 2

3 kQ kQ
 3
(2) 4 R R
t (s) 4R
8 12  R3 
3
1 kQ kQ

(y2 – y1) m 4 R R4
240
 R4 = 4R  R4 > 2R
21. Monochromatic light is incident on a glass prism of
(3) angle A. If the refractive index of the material of the
t (s) prism is , a ray, incident at an angle , on the face
t 8 12 AB would get transmitted through the face AC of the
prism provided.
(y2 – y1) m
240
A

(4) 

t (s)
12
Answer (2) B C
Sol. Till both are in air (From t = 0 to t = 8 sec)
1
⎡ ⎛ 1 ⎛ 1 ⎞ ⎞
⎤
x = x2 – x1 = 30t (1)   cos ⎢ sin ⎜ A  sin ⎜  ⎟ ⎟ ⎥
⎣⎢ ⎝ ⎝ ⎠ ⎠ ⎦⎥
 x  t
1
⎡ ⎛ 1 ⎛ 1 ⎞ ⎞
⎤
(2)   cos ⎢ sin ⎜ A  sin ⎜  ⎟ ⎟ ⎥
When second stone hits ground and first stone is in
air x decreases. ⎢⎣ ⎝ ⎝ ⎠ ⎠ ⎥⎦
20. A uniformly charged solid sphere of radius R has ⎡ ⎤
⎛ 1 ⎛ 1 ⎞ ⎞
potential V0 (measured with respect to ) on its 1
(3)   sin ⎢ sin ⎜ A  sin ⎜  ⎟ ⎟ ⎥
surface. For this sphere the equipotential surfaces ⎣⎢ ⎝ ⎝ ⎠ ⎠ ⎦⎥
3V0 5V0 3V0 V ⎡ ⎛ ⎤
with potentials , , and 0 have radius 1 1 ⎛ 1 ⎞ ⎞
2 4 4 4 (4)   sin ⎢ sin ⎜ A  sin ⎜  ⎟ ⎟ ⎥
R1, R2, R3 and R4 respectively. Then ⎣⎢ ⎝ ⎝ ⎠ ⎠ ⎦⎥

7
Answer (3) z

B
(b) I
 r I y
1 r2 I
Sol. x I
z

sin  =  sin r1 I
B
I
sin  (c) I
y
 sin r1 =
 I
x
z
⎛ sin  ⎞
1
 r1 = sin ⎜ ⎟
⎝  ⎠ B
(d) I
⎛ sin  ⎞ I y
r2 = A – sin 1 ⎜ ⎟ I
⎝  ⎠ x I
If there is a uniform magnetic field of 0.3 T in the
⎛1⎞
1
 r2 < sin ⎜ ⎟ positive z direction, in which orientations the loop
⎝⎠
would be in (i) stable equilibrium and (ii) unstable
equilibrium?
⎛ sin  ⎞ 1 ⎛ 1 ⎞
A  sin 1 ⎜ ⎟  sin ⎜ ⎟
⎝  ⎠ ⎝⎠ (1) (b) and (d), respectively

(2) (b) and (c), respectively

⎛1⎞ ⎛ sin  ⎞
 A  sin 1 ⎜ ⎟  sin 1 ⎜ ⎟

⎝ ⎠ ⎝  ⎠ (3) (a) and (b), respectively

(4) (a) and (c), respectively

⎛ 1 ⎛ 1 ⎞ ⎞ sin 
 sin ⎜ A  sin ⎜  ⎟ ⎟   Answer (1)
⎝ ⎝ ⎠⎠
 
Stable equilibrium M||B
⎛ ⎛ 1 ⎛ 1 ⎞ ⎞
⎞
  ⎜⎜ sin ⎜ A  sin ⎜  ⎟ ⎟ ⎟⎟  sin  z
⎝ ⎝ ⎝ ⎠⎠⎠

B
⎛ 1 ⎛ 1 ⎛ 1 ⎞ ⎞
⎞
 sin ⎜⎜  sin ⎜ A  sin ⎜  ⎟ ⎟ ⎟⎟   I
⎝ ⎝ ⎝ ⎠⎠⎠ I y
I
x I
22. A rectangular loop of sides 10 cm and 5 cm carrying
 
 
a current I of 12 A is placed in different orientations
Unstable equilibrium M|| B
as shown in the figures below:
z
z
I
B B
I I
(a)
y I I
y
I I
x x I

8
23. Two coaxial solenoids of different radii carry Answer (1)

current I in the same direction. Let F1 be the
 1
magnetic force on the inner solenoid due to the Sol.    ...(i)
3 RT
2 d ⎛⎜ ⎞⎟
 vrms 2 N
outer one and F2 be the magnetic force on the outer ⎝V ⎠ M
solenoid due to the inner one. Then
  V
(1) F1 is radially inwards and F2 = 0  ...(ii)
T
 
(2) F1 is radially outwards and F2 = 0 TV – 1 = k ...(iii)
   1
(3) F1 = F2 = 0  V 2

 
(4) F1 is radially inwards and F2 is radially 26. From a solid sphere of mass M and radius R, a
outwards R
spherical portion of radius is removed, as
2
Answer (3) shown in the figure. Taking gravitational potential
Sol. Net force on each of them would be zero. V = 0 at r = , the potential at the centre of the
cavity thus formed is
24. A particle of mass m moving in the x direction with
speed 2v is hit by another particle of mass 2m (G = gravitational constant)
moving in the y direction wth speed v. If the
collision is perfectly inelastic, the percentage loss in
the energy during the collision is close to
(1) 56% (2) 62%
(3) 44% (4) 50%
2GM 2GM
Answer (1) (1) (2)
3R R
Sol. m 2v GM GM
v v'
(3) (4)
2R R
= 2mv 2
 v' Answer (4)
3m
Sol. V = V1 – V2
2m
GM ⎡ 2 ⎛ R ⎞ 2 ⎤
1 1 V1   ⎢ 3R  ⎜ ⎟ ⎥
KE loss = m  2 v    2 m  v
2 2 2 R3 ⎣ ⎝2⎠ ⎦
2 2
M
3G ⎛⎜ ⎞⎟
2 V2   ⎝ 8 ⎠
1 ⎛ 2mv 2 ⎞ 5 2 ⎛ R⎞
   3m  ⎜⎜ ⎟⎟  mv 2⎜ ⎟
2 ⎝ 3m ⎠ 3 ⎝2⎠

5 GM
mv 2  V
3 R
Required % =  100  56%
2mv 2  mv 2
F
25. Consider an ideal gas confined in an isolated closed 27. A B
chamber. As the gas undergoes an adiabatic
expansion, the average time of collision between
molecules increases as Vq, where V is the volume of
the gas. The value of q is
Given in the figure are two blocks A and B of
⎛ CP ⎞ weight 20 N and 100 N, respectively. These are
⎜  ⎟
⎝ Cv ⎠ being pressed against a wall by a force F as shown.
If the coefficient of friction between the blocks is 0.1
1 1 and between block B and the wall is 0.15, the
(1) (2)
2 2 frictional force applied by the wall on block B is
3  5 3  5 (1) 120 N (2) 150 N
(3) (4)
6 6 (3) 100 N (4) 80 N

9
Answer (1) (3) Its kinetic energy increases but potential energy
and total energy decrease
(4) Kinetic energy, potential energy and total energy
fs decrease
A B
Sol. F N Answer (3)

20 N 100 N z2
Sol. PE  27.2 eV
n2
Clearly fs = 120 N (for vertical equilibrium of the
system) 13.6 z 2
TE   eV
n2
28. A long cylindrical shell carries positive surface
charge  in the upper half and negative surface
13.6 z 2
charge – in the lower half. The electric field lines KE  eV
n2
around the cylinder will look like figure given in

(figures are schematic and not drawn to scale) 13.6

KE  eV , As n decreases, KE
n2

++ ++ 27.2
+ + PE   eV , as n decreases, PE
(1) –– ––
–– –– n2

13.6
TE   eV , as n decreases, TE
n2

(2) 30. Match List-I (Fundamental Experiment) with List-II

(its conclusion) and select the correct option from
the choices given below the list:

List -I List-II
++++
+
––
+
––
(A) Franck-Hertz (i) Particle nature
(3) –– –– experiment of light
(B) Photo-electric (ii) Discrete energy
experiment levels of atom
(C) Davison-Germer (iii) Wave nature of
experiment electron
+ (iv) Structure of
++
+
++
–– –– atom
(4) –– ––

Answer (3) (1) (A) - (ii) (B) - (i) (C) - (iii)

(2) (A) - (iv) (B) - (iii) (C) - (ii)
Sol. The field line should resemble that of a dipole.
(3) (A) - (i) (B) - (iv) (C) - (iii)
29. As an electron makes a transition from an excited
state to the ground state of a hydrogen-like atom/ion (4) (A) - (ii) (B) - (iv) (C) - (iii)

(1) Kinetic energy decreases, potential energy Answer (1)

increases but total energy remains same Sol. Franck-Hertz exp.– Discrete energy level.

(2) Kinetic energy and total energy decrease but Photo-electric effect– Particle nature of light
potential energy increases Davison-Germer exp.– Diffraction of electron beam.

10
 PART–B : MATHEMATICS

   33. If the angles of elevation of the top of a tower from

31. Let a , b and c be three non-zero vectors such that
three collinear points A, B and C, on a line leading
no two of them are collinear and to the foot of the tower, are 30º, 45º and 60º
   1    respectively, then the ratio, AB : BC, is
( a  b )  c  |b ||c | a . If  is the angle between
3
 (1) 1 : 3 (2) 2 : 3
vectors b and c , then a value of sin  is
(3) 3 : 1 (4) 3 : 2
2 2 3 Answer (3)
(1) (2) P
3 3
Sol. AO = h cot 30º

2 2  2 h 3
(3) (4)
3 3 h
BO = h
Answer (3)
h
CO  30º 45º 60º
      1    3 A
Sol. ( a  c ) b  (b  c ) a  |b ||c | a B C O
3
AB AO  BO
   
1   BC BO  CO
  (b  c )  |b ||c |
3
h 3 h
1 
 cos    h
3 h
3

2 2
 sin    3
3
34. The number of points, having both co-ordinates as
32. Let O be the vertex and Q be any point on the integers, that lie in the interior of the triangle with
parabola, x2 = 8y. If the point P divides the line vertices (0, 0), (0, 41) and (41, 0), is
segment OQ internally in the ratio 1 : 3, then the
locus of P is (1) 820 (2) 780
(3) 901 (4) 861
(1) y 2  2 x (2) x 2  2 y
Answer (2)

(3) x 2  y (4) y 2  x
Sol. (0, 41)
Answer (2)
Sol. x2 = 8y A39
Let Q be (4t, 2t2)
y
⎛ t ⎞ 2 A2
2 B2
 P  ⎜ t, Q(4t, 2t )
⎝ 2 ⎟⎠ 3 A1 B1
P
1
Let P be (h, k) x (0, 0) (41, 0)
O
t2
 h = t, k  Total number of integral coordinates as required
2
= 39 + 38 + 37 + ....... + 1
 2k  h 2
39  40
  780
 Locus of (h, k) is x2 = 2y. 2

11
35. The equation of the plane containing the line 2x – Answer (1)
5y + z = 3; x + y + 4z = 5, and parallel to the plane, Sol. After solving equation (i) & (ii)
x + 3y + 6z = 1, is
2x – 3y + 4 = 0 ...(i)
(1) x  3y  6 z  7 (2) 2 x  6 y  12 z  13 2x – 4y + 6 = 0 ...(ii)
x = 1 and y = 2
(3) 2 x  6 y  12 z  13 (4) x  3y  6 z  7 A
Slope of AB × Slope of MN = – 1
(2, 3)
Answer (1) b3
2 ⎛ a  2 b  3⎞
b3 M⎜ ,
Sol. Required plane is  2  1 ⎝ 2 2 ⎠
⎟
a2 a2 N
1 (1, 2)
(2x – 5y + z – 3) + (x + y + 4z – 5) = 0 2
It is parallel to x + 3y + 6z = 1 (y – 3)(y – 1) = –(x – 2)x
(a, b)
2   5   1  4  y2 – 4y + 3 = –x2 + 2x
B (Image of A)
  
1 3 6 x2 + y2 – 2x – 4y + 3 = 0

11 Circle of radius = 2

Solving  =
2
 1  cos 2 x  3  cos x 
38. lim is equal to
 Required plane is x 0 x tan 4x

11 1
(2x – 5y + z – 3) – (x + y + 4z – 5) = 0 (1) 2 (2)
2 2
(3) 4 (4) 3
 x + 3y + 6z – 7 = 0
Answer (1)
36. Let A and B be two sets containing four and two
elements respectively. Then the number of subsets of 2 sin 2 x   3  cos x  x 2
Sol. lim  =2
tan 4 x x
x2
x0
the set A × B, each having at least three elements is  4x
4x
(1) 275 (2) 510
39. The distance of the point (1, 0, 2) from the point of
(3) 219 (4) 256 x2 y1 z2
intersection of the line   and the
Answer (3) 3 4 12
plane x – y + z = 16, is
Sol. n(A) = 4, n(B) = 2
n(A × B) = 8 (1) 3 21 (2) 13

Required numbers = 8C3 + 8C4 + ...... + 8C8 (3) 2 14 (4) 8

= 28 – (8C0 + 8C1 + 8C2) Answer (2)

= 256 – 37 x2 y1 z2

Sol.   
3 4 12
= 219
P  3  2, 4  1, 12   2 
37. Locus of the image of the point (2, 3) in the line
(2x – 3y + 4) + k(x – 2y + 3) = 0, k  R, is a Lies on plane x – y + z = 16
Then,
(1) Circle of radius 2
3  2  4   1  12   2  16
(2) Circle of radius 3 11  5  16

(3) Straight line parallel to x-axis 1 P  5, 3, 14

(4) Straight line parallel to y-axis Distance = 16  9  144  169  13

12
40. The sum of coefficients of integral powers of x in 42. The area (in sq. units) of the region described by
{(x, y) : y2  2x and y  4x – 1} is
 
50
the binomial expansion of 1  2 x is
15 9
(1) (2)
64 32
1 50 1 50
(1) (3  1) (2) (2  1)
2 2 7 5
(3) (4)
32 64
1 50 1 50 Answer (2)
(3) (3  1) (4) (3 )
2 2
y=1 1 y=1
Answer (3) Sol.

1  2 x   
50 50 50 1
Sol.  C0  C1 2 x  50 C 2 (2 x )2  .....
1
 50 C 50 ( 2 x )50
2
Sum of coefficient of integral power of x
50
 C0 2 0  50 C 2  2 2  50 C 4  2 4    50 C 50  2 50

We know that After solving y = 4x – 1 and y2 = 2x

(1 + 2)50 = 50
C0  50 C1  2  .....  50 C 50  2 50 y2
y  4 1
2
Then,
2y2 – y – 1 = 0

50 350  1 1 18 1 3 1
C0  50 C 2  2 2  .....  50 C 50  2 50  y  y  1,
2 4 4 2
41. The sum of first 9 terms of the series 1 1 2
⎛ y1⎞ y
1 3 1 3  2 3 13  2 3  3 3
A ∫ ⎜⎝ 4 ⎟⎠ dy  ∫ 2 dy
1/2 1/2
   ........ is
1 13 135 1 1
1 ⎡ y2 ⎤ 1 ⎡ y3 ⎤
(1) 142 (2) 192  ⎢  y ⎥  ⎢ ⎥
4 ⎣⎢ 2 ⎦⎥ 1/2 2 ⎢⎣ 3 ⎦⎥ 1/2
(3) 71 (4) 96
1 ⎡ 4  8  1  4 ⎤ 1 ⎡8  1⎤
Answer (4)  ⎥  2 ⎢ 24 ⎥
4 ⎢⎣ 8 ⎦ ⎣ ⎦
2
⎡ n  n  1 ⎤ 1 ⎡ 15 ⎤ 9
⎢ ⎥  
Sol.
tn 
⎣ 2 ⎦ 4 ⎢⎣ 8 ⎥⎦ 48
n2
15 6 9
=  
32 32 32
 n  1 2

4 43. The set of all values of  for which the system of
linear equations
1⎡ 2 2x1 – 2x2 + x3 = x1
 n  2n  1⎤⎦
4⎣ 2x1 – 3x2 + 2x3 = x2

1 ⎡ n  n  1  2n  1  2  n  n  1  ⎤ –x1 + 2x2 = x3

 ⎢   1⎥
4⎣ 6 2 has a non-trivial solution
⎦
(1) Contains two elements
1 ⎡ 9  10  19 ⎤ (2) Contains more than two elements
  9  10  9 ⎥
4 ⎢⎣ 6 ⎦ (3) Is an empty set
= 96 (4) Is a singleton

13
Answer (1) 45. The number of common tangents to the circles
Sol. x1 (2   )  2 x2  x3  0 x2 + y2 – 4x – 6y – 12 = 0 and
x2 + y2 + 6x + 18y + 26 = 0, is
2 x1  x2 (   3)  2 x3  0
(1) 3 (2) 4
 x1  2 x2  x3  0 (3) 1 (4) 2
2 2 1 Answer (1)
2   3 2 0 Sol. x2 + y2 – 4x – 6y – 12 = 0
1 2 
C1(center) = (2, 3), r = 2 2  32  12  5
(2   )(  2  3  4)  2 ( 2   2)  (4    3)  0 x2 + y2 + 6x + 18y + 26 = 0
C2(center) (– 3, –9), r  9  81  26
2 2  6  8   3  3 2  4  4  4    1  0
 64  8
  3   2  5  3  0
C1C2 = 13, C1C2 = r1 + r2
  3   2  5  3  0 Number of common tangent is 3.
3 2 2
    2   2   3  3  0 46. The number of integers greater than 6,000 that can
2 be formed, using the digits 3, 5, 6, 7 and 8, without
 (   1)  2  (   1)  3(   1)  0
repetition, is
(   1)(  2  2   3)  0 (1) 120 (2) 72
(   1)(   3)(   1)  0 (3) 216 (4) 192
   1, 1,  3 Answer (4)
Two elements. Sol. 4 digit numbers
44. A complex number z is said to be unimodular if 3, 5, 6, 7, 8
|z| = 1. Suppose z1 and z2 are complex numbers 678
z1  2 z2
such that is unimodular and z 2 is not
2  z1 z2
3 4 5 2 = 72
unimodular. Then the point z1 lies on a
5 digit numbers
(1) Circle of radius 2
(2) Circle of radius 2
(3) Straight line parallel to x-axis
5
(4) Straight line parallel to y-axis 5 × 4 × 3 × 2 × 1 = 120
Answer (1) Total number of integers = 72 + 120 = 192
⎛ z1  2 z2 ⎞ 47. Let y(x) be the solution of the differential equation
Sol. ⎜ 2  z z ⎟1
⎝ 1 2 ⎠ dy
 x log x   y  2 x log x , ( x  1).
⎛ z1  2 z2 ⎞ ⎛ z1  2 z2 ⎞ dx
⎜ ⎟⎜ ⎟1 Then y(e) is equal to
⎝ 2  z1 z2 ⎠ ⎝ 2  z1 z2 ⎠
(1) 2 (2) 2e
z1 z1  2 z1 z2  2 z2 z1  4 z2 z2
(3) e (4) 0
 4  2 z1 z2  2 z1 z2  z1 z1 z2 z2
Answer (1)*
z1 z1  4 z2 z2  4  z1 z1 z2 z2 Sol. It is best option. Theoretically question is wrong,
zz1  1  z2 z2   4  1  z2 z2   0 because initial condition is not given.
dy
 z1 z1  4  1  z2 z2   0 x log x
dx
+ y = 2x log x If x = 1 then y = 0

 z1 z1  4 dy y
 2
|z| = 2, i.e. z lies on circle of radius 2. dx x log x

14
 1 2
∫ x log x dx log log x ⎛ n⎞ 4
I.F.  e e  log x G2  l ⎜ ⎟
⎝ l⎠
Solution is y  log x  ∫ 2 log x dx  c 3
⎛ n⎞ 4
y log x  2( x log x  x )  c G3  l ⎜ ⎟
⎝ l⎠
x = 1, y = 0
Now G14  2G24  G33
Then, c = 2, y(e) = 2
2 3
n ⎛ n⎞ ⎛ n⎞
l4   2  (l 2 ) ⎜ ⎟  l 4 ⎜ ⎟
⎡1 2 2 ⎤ l ⎝ l⎠ ⎝ l⎠
48. If A = ⎢⎢ 2 1 2 ⎥⎥ is a matrix satisfying the = nl3 + 2n2l2 + n3l
⎢⎣ a 2 b ⎥⎦ = 2n2l2 + nl(n2 + l2)
equation AAT = 9I, where I is 3 × 3 identity matrix, = 2n2l2 + nl((n + l)2 – 2nl)
then the ordered pair (a, b) is equal to = nl(n + l)2
(1) (2, 1) (2) (–2, –1) = nl (2m)2

(3) (2, –1) (4) (–2, 1) = 4 nlm2

50. The negation of ~ s  (~ r s) is equivalent to
Answer (2)
(1) s  (r  ~ s) (2) s  r
⎡1 2 2 ⎤ ⎡ 1 2 a⎤ ⎡9 0 0⎤ (3) s  ~ r (4) s  (r  ~ s)
⎢ 2 1 2 ⎥ ⎢ 2 1 2 ⎥⎥  ⎢⎢ 0 9 0 ⎥⎥
Sol. ⎢ ⎥⎢ Answer (2)
⎢⎣ a 2 b ⎥⎦ ⎢⎣ 2 2 b ⎥⎦ ⎢⎣0 0 9 ⎥⎦
Sol. ∼ ( ∼ s  ( ∼ r  s ))
a  4  2b  0 = s  (r  ∼ s )
2 a  2  2b  0 = (s  r )  (s  ∼ s )
a1b  0 = s r
2 a  2 b  2 dx
a  2 b  4
51. The integral ∫x 2
( x 4  1)3/4
equals

1
3 a  6 1
⎛ x4  1⎞ 4
(1) ( x 4  1)  c 4
(2)  ⎜ 4 ⎟  c
a  2 ⎝ x ⎠
1
2  1  b  0
⎛ x4  1⎞ 4 1

b=–1 (3) ⎜ 4 ⎟  c (4) ( x 4  1) 4  c

⎝ x ⎠
a=–2
Answer (2)
(–2, –1)
dx dx
Sol. I  ∫
x 2 ( x 4  1)3/4 ∫
49. If m is the A.M. of two distinct real numbers l and  3/4
⎛ 1⎞
n (l, n > 1) and G1, G2 and G3 are three geometric x5 ⎜ 1  4 ⎟
⎝ x ⎠
means between l and n, then G14  2G24  G34 equals.
 4
(1) 4 lmn2 (2) 4 l2m2n2 Let 1  4
 t ⇒ 5 dx  dt
x x
(3) 4 l2mn (4) 4 lm2n
1 dt 1 3/4
Answer (4)
So, I  ∫
4 t 3/4

4 ∫
t dt

ln 1 ⎛ t 1/4 ⎞
Sol. m  c
2 4 ⎜⎝ 1 / 4 ⎟⎠
l + n = 2m …(i)
1/4
⎛ 1 ⎞
1 = ⎜1  4 ⎟ c
⎛ n⎞ 4 ⎝ x ⎠
G1  l ⎜ ⎟
⎝ l⎠ So, option (2).

15
52. The normal to the curve, x2 + 2xy – 3y2 = 0 at (1,1) : Answer (3)
(1) Meets the curve again in the third quadrant ⎪⎧ k x  1 , 0x3
Sol. g( x )  ⎨
(2) Meets the curve again in the fourth quadrant ⎪⎩ mx  2 , 3x5
(3) Does not meet the curve again R.H.D.
(4) Meets the curve again in the second quadrant g(3  h )  g(3)
lim
Answer (2) h0 h
Sol. Curve is x2 + 2xy – 3y2 = 0 m(3  h )  2  2 k
= lim
⎡ dy ⎤ dy
h0 h
Differentiate wr.t. x, 2 x  2 ⎢ x  y ⎥  6y  0 (3m  2 k )  mh  2
⎣ dx ⎦ dx  lim m
h0 h
⎛ dy ⎞ and 3m – 2k + 2 = 0
 ⎜ ⎟ 1
⎝ dx ⎠ (1, 1) L.H.D.
So equation of normal at (1, 1) is k (3  h )  1  2 k
lim
y – 1 = – 1 (x – 1) h0 h
 y=2–x  k[ 4  h  2]
lim
Solving it with the curve, we get h0 h
x2 + 2x(2 – x) – 3(2 – x)2 = 0 4h4 k
lim  k  
 –4x2 + 16x – 12 = 0 h0 h( 4  h  2) 4
 x2 – 4x + 3 = 0 From above,
 x = 1, 3 k
 m and 3m – 2k + 2 = 0
So points of intersections are (1, 1) & (3, –1) i.e. 4
normal cuts the curve again in fourth quadrant. 2 8
m and k 
5 5
⎛ 2x ⎞
53. Let tan 1 y  tan 1 x  tan 1 ⎜ 8 2 10
⎝ 1  x 2 ⎟⎠ km   2
5 5 5
1 Alternative Answer
where |x| . Then a value of y is
3
⎪⎧ k x  1 , 0  x  3
3x  x 3 3x  x 3 g( x )  ⎨
(1) (2) ⎪⎩ mx  2 , 3  x  5
1  3x 2 1  3x 2
g is constant at x = 3
3x  x 3 3x  x 3
(3)
1  3x 2
(4)
1  3x 2 k 4  3m  2
Answer (3) 2k = 3m + 2 …(i)
⎛ k ⎞
⎛ 2x ⎞ Also ⎜⎝ ⎟ m
Sol. tan 1 y  tan 1 x  tan 1 ⎜ 2 x  1 ⎠ x3
⎝ 1  x 2 ⎟⎠
k
⎛ 3x  x 3 ⎞
1
m
3tan–1 x= tan ⎜⎝ 1  3x 2 ⎟⎠ 4
k=4m …(ii)
3x  x 3
8m=3m+2
y
1  3x 2 2 8
m ,k
54. If the function. 5 5
2 8
⎧⎪ k x  1 , 0x3 m k    2
g( x )  ⎨ 5 5
⎪⎩ mx  2 , 3x5 55. The mean of the data set comprising of 16
is differentiable, the value of k + m is observations is 16. If one of the observation valued
16 is deleted and three new observations valued 3,
10 4 and 5 are added to the data, then the mean of the
(1) (2) 4
3 resultant data, is
16 (1) 15.8 (2) 14.0
(3) 2 (4)
5 (3) 16.8 (4) 16.0

16
Answer (2) Sol. Let f(x) = a0 + a1x + a2x2 + a3x3 + a4x4
Sol. Mean = 16 ⎡ f (x) ⎤
Sum = 16 × 16 = 256 Using lim ⎢ 1  2 ⎥  3
x 0 ⎣ x ⎦
New sum = 256 – 16 + 3 + 4 + 5 = 252 f (x)
 lim 2  2
252 x 0 x
Mean = = 14
18 a  a x  a2 x 2  a3 x 3  a4 x 4
4  lim 0 1 2
log x 2 x 0 x2
56. The integral ∫ 2
 log(36 – 12 x  x 2 )
dx is equal
So, a0 = 0, a1 = 0, a2 = 2
2 log x
to i.e., f(x) = 2x2 + a3x3 + a4x4
(1) 1 (2) 6 Now, f (x) = 4x + 3a3x2 + 4a4x3
(3) 2 (4) 4 = x[4 + 3a3x + 4a4x2]
Answer (1) Given, f (1) = 0 and f (2) = 0
4  3a3 + 4a4 + 4 = 0 …(i)
log x 2 dx
Sol. I  ∫ 2
and 6a3 + 16a4 + 4 = 0 …(ii)
2 log x  log(36 – 12 x  x 2 )
1
4 2
Solving, a4  , a = –2
log(6 – x ) dx 2 3
I∫
2
 log(6 – x )2 2 3 1 4
2 log x i.e., f ( x )  2 x – 2 x  x
2
4
2 I  ∫ 1 dx i.e., f (2)  0
2 59. The area (in sq. units) of the quadrilateral formed by
2I = 2 the tangents at the end points of the latera recta to
I=1 x2 y2
the ellipse   1 , is
57. Let  and  be the roots of equation x2 – 6x – 2 = 0. 9 5
a10 – 2 a8 27
If an = n – n, for n  1, then the value of (1) (2) 27
2 a9 2
is equal to 27
(3) (4) 18
(1) 3 (2) –3 4
(3) 6 (4) –6 Answer (2)
Answer (1) x2 y2
Sol. Ellipse is  1
Sol. From equation, 9 5
+=6 i.e., a2 = 9, b2 = 5
 = –2 2
So, e 
10 10 8 8 3
a10 – 2 a8      (   ) 2
As, required area  2a  2  9  27
The value of
2 a9 2( 9  9 )
e (2/3)
9 (  )  9 (  )
 60. If 12 identical balls are to be placed in 3 identical
2(9  9 ) boxes, then the probability that one the boxes
 6 contains exactly 3 balls is
 3  12 11
2 2 ⎛1⎞ ⎛1⎞
58. Let f(x) be a polynomial of degree four having extreme (1) 220 ⎜ ⎟ (2) 22 ⎜ ⎟
⎝3⎠ ⎝3⎠
⎡ f (x) ⎤ 11 10
values at x = 1 and x = 2. If lim ⎢ 1  55 ⎛ 2 ⎞ ⎛2⎞
⎥  3 , then (3) ⎜ ⎟ (4) 55
x 0 ⎣ x2 ⎦ 3 ⎝3⎠ ⎜ ⎟
⎝3⎠
f(2) is equal to Answer (3)*
(1) 0 (2) 4 Sol. Question is wrong but the best suitable option is (3).
(3) –8 (4) –4 11
12 29 55 ⎛ 2 ⎞
Answer (1) Required probability = C3 = ⎜ ⎟
312 3 ⎝3⎠
17
 PART–C : CHEMISTRY

61. Which compound would give 5-keto-2-methyl

CN
hexanal upon ozonolysis?

CH3 CH3 (1)

H3C
(1) (2) CH3

CH3 CH3

CH3 CH3 (2)

CH3
(3) (4) COOH

CH3
(3)
Answer (4)
CH3
Sol. 5-keto-2-methylhexanal is

O O
(4) H3C CH3
H
Answer (1)
+ –
O3 O O NH2 N2Cl CN
Zn
+
H NaNO2/HCl CuCN/KCN
H Sol. + N2
0°C - 5°C 

62. Which of the vitamins given below is water soluble? CH3 CH3 CH3
(1) Vitamin E (2) Vitamin K (D) (E)
(3) Vitamin C (4) Vitamin D
65. Sodium metal crystallizes in a body centred cubic
Answer (3)
lattice with a unit cell edge of 4.29 Å. The radius of
Sol. Vitamin C is water soluble vitamin.
sodium atom is approximately
63. Which one of the following alkaline earth metal
sulphates has its hydration enthalpy greater than (1) 5.72 Å (2) 0.93 Å
its lattice enthalpy?
(3) 1.86 Å (4) 3.22 Å
(1) BaSO4 (2) SrSO4
Answer (3)
(3) CaSO4 (4) BeSO4
Sol. Edge length of BCC is 4.29 Å.
Answer (4)
In BCC,
Sol. BeSO4 has hydration energy greater than its lattice
energy.
4
edge length = r
64. In the reaction 3
NH2
4
NaNO2/HCl CuCN/KCN 4.29  r
0-5°C
D 
E + N2 , 3

CH3 4.29
r 3  1.86 Å
the product E is 4

18
66. Which of the following compounds is not colored 70. In the context of the Hall-Heroult process for the
yellow? extraction of Al, which of the following statement is
(1) (NH4)3[As (Mo3O10)4] false?
(1) Al 3+ is reduced at the cathode to form Al
(2) BaCrO4
(2) Na3AlF6 serves as the electrolyte
(3) Zn2[Fe(CN)6]
(3) CO and CO2 are produced in this process
(4) K3[Co(NO2)6]
(4) Al2O3 is mixed with CaF 2 which lowers the
Answer (3) melting point of the mixture and brings
Sol. (NH4)3[As (Mo3O10)4], BaCrO4 and K3[Co(NO2)6] are conductivity
yellow colored compounds but Zn2[Fe(CN)6] is not Answer (2)
yellow colored compound.
Sol. In Hall-Heroult process Al2O3 (molten) is electrolyte.
67. Which of the following is the energy of a possible 71. In the following sequence of reactions :
excited state of hydrogen?
KMnO SOCl H /Pd
(1) –3.4 eV Toluene 
4
 A 
2
 B 
2
BaSO
 C,
4

(2) +6.8 eV the product C is

(3) +13.6 eV (1) C6H5CH2OH (2) C6H5CHO
(4) –6.8 eV (3) C6H5COOH (4) C6H5CH3

Answer (1) Answer (2)

CH3 COOH COCl CHO
Sol. Energy of excited state is negative and correspond to
n > 1. KMnO4 SOCl2 H2/Pd
Sol. BaSO4
–13.6 (A) (B) (C)
n=
E excited state 72. Higher order (>3) reactions are rare due to
–13.6 (1) Shifting of equilibrium towards reactants due to
= = 4 =2 elastic collisions
–3.4
(2) Loss of active species on collision
68. Which of the following compounds is not an
antacid? (3) Low probability of simultaneous collision of all
the reacting species
(1) Phenelzine
(4) Increase in entropy and activation energy as
(2) Ranitidine more molecules are involved
(3) Aluminium Hydroxide Answer (3)
(4) Cimetidine Sol. Higher order greater than 3 for reaction is rare
because there is low probability of simultaneous
Answer (1) collision of all the reacting species.
Sol. Phenelzine is not antacid, it is anti-depressant. 73. Which of the following compounds will exhibit
69. The ionic radii (in Å) of N 3– , O 2– and F– are geometrical isomerism?
respectively (1) 2 - Phenyl - 1 - butene
(1) 1.71, 1.40 and 1.36 (2) 1, 1 - Diphenyl - 1 propane
(2) 1.71, 1.36 and 1.40 (3) 1 - Phenyl - 2 - butene
(4) 3 - Phenyl - 1 - butene
(3) 1.36, 1.40 and 1.71
Answer (3)
(4) 1.36, 1.71 and 1.40
Sol. For geometrical isomerism doubly bonded carbon
Answer (1) must be bonded to two different groups which is
Sol. Radius of N3–, O2– and F– follow order only satisfied by 1 - Phenyl - 2 - butene.
H H H CH3
N3– > O2– > F–
C=C C=C
As per inequality only option (1) is correct Ph – CH2 CH3 Ph – CH2 H
that is 1.71 Å, 1.40 Å and 1.36 Å cis trans

19
74. Match the catalysts to the correct processes : 78. The number of geometric isomers that can exist for
Catalyst Process square planar [Pt(Cl)(py)(NH 3 )(NH 2 OH)] + is
(py = pyridine)
a. TiCl3 (i) Wacker process
(1) 4 (2) 6
b. PdCl2 (ii) Ziegler-Natta
polymerization (3) 2 (4) 3
c. CuCl2 (iii) Contact process Answer (4)
d. V2O5 (iv) Deacon's process a a a
b c b
(1) a(ii), b(iii), c(iv), d(i) (2) a(iii), b(i), c(ii), d(iv) Sol. Pt Pt Pt
(3) a(iii), b(ii), c(iv), d(i) (4) a(ii), b(i), c(iv), d(iii) d c d b c d
Answer (4) as per question a = Cl, b = py, c = NH 3 and
d = NH2OH are assumed.
Sol. TiCl3 - Ziegler-Natta polymerisation
V2O5 - Contact process 79. In Carius method of estimation of halogens, 250 mg
of an organic compound gave 141 mg of AgBr. The
PdCl2 - Wacker process percentage of bromine in the compound is
CuCl2 - Deacon's process (At. mass Ag = 108; Br = 80)
75. The intermolecular interaction that is dependent on
(1) 48 (2) 60
the inverse cube of distance between the molecules
is (3) 24 (4) 36
(1) London force (2) Hydrogen bond Answer (3)
(3) Ion-ion interaction (4) Ion-dipole interaction Sol. Percentage of Br
Answer (2)
Weight of AgBr Mol. mass of Br
Sol. H-bond is one of the dipole-dipole interaction and = Mol. mass of AgBr  Weight of O.C.  0
dependent on inverse cube of distance between the
molecules.
141 80
76. The molecular formula of a commercial resin used =   100
for exchanging ions in water softening is 188 250
C8H 7SO 3Na (mol. wt. 206). What would be the = 24%
maximum uptake of Ca2+ ions by the resin when
expressed in mole per gram resin? 80. The color of KMnO4 is due to

2 1 (1) L  M charge transfer transition

(1) (2)
309 412 (2)  - * transition
1 1 (3) M  L charge transfer transition
(3) (4)
103 206
(4) d - d transition
Answer (2)
Answer (1)
Sol. Ca+2 + 2C8H7SO3–Na+  Ca(C8H7SO3–)2 + 2Na+
Sol. Charge transfer spectra from ligand (L) to metal (M)
1 mol 2 mol
is responsible for color of KMnO4.
1 1
The maximum uptake =  mol/g 81. The synthesis of alkyl fluorides is best
206  2 412 accomplished by
77. Two faraday of electricity is passed through a
(1) Finkelstein reaction
solution of CuSO4. The mass of copper deposited at
the cathode is (at. mass of Cu = 63.5 amu) (2) Swarts reaction
(1) 2 g (2) 127 g (3) Free radical fluorination
(3) 0 g (4) 63.5 g (4) Sandmeyer's reaction
Answer (4) Answer (2)
Sol. Cu+2 + 2e  Cu Sol. Swart's reaction
So, 2 F charge deposite 1 mol of Cu. Mass deposited

= 63.5 g. CH 3  Cl  AgF  CH 3 F  AgCl

20
82. 3 g of activated charcoal was added to 50 mL of 85. The standard Gibbs energy change at 300 K for the
acetic acid solution (0.06N) in a flask. After an hour


reaction 2A 
 B + C is 2494.2 J. At a given time,
it was filtered and the strength of the filtrate was
found to be 0.042 N. The amount of acetic acid the composition of the reaction mixture is
adsorbed (per gram of charcoal) is
1 1
(1) 42 mg (2) 54 mg A   , B   2 and C   . The reaction proceeds
2 2
(3) 18 mg (4) 36 mg in the : [R = 8.314 J/K/mol, e = 2.718]
Answer (3) (1) Forward direction because Q < KC
Sol. Number of moles of acetic acid adsorbed
(2) Reverse direction because Q < KC
⎛ 50 50 ⎞
 ⎜ 0.06   0.042  ⎟ (3) Forward direction because Q > KC
⎝ 1000 1000 ⎠
(4) Reverse direction because Q > KC
0.9
 moles Answer (4)
1000
 Weight of acetic acid adsorbed = 0.9 × 60 mg 

 B + C, G° = 2494.2 J
Sol. 2A 
= 54 mg
As we know G° = –2.303 RT logKC
Hence, the amount of acetic acid adsorbed per g of
54  2494.2 = –2.303 × 8.314 × 300 log KC
charcoal = mg
3  –0.434 = log KC
= 18 mg  KC = antilog (–0.434)
Hence, option (3) is correct.  KC = 0.367
83. The vapour pressure of acetone at 20°C is 185 torr.
1 1
When 1.2 g of a non-volatile substance was Now A   , B   2 and  C  
dissolved in 100 g of acetone at 20°C, its vapour 2 2
pressure was 183 torr. The molar mass (g mol–1) of
1
⎛ ⎞
the substance is
 C B  ⎜⎝ 2 ⎟⎠
2
(1) 128 (2) 488 Now QC   4
A 2 ⎛1⎞
2
(3) 32 (4) 64 ⎜ ⎟
⎝2⎠
Answer (4)
as QC > KC, hence reaction will shift in backward
Sol. Vapour pressure of pure acetone P°A  185 torr direction.
Vapour pressure of solution, PS = 183 torr 86. Assertion : Nitrogen and Oxygen are the main
Molar mass of solvent, MA = 58 g/mole components in the atmosphere but these
do not react to form oxides of nitrogen.
P°A  PS n B Reason : The reaction between nitrogen and
as we know 
PS nA oxygen requires high temperature.
185  183 WB M A (1) The assertion is incorrect, but the reason is
⇒  
183 M B WA correct
2 1.2 58 (2) Both the assertion and reason are incorrect
⇒  
183 M B 100 (3) Both assertion and reason are correct, and the
1.2 58 reason is the correct explanation for the
⇒ MB    183 assertion
2 100
(4) Both assertion and reason are correct, but the
 63.68 g/mole
reason is not the correct explanation for the
84. Which among the following is the most reactive? assertion
(1) I2 (2) ICl Answer (3)
(3) Cl2 (4) Br2 Sol. N2 + O2  2NO
Answer (2) Required temperature for above reaction is around
Sol. Because of polarity and weak bond interhalogen 3000°C which is a quite high temperature. This
compounds are more reactive. reaction is observed during thunderstorm.

21
87. Which one has the highest boiling point?
 2NO (g)
Sol. 2NO(g) + O2(g)  2
(1) Kr (2) Xe
(3) He (4) Ne
Answer (2)  G  
reaction ⎣ 
 ⎡⎢  G 
formation ⎥
⎤
⎦ product
Sol. Down the group strength of van der Waal's force of  ⎡⎢   G 
 ⎤
⎥ reactant
attraction increases hence Xe have highest boiling ⎣ formation ⎦

point.
88. Which polymer is used in the manufacture of paints ⇒ RT ln K P  2   G    2  G  
NO 2 NO
and lacquers?
(1) Polypropene (2) Poly vinyl chloride ⇒  G    2  G    RT ln K P
NO 2 NO
(3) Bakelite (4) Glyptal
Answer (4) 2  86600  R  298  ln K P
Sol. Glyptal is used in manufacture of paints and
⇒ G 
 NO 2

2
lacquires.
89. The following reaction is performed at 298 K. 2  86600  R  298  ln 1.6  1012

2
 2NO (g)
2NO(g) + O2(g)  2

The standard free energy of formation of NO(g) is  0.5 ⎡⎣ 2  86, 600  R  298  ln 1.6  1012 ⎤⎦
86.6 kJ/mol at 298 K. What is the standard free
energy of formation of NO2(g) at 298 K? 90. From the following statement regarding H 2O 2,
choose the incorrect statement
(Kp = 1.6 × 1012)
(1) It has to be stored in plastic or wax lined glass

ln 1.6  10 12  bottles in dark.
(1) 86600 
R  298  (2) It has to be kept away from dust
(3) It can act only as an oxidizing agent
(2) 0.5 ⎡⎣ 2  86, 600  R  298  ln 1.6  10 ⎤⎦
12
(4) It decomposes on exposure to light
(3) R(298) ln(1.6 × 1012) – 86600 Answer (3)
(4) 86600 + R(298) ln(1.6 × 1012) Sol. H2O2 can be reduced or oxidised. Hence, it can act
Answer (2) as reducing as well as oxidising agent.

  

22
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