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 Sulfur-Vanadium Binary Phase Diagram (1990 Smith J.F.)

Image
Binary phase diagram

Diagram information
Diagram type binary phase diagram

Elements S (Sulfur), V (Vanadium)

Concentration range
0-100 at.% V
Concentration range description full composition

Temperature 0 to 2000 °C    

Nature of investigation experimental

APDIC diagram APDIC

Unique ID No. 902058

Source information
Year 1990 [1]

Title
S-V (Sulfur-Vanadium)
Language English

Journal abbreviated

ASM Alloy Phase Diagram Database, P. Villars, editor-in-chief; H. Okamoto and K. Cenzual, section editors
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Binary Alloy Phase Diagrams, II Ed., Ed. T.B. Massalski

Authors
Smith J.F.
Original diagram
S-V phase diagram
Original scope
T[0-2000 °C] vs. V conc.[0-100 at.%]
Original size 9/12

Remarks

Crystal Data
Phases shown in this diagram Hide table

APD phase label, published phase Formula Prototype Pearson symbol, space Density Volume Cell parameters Cell parameters Ref

label group (Mg/m^3) (nm^3) (nm) (°)

S S oF128 2.07 3.2985 a=1.04633 α=90 [3]

(S) 8 α rt
Fddd b=1.28786 β=90

c=2.44784 γ=90
(αS)

V W cI2 6.08 0.0278 a=0.303 α=90 [4]

(V)
Im-3m b=0.303 β=90

c=0.303 γ=90
(V)

S S mP64 2.01 1.27289 a=1.0926 α=90 [5]

(S) 8 β ht
P121/c1 b=1.0855 β=95.92

c=1.0790 γ=90
(βS)
T=297 K

VS4 VS4 mS40 2.83 0.84007 a=1.272 α=90 [6]

VS4
C12/c1 b=1.042 β=110.8

c=0.6780 γ=90
S4V

V5S8 V5S8 mS26 3.97 0.42746 a=1.1293 α=90 [7]

V5S8 rt
C12/m1 b=0.6645 β=134.01

c=0.792 γ=90
S8V5

V3S4 Cr3S4 mS14 4.23 0.2205 a=1.2638 α=90 [8]

V3S4 rt
C12/m1 b=0.3294 β=115.68

c=0.5878 γ=90
S4V3

VS0.85 FeAs oP8 4.6 0.1128 a=0.586 α=90 [9]

VS rt
Pnma b=0.3304 β=90

c=0.5826 γ=90
SyV

VS NiAs hP4 4.85 0.05683 a=0.336 α=90 [10]

VS ht
P63/mmc b=0.336 β=90

c=0.5813 γ=120
S2V1+x

V5S4 Ti5Te4 tI18 4.89 0.25996 a=0.8981 α=90 [11]

V5S4 rt
I4/m b=0.8981 β=90

c=0.3223 γ=90
S4V5
T=293 K

V3S V3S tP32 5.99 0.41036 a=0.9381 α=90 [12]

V3S rt
P42/nbc b=0.9381 β=90

c=0.4663 γ=90
βSV3

V3S V3S tI32 5.97 0.4085 a=0.9470 α=90 [12]

V3S ht
I-42m b=0.9470 β=90

c=0.4589 γ=90
αSV3

Phases shown in other diagrams for Hide table

this system

APD phase label Formula Prototype Pearson symbol, space group Density (Mg/m^3) Volume (nm^3) Cell parameters (nm) Cell parameters (°) Ref

(S) 7 γ S S mP28 2.19 0.68053 a=0.9680 α=90 [13]

ASM Alloy Phase Diagram Database, P. Villars, editor-in-chief; H. Okamoto and K. Cenzual, section editors
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Reaction Data
Reaction data selected for the Hide table
complete system

Reaction A (%) B (%) C (%) Temperature (°C) Reaction type Ref

L = (V) + V3S ht 80 100 75 1315 Eutectic [2]

VS ht = V3S4 rt 43 1200 Maximum [2]

L + VS ht = V3S ht 78 51 75 1350 Peritectic [2]

V3S ht = V3S rt 75 850 Polymorphic [2]

V3S ht + VS ht = V5S4 rt 75 51.8 55.6 900 Peritectoid [2]

L = VS ht 48 1750 Congruent [2]

V3S4 rt + VS ht = V5S8 rt 40 39 39.5 850 Peritectoid [2]

VS4 + (S) 8 β ht + (S) 8 α rt 100 95.5 unknown [2]

L = VS4 + (S) 8 β ht 20 115 Eutectic [2]

L + VS ht = VS4 36 20 400 Peritectic [2]

Transformations
Pure metal melting points and Hide table
allotropic transformations

Element phase Common name Reaction Temperature (°C) Prototype Pearson symbol Space group

(S) 8 β ht βS L ↔ (S) 8 β ht 115.22 S P21/c

mP64

(S) 8 α rt αS (S) 8 β ht ↔ (S) 8 α rt 95.5 S Fddd

oF128

(V) V L ↔ (V) 1910 W Im-3m

cI2

References
References Hide table

Ref Citation

[1] Smith J.F., S-V (Sulfur-Vanadium), Binary Alloy Phase Diagrams, II Ed., Ed. T.B. Massalski,

[2] Okamoto H., Phase Diagrams for Binary Alloys, Desk Handbook, , Vol. , 2000,

[3] Coppens P., Yang Y.W., Blessing R.H., Cooper W.F., and Larsen F.K., The Experimental Ch

[4] Lomnytska Y.F., V-Si-Sb phase diagram. Isothermal section at 1070 K, Powder Metall. Met.

[5] Templeton L.K., Templeton D.H., and Zalkin A., Crystal structure of monoclinic sulfur, Inorg.

[6] Allmann R., Baumann I., Kutoglu A., Rösch H., and Hellner E., Die Kristallstruktur des Patro

[7] Kawada I., Nakano Onoda M., Ishii M., Saeki M., and Nakahira M., Crystal Structures of V

[8] Mujica C., Llanos J., and Wittke O., Structure refinement of monoclinic V

[9] Franzen H.F., and Westman S., A New Vanadium Monosulfide, Acta Chem. Scand., Vol. 17

[10] Oudet X., Structures cristallines et liaisons, Ann. Chim. (Paris), Vol. 8, 1983, p 483-507

[11] De Vries A.B., and Jellinek F., A structural study of vanadium sulfides, Rev. Chim. Miner., Vo

[12] Pedersen B.F., and Gronvold F., The Crystal Structures of α-V3S and β-V

[13] Steudel R., Steidel J., Pickardt J., Schuster F., and Reinhardt R., X-ray Structural Analyses

[14] Gallacher A.C., and Pinkerton A.A., A Redetermination of Monoclinic γ-Sulfur, Acta Crystallo

[15] Steidel J., Pickardt J., and Steudel R., Redetermination of the Crystal and Molecular Structu

[16] Steudel R., Steidel J., and Sandow T., Preparation, crystal structure, and vibrational spectra

[17] Steudel R., and Steidel J., X-Ray structural analyses of cyclodecasulfur (S

ASM Alloy Phase Diagram Database, P. Villars, editor-in-chief; H. Okamoto and K. Cenzual, section editors
Terms and Conditions    Copyright © 2006-2018 ASM International

3 of 4 10/19/18, 2:05 PM
 https://matdata.asminternational.org/apd/datashe...

ASM Alloy Phase Diagram Database, P. Villars, editor-in-chief; H. Okamoto and K. Cenzual, section editors
Terms and Conditions    Copyright © 2006-2018 ASM International

4 of 4 10/19/18, 2:05 PM