Zippo Premium Butane Gas 100 ml

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH)
Date of issue:2/3/2016 Revision date:2/3/2016 : Version: 1.00

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Trade name : Zippo Premium Butane Gas 100 ml
Vaporizer : Aerosol

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Intended for general public
Main use category : Consumer use,Professional use
Use of the substance/mixture : Gas

1.2.2. Uses advised against

No additional information available
1.3. Details of the supplier of the safety data sheet
Supplier Email competent person
Zippo U.K. Ltd sds@kft.de
The Barley Mow Centre
10 Barley Passage London W4 4PH - England
T 0044 208 964 0666

1.4. Emergency telephone number

Emergency number : National Poison Information Service (NPIS)
24 hour national number professionals only
0844 892 0111

National Health Service (NHS)

24 hour national number consumer
England and Scotland: 111
Wales: 0845 46 47
Northern Ireland: call your local General Practitioner

Call 999 if there is a life-threatening incident.

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Aerosol, Category 1 H222;H229
Full text of hazard classes and H-statements : see section 16

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :

GHS02
Signal word (CLP) : Danger
Hazard statements (CLP) : H222 - Extremely flammable aerosol
H229 - Pressurised container: May burst if heated
Precautionary statements (CLP) : P102 - Keep out of reach of children
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking
P211 - Do not spray on an open flame or other ignition source
P251 - Do not pierce or burn, even after use
P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F

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Zippo Premium Butane Gas 100 ml
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

2.3. Other hazards

No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable

3.2. Mixture

Name Product identifier % Classification according to

Regulation (EC) No.
1272/2008 [CLP]
isobutane (CAS No) 75-28-5 >= 90 Flam. Gas 1, H220
(EC no) 200-857-2 Press. Gas
(EC index no) 601-004-00-0
(REACH-no) 01-2119485395-27
butane (CAS No) 106-97-8 2.5 - 5 Flam. Gas 1, H220
(EC no) 203-448-7 Press. Gas
(EC index no) 601-004-00-0
(REACH-no) 01-2119474691-32
propane (CAS No) 74-98-6 1 - 2.5 Flam. Gas 1, H220
(EC no) 200-827-9 Press. Gas
(EC index no) 601-003-00-5
(REACH-no) 01-2119486944-21

Full text of H-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : In case of doubt or persistent symptoms, consult always a physician.
First-aid measures after inhalation : Move to fresh air. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Rinse skin with water/shower. If skin irritation persists, take medical advice.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. If eye irritation persists: Get medical
advice/attention.
First-aid measures after ingestion : Ingestion unlikely.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Headache. Nausea. Dizziness. Frostbites.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Foam. Sand. extinguishing powder.
Unsuitable extinguishing media : Strong water jet.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable gas.
Explosion hazard : Contains gas under pressure; may explode if heated.
Hazardous decomposition products in case of : Toxic fumes may be released. Carbon monoxide. Carbon dioxide. Sulphur oxides. Vapours
fire may ignite. Vapours are heavier than air.
5.3. Advice for firefighters
Firefighting instructions : Use water spray to cool exposed surfaces.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Self-contained breathing apparatus.
Other information : Do not allow run-off from fire fighting to enter drains or water courses.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : Ensure adequate air ventilation. Avoid contact with skin and eyes. Remove all sources of
ignition.

6.1.1. For non-emergency personnel

Protective equipment : Concerning personal protective equipment to use, see section 8.

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Zippo Premium Butane Gas 100 ml
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

6.1.2. For emergency responders

Protective equipment : Concerning personal protective equipment to use, see section 8.
6.2. Environmental precautions
No special environmental precautions required.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : If possible, allow spill to evaporate under surveillance.
6.4. Reference to other sections
Information for safe handling. See Heading 7. Concerning personal protective equipment to use, see section 8. For further information refer to
section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Handle and open container with care. Use only in well
ventilated areas. Keep away from sources of ignition - No smoking. Avoid the build-up of
electrostatic charge.
Hygiene measures : Do not eat, drink or smoke when using this product.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep cool. Keep container tightly closed. Keep away from heat
and direct sunlight. Store always product in container of same material as original container.
Incompatible products : Oxidizing agent.
Prohibitions on mixed storage : Keep away from strong oxidizers. Keep away from food, drink and animal feeding stuffs. Do not
store with: Oxidizing materials.
7.3. Specific end use(s)
No additional information available.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

butane (106-97-8)
United Kingdom Local name Butane
United Kingdom WEL TWA (mg/m³) 1450 mg/m³
United Kingdom WEL TWA (ppm) 600 ppm
United Kingdom WEL STEL (mg/m³) 1810 mg/m³
United Kingdom WEL STEL (ppm) 750 ppm
United Kingdom Remark (WEL) Carc (Capable of causing cancer and/or heritable
genetic damage. See paragraphs 49–51), (only
applies if Butane contains more than 0.1% of buta-1,3-
diene)

8.2. Exposure controls

Appropriate engineering controls : Ensure good ventilation of the work station.
Hand protection : Not required
Eye protection : Not required
Respiratory protection : Accidental release measures. Breathing apparatus with filter. Filter AX (brown)
Other information : Wash hands before breaks and after work. Do not breathe gas/vapour/aerosol. Avoid contact
with skin and eyes. Precautions manipulation.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Aerosol
Colour : colourless.
Odour : No data available
Odour threshold : Not determined
pH : Not specifically applicable
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : -11.7 °C
Flash point : -60 °C

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Zippo Premium Butane Gas 100 ml
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Auto-ignition temperature : No data available

Decomposition temperature : No data available
Flammability (solid, gas) : ≈ 460 °C (DIN 51794)
Vapour pressure : 1.2 bar (at 20°C)
Relative vapour density at 20 °C : No data available
Relative density : No data available
Density : 600 kg/m³ (at 0°C)
Solubility : Water: practically insoluble
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : 0.2 - 12 mPa.s (at 0°C)
Explosive properties : Product is not explosive. Can form explosive mixtures with air.
Oxidising properties : No data available
Explosive limits : ≈ 1.4 vol %
≈ 9.3 vol %

9.2. Other information

Other properties : Flammable aerosol.

SECTION 10: Stability and reactivity

10.1. Reactivity
No additional information available
10.2. Chemical stability
No decomposition if stored normally.
10.3. Possibility of hazardous reactions
Explosive vapour/air mixtures may be formed.
10.4. Conditions to avoid
heat. Direct sunlight.
10.5. Incompatible materials
Strong oxidizing agent.
10.6. Hazardous decomposition products
None under normal use.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity : Not classified

Skin corrosion/irritation : Not classified (Based on available data, the classification criteria are not met)
pH: Not specifically applicable
Serious eye damage/irritation : Not classified (Based on available data, the classification criteria are not met)
pH: Not specifically applicable
Respiratory or skin sensitisation : Not classified (Based on available data, the classification criteria are not met)
Germ cell mutagenicity : Not classified (Based on available data, the classification criteria are not met)
Carcinogenicity : Not classified (Based on available data, the classification criteria are not met)
Reproductive toxicity : Not classified (Based on available data, the classification criteria are not met)
Specific target organ toxicity (single exposure) : Not classified (Based on available data, the classification criteria are not met)
Specific target organ toxicity (repeated : Not classified (Based on available data, the classification criteria are not met)
exposure)
Aspiration hazard : Not classified (Based on available data, the classification criteria are not met)
Zippo Premium Butane Gas 100 ml
Vaporizer Aerosol

SECTION 12: Ecological information

12.1. Toxicity
No additional information available

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Zippo Premium Butane Gas 100 ml
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

12.2. Persistence and degradability

Zippo Premium Butane Gas 100 ml
Persistence and degradability No additional information available.

12.3. Bioaccumulative potential

Zippo Premium Butane Gas 100 ml
Bioaccumulative potential low mobility.

12.4. Mobility in soil

Zippo Premium Butane Gas 100 ml
Ecology - soil No additional information available.

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Regional legislation (waste)
Waste treatment methods
Waste disposal recommendations
European List of Waste (LoW) code
: Disposal must be done according to official regulations.
: European waste catalogue.
: Avoid release to the environment. Comply with local regulations for disposal.
: 16 00 00 - WASTES NOT OTHERWISE SPECIFIED IN THE LIST
16 05 00 - gases in pressure containers and discarded chemicals
16 05 05 - gases in pressure containers other than those mentioned in 16 05 04

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN

ADR IMDG IATA ADN RID

14.1. UN number
1057 1057 1057 1057 1057
14.2. UN proper shipping name
LIGHTER REFILLS LIGHTER REFILLS Lighter refills LIGHTER REFILLS LIGHTER REFILLS
Transport document description
UN 1057 LIGHTER UN 1057 LIGHTER Lighter refills LIGHTER REFILLS LIGHTER REFILLS
REFILLS, 2.1, (D) REFILLS, 2.1
14.3. Transport hazard class(es)
2.1 2.1 2.1 2.1 2.1

14.4. Packing group

Not applicable Not applicable Not applicable Not applicable Not applicable

14.5. Environmental hazards

Dangerous for the Dangerous for the Dangerous for the Dangerous for the Dangerous for the
environment : No environment : No environment : No environment : No environment : No
Marine pollutant : No
No supplementary information available

14.6. Special precautions for user

- Overland transport
Classification code (ADR) : 6F
Special provisions (ADR) : 201, 654, 658
Limited quantities (ADR) : 0
Excepted quantities (ADR) : E0
Transport category (ADR) : 2
Tunnel restriction code (ADR) : D

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Zippo Premium Butane Gas 100 ml
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

- Transport by sea
Special provisions (IMDG) : 201
Limited quantities (IMDG) : 0
Excepted quantities (IMDG) : E0
EmS-No. (Fire) : F-D
EmS-No. (Spillage) : S-U
Stowage category (IMDG) : B
Flash point (IMDG) : - 60 °C
Properties and observations (IMDG) : Lighters or lighter refills containing butane or other flammable gas.
MFAG-No : 115

- Air transport
PCA Excepted quantities (IATA) : E0
PCA Limited quantities (IATA) : Forbidden
PCA limited quantity max net quantity (IATA) : Forbidden
PCA packing instructions (IATA) : 201
PCA max net quantity (IATA) : 1kg
CAO packing instructions (IATA) : 201
CAO max net quantity (IATA) : 15kg
ERG code (IATA) : 10L

- Inland waterway transport

Classification code (ADN) : 6F
Special provisions (ADN) : 201, 654, 658
Limited quantities (ADN) : 0
Excepted quantities (ADN) : E0

- Rail transport
Classification code (RID) : 6F
Special provisions (RID) : 201, 654, 658
Limited quantities (RID) : 0
Excepted quantities (RID) : E0
Transport category (RID) : 2
Hazard identification number (RID) : 23
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
IBC code : Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

Contains no REACH substances with Annex XVII restrictions

Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances

Seveso Information : P3a FLAMMABLE AEROSOLS

‘Flammable’ aerosols Category 1 or 2, containing flammable gases Category 1 or 2 or
flammable liquids Category 1

15.1.2. National regulations

No additional information available

15.2. Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information

Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006. ECHA (European Chemicals Agency).

2/3/2016 EN (English) 6/7

 Zippo Premium Butane Gas 100 ml
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Department issuing data specification sheet: : KFT Chemieservice GmbH

Im Leuschnerpark. 3 64347 Griesheim
Postfach 1451 64345 Griesheim
Germany

Phone: +49 6155 86829-0 Fax: +49 6155 86829-25

Safety Data Sheet Service: +49 6155 86829-22
Contact person : Dr. Sonja Fischer
Full text of H- and EUH-statements:
Aerosol 1 Aerosol, Category 1
Flam. Gas 1 Flammable gases, Category 1
Press. Gas Gases under pressure
H220 Extremely flammable gas
H222 Extremely flammable aerosol
H229 Pressurised container: May burst if heated
Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]:
Aerosol 1 H222;H229 Auf der Basis von Prüfdaten

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product

2/3/2016 EN (English) 7/7

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