Laoac is politically subdivided into 22 barangays.

 Anis (Cabilaoan East)  Casanestebanan  Nanbagatan

 Balligi  Cabilaoan  Casantiagoan  Panaga
 Banuar  Cabulalaan  Inmanduyan  Talogtog
 Botigue  Calaoagan  Poblacion (Laoac)  Turko
 Caaringayan  Calmay  Lebueg  Yatyat
 Domingo  Casampagaan  Maraboc
Alarcio