SITI ZAHIDAH

SEM

 Referensi (sesuai penulisan daftar pustaka yang benar) Yang perlu ditemukan
 Text asli Keterangan gambar sesuai jurnal dalam jurnal:
 Gambar SEM  Morfologi Material
(Terbentu/Tidaknya
material)
 Bukti materialnya
terbentuk/ada yang
nempel/berabung)
 Ukuran rata-rata
partikel
 Informasi lain yang
disampaikan oleh
peneliti
Jurnal 1 Isi narasi

Luo,H., Law,W,W., Wu,Y., Zhu,W dan Yang,E. 2018. Hydrothermal Gambar disamping ialah
Synthesis Of Needle-Like Nanocrystalline Zeolites From Metakaolin gambar hasil analisa
And Their Applications For Efficient Removal Of Organic Pollutants morfologi metakaolin
And Heavy Metals. Microporous and Mesoporous Material. 272: 8- murni dan metakaolin
15. yang telah melewati
proses hidrotermal.

 Gambar yang diatas

merupakan morfologi
metakaolin murni.
Sedangkan gambar
yang dibawah
merupakan morfologi
dari metakaolin
hidrotermal.

 Ukuran rata-rata
partikel ialah 100 nm..

Fig 1. SEM micrographs of the raw (upper) and hydrothermally

treated (bottom) metakaolin  Pada analisa SEM ini
dilakukan 3x
Fig. 1 shows the morphology of the raw (upper) and the perbesaran (gambar
hydrothermally treated (bottom) MK at the similar magnifications. As atas :30.000x, 50.000x
can be seen, significant changes in morphology of MK were observed dan 100.000x) . Dapat
following the hydrothermal treatment. The microstructure of raw MK dilihat gambar yang
particles was platy in shape and had tendency to create higher diatas bentuk dari
agglomerate of circle shape. SEM micrographs of the samples suggest metakaolin murni
that the surface was layered structure for raw MK. This sheet-like form berupa gumpalan
may be attributed to the dehydroxylation of kaolin, which was an berbentuk lingkaran
endothermic process due to the large amount of energy required to dan berlapis.
remove the chemically bonded hydroxyl ions. Above certain
temperature range, kaolinite transforms into MK, a complex  Perbesaran gambar
amorphous structure which retains some long-range order due to layer yang dibawah
stacking. (20.000x, 50.000x dan
100.000x) Pada
However, the sheet-like MK was converted into needle-like gambar yang dibawah
nanocrystal materials after hydrothermal treatment (Fig. 1). These terjadi perubahan
remarkable changes in surface morphology and internal structure were bentuk dari gumpalan
caused by the formation of new crystal phases under alkaline berlapis berubah
condition. More specifically, the hydrothermal synthesis of needle-like menjadi bentuk jarum.
nanomaterials was achieved through the alkali-activated dissolution of Hal ini disebabkan
Si and Alcontaining minerals and subsequent re-precipitation with Na. oleh sintesis
Thus, the reaction products may be mostly zeolite-type minerals. To hidrotermal dimana
the best of our knowledge, the current study is the first one to report metakaolin tersebut
and synthesize the needle-shaped zeolite nanocrystals using a diaktivasi dengan
commercial MK sample as the starting material. alkali,sampel dibawah
kondisi basa. Sehingga
terbentuklah bahan
nano seperti jarum.
Jurnal 2 Isi narasi

DTA/DSC/TGA
 Referensi (sesuai penulisan daftar pustaka yang Yang perlu ditemukan dalam jurnal:
benar)  Tg/Tc/Tm/Td dan Stabilitas termal
 Text asli Keterangan gambar sesuai jurnal  Reaksi Endoterm dan Eksoterm
 Gambar DTA/DSC/TGA  Materi yang lepas dengan
peningkatan suhu
 Informasi lain yang disampaikan oleh
peneliti
Jurnal 1 Isi narasi

Luo,H., Law,W,W., Wu,Y., Zhu,W dan Yang,E. Gambar disamping ialah kurva hasil
2018. Hydrothermal Synthesis Of Needle-Like karakterisasi metakolin murni serta
Nanocrystalline Zeolites From Metakaolin And metakaolin hidotermal.
Their Applications For Efficient Removal Of
Organic Pollutants And Heavy Metals. Microporous  Garis warna hitam merupakan
and Mesoporous Material. 272: 8-15. metakaolin murni dan garis merah
metakaolin hidrotermal. Dapat dilihat
kedua bahan tersebut menunjukkan
 terjadi penurunan massa akibat
kenaikan suhu.

 Pada metakaolin murni terjadi

penurunan massa 2% sedangkan pada
metakaolin hidrotermal terjadi
penurunan massa 14%. Hal ini
disebabkan karena air yang diserap
pada pori-pori atau permukaan sampel
dilepas pada suhu rendah.

 Penurunan massa terus berlangsung

hingga pada suhu 600 °C yang
disebabkan oleh dehidrasi dan proses
Fig. 2. (c) TGA curves of the raw (black line) and dekomposisi, hasil ini sesuai dengan
the hydrothermally treated (red line) metakaolin. laporan sebelumnya di mana transisi
termal dari material ini selesai pada
Fig. 2c shows the TGA curves of the raw and the 600 ° C.
treated MK. As can be seen, the raw MK exhibited a
mass loss of less than 2%, whereas a mass loss of
14% was observed for the treated MK. It is known
that the absorbed water in pores or on the surfaces
was released at low temperature. Thus, the
accumulated loss between 100 °C and 175 °C in the
treated MK may be related to the loss of water
located in the upper cages of the zeolite structure,
while the loss at higher temperature could be
attributed to the more tightly bound molecules in the
sodalite cage. The thermal behavior of the treated
MK revealed a continuous weight loss up to∼600
°C, which was attributed to the dehydration and
decomposition processes, consistent with previous
reports in which the thermal transition from
cancrisilite to nepheline was complete at 600 °C.
Jurnal 2 Isi narasi

GSA-N2 Fisisorpsi (BET)

 Referensi (sesuai penulisan daftar pustaka yang Yang perlu ditemukan dalam jurnal:
benar)  Profil Adsorpsi/Desepsi
 Text asli Keterangan gambar sesuai jurnal  Luas permukaan spesifik
 Gambar GSA (Profil Adsorbsi-desorpsi dll)  Jari-jari/Diameter pori
 Distribusi Pori
 Volume Pori
  Informasi lain yang disampaikan
oleh peneliti
Jurnal 1
Gambar disamping ialah isoterm
Luo,H., Law,W,W., Wu,Y., Zhu,W dan Yang,E. 2018. adsorpsi-desorpsi N2 dari metaolin
Hydrothermal Synthesis Of Needle-Like murni (garis hitam) dan metakaolin
Nanocrystalline Zeolites From Metakaolin And Their hidrotermal (garis merah).
Applications For Efficient Removal Of Organic
Pollutants And Heavy Metals. Microporous and  Dapat dilihat bahwa pada
Mesoporous Material. 272: 8-15. metakaolin hidrotermal terjadi
adsorpsi dan desorpsi gas N2 pada
tekanan yang tinggi yaitu dimulai
pada 0,5 dibandingkan dengan
metakaolin murni.

 Dari hubungan antara adsorpsi

dengan tekanan tersebut akan
diplot secara otomatis oleh
software computer sehingga
diperoleh luas permukaan
metakaolin hidrotermal lebih besar
(29.84 m2g-1) dibandingkan
metakaolin murni yaitu 12.59
m2g1).

Fig. 3. (a) N2 adsorption-desorption isotherms

Surface properties of the raw and the treated MK are

illustrated in Fig. 3. The N2 adsorption-desorption
isotherms of the raw and treated MK are shown in Fig.
3a. After hydrothermal treatment, substantial increase in
N2 sorption capacity of MK was observed. Specifically,
the calculated BET surface area of MK increased from
12.59 to 29.84m2 g−1, suggesting the evolution of
porosity and potential for pollutants removal. As per the
instructions from IUPAC, the N2 sorption isotherms
could be classified as type IV with a hysteresis loop of
type H3. At high relative pressure, the presence of the
hysteresis loop indicated a mesoporous structure in the
treated MK, whereas the N2 sorption capacity was
attributed to the micropores at low relative pressure.

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