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    The document discusses aromatic, antiaromatic, and nonaromatic compounds. It provides examples of aromatic compounds like benzene derivatives that contain (4n+2) pi electrons, and antiaromatic compounds that contain 4n pi electrons. It notes that cyclooctatetraene is nonplanar to avoid antiaromaticity, becoming tub-shaped instead. Ionization of 7-bromo-1,3,5-cycloheptatriene gives the aromatic and stable tropylium ion, while 5-bromo-1,3-cyclopentadiene gives the antiaromatic and unstable 1,3-cyclopentadienyl cation.

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    The document discusses aromatic, antiaromatic, and nonaromatic compounds. It provides examples of aromatic compounds like benzene derivatives that contain (4n+2) pi electrons, and antiaromatic compounds that contain 4n pi electrons. It notes that cyclooctatetraene is nonplanar to avoid antiaromaticity, becoming tub-shaped instead. Ionization of 7-bromo-1,3,5-cycloheptatriene gives the aromatic and stable tropylium ion, while 5-bromo-1,3-cyclopentadiene gives the antiaromatic and unstable 1,3-cyclopentadienyl cation.

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    30 views1 page

    Answer Aromaticity 09 PDF

    Uploaded by

    Ritesh Sonawane
    The document discusses aromatic, antiaromatic, and nonaromatic compounds. It provides examples of aromatic compounds like benzene derivatives that contain (4n+2) pi electrons, and antiaromatic compounds that contain 4n pi electrons. It notes that cyclooctatetraene is nonplanar to avoid antiaromaticity, becoming tub-shaped instead. Ionization of 7-bromo-1,3,5-cycloheptatriene gives the aromatic and stable tropylium ion, while 5-bromo-1,3-cyclopentadiene gives the antiaromatic and unstable 1,3-cyclopentadienyl cation.

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    PART-A SUBJECTIVE QUESTIONS

    1. Aromatic : (a), (b), (c), (d), (e), (f), (h), (m) ; Antiaromatic : (g), (i), (j), (l), (n) ; Nonaromatic : (k)

    2. Cyclooctatetraene is nonplanar due to avoid its anti aromaticity and it becomes tub-shaped structure.

    3. 7-bromo-1, 3, 5-cycloheptatriene on ionisation gives tropylium ion which is aromatic & highly

    stable, but ionisation of 5-bromo-1, 3-cyclopentadiene gives 1, 3-cyclopentadienyl cation which is

    anti aromatic & unstable. (non existent)

    4. Aromatic – a, c, g, h, i, j, k ; Antiaromatic – b, d, e ; Nonaromatic – f


    5. Aromatic cyclic, planner, conjugated system having (4n + 2)electrons.
    Antiaromatic  Cyclic, Planner, conjugated system having 4n electrons.

    PART-B:OBJECIVE QUESTIONS

    H-1*. (A,B,C,D)

    6. (C)

    7. (B)
    8. (D)
    9. (B, C)

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