Calculation

Know: 𝑉𝑐𝑜𝑟𝑛 𝑜𝑖𝑙 = 2 𝑚𝐿

𝑔
𝜌𝑐𝑜𝑟𝑛 𝑜𝑖𝑙 = 𝜌𝑙𝑖𝑛𝑜𝑙𝑒𝑖𝑐 𝑎𝑐𝑖𝑑 = 0.902 𝑚𝐿

𝑚𝑐𝑜𝑟𝑛 𝑜𝑖𝑙 = 𝑉𝑐𝑜𝑟𝑛 𝑜𝑖𝑙 𝑥𝜌𝑐𝑜𝑟𝑛 𝑜𝑖𝑙

= 2 mL x 0.902 g/mL
= 1.804 g
N Na2S2O3 = M x mol.eq
= 0.1 M x 2
= 0.2 N
Mr linoleic acid = 280.4472 g/mL
1.804 𝑔
mmol corn oil = 𝑔 = 6.432. 10−3 = 6.432 𝑚𝑚𝑜𝑙
280.4472
𝑚𝐿

Determine x value.
 t = 900 s. V Na2S2O3 = 1,60 mL
moleq corn oil = moleq Na2S2O3
= N.V
= 0.2 N x 1,60 mL
= 0,32 mmol
 t = 1800 s. V Na2S2O3 = 1.7 mL
moleq corn oil = moleq Na2S2O3
= N.V
= 0.2 N x 1.7 mL
= 0.34 mmol
 t = 2700 s. V Na2S2O3 = 1.85 mL
moleq corn oil = moleq Na2S2O3
= N.V
= 0.2 N x 1.8 mL
= 0.37 mmol
 t = 3600 s. V Na2S2O3 = 2 mL
moleq corn oil = moleq Na2S2O3
= N.V
= 0.2 N x 2 mL
 = 0.40 mmol
 t = 6000 s. V Na2S2O3 = 2.2 mL
moleq corn oil = moleq Na2S2O3
= N.V
= 0.2 N x 2.2 mL
= 0.44 mmol
The calculation of this experiment are represented in table below.
t (s) a x (a-x) ln(a-x) 1/a-x ½(a-x)2
900 6.432 0.32 6.112 1.810 0.164 0.013
1800 6.432 0.34 6.092 1.807 0.164 0.013
2700 6.432 0.37 6.062 1.802 0.165 0.014
3600 6.432 0.40 6.032 1.797 0.166 0.014
6000 6.432 0.44 5.992 1.790 0.167 0.015

Determining of Peroxide Number

Known:
𝑉𝑐𝑜𝑟𝑛 𝑜𝑖𝑙 = 2 𝑚𝐿
𝜌𝑐𝑜𝑟𝑛 𝑜𝑖𝑙 = 0.902 𝑔/𝑚𝐿
Vblanco = 0.5 mL
V1 = 1.6 mL
V2 = 1.7 mL
V3 = 1.85 mL
V4 = 2.0 mL
V5 = 2.2 mL
N Na2S2O3 = 0.2 N
Peroxide Number Formula is:
(𝑎 − 𝑏)𝑚𝐿 𝑥 𝑁 𝑁𝑎2 𝑆2 𝑂3 𝑥 100 𝑥 8
𝑚𝑎𝑠𝑠 (𝑔)
(1.6−0.5)𝑚𝐿𝑥 0.2 𝑁 𝑥 1000
 Peroxide Number on 900 s = = 121,95 𝑚𝑜𝑙𝑒𝑞/𝑔𝑟𝑎𝑚
1.804 𝑔
(1.7−0.5)𝑚𝐿𝑥 0.2 𝑁 𝑥 1000
 Peroxide Number on 1800 s= = 133.04 𝑚𝑜𝑙𝑒𝑞/𝑔𝑟𝑎𝑚
1.804 𝑔
(1.85−0.5)𝑚𝐿𝑥 0.2 𝑁 𝑥 1000
 Peroxide Number on 2700 s= 1.804 𝑔
= 149.67 𝑚𝑜𝑙𝑒𝑞/𝑔𝑟𝑎𝑚
 (2−0.5)𝑚𝐿𝑥 0.2 𝑁 𝑥 1000
 Peroxide Number on 3600 s = = 166,29 𝑚𝑜𝑙𝑒𝑞/𝑔𝑟𝑎𝑚
1.804 𝑔
(2.2−0.5)𝑚𝐿𝑥 0.2 𝑁 𝑥 1000
 Peroxide Number on 6000 s= = 188.47 𝑚𝑜𝑙𝑒𝑞/𝑔𝑟𝑎𝑚
1.804 𝑔

Determining the value of K.

1 𝑎
First-order assumption 𝑘 = 𝑡 𝑙𝑛 𝑎−𝑥

 t = 900 s
1 𝑎
𝑘= 𝑙𝑛
𝑡 𝑎−𝑥
1 6.432
𝑘= 𝑙𝑛
900 6.432 − 0.32
𝑘 = 5.6 × 10−5
 t = 1800 s
1 𝑎
𝑘= 𝑙𝑛
𝑡 𝑎−𝑥
1 6.432
𝑘= 𝑙𝑛
1800 6.432 − 0.34
𝑘 = 3 × 10−5
 t = 2700 s
1 𝑎
𝑘= 𝑙𝑛
𝑡 𝑎−𝑥
1 6.432
𝑘= 𝑙𝑛
2700 6.432 − 0.37
𝑘 = 2.2 × 10−5
 t = 3600 s
1 𝑎
𝑘= 𝑙𝑛
𝑡 𝑎−𝑥
1 6.432
𝑘= 𝑙𝑛
3600 6.432 − 0.4
𝑘 = 1.8 × 10−5
 t = 6000 s
1 𝑎
𝑘= 𝑙𝑛
𝑡 𝑎−𝑥
1 6.432
𝑘= 𝑙𝑛
6000 6.432 − 0.44
 𝑘 = 1.2 × 10−5
1 1
−
(𝑎−𝑥) 𝑎
Second-order assumption. 𝑘 = 𝑡

 t = 900 s
1 1
− 6.432
(6.432 − 0.32)
𝑘=
900
𝑘 = 9 × 10−6
 t = 1800 s
1 1
− 6.432
(6.432 − 0.34)
𝑘=
1800
𝑘 = 4.8 × 10−6
 t = 2700 s
1 1
− 6.432
(6.432 − 0.37)
𝑘=
2700
𝑘 = 3.5 × 10−6
 t = 3600 s
1 1
− 6.432
(6.432 − 0.4)
𝑘=
3600
𝑘 = 2.7 × 10−6
 t = 6000 s
1 1
− 6.432
(6.432 − 0.44)
𝑘=
6000
𝑘 = 1.9 × 10−6

1 1
−
2(𝑎−𝑥)2 2𝑎2
Third-order assumption. 𝑘 = 𝑡

 t = 900 s
1 1
2 −
2(6.432 − 0.32) 2(6.432)2
𝑘=
900
𝑘 = 1.44 × 10−6
 t = 1800 s
1 1
2 −
2(6.432 − 0.34) 2(6.432)2
𝑘=
1800
𝑘 = 7.69 × 10−6
 t = 2700 s
1 1
−
2(6.432 − 0.37)2 2(6.432)2
𝑘=
2700
𝑘 = 5.18 × 10−7
 t = 3600 s
1 1
−
2(6.432 − 0.4)2 2(6.432)2
𝑘=
3600
𝑘 = 3.93 × 10−7
 t = 6000 s
1 1
−
2(6.432 − 0.44)2 2(6.432)2
𝑘=
6000
𝑘 = 3.07 × 10−7

Graphic Peroxide Number

Graphic Peroxide Number

250

200 y = 0.0134x + 111.78

Peroxide Number

R² = 0.9758
150
Peroxide Number
100
Linear (Peroxide
50 Number)

0
0 2000 4000 6000 8000
times (s)

Graphic Rancidy Oil