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(Ebook) Make The Right Choice: Total and Partial Pressure - Dalton'S Law of Partial Pressures
(Ebook) Make The Right Choice: Total and Partial Pressure - Dalton'S Law of Partial Pressures
(Ebook) Make The Right Choice: Total and Partial Pressure - Dalton'S Law of Partial Pressures
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The term partial pressure is used when we have a mixture of two or several gases in the same volume, and it expresses the pressure that is
caused by each of the induvidual gases in the mixture.
The total pressure of the gas mixture is the sum of the partial pressure of the component gases:
Where
Pi = the pressure of component i (i can vary from 1,2,3.....up to the number of different gases in the mixture)
PV = nRT or P = nRT / V
Then,
where
ntot = the total number of moles in the gas mixture, which is the sum of all ni.
R = the gas constant = 8.3145 [J/mol K] = 0.08206 [L atm/mol K] = 62.37 [L torr /mol K]
For a gas mixture, the temperature and the volume is the same for all gases, and the gas constant is always the same, and then we get:
We can express the concentration of one gas in the gas mixture as the mole fraction, Xi:
Xi = ni/ntot
and then
Pi/Ptot = Xi or Pi = XiPtot
See also Non-ideal gas - Van der Waal's equation and constants
Example 1.
Dry air consists mainly of nitrogen (78.09vol% or 75.47wt%),oxygen (20.95vol% or 23.20 wt%), argon (0.93vol% or 1.28wt%) and carbondioxide
(0.03vol% or 0.046wt%).
If you have 100 g of dry air in a 50 liter closed container, what will the partial pressure of each gas be, and what will the total pressure be at 120°
C?
https://www.engineeringtoolbox.com/partial-pressure-ideal-gas-law-total-mixture-ble... 11/16/2019
Total and partial pressure - Dalton's law of partial pressures Page 2 of 6
First, we must find how many moles of each gas, using the weight fraction of each gas and molweight of the gases:
The total pressure, Ptot = ntotRT/V = 3.451 [mol]* 0.08206 [L atm/mol K]* (273+120) [K] / 50 [L] = 2.226 atm
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