LEMBAR PERHITUNGAN REAGEN

Volume Basis: 450 ml

1. Menghitung 𝜌 pati
𝑚 𝑝𝑎𝑡𝑖
𝜌 pati = ∆𝑣
1 𝑔𝑟
= 1,1 𝑚𝑙

= 0,909 gr/ml

Massa picno kosong = 19,96 gr

Massa picno + Aquades = 44,87 gr
44,87−19,96
V picno = = 25,01 𝑚𝑙
0,996

2. Menghitung 𝜌 HCl dan H2SO4

a. HCl
Volume picno = 25,01ml
Massa picno kosong = 19,96 gr
Massa picno + HCl = 48,7215 gr

𝑚2−𝑚1
𝜌 HCl = 𝑣 𝑝𝑖𝑐𝑛𝑜
48,7215 −19,96
= 25,01 𝑚𝑙

= 1,15 gr/ml

b. H2SO4
Volume picno = 25,01 ml
Massa picno kosong = 19,96 gr
Massa picno + H2SO4 = 65,228 gr

𝑚2−𝑚1
𝜌 H2SO4 = 𝑣 𝑝𝑖𝑐𝑛𝑜
65,228 − 19,96
= 25,01 𝑚𝑙

= 1,81 gr/ml

3. Menghitung kebutuhan katalis

a. Variabel 1 (H2SO4)
Menghitung kebutuhan H2SO4

1
 𝑁 𝐻𝐶𝑙 𝑥 𝐵𝑀 𝐻𝐶𝑙 𝑥 𝑉 𝑏𝑎𝑠𝑖𝑠
V HCl = 𝜌 𝐻𝐶𝑙 𝑥 % 𝑥 1000 𝑥 𝑔𝑟𝑒𝑘
0,2 𝑥 98 𝑥 450
= 1,81 𝑥 0,95 𝑥 1000 𝑥 2

= 2,564 ml
b. Variabel (HCL)
Menghitung kebutuhan HCL
𝑁 H2SO4 𝑥 𝐵𝑀 H2SO4 𝑥 𝑉 𝑏𝑎𝑠𝑖𝑠
V H2SO4 = 𝜌 𝐻𝐶𝑙 𝑥 % 𝑥 1000 𝑥 𝑔𝑟𝑒𝑘
0,2 𝑥 36,5 𝑥 450
= 1,15 𝑥 0,25 𝑥 1000 𝑥 1

= 11,426 ml

4. Menghitung kebutuhan pati

Perbandingan V aquades : V pati = 12 : 1
V basis = V pati + V katalis + V aquades
V basis = V pati + V katalis + 12V pati
13V pati = V basis – V katalis
a. Variabel 1 (H2SO4)
13V pati = 450 ml –2,564 ml
13V pati = 447,436 ml
V pati = 34,42 ml
Wpati = 𝜌 pati x V pati
= 0,909 x 34,42
= 31,29 gr
Vaquades = 12V pati
= 12 x 34,42
= 413,04 ml

b. Variabel 2 (HCL)
13V pati = 450 ml – 11,426ml
13V pati = 438,574 ml
V pati = 33,736 ml
Wpati = 𝜌 pati x V pati
= 0,909 x 33,736
= 30,666 gr
Vaquades = 12V pati
= 12 x 33,736
= 413,04 ml

2
 LEMBAR PERHITUNGAN

1. Perhitungan Kadar Pati Awal

500 100
(𝐹−𝑀)𝑥 𝑁 𝑔𝑙𝑢𝑘𝑜𝑠𝑎 𝑥 𝑥 𝑥 0,9
𝑉𝑜𝑙.𝑏𝑎𝑠𝑖𝑠 5
Xpo = 𝑤

N glukosa = 0,002 gr/ml

F = 19,5 ml

a. H2SO4
M = 12,5 ml
500 100
(19,5 −12,5)𝑥 0,002 𝑥 𝑥 𝑥 0,9
450 5
Xpo = 31,29

= 0,00894

b. HCL
M = 12 ml
500 100
(19,5 −12)𝑥 0,002 𝑥 𝑥 𝑥 0,9
450 5
Xpo = 30,666

= 0,00978

2. Perhitungan Kadar Pati

100
(𝐹−𝑀)𝑥 𝑁 𝑔𝑙𝑢𝑘𝑜𝑠𝑎 𝑥 𝑥 0,9
5
Xp = 𝑤
𝑋𝑝
XA = 𝑋𝑝𝑜

a. H2SO4
 t = 5 ; M = 17 ml
100
(19,5−17)𝑥 0,002 𝑥 𝑥 0,9
5
Xp = 31,29

= 0,00287
0,00287
XA = 0,00894

= 0,321
 t = 10 ; M = 16 ml
100
(19,5−16)𝑥 0,002 𝑥 𝑥 0,9
5
Xp = 31,29

= 0,00402

3
 0,00402
XA = 0,00894

= 0,449
 t = 15 ; M = 15 ml
100
(19,5−15)𝑥 0,002 𝑥 𝑥 0,9
5
Xp = 31,29

= 0,00517
0,00517
XA = 0,00894

= 0,578
 t = 20 ; M = 13 ml
100
(19,5−13)𝑥 0,002 𝑥 𝑥 0,9
5
Xp = 31,29

= 0,00747
0,00747
XA = 0,00894

=0,835
 t = 25 ; M = 11,5 ml
100
(19,5−11,5)𝑥 0,002 𝑥 𝑥 0,9
5
Xp = 31,29

= 0,00920
0,00920
XA = 0,00894

= 1,029
b. HCL
 t = 5 ; M = 16 ml
100
(19,5−16)𝑥 0,002 𝑥 𝑥 0,9
5
Xp = 30,666

= 0,00411
0,00411
XA = 0,00978

= 0,420
 t = 10 ; M = 15 ml
100
(19,5−15)𝑥 0,002 𝑥 𝑥 0,9
5
Xp = 30,666

= 0,00528
0,00528
XA = 0,00978

= 0,539
 t = 15 ; M = 13 ml
100
(19,5−13)𝑥 0,002 𝑥 𝑥 0,9
5
Xp = 30,666

4
 = 0,00763
0,00763
XA = 0,00978

= 0,780
 t = 20 ; M = 12, 4 ml
100
(19,5−12,4)𝑥 0,002 𝑥 𝑥 0,9
5
Xp = 30,666

= 0,00833
0,00833
XA = 0,00978

= 0,851
 t = 25 ; M = 10,5 ml
100
(19,5−10,5)𝑥 0,002 𝑥 𝑥 0,9
5
Xp = 30,666

= 0,01056
0,01056
XA = 0,00978

= 1,079

Hasil Perhitungan Variabel H2SO4

t (menit) M (ml) Xp XA 1
ln 1−𝑋𝐴

5 17 0,00287 0,321 0,387

10 16 0,00402 0,449 0,596
15 15 0,00517 0,578 0,862
20 13 0,00747 0,835 1,802
25 11,5 0,00920 1,029

Hasil Perhitungan Variabel HCL

t (menit) M (ml) Xp XA 1
ln 1−𝑋𝐴

5 16 0,00411 0,420 0,544

10 15 0,00528 0,539 0,774
15 13 0,00763 0,780 1,514
20 12,4 0,00833 0,851 1,903
25 10,5 0,01056 1,079