Area Na Kadar

Kadar natrium Persamaan

No. siklamat aspartam Area aspartam
siklamat (ppm) (x) Regresi Linear
(y) (ppm)

1 900 401590 a 15 571324

2 1200 554758 26522.74 20 768342
3 1500 681156 b 25 958786
4 1800 809439 431.26 30 1158916
5 2100 918098 r 35 1353874
6 2400 1063577 0.9990 40 1536570
y=431,26x+0,9990
Parameter linearitas = nilai r yang baik adalah 1, sehingga metode diatas sudah sesuai

Perhitungan LOD dan LOQ

Area Na
NO. Kadar natrium Y^ (y-y^)^2
siklamat Σ((y-y^)^2)
siklamat (ppm) (x)
(y)

1 900 401590 414657.428571429 170757689 591993105.08572

2 1200 554758 544035.657142857 114968636 421235415.61633
3 1500 681156 673413.885714286 59940333.61 306266779.27021
4 1800 809439 802792.114285714 44181089.7 246326445.65714
5 2100 918098 932170.342857143 198030833 206758441.70893
6 2400 1063577 1061548.57142857 4114522.469 9875608.2203177

NO. Kadar aspartam Area y^ (y-y^)^2

(ppm) aspartam
Σ((y-y^)^2)

1 15 571324 573471.80952381 4613085.751 89232849.676193

2 20 768342 767270.552380953 1148000 84619763.925626
3 25 958786 961069.295238095 5213437.144 83471763.925263
4 30 1158916 1154868.03809524 16385995.58 78258326.780954
5 35 1353874 1348666.78095238 27115130.21 61872331.198551
6 40 1536570 1542465.52380952 34757201 34757200.988665

Presisi
Asparta
No. Na-siklamat (ppm)
m (ppm)
1. 1504.54 24.54
2. 1507.22 24.59
3. 1506.12 24.57
4. 1516.67 24.71
5. 1518.64 24.71
6. 1524.76 24.81
Rata-rata
1512.99 24.66
SD 8.20 0.10
CV atau
RSD 0.54 0.42
C (g/g) 1.51 g/1000g 0.02 g/1000g
0.0015129917 g/g 0.000024655 g/g
RSD
teoritis 2.65 4.91
HORRATr 0.20 0.09
Niliai kebertiramaan 0,5 - 2

Akurasi
Na Siklamat
Kadar Kadar
Kadar standard %Rec
Akurasi Standar+sampel Sampel
(ppm)
(ppm) (ppm)

2961.26 1664.98 1213.23 106.85

80% 2953.81 1664.98 1213.23 106.23
2958.9 1664.98 1213.23 106.65
3167.52 1664.98 1517.95 98.98
100% 3190.63 1664.98 1517.95 100.51
3195.51 1664.98 1517.95 100.83
3615.08 1664.98 1815.41 107.42
120% 3631.14 1664.98 1815.41 108.30
3627.57 1664.98 1815.41 108.11
Rata-rata 104.88
Nilai keberterimaan = 90-108%

Kadar
Area Na
Kode Area
Bobot sampel (g) siklamat
sampel aspartam (Y)
(Y)
MS_1 8.1839 763890 799947
MS_2 8.0042 755890 801131
MS_3 8.1203 755432 799219

1. Konsentrasi larutan sampel

MS_1 1709.794
 Persamaan Regresi
Linear

a
-7924.42
b
38759.75
r
0.9999
y=38759,75x-7924,42

sy/x LOD LOQ

12165.5 93.0898 282.09

sy/x LOD LOQ

4723.2 0.4021 1.22

Aspartam
Kadar
Kadar Kadar
Standar+
Akurasi Sampel standard
sampel
(ppm) (ppm)
(ppm) %Rec
43.3 23.4 19.93 99.85
80% 43.43 23.4 19.93 100.50
43.22 23.4 19.93 99.45
46.55 23.4 24.94 92.82
100% 47.57 23.4 24.94 96.91
47.46 23.4 24.94 96.47
53.7 23.4 30.1 100.66
120% 53.7 23.4 30.1 100.66
53.37 23.4 30.1 99.57
Rata-rata 98.54
Nilai Keberterimaan = 85-110%
y=bx+a
x= y-a/b
 1664.98
1664.98
1664.98
100% 1664.98
1664.98
1664.98 1517.95
120% 1664.98 1815.41
1664.98 1815.41
1664.98 1815.41

Hasil
pembaca
an
perolehan
kembali
aspartam
sebagai
berikut:

Kadar
Kadar Kadar
Standar+
Akurasi Sampel standard
sampel
(ppm) (ppm)
(ppm)
43.3 23.4 19.93
80% 43.43 23.4 19.93
43.22 23.4 19.93
46.55 23.4 24.94
100% 47.57 23.4 24.94
47.46 23.4 24.94
53.7 23.4 30.1
120% 53.7 23.4 30.1
53.37 23.4 30.1