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Safety Data Sheet: 1 Identification of The Substance/preparation and of The Company/undertaking
Safety Data Sheet: 1 Identification of The Substance/preparation and of The Company/undertaking
2 Hazards identification
· Hazard description:
Xn Harmful
Warning
Warning
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 03.06.2010 version no: 1 Revision: 03.06.2010
3 Composition/information on ingredients
*
· Chemical characterization
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 123-31-9 Hydroquinone (1,4-dihydroxybenzene) <2.5 %
EINECS: 204-617-8 Carc. Cat. 3, Muta. Cat. 3; Xn, Xi, N; R 22-40-41-43-68-50
Danger: 3.3/1
Warning: 3.5/2, 3.6/2; 4.1.A/1; 3.1.O/4, 3.4.S/1
CAS: 111-46-6 diethylene glycol 0.5-2
EINECS: 203-872-2 Xn; R 22 %
Warning: 3.1.O/4
CAS: 111-30-8 glutaral 0.5-2
EINECS: 203-856-5 T, C, N; R 23/25-34-42/43-50 %
Danger: 3.1.O/3, 3.1.I/3; 3.4.R/1; 3.2/1B
Warning: 4.1.A/1; 3.4.S/1
CAS: 140-01-2 Sodium diethylene triamine pentaacetic aicd (DTPA-Na5) 0.5-2
EINECS: 205-391-3 Xi; R 36 %
Warning: 3.3/2
CAS: 13047-13-7 4-(hydroxymethyl)-4-methyl-1-phenylpyrazolidin-3-one 0.5-2
EINECS: 235-920-3 Xn, Xi, N; R 22-36-43-51/53 %
Warning: 3.1.O/4, 3.3/2, 3.4.S/1
4.1.C/2
· Additional information: For the wording of the listed risk phrases refer to section 16.
5 Fire-fighting measures
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards caused by the substance, its products of combustion or resulting gases:
Under certain fire conditions, traces of other toxic gases cannot be excluded.
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 03.06.2010 version no: 1 Revision: 03.06.2010
DR
Page 4/ 8
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 03.06.2010 version no: 1 Revision: 03.06.2010
DR
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 03.06.2010 version no: 1 Revision: 03.06.2010
Protective gloves
Impervious gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the prepara tion/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks o f quality
and varies from manufacturer to manufacturer. As th e product is a preparation of several substances, t he
resistance of the glove material can not be calcula ted in advance and has therefore to be checked prio r to the
application.
Butyl rubber, BR
Nitrile rubber, NBR
· Penetration time of glove material
Gove material: Butyl rubber with breakthroug-time: ≥ 480 min, layer thickness: ≥0,4 mm
Gloves made of nitrile rubber with layer thickness >0,38mm and breakthrough-time >480min
Glove material: Neopren with breakthrough time: >240 min, layer thickness: >0,65 mm
-
The exact break trough time has to be found out by the manufacturer of the protective gloves and has t o be
observed.
· Eye protection:
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 03.06.2010 version no: 1 Revision: 03.06.2010
11 Toxicological information
· Acute toxicity:
· LD/LC50 values relevant for classification:
123-31-9 Hydroquinone (1,4-dihydroxybenzene)
Oral LD50 320 mg/kg (rat )
Dermal LD50 >900 mg/kg (rat )
LD50 72 h: 1 mg/l (alg )
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: No irritating effect.
· Sensitization: Sensitization possible through skin contact.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version: Irritant
· Sensitisation May cause sensitisation by skin contact.
12 Ecological information
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
GB
( Contd. on page 6)
( Contd. of page 5)
13 Disposal considerations
· Product:
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· European waste catalogue
09 01 01 water-based developer and activator solutions
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
· Recommended cleansing agents: Water, if necessary together with cleansing agents.
14 Transport information
· Land transport ADR/RID (cross-border)
· ADR/RID class: -
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 03.06.2010 version no: 1 Revision: 03.06.2010
15 Regulatory information
· Labelling according to EU guidelines:
The product has been classified and marked in accor dance with EU Directives / Ordinance on Hazardous
Materials.
· Code letter and hazard designation of product:
Xn Harmful
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant R-phrases
22 Harmful if swallowed.
23/25 Toxic by inhalation and if swallowed.
34 Causes burns.
36 Irritating to eyes.
40 Limited evidence of a carcinogenic effect.
41 Risk of serious damage to eyes.
42/43 May cause sensitisation by inhalation and skin contact.
43 May cause sensitisation by skin contact.
50 Very toxic to aquatic organisms.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
68 Possible risk of irreversible effects.
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 03.06.2010 version no: 1 Revision: 03.06.2010
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