Iit-Jee 20: CTY, ITY179 X, Z (05-APR)

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CTY, ITY179 X, Z (05-APR) TEST ID

IIT-JEE 2019
8906212
Time: 180 minute Maximum Marks: 360
Please read the instructions carefully.
INSTRUCTIONS

A: General :
1. Immediately fill in the particulars on this page of the Test Booklet with Blue/Black Ball point
pen.
2. Use Black Ball Point Pen only for writing particulars on Answer Sheet. Use of pencil is strictly
prohibited.
3. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and
electronic gadgets in any form are not allowed.
4. The answer sheet, a machine-gradable Objective Response Sheet (ORS) is provided separately.
5. Do not Tamper/mutilate the ORS or this booklet.
6. No additional sheets will be provided for rough work.
7. On completion of this test, the candidate must hand over the Answer Sheet to the Invigilator on
duty in the Room/Hall. However, the candidates are allowed to take away this Test Booklet
with them.

B: Questions paper format & Marking Schema:


1. The question paper consists of THREE Parts:Physics (PH), Chemistry (CH), Mathematics (MT).
2. Each Part I, II & III has ONESections:
3. For each question, you will be awarded 4 marks if you darken ALL the bubble(s) corresponding
to the correct answer ONLY and zero (0) marks if no bubbles are darkened. In all other cases,
minus one (−1) mark will be awarded.
OJEMD180C01

Enrollment No. : Batch :

Name :

Candidate’s Signature Invigilator’s Signature:

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PART – I: Physics (PH)

SECTION A Single Correct Choice Type

Each question has 4 choices (A), (B) (C) and (D) for its answer, out of which ONLY ONE is correct.
1. Three charges –q1 , q2 , q3 are placed in a plane as shown in figure. The x  component of the force on –q1 is
proportional to

q2 q3 q2 q3
(A)  sin  (B)  cos 
b2 a2 b2 a2
q2 q3 q2 q3
(C)  sin  (D)  cos 
b2 a2 b2 a2

2. A uniformly charged non-conducting hemispherical shell is shown in figure. What is correct direction of net electric
field at point A on its open plane surface?

(A) 1 (B) 2
(C) 3 (D) 4

3.  
The potential in an electric field has the form V  a x2  y2  z2 . The modulus of the electric field at a point

 x, y, z  is
3
(A) 2a  x2  y2  z2  2 (B) 2a x2  y2  z2
2a
(C) a x 2  y 2  z2 (D)
x 2  y 2  z2
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4. Which of the following represents the field due to a small dipole of dipole moment p at a position r relative to its
centre?
p 2 p  r  r p 2 p  r  r
(A)  (B)  
4 0 r 3 4 0 r 5 4 0 r 3 4 0 r 5
p 3p  r  r p 3 p  r  r
(C)   (D) 
4 0 r 3 4 0 r 5 4 0 r 3 4 0 r 5

5. A thin metallic spherical shell contains a charge Q on it. A point charge q1 is


Q
placed at the centre O of the shell and another charge q is placed at P , at a r p
distance d , (d  r ) from the centre as shown in the figure. The incorrect option
O q1 d q
is
(A) Force on q1 due to the charge on shell [ Q and induced charges] is
towards right
(B) Force on q1 due to all the charges [ Q , q and the induced charges) is zero
(C) Force on q1 due to q is towards left
kQq kq1q
(D) Force on q due to Q and q1 is 
r 2
 d  r 2

6. A point charge ' q' is placed inside a conducting spherical shell of inner radius 2R and outer radius 3R at a
distance 'R' from the centre of the shell. The electric potential at the centre of the shell is:
kq 4kq
(A) (B)
2R 3R
5kq 2kq
(C) (D)
6R 3R

7. The capacitance of a spherical capacitor of inner radius ' a' and outer radius 'b' , when outer is charged and inner
is earthed is:
4 0 a2 2 0 b2
(A) (B)
ba ba
4 0 ab 4 0 b2
(C) (D)
ba ba
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8. A and B are two concentric spheres with their centers at O and of radius R and 2R respectively. C and D are
two other concentric spheres of radius R and 2R and their center is at O’ . O and O’ are at a separated by a large
distance. Initially the charge on sphere A is –q and on B is q . When the switch is connected the charge on the
sphere D and C is
B D

A R C R

O S O
2 2 ’
R R

q q
(A) , ZERO (B)  , ZERO
2 2
q q
(C) ,  (D) ZERO, ZERO
2 2

9. The capacitance of an infinite circuit formed by the repetition of same link consisting of two identical capacitors,
each with capacitance ' C ' is

5 1
(A) ZERO (B) C
2
5 1
(C) C (D) Infinite
2

4
10. Capacitance of a capacitor becomes times its original value if a dielectric slab of same cross section area of the
3
is inserted between the plates  d  separation between the plates  . The dielectric
d
plates and thickness t 
2
constant of the plates is
(A) 2 (B) 4
(C) 6 (D) 8
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11. The current in a wire varies with time according to the equation I  4  2t ; where, I is in ampere and t is in sec.
The quantity of charge which has passed through a cross-section of the wire during the time t  2 sec to t  6
sec will be
(A) 60 coulomb (B) 24 coulomb
(C) 48 coulomb (D) 30 coulomb

12. A uniform copper wire of length 1 m and cross-sectional area 5  107 m2 carries of 1A . Assuming that there are
8  1028 free electron per m3 in copper, how long will an electron take to drift from one end of the wire to the
other?
(A) 0.8  103 s (B) 1.6  103 s
(C) 3.2  103 s (D) 6.4  103 s

13. Eight resistances each of resistance 5  are connected in the circuit as shown in figure.
The equivalent resistance between A and B is:
8 16
(A)  (B) 
3 3
15 19
(C)  (D) 
7 2

14. The value of current passed through point ‘A’ when the switch ‘S’ is pressed is

(A) 7A (B) 1A
42 7
(C) A (D) A
11 11
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15. A battery of e.m.f. 'E’ and internal resistance ‘r’ is connected across a resistance R .
R is having any value such that R  0 . A graph is plotted between current i and
potential difference then
(A) Internal resistance of battery is 10 
(B) e.m.f. of battery is 20 V
(C) maximum current drawn is 2 A
(D) All of the above

16. The time constants in microsecond of circuits 1 , 2 and 3 shown in figure are

(R1  1, R2  2, C1  2mF, C2  4mF)


8 8
(A) 4, , 18 (B) 4 , 18 ,
9 9
8 8
(C) 18 , , 4 (D) 18 , 4 ,
9 9

17. In the given circuit, the potential difference across the 6 F capacitor in
steady state is
(A) 1 V
(B) 6 V
(C) 3 V
(D) 4 V

18. A galvanometer of resistance 20  gives full scale deflection when a current of 1 mA is passed through it. It is
converted into a voltmeter by connecting a resistance of 4980  in series with it. The maximum potential difference
this voltmeter can measure is
(A) 5 mV (B) 0.05 V
(C) 5.0 V (D) 50 V
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19. In the arrangement shown in the figure when the switch S2 is open, the galvanometer shows no deflection for
L 5
 . When the switch S2 is closed, the galvanometer shows no deflection for  L . The internal resistance
2 12
r  of 6 V cell, and the emf E of the other battery are respectively

(A) 3 , 8V (B) 2  , 12 V
(C) 2  , 24 V (D) 3  , 12 V

20. The wheat stone Bridge in the fig. is balanced if the position of the cell E and the galvanometer G are now
interchanged, G shows zero deflection then

(A) R1  R2 (B) all the resistances are equal


R1 R2
(C) R1  R3 and R2  R4 (D) 
R3 R4

21. Three identical bar magnets each of magnetic moment M , are placed in the form of an
equilateral triangle with North Pole of one touching the south pole of the other (figure). The net
magnetic moment of the system is
(A) ZERO (B) 3M
3M
(C) (D) M 3
2
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22. A bar magnet is equivalent to


(A) Straight conductor carrying current (B) Toroid carrying current
(C) Solenoid carrying current (D) None of these

23. The coereivity of a small bar magnet is 4  103 Amp m1 . It is inserted inside a solenoid of 500 turns and length
1 m to demagnetize it. The amount of current to be passed through the solenoid will be
(A) 2.5 A (B) 5 A
(C) 8 A (D) 10 A

24. The dipole moment of each molecule of a paramagnetic gas is 1.5  1023 Amp  m2 . The temperature of gas is
27o C and the number of molecules per unit volume in it is 2 1026 m3 . The maximum possible intensity of
magnetization in the gas will be
(A) 3  103 Ampm1 (B) 4  103 Ampm1
(C) 5  105 Ampm1 (D) 6  104 Ampm1

25. A dip circle is so set that it moves freely in the magnetic meridian. In this position, the angle of dip is 40°. Now the
dip circle is rotated so that the plane in which the needle moves makes an angle of 30 with the magnetic
meridian. In this position, the needle will dip by the angle
(A) 40 (B) 30
(C) More than 40 (D) Less than 40

26. In the figure shown a coil of single turn is wound on a sphere of radius r and mass m.
The plane of the coil is parallel to the inclined plane and lies in the equatorial plane of
the sphere. If sphere is in rotational equilibrium, the value of B is (Current in the coil
is )
mg mgsin
(A) (B)
r 
mgr sin
(C) (D) None of these

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27. A thin uniform rod of mass m and length is in equilibrium as shown.


P is pivot when a current flows along the rod, it rotates from its place
about point P . Assume that there is no effect of current on the spring
and the spring remain horizontal. The torque experienced by the rod
about P and the spring force, when the rod makes an angle  with the
horizontal, would be:
iB 2 mg
(A)  cos  ; K cos
2 2
iB 2
(B)  K 2 sin  cos  ; K sin 
2
iB 2 mg
(C)  cos   K 2 sin  cos  ; K cos
2 2
(D) 0 ; K cos

28. Electric field and magnetic field in a region of space are given by E  E0ˆj and B  B0ˆj . A particle of specific
charge  (charge per unit mass) is released from origin with velocity V  V ˆi . The position of particle at any time
0

t is
V0 1 V
(A) r cos  B0t  ˆi  E0t 2ˆj  0 sin  B0t  kˆ
B0 2 B0
V0 1 V
(B) r cos  B0t  ˆi  E0t 2ˆj  0  1  sinB0t  kˆ
B0 2 B0
V0 1 V
(C) r sin  B0t  ˆi  E0t 2ˆj  0  1 cosB0t  kˆ
B0 2 B0
(D) None of these

29. A proton and an   particle enter a magnetic field normally. If the force experienced by the proton is double of
that experienced by the   particle , the ratio of their speeds is
(A) 0.5 (B) 1
(C) 2 (D) 4

30. A particle of mass m having a charge q enters into a circular region of radius R with velocity v directed towards
the centre. The strength of magnetic field is B . The deviation in path of the particle is

 mv   mv 
(A)   2tan1   (B)     tan1  
 qBR   qBR 
 2mv   2mv 
(C)   tan1   (D)     tan1  
 qBR   qBR 
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PART – II: Chemistry (CH)


SECTION A Single Correct Choice Type

Each question has 4 choices (A), (B) (C) and (D) for its answer, out of which ONLY ONE is correct.
31. Arrange the following compounds in decreasing order of their reactivity for hydrolysis reaction
C6H5 CH C2H5
(I) C6H5  CH2  Br (II)
Br
CH3 Br
(III) (IV)
Br CH

(A)  I    II    III    IV  (B)  IV    II    I    III 


(C)  III    IV    II    I  (D)  IV    III    II    I 

32. Choose the incorrect statement(s) for the reaction


OH
O O

O 
AlCl3 / CS2
heat
+ HO
CH3 CH3
CH3
(b) (a)
O
(A) (b) is formed more rapidly at higher temperature (B) (b) is more volatile than (a)
(C) (a) is more volatile than (b) (D) (a) is formed in higher yields at lower temperature

33. Achiral C5H10O ether reacts with hot HI to give a C5H10I2 product. Treatment of this with hot KOH in ethanol
produces 1, 3-pentadiene. What is the structure of the original ether?

(A) (B)

(C) (D)

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Br
Mg (i) 14CO2 NaHCO3
34. (A) (B) (C) gas, product C is:
(ii) H+/H2O
14
(A) CO (B) CO2
14
(C) CO2 (D) A mixture CO2 and CO2

35. Which one of the following is having highest pKa value?


H H
(A) N (B) N

H H
(C)
N (D) N

36. Dipole moment of cyanides and isocyanides are related as:


(A)   RCN     RNC  (B)   RCN     RNC 
(C)   RCN     RNC  (D) (RCN) < (RNC)

37. Identify the major product in the following reaction

(A) (B)

(C) (D)

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38. The following reaction gives product In which way the product will form:
Me Me
?
Me Cl + NaOH Me OH
Me Me
(A) SN1 (B) SN2
(C) both ways (D) no product will form

39. The end product of following reaction would be,

(A) (B)

(C) (D)

40. Consider the given reaction


Br / 
RCOOAg   R  Br
Which one of the following acid will give maximum yield of R–Br in the above reaction?
CH3  CH  COOH
(A) | (B) CH3 – CH2 – CH2 – COOH
CH3
CH3
|
(C) CH3  C  COOH (D) All will give same yield
|
CH3
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41.

(A) (B)

(C) (D) B & C both are correct

42. 1–Chlorobutane on reaction with aqueous potash gives


(A) 1–Butene (B) 1–Butanol
(C) 2–Butene (D) 2–Butanol

43. In the following reaction sequence, the structure of A and B are, respectively-

(A) O H (B)
and H O H
and
H
and CHO
(C) and (D)
OH

44. In the given reaction


1.HCHO/H
X
2.H2O
X is:

OH OH
(A) (B)
OH
OH
OH
OH
(C) (D)
OH

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45. CH3  CH  CH  CH2  OH 


HBr
P

CH3 CH2 CH CH2 OH


(A) (B)
Br

(C) CH2  CH  CH  CH2 (D)

46. Which one of the following substrate will give racemised product?
CH3
CI
(A) H19C9 (B) H3C Br
C6H5
CH3
H3C Br Br
(C) (D)
CH3 H5C6 C6H5
H
Br2+H2O NaOH NH3
47. Product
Or (HOBr)
H3C
The product is:
H
H2N
H 2N
(A) (B) H
H3C
H3C
HO
HO
H HO
(C) HO (D) H
H3C H3C
H 2N H 2N

48. Cannizaro reaction is not given by


(A) Trimethyl acetaldehyde (B) Acetaldehyde
(C) Benzaldehyde (D) Formaldehyde
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49. Replacement of Cl of chloro benzene to give phenol requires drastic conditions but chlorine of 2, 4-dinitro chloro
benzene is readily replaced because
(A) - NO2 makes the ring electron rich at ortho and para positions
(B) - NO2 withdraws electrons at meta position
(C) - NO2 donate electrons at meta position
(D) - NO2 group withdraws electrons at ortho and para position

50. In the following reaction, predict the product (* means C-13)

(A) (B)

(C) (D)

O O
51. Conc.NaOH
Ph C C H X
The product ‘x’ is
(A) Ph CO CO2H (B) Ph CH  OH  CO2Na
(C) Ph  CH  OH  CH2OH (D) Ph  CH  CH2
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52.

In the above reaction  P  and  Q  are respectively:

(A) (B)

(C) (D)

CH3 CH3 NaNO2


53. OH NH2 A. A is
HCl
CH3 CH3
O CH3 CH3 CH3
(A) H3C C C CH3 (B) CH3 CH3
OH OH
CH3
CH3
H3C CH3
CH3
(C) (D)
H3C
H3C CH3
CH3

54. Which one of the following reactions leads to formation of optically inactive mixture?

CH3 CH3
NaI OH-
(A) H I acetone (B) Ph Br
(aq.)
CH2CH3 H

CH2CH3
H3O+
(C) Ph OH (D) both (A) & (C)

CH2CH3
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55. Synthesis of hexane-3, 4-diol from trans-3-hexene may be accomplished in two ways:
(i) OsO4 hydroxylation &
(ii) C6H5CO3H epoxidation followed by NaOH opening of the epoxide ring.
Which of the following statements about the products from these reactions is correct?
(A) The two methods give the same product
(B) (i) gives a chiral isomer, (ii) gives an achiral isomer
(C) (i) gives an achiral isomer, (ii) gives a chiral isomer
(D) Two different isomers are formed, but both are chiral

56. In the Cannizzaro reaction, which is the slowest step?


OH-
2 PhCHO PhCH2OH + PhCOO-
(A) The attack of OH at the carboxyl group (B) The transfer of hydride to the carbonyl group
(C) The abstraction of proton from the carboxylic acid (D) The deprotonation of PhCH2OH

57. What will be the most probable product when compound 'X' is treated with two equivalents of NaOH,
HO COOH

X= C CH

HO NO2

O COOH O COO

(A) C CH (B) C CH

O NO2 HO NO2

HO COO HO COO

(C) C C (D) C CH

HO NO2 O NO2
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58. In the given reaction:


COOC2H5
+ |
Pyridne
  X
COOC2H5

 X will be :

(A) (B)

(C) (D)

59. About the following reaction


H3C
OH
H+ O3/Zn aq. NaOH
P Q R
 CH3COOH
Which of the following options (s) is/are correct?
CH3

CH3
(A) Compound P is (B) Compound P is

O O
CH3
C
(C) Compound R is (D) Compound R is
CH3

60. Which of the following ketone recemises in aqueous solution containing some acidic or basic impurities.
CH3CH CH C CH3
(A) (B) C2H5 CH C CH3
Ph Ph O
CH3 O
CH3 O
Ph
C6H5 C C C2H5 Me
(C) (D)
Me
O Ph

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PART – III: Mathematics (MT)

SECTION A Single Correct Choice Type

Each question has 4 choices (A), (B) (C) and (D) for its answer, out of which ONLY ONE is correct.
61. Let f  x  x3  ax2  bx  5sin2 x be an increasing function in the set of the real numbers R . Then a and b satisfy
the condition.
(A) a2  3b  15  0 (B) a2  3b  15  0
(C) a2  3b  15  0 (D) a  0 and b  0

 x dx ; where,   denotes the fractional part function, is


4
62. The value of
0

1
(A) (B) 1
3
5 7
(C) (D)
3 3

1
 x4  x  4
63.
 x5
dx is equal to
5 5
4 1 4 4 1 4
(A)  1 3   c (B)  1 3   c
15  x  5 x 
5
4 1 4
(C)  1 3   c (D) None of these
15  x 

64. 
f  x   sin log  x  1 x2  is 
(A) even function (B) odd function
(C) Periodic function (D) None of the above
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x3  8
65. The value of the limit of as x tends to 2 is
x2  4
3
(A) 3 (B)
2
(C) 1 (D) 0


2

66.
 sin x dx equals
0
5

8 4
(A) (B)
15 15
8  8
(C) (D)
15 15


 2  x2  5x  6 , x  2
67. f x   , then the range of a , so that f  x  has maxima at x  2 , is

 a2  1, x  2
(A) a  1 (B) a  1
(C) a  1 (D) a  1

 asin x  bcos x equals -


dx
68.

1  1 b  1   b 
(A) log  tan  x  tan1    C (B) log  tan  x  tan1    C
a b
2 2
 2  a  a b
2 2
  a 
1  1 b 
(C) log  tan  x  tan1    C (D) None of these
a2  b2  2 a 
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4  x2  x2  1 is a,b , then b  a is
2 2
69. Range of
(A) 1 (B) 4
(C) 5 (D) None of these

 1  2  3  4  5  6  .....  2n 
70. lim is equal to
n 
 n2  1   4n2  1
(A) - 1 (B) 1
1 1
(C) - (D)
3 3

2x  3

3
71. If dx  18 3  x    3  x  2  c , then  is
3x
4
(A) 1 (B)
3
2 3
(C) (D)
3 2

If R  { x, y  : x, y Z, x  y  4} is a relation in Z, then domain of R is


2 2
72.
(A) 0,1,2 (B)  –2,–1,0
(C)  –2,–1,0,1,2 (D) None of these.

4x  1 2  80 
73. f  x  and f  x   f 1  x   1 , then f    f    .....f   is equal to
4 2
x
 81  81  81 
(A) 80 (B) 40
(C) 1 (D) 0
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74. The sum of intercepts of the tangent to the curve x  y  a upon the coordinates axes is
(A) 2a (B) a
(C) 2 2a (D) None of these


x2  t 2
75. If f(x) = dt , then the curve y  f  x  represents a
2t
0
(A) straight line (B) parabola
(C) hyperbola (D) None of these

 t  1 t  
dt
76. 2

(A) In 1 t2  C (B) In t  c
t
(C) In c (D) None of these
1 t2

 3x , 1  x  1
77. If f  x    , then
4  x, 1  x  4
(A) is continuous as well as differentiable at x = 1
(B) f  x  is continuous but not differentiable at x  1
(C) f  x  is a differentiable but not continuous at x  1
(D) None of these

d2 y 
78. x  2cos t  cos 2t , y  2 sin t  sin 2t , then at t  is
dx 2 2
5 3
(A) (B)
2 2
3 5
(C) (D)
2 2
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79. N be defined by f  x   x2  x  1, x  N . Then f is


Let f : N 
(A) one-one onto (B) many-one onto
(C) one-one but not onto (D) None of these

 x x  1 dx is equal to
dx
80.
n

1  xn  1  xn  1 
(A) log  n   c (B) log  n   c
n  x  1 n  x 
 xn 
(C) log    c (D) None of these
 xn  1 


81. If f "  x   0 , x  , f '  3   0 and g  x   f  tan2 x  2 tan x  4  , 0  x  , then g  x  is increasing in
2
   
(A)  0,  (B)  , 
 4 6 3
    
(C)  0,  (D)  , 
 3 4 2

82. Let R   3,3  ,  6,6  ,  9,9 ,  12,12 ,  6,12 ,  3,9 ,  3,12 ,  3,6  be a relation on the set A   3,6,9,12 . The
relation is
(A) Reflexive and symmetric only (B) an equivalence relation
(C) Reflexive only (D) Reflexive and transitive only

dy
83. If y  xloge x , then at x  e is
dx
1 1
(A) (B)
e e
(C) e (D) None of these

84.
 e  x  In x   x  1 dx is equal to
x

(A) xex  x  Inx  1  c (B) xex  Inx  1  c


(C) xex  x  Inx 1  c (D) xex  x  Inx  1  c
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 2 x  1
The domain of f  x   cos    log  3  x   is
1
85.
 4 
(A)  2,6  (B)  6,2    2,3 
(C)  6,2  (D)  2,2    2,3 

 x2
   ,x  0
86. Consider f x   x
0 ,x  0

(A) f  x  is discontinuous everywhere
(B) f  x  is continuous everywhere but not differentiable at x  0
(C) f  x  exists in  –1, 1
(D) f '  x  exists in  2,2 

87. Find the height of the cylinder of maximum volume which can be inscribed in a sphere of radius ‘r’ is
r
(A) 3r (B)
3
2r r
(C) (D)
3 2 3

cosn1 x sin x  
88. If
 cosn xdx 
n 
 f n cosn  2 x dx , then f  5  

1 2
(A) (B)
5 5
3 4
(C) (D)
5 5

89. The number of solution of the equation  2x    x  1  2x must be equal to


(A) 1 (B) 2
(C) 3 (D) 0

90. The distance between the origin and the tangent to the curve y  e2x  x2 drawn at the point x = 0 is
1 2
(A) (B)
5 5
1 2
(C) (D)
5 3
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