I

ozz1,?,o?o lelPElMs 2011

CHEMI SRTY
UNIT2-FAPER02
MAY/JUNE 2011

Question 1

Specif,ic Objeetsives; 2.4, 2'6, 2'9 KC UK xs

1
(a) (ii) lest: KMnOr/ H* or K?cr2 o?/ tl'

Obs: purple Lo eolourless or orange to green when 1

feacted with comPound A

(IJ{) obs: silver mirror when reacEed wlEh comPound B 1

!.
( j.v) 'Facl.. 2, 4 - dinitroPhenylhYdrazine
I
Obs: Yellow precipitate wiEh Conpound B

(b) (i)

eH, eH_
t- t'
!{3e-e- eH3
(9
r-l
(1)\>ar (1)
4
au
t'
IIr
I

CH, + OH --+ BrC-?-"*,

1)
oH (1)

(ii ) Su1 ot' 2-step nueleophilic substj'tution or L

unimoler:'ular nucleophilic substitution

1
(c) (i) St.eP 13 s;rrnC. H2SOa
2
t 1
Step 2: e qltc . HzSOr and HzO ( lt2sQi (aq ) )

Step 3: KHt Or lH* or KsCr2 07f H'

(ii) x
Oxidati,on

Eetal l-5 lnEtka

 122L2O?OICAPE/MS 2011
CHEMISRTY
UNIT2-PAPER02
MAY/.]UNE 2 011

Qgestion 2

Specifie Objeetives; 1.1, !,2,1.3

KC UR xg
(a) BoE.hrefer t6 the closeness of agreehenE between two or 1
more measurements. whereas preclsioR refers to 1
meaEurements of the same guantity.

accuracy reters to the closeness of a measurement to the 1

true value of the quanrity being measured
(b) burette, pipette, measuring cylinder, volumetric flask.
(A11 3 correct for 2 marks; only 2 co=rcct - 1 marlc) 2

(c) (i) Student s.D

l_ 0.055
2 1. ls
3 3.{5
4 0.082
All f,our eorrect - 2 meEks
2tso3oo=reet-1m=rk
{ii ) Student,
1- precise but- not. accurat,e 1
2- accurate but. not precise 1
3- neither precise Ror aecurate I
4- both accuratc and precise 1

(d) 1 Weigh a (elean, dry, empEy) beaEer on an anal ytical

balance.
I Condition a .l.0 cml pj.pet.ce.
')
Fi11 pipet, l:e to Ehe mark with !,ratef aE room
Eemperature .

4 Transfer cclnt.ent.s of pipeEte to the beaker (urithout

{
spi1J.in9 ) .
5 0leigh accurately beaker and h,auer.
6 Record weight in a sultable Eahle.
7 Repeat, steps 3-6 until consistenE water masses. are
obtained.
eorreet Beeluenoe !
AnyTsteps-{rnarlss
6steps-3marlt'a
Ssteps-2marks
tleteps-1mall(
Total 15 marke 5 6 4
 022L202O|CA.PE/MS 2011
CHEI']SRTY
UNIT2-PAPER02
MAY/JUNE 2011

Quest ion 3
Speclfie ObJeetlver: 3.1, 3.2, 5.1 /
' I KC UK xs
(a) - Crude oil is a mixture of hydrocarbons' 'i'Y" 't[1"'t:'i
- Heattng separales eomPonents according t"o volati lity
(b"pts). 3
-frectionaEing !
- Components are eolleeEecl by use of a -*----- .*.er
(more volatile coflected ftrst) .
.-d
3X 1*nrEEI(.

(b) crackinq: the breaking up of large mofecules into sma l-1er 1

ones.

Reforming: the realrangement of.atoms in rnolecules to form 1

new struetures (molecules)
(c) Cn Hrs eaHrq * 2C;Hr Produet (1), Ba].anoed (1) 2
(Butsane given)
(t ma.rks) tl i.i
t'i.,
(d) I'he producLj.on of insulaEors (clothing) '-{
.,., j ,' l.-
'41;
text i }es
plas t ies tl;i''l''..r I ...-ii
l^tl'"iYtiY 3
sofvenEs \'.itrthr
pharmaeeutieals
r'lri 1r'l'tt'
(any three) 3 marhs
(e) (i) At Yeast 1
i. /.. f". -

B: starch or sugar (sucrose) ; .tJ

1

(ii) eonical flask - effervescenee 1

beaker - white ppt formed hirll''rr

I
,",i,,.1-, ,f i Xr.'r1'' l'.: t
1
,I
(iii ) High temperaEures w j..11 ki]1 Ehe yeast ' 1

Totrl 15 marke 5 5 5
 vzzlzvza I ce^PE,/Ms 2o11
CIIIIMf SRTY
UNIT2-PAPER02
MAY/JUNE 2011

P-es_qE_eu
Speeific Ol:jeetives: 3. 1 1 4 1 7
KC UK
(a) StrucEural. isomerism - refers to compounds wiEh t.he same
(1) (1)
(i) mo.IecuLar formula but cliffer ent, struc t-ura L formula. 2

(ii ) Types of structura.l isomers :

- Chain
HHHH HH
lltl
c -- c-c-c -H
rl H
I
H
rrll
HHTIH
and
lt
,,
I
H
H

/\
HH H

(Any other suitable pair)

- FuncEional Group

o HO
HrC
ll
CHr and HrC
llt H 4
-C - -C
il -C-
I

(Any other suita.bls pa{r)

- Fosi tiona]
HII
lt
lt_c _c
H
I
}IHH
ttl
tt
HOH I,I
-t{ and H-C_ C_c _H
lll
HHOH
(Any other suitaJrle pair)
(Any two t11pes for 2 marks eaoh)
 o22L2020 /Ca.PE,/MS 2011
CI{[:M.I SRTY
UI{I',t' 2 - FA!rU'* {;i
MAY/JirNri 2(l Ll

!lr.r_e.i i..'.:.9! )
4 (:()lt L' (-l
KC UK

( :l i (J, t.i, .t (.r t/n, (),

--->
r' co' + y/2 lltQ I
.l C (jrn' J5 ctn 20 cm'
(1)
,)
rnolc rat:io 3.5

ll Ylq =15
2
(1) 4
'/tl - 3.5 2

Y
/,i 1.5

6
(1)
l.r t: C, il,.
(1)

lr':l (-) r: cle r.i. tl,:r:eas -i rrg ,aeicli Ly .

o f 1
1ri rc;tte.l s < r:a::i,rqrry t..i,g
,.r t.cc;ir<:l.g ,< .:rriidrJ

irl.::ohcrl.s ;!-re r'leal<e-st lrec.luSe ir. ql:6utr) is elec'l:rcrtt rcieas'i'rrg

wlr ielt tnakt"s r'he treg;rt:ive clt;rr:ge I.oc:a'ti''r-'lc1 on l-lte r-rxYgenr 1

l:iir,:refi::e, i!: ,i..s .l erss l.ikely t.ci rFJltilasn a [].891(]R'

"PtretrolSare'*"e.:kacidsLlee:auseofel:ee'lecr-lcil'l:--hcJr:at':i;-'g
ahi11t..y o( l.he pherryl ring lncf king l;lre PherrolaLe j.on 1
resonfl nce s[abi]rr.ed.
Car:boxyIaLc+ ions are resont?nce stc'lbi^Ij.zed 1

.'> O oO
J=[ _co 4-i, R
I
o
1

'Iirey.rre aiSO ies.s liicely tO holcl on to t.he Prot-on trecau.se F.Ite

i'.lself dr,/it'l' f I: otn
e.l ecLronegaE j.v'-. c)xygen pu.l Is eler:l.rotrs t:o,+rarqll.-'
t-lrct Ct - ll horrrl {.i rrdUr:l-j.ue ef IIeUE) .
EoLaI 15 marke t '=F-
I
9
 022L2020/CI.PE/MS 2011
CHEMI SRTY
UNTT2-PAPER02
MAY/JUNE 2011

QqesEr q4.!
Specific Objeetives: 5 .tr, 5.2, 5.4, 5.5
KC UK
1a) (i) ElecEronic absorption between molecu-lar energy ]-evels I
(ii) 5 transltions -3 marks
4 transitions _, markg
3 transitions -1 mark

H
h 3
o o{,
tr
f{ ,[+
TT n
Il
o

(b) (i) Clrromophore: a group of aEoms in a molecule responsible 1

for (producing) the absorption of electromagnetic
radiation.
(ii) Chromophore - benzene structure OR
- conjugated syst.em of doubl-e bonds 1

(iil) Using A EC1

1 rnark
t.2 288 x 1x C

3
1.2
=c ?-Ad il\
L ru.ask

4.2 x 10-l mol dnr-) l rnark(with un'its)

(e) alcsorbance of standard solns is obta:. rred (solns of known
conc. ) (1)
plot curve of absorbance vs conc (1) calibration curve (1) 4
(:onc, of urrknown soLn can l,hen be determined using ealibration
curve (1)
(d) - determining amount of glucose in blood
- determining amount of urea 1n blood
2
- detormining the extent of cyanide pollutior: of water
* analy.sis of l ron i n iron tab.lets
Arry two
Totatr 15 ma=ks 7 I
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