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Dr. Sathish Kumar R.

VIT Bhopal University


 Iron-Carbide System

 Iron-Carbon phase diagram


 Iron
 Till 912°C  α-Iron or Ferrite  BCC
 Till 1394°C  γ-Iron or Austenite  FCC
 Till 1538°C  δ ferrite  BCC

 Carbon and cementite


 6.70 wt% C  Cementite or Iron carbide,
Fe3C
 Two parts; only one part shown
 All steels and cast irons < 6.70 wt% C
 Interstitial solid solution with α,γ and δ-iron.
 (α & C) Maximum
solubility is
0.0022 wt% C
(727°C)

 Presence of C in
α-Iron
 soft,
 magnetic
(<768°C)
 Density  7.88
g/cm2
 (γ & C) Maximum
solubility is 2.14
wt% C (1147°C)

 Austenite is non-
magnetic.

 δ ferrite same as α
ferrite. No further
discussions
 Cementite
 α+Fe3C  <727°C
 γ+Fe3C  <1147°C

 Cementite is very hard and brittle.

 Increases the strength of some steels

 Metastable; α+Fe3C  α+C (graphite)


(650-700°C) (long years, slow)
 One eutectic point (4.30 wt% C at 1147°C)

 One eutectoid point (0.76 wt% C at 727°C)


 Classification of ferrous alloys;

Iron  0.008 wt% C (α-phase)

Steel  0.008 – 2.14 wt% C (real <1wt%)


(α and Fe3C phase)

Cast Iron  2.14 – 6.70 wt% C


(commercially <4.5 wt%)

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