Standardization Titration of KIO4 solutions with standardized Na2S2O3

Trial Temperature (C)

Solution Solvent
I II I
Final buret reading, mL 55 61 1 distilled H2O 19
Initial buret reading, mL 50 55 2 0.20 M NaNO3 31
Volume used, mL 5 6 3 0.10 M NaNO3 31
Mass 0.0645 0.0662 4 0.20 M KNO3 19
Molarity 0.46627 0.3988 5 0.10 M KNO3 19
average molarity 0.43253
Activity
Solvent
IO4-
distilled H2O 0.0335210843
0.20 M NaNO3 0.0435233434
0.10 M NaNO3 0.0451453313
0.20 M KNO3 0.0110835843
0.10 M KNO3 0.0170308735

Coated with counterion - salting in

Common ion - lower solubility than distilled water
ardized Na2S2O3 Volume of Na2S2O3, mL
Temperature (C) Volume of aliquot, mL Vfinal
II I II I II
19 10 10 89.2 95.4
31 10 10 70.1 57.2
31 10 10 79.4 66
19 10 10 54 56.1
19 10 10 82.8 59

KSP I gamma sigma

K+
0.0335210843 0.0011236631 0.6024023807 0.4026630347 0.055645670
0.0435233434 0.0018942814 0.8024023807 0.3499882785 0.0542412939
0.0451453313 0.002038 0.7024023807 0.3744638539 0.0642727482
0.2110835843 0.0023395627 0.8024023807 0.3499882785 0.0705864962
0.1170308735 0.001993138 0.7024023807 0.3744638539 0.0792827946
 Vinitial Vol used Average
I II I II
82.8 89.4 6.4 6 6.2
61.2 50 8.9 7.2 8.05
70.1 58.6 9.3 7.4 8.35
52 54 2 2.1 2.05
79.4 56.1 3.4 2.9 3.15