Table 8.3. Titration of HCl solns with std 0.

01 M NaOH
0.005 0.01
Parameter
I II III IV I II III
Vol aliquot, mL 10 10 10 10 10 10 10
Mass aliquot, g
Vol NaOH
final rdg, mL 12.4 13.8 1 1.1 5.4 11.1 6.4
initial rdg, mL 11.1 12.4 0 0 0 5.4 0
vol used, mL 1.3 1.4 1 1.1 5.4 5.7 6.4
In aliquot
moles HCl 1.924E-05 2.1E-05 1.5E-05 1.6E-05 8.0E-05 8.4E-05 9.5E-05
Mass HCl, g 7.0E-04 7.6E-04 5.4E-04 5.9E-04 2.9E-03 3.1E-03 3.5E-03
Aveage m, HCl 7.28606E-04 5.7E-04 3.0E-03 3.3E-03
Mass water, g 10.0055 10.0057 9.9558 9.9555
Actual molality 0.001923 0.0015 0.0080 0.0095

Mass aliquot

0.005 10.0063
KHP 0.0508 0.0516
Final 17.2 20.9 0.01 9.95884
Initial 3 0
Vol used 14.2 20.9
Molarity 0.01752 0.01209
Average Molarity 0.0148035557 0.015 9.9187

0.02 9.97116

0.025 9.97356
0.01 0.015 0.02
IV I II III IV I II III
10 10 10 10 10 10 10 10

6 35.6 9.1 7 8.5 13.8 27.7 12

0 27.7 0 0 0 0 13.8 0
6 7.9 9.1 7 8.5 13.8 13.9 12

8.9E-05 1.2E-04 1.3E-04 1.0E-04 1.3E-04 2.0E-04 2.1E-04 1.8E-04

3.2E-03 4.3E-03 4.9E-03 3.8E-03 4.6E-03 7.4E-03 7.5E-03 6.5E-03
4.6E-03 4.2E-03 7.5E-03 7.0E-03
9.9141 9.9145 9.9637 9.9641
0.01180 0.0105 0.0205 0.0178

36.458

1.9E-05
9.66733 Molarity Trial mass HCl, g
I 0.0007
0.005 II 0.0006
I 0.0030
0.01 II 0.0033
I 0.0046
0.015 II 0.0042
I 0.0075
0.02 II 0.0070
I 0.0078
0.025 II 0.0097
0.02 0.025
IV I II III
10 10 10 10

14 31.4 14.8 18
0 17.2 0 0
14 14.2 14.8 18

2.1E-04 2.1E-04 2.2E-04 2.7E-04

7.6E-03 7.7E-03 8.0E-03 9.7E-03
7.8E-03 9.7E-03
9.9657 9.9638
0.0211 0.0267

mass water, g Actual molality, m

9.6673 0.0020
9.6675 0.0015
9.9368 0.0080
9.9365 0.0095
9.9141 0.0118
9.9145 0.0105
9.9637 0.0205
9.9641 0.0178
9.9657 0.0211
9.9638 0.0267
 IV
10

18.1
0
18.1

2.7E-04
9.8E-03
Table 8.2. Density measurements of the HCl solutions
Mass of pyc, g
Concentration, M Rep Mass liquid, g
Empty (+) liquid
I 17.8715 28.0651 10.1936
0.005
II 17.6144 27.1735 9.5591
I 17.8715 28.0556 10.1841
0.01
II 17.6144 27.092 9.4776
I 17.8715 28.0567 10.1852
water
II 17.6144 27.113 9.4986
I 17.3349 27.196 9.8611
0.015
II 17.3349 27.2812 9.9463
I 17.3349 27.2869 9.952
0.02
II 17.3349 27.2951 9.9602
I 17.3349 27.2911 9.9562
0.025
II 17.3349 27.2957 9.9608
I 17.3349 27.2957 9.9608
water
II 17.3349 27.2848 9.9499
Density, g/mL Average density Mass aliquot
0.997862 1.000626 10.0062639564
1.003391
0.996932 0.995884 9.9588400592
0.994836

0.987060 0.991870 9.9186982471

0.996679
0.996159 0.997116 9.97115637
0.998072
0.996580 0.997356 9.9735590121
0.998132
Measured emf and other calculated data for the HCl solutions
Actual molality, m emf, V
E not, g
M I II I II
0.005 0.0019233976 0.0014795127 0.234 0.231
0.01 0.0080293741 0.0095166305 0.273 0.276
0.015 0.0117961251 0.010451836 0.289 0.288 0.0297112177
0.02 0.0205033723 0.0178281985 0.298 0.296
0.025 0.0210933292 0.0267431644 0.305 0.305

sqrt(m) E+0.0592logm gamma

0.005 I 0.0438565569 0.0732168887 0.1786100554 0.2197728895
II 0.0384644337 0.0634710262 0.2609357235
0.01 I 0.0896067746 0.1489571561 0.0096960388 0.0084878763
II 0.0975532189 0.1563262059 0.0072797139
0.015 I 0.1086099678 0.1748469707 0.0035488224 0.0038564854
II 0.1022342213 0.1707362012 0.0041641484
0.02 I 0.1431899867 0.1980600576 0.0014386277 0.0016134913
II 0.1335222773 0.1924655617 0.0017883549
0.025 I 0.1452354267 0.2057893917 0.0010650808 0.00095256
II 0.1635333739 0.2118909974 0.0008400392

0.005 0.226555279
0.010 0.008470644
0.015 0.003841388
0.020 0.001607259
0.025 0.000948906
 gamma activitity
I II Ave I II Average
0.18412252 0.2689880373 0.2265552786 0.0003541408 0.0003979712 0.000376056
0.0096763262 0.0072649613 0.0084706438 7.769484E-05 0.000069138 7.3416398E-05
0.0035349441 0.0041478327 0.0038413884 4.169864E-05 4.335247E-05 4.2525555E-05
0.0014330772 0.0017814401 0.0016072587 2.938292E-05 3.175987E-05 3.0571392E-05
0.0010609783 0.0008368331 0.0009489057 2.237957E-05 2.237957E-05 2.2379566E-05
slope 1.2184656401
activity y-int 0.0297112177
0.0004207514 0.0004467887 r 0.9753905426
0.0004728259 r2 0.9513867105
9.231E-05 8.722534E-05
8.214E-05 0.25
4.954E-05 5.052422E-05
0.2 f(x) = 1.2184656401x +
5.151E-05 R² = 0.9513867105
3.491E-05 3.632159E-05 0.15

Axis Title
3.773E-05
0.1
2.659E-05 0.000026589
2.659E-05 0.05

0
0.000376056 0.02 0.04 0.06 0.08
0.000073416
0.000042526
0.000030571
0.000022380
 f(x) = 1.2184656401x + 0.0297112177
R² = 0.9513867105

0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18

Axis Title