Technical Data Sheet

PRIMAL™ SF-016 ER Acrylic Emulsion

Pure Acrylic Polymer For Interior and Exterior Paints

Regional Product EMEA

Availability

Description PRIMALTM SF-016 ER Acrylic Emulsion has been designed for the formulation of low odour,
interior and exterior coatings. It has excellent pigment binding capacity, which permits
formulation of flat wall paints at high pigment volume concentration while maintaining good
scrub resistance and excellent exterior durability capability. Thus, PRIMAL SF-016 ER can
be formulated economically in solvent free flat paints compared to competitive technologies
and has large formulation versatility.

High PVC wall paints based on PRIMAL SF-016 ER Acrylic Emulsion exhibit excellent wet
colour rub, particularly visible in deep tones, which further distinguish it from other solvent
free products and allow the formulation of superior coatings.

In addition, PRIMAL SF-016 ER Acrylic Emulsion allows the manufacture of interior sheen
paints with good resistance to block and dirt pick up. Its all acrylic composition permits use
in exterior coatings for mineral substrates such as masonry and on wood.

Environmental • Film formation without the need for coalescent and solvent
Properties • Ammonia-free*
• Formaldehyde-free*
• Alkyl phenol ethoxylate-free*
• Low residual monomer levels and low odour
*Ammonia, Formaldehyde and APEO are not intentionally added and are not knowingly introduced from another
raw material.

Characteristics • High pigment binding capacity affording economical interior wall paints
of the Product • Excellent scrub resistance
• Easy removal of stains
• Exterior durability

Typical Physical (The properties are typical but do not constitute specifications)
Properties
Property Typical Values
Appearance Milky white liquid
Solids Content 50–51%
pH 8.5–9.5
Brookfield LV Viscosity (spindle 3, 60 rpm) <500 mPa.s
Minimum Film Formation Temperature ~1°C
Specific gravity (wet polymer) 1.06 g/cm3
Specific gravity (dry polymer) 1.12 g/cm3

®TM Trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow 843-02005-1111-EN
Page 1 of 8 PRIMAL™ SF-016 ER Acrylic Polymer / Dow Coating Materials 04/2016, Rev.2
Formulation PRIMAL™ SF-016 ER Acrylic Emulsion allows specific solvent-free formulation
Guidelines development and demonstrates wide formulation latitude from satin to flat paints including
wood stains, which are suitable for both interior and exterior applications. It is a versatile
binder for paint companies wishing to stock in bulk a minimum number of raw materials.

Below are some guidelines to help formulators:

Dispersants
In our studies, good pigment dispersion and stability results were obtained with OROTAN™
731-A ER or OROTAN N-4045 at 0.8%–1% active ingredient level based on pigment and
extenders.

Defoamers
Standard defoamers can be used with PRIMAL™ SF-016 ER Acrylic Emulsion. For
example, Tego Foamex 1495 or Byk-024 gives good results.

Rheology Modifiers & Thickeners

ACRYSOL™ RM-12W, ACRYSOL DR-73 ER, ACRYSOL DR-72 and HEUR Rheology
Modifiers (ACRYSOL RM-8W, ACRYSOL RM-5000) have all been used successfully in
formulating semi-gloss to matt paints based on PRIMAL SF-016 ER Acrylic Emulsion.

Coalescents and co-solvents

No coalescing agent is required with PRIMAL™ SF-016 ER Acrylic Emulsion to achieve
good film formation down to 0°C. However, an addition of UCAR TM Filmer IBT at 2–3% on
polymer solids improves early water resistance in exterior masonry formulations.

Extenders and opaque polymer

Standard extenders can be used in paints formulated with PRIMAL™ SF-016 ER Acrylic
Emulsion. ROPAQUE™ Ultra E Organic Opacifier has shown excellent results when used in
satin to matt formulations based on PRIMAL SF-016 ER Acrylic Emulsion. Additionally, the
use of ROPAQUE Ultra E in exterior coatings is suggested to further improve dirt pick up,
algae and mould resistance and color retention.

Adjustment of pH
The pH of paints based on PRIMAL™ SF-016 ER Acrylic Emulsion needs to be
adjusted between 8.5–9.5 to ensure good mechanical shear stability and avoid
flocculation.

Any base can be used for pH adjustment, the final choice will depend on the paint type
(typically ammonia for exterior coatings and low odour hard bases for interior).

Biocides
Although standard in can preservatives could be used by the formulators, it is always
recommended to test compatibility and efficacy in small scale quantities.

ROCIMA™ 564 is suggested as in-can preservative. If PRIMAL™ SF-016 ER Acrylic

Emulsion is used in wet rooms or in exterior coatings it is suggested to use a film
preservative like ROCIMA 350.

®TM Trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow 843-02005-1111-EN
Page 2 of 8 PRIMAL™ SF-016 ER Acrylic Polymer / Dow Coating Materials 04/2016, Rev.2
 Interior Solvent Free Satin Formulation
based on PRIMAL™ SF-016 ER Acrylic Polymer (PVC 42%) S-016-42-01
Material Name Kilograms Liters PVC
Grind
Water 150.0 150.0
OROTAN™ N-4045 Dispersant 6.0 4.6
(45%)
Tego Foamex 1495 1 2.0 2.0
Tioxide TR92 pigment2 170.0 42.5 15.2%
Durcal 5 calcium carbonate3 50.0 18.2 6.5%
Talc AT-14 50.0 17.2 6.2%
ACRYSOL™ DR-72 Thickener 4.0 3.8
(30%)
Potassium Hydroxide 3.0 3.3
(10% in water)
Grind Sub-total 435.0 241.6
Let Down
PRIMAL™ SF-016 ER (50.5%) 360.0 340.9
ROPAQUE™ Ultra E Opacifier 80.0 78.0 14.5%
(30%)
KATHON™ LXE (1.5%) 2.0 2.0
Potassium Hydroxide 9.0 9.9
(10% in water)
ACRYSOL DR-73 ER (30%) 16.4 15.4
Water 97.6 97.6
Totals 1000.0 785.4 42.4%
Suppliers:
1 Tego Chemie Service GmbH, Essen, Germany 3 Omya UK Ltd, Dorking, UK
2 Hunstman Tioxide, London, UK 4 Talc de Luzenac, Toulouse, France
Paint Properties
Volume Solids: 37%
Weight Solids: 49%
Density: 1.270
pH: ~9.3
Dispersant (active based on total powders): 1.0%
Coalescent (based on polymer solids): 0.0%
Calculated VOC** content (g/L of wet paint): <0.1
** VOC: Amount in g/L of organic compounds having an initial boiling point less than or equal to 250°C measured at a
standard pressure of 101.3 kPa
Viscosities
Krebs Stormer (KU): 118–128
ICI (Poise): 1.4–1.8
Brookfield (spindle 4/60 rpm) (mPa.s): 6200–7400
Brookfield (spindle 4/6 rpm) (mPa.s): 16000–20000
Film Properties
Gloss (100 µm, on glass):
Gloss 20°: 2–3
Gloss 60°: 13–14
Sheen 85°: 27–28
Contrast ratio:
CR at 150 µm wet: 97.1%

®TM Trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow 843-02005-1111-EN
Page 3 of 8 PRIMAL™ SF-016 ER Acrylic Polymer / Dow Coating Materials 04/2016, Rev.2
 Interior/Exterior Solvent Free Matt Formulation
based on PRIMAL™ SF-016 ER Acrylic Polymer (PVC 50%) M-016-50-01
Material Name Kilograms Liters PVC
Grind
Water 124.5 124.5
OROTAN™ 731A-ER Dispersant 13.0 11.8
(25%)
Tego Foamex 14951 2.0 2.0
Tioxide TR92 pigment2 170.0 42.5 14.8%
Durcal 2 calcium carbonate3 50.0 18.2 6.3%
Calibrite SL filler3 90.0 33.3 11.6%
Talc AT-14 40.0 13.8 4.8%
ACRYSOL™ RM-8W Thickener 4.0 3.8
(21.5%)
Grind Sub-total 493.5 249.9
Let Down
PRIMAL™ SF-016 ER (50.5%) 320.0 303.0
ROPAQUE™ Ultra E Opacifier 70.0 68.3 12.4%
(30%)
KATHON™ LXE (1.5%) 2.0 2.0
ACRYSOL RM-5000 (18.5%) 21.0 20.1
ACRYSOL DR-73 ER (21.5%) 23.6 22.7
Water 69.9 69.9
Totals 1000.0 735.9 49.9%

Suppliers:
1 Tego Chemie Service GmbH, Essen, Germany 3 Omya UK Ltd, Dorking, UK
2 Hunstman Tioxide, London, UK 4 Talc de Luzenac, Toulouse, France
Paint Properties
Volume Solids: 40%
Weight Solids: 55%
Density: 1.360
pH: ~9.2
Dispersant (active based on total powders): 0.9%
Coalescent (based on polymer solids): 0.0%
Calculated VOC** content (g/L of wet paint): <0.1
** VOC: Amount in g/L of organic compounds having an initial boiling point less than or equal to 250°C measured at a
standard pressure of 101.3 kPa.
Viscosities
Krebs Stormer (KU): 115–125
ICI (Poise): 1.6–2.0
Film Properties
Gloss (100 µm, on glass):
Gloss 20°: 2–3
Gloss 60°: 8–9
Sheen 85°: 5–6
Contrast ratio:
CR at 150 µm wet: 95.9%
Wet scrub resistance (200 scrubs):
Loss of thickness (µm) 3.4
ISO 11998: Class 1

®TM Trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow
PRIMAL™ SF-016 ER Acrylic Polymer / Dow Coating Materials

843-02005-1111-EN
Page 4 of 8 04/2016, Rev.2
 Exterior Masonry Formulation
based on PRIMAL™ SF-016 ER Acrylic Polymer (PVC 61%) Mas-016-61-01
Material Name Kilograms Liters PVC
Grind
Water 148.0 148.0
OROTAN™ 731-A-ER 15.0 13.6
Dispersant (25%)
Potassium Hydroxide 3.0 3.3
(10% in water)
Tego Foamex 14951 2.0 2.0
Tioxide TR92 pigment2 160.0 40.0 14.6%
Durcal 2 calcium carbonate2 70.0 25.4 9.3%
Calibrite SL filler3 140.0 51.9 18.9%
Talc AT-14 40.0 13.8 5.0%
ACRYSOL™ RM-8W Thickener 5.0 4.8
(21.5%)
Grind Sub-total 583.0 302.8
Let Down
PRIMAL™ SF-016 ER (50.5%) 240.0 227.3
Water 30.0 30.0
UCAR™ Filmer IBT 3.6 3.8
ROPAQUE™ Ultra E Opacifier 70.0 68.3 13.0%
(30%)
KATHON™ LXE (1.5%) 2.0 2.0
ACRYSOL RM-12W (19%) 1.4 1.4
ACRYSOL RM-5000 (18.5%) 20.5 19.7
ACRYSOL RM-8W (21.5%) 20.5 19.7
Water 29.0 29.0
Totals 1000.0 704.0 60.8%
Suppliers:
1 Tego Chemie Service GmbH, Essen, Germany 3 Omya UK Ltd, Dorking, UK
2 Hunstman Tioxide, London, UK 4 Talc de Luzenac, Toulouse, France
Paint Properties
Volume Solids: 40%
Weight Solids: 57%
Density: 1.420
pH: ~9.0
Dispersant (active based on total powders): 0.9%
Coalescent (based on polymer solids): 2.5%
Calculated VOC** content (g/L of wet paint): <0.1
**VOC: Amount in g/L of organic compounds having an initial boiling point less than or equal to 250°C measured at a
standard pressure of 101.3 kPa.
Viscosities
Krebs Stormer (KU): 115–125
ICI (Poise): 1.5–1.9
Film Properties
Gloss (100 µm, on glass):
Gloss 60°: 2–3
Sheen 85°: 6–7
Contrast ratio:
CR at 150 µm wet: 95.1%

®TM Trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow
PRIMAL™ SF-016 ER Acrylic Polymer / Dow Coating Materials

843-02005-1111-EN
Page 5 of 8 04/2016, Rev.2
 Interior Solvent Free Matt Formulation
based on PRIMAL™ SF-016 ER Acrylic Polymer (PVC 70%) M-016-70-01
Material Name Kilograms Liters PVC
Grind
Water 150.0 150.0
OROTAN™ N-4045 Dispersant 9.0 6.9
(45%)
Potassium Hydroxide 3.0 2.8
(10% in water)
TRITON™ DF-16 Surfactant 2.0 1.9
ACRYSOL™ DR-73 ER 5.0 4.7
Thickener (30%)
Tego Foamex 14951 2.0 2.0
Tioxide TR92 pigment 2 150.0 37.5 14.9%
Durcal 2 calcium carbonate3 70.0 25.4 10.1%
Durcal 53 140.0 50.9 20.3%
P-8204 30.0 13.6 5.4%
Talc AT-15 50.0 17.2 6.9%
Grind Sub-total 611.0 312.9
Let Down
PRIMAL SF-016 ER (50.5%) 170.0 161.0
ROPAQUE™ Ultra E Opacifier 60.0 58.5 12.1%
(30%)
KATHON™ LXE (1.5%) 2.0 2.0
ACRYSOL DR-73 ER (30%) 9.0 8.5
ACRYSOL DR-72 (30%) 2.0 1.9
Potassium Hydroxide 12.0 11.0
(10% in water)
Water 134.0 134.0
Totals 1000.0 689.8 69.7%
Suppliers:
1 Tego Chemie Service GmbH, Essen, Germany 4 Degussa Huels AG, Francfort, Germany
2 Hunstman Tioxide, London, UK 5 Talc de Luzenac, Toulouse, France
3 Omya UK Ltd, Dorking, UK

Paint Properties
Volume Solids: 38%
Weight Solids: 56%
Density: 1.450
pH: ~9.2
Dispersant (active based on total powders): 0.9%
Coalescent (based on polymer solids): 0.0%
Calculated VOC** content (g/L of wet paint): <0.1
**VOC: Amount in g/L of organic compounds having an initial boiling point less than or equal to 250°C measured at a
standard pressure of 101.3 kPa.
Viscosities
Krebs Stormer (KU): 113–123
ICI (Poise): 1.5–1.9
Brookfield (spindle 4/60 rpm) (mPa.s): 4400–5400
Brookfield (spindle 4/6 rpm) (mPa.s): 10000–12000
Film Properties
Gloss (100 µm, on glass):
Gloss 60°: 3–4
Sheen 85°: 5–6
Contrast ratio:
CR at 150 µm wet: 99.1%
Wet scrub resistance (200 scrubs):
Loss of thickness (µm) 17.0
ISO 11998: Class 2

843-02005-1111-EN
Page 6 of 8 ®TM Trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow 04/2016, Rev.2
PRIMAL™ SF-016 ER Acrylic Polymer / Dow Coating Materials
 Interior Solvent Free Matt Formulation
based on PRIMAL™ SF-016 ER Acrylic Polymer (PVC 79%) M-016-79-01
Material Name Kilograms Liters PVC
Grind
Water 150.0 150.0
OROTAN™ N-4045 Dispersant 12.0 9.2
(45%)
Potassium Hydroxide 2.8 2.6
(10% in water)
TRITON™ DF-16 Surfactant 2.0 1.9
Tego Foamex 14952 2.0 2.0
Tioxide TR92 pigment 3 110.0 27.5 10.6%
Durcal 2 calcium carbonate4 100.0 36.3 14.0%
Durcal 54 210.0 76.3 29.3%
Socal ® P2 calcium carbonate 5 60.0 22.2 8.5%
Talc AT-16 40.0 13.8 5.3%
ACRYSOL™ DR-72 Thickener 3.0 2.8
(30%)
Grind Sub-total 691.8 344.6
Let Down
PRIMAL SF-016 ER (50.5%) 120.0 113.6
ROPAQUE™ Ultra E Opacifier 60.0 58.5 11.7%
(30%)
KATHON™ LXE (1.5%) 2.0 2.0
ACRYSOL DR-73 ER (30%) 8.0 7.5
ACRYSOL DR-72 (30%) 1.2 1.1
Potassium Hydroxide 11.2 10.3
(10% in water)
Water 105.8 105.8
Totals 1000.0 643.4 79.4%

Suppliers:
2 Tego Chemie Service GmbH, Essen, Germany 5 Solvay Chemicals Ltd, Hemel Hempstead, UK
3 Hunstman Tioxide, London, UK 6Talc de Luzenac, Toulouse, France
4 Omya UK Ltd, Dorking, UK

Paint Properties
Volume Solids: 42%
Weight Solids: 61%
Density: 1.550
pH: ~9.5
Dispersant (active based on total powders): 1.0%
Coalescent (based on polymer solids): 0.0%
Calculated VOC* content (g/L of wet paint): <0.1
** VOC: Amount in g/L of organic compounds having an initial boiling point less than or equal to 250°C measured at a
standard pressure of 101.3 kPa.
Viscosities
Krebs Stormer (KU): 118–128
ICI (Poise): 1.3–1.7
Brookfield (spindle 4/60 rpm) (mPa.s): 5300–6300
Brookfield (spindle 4/6 rpm) (mPa.s): 11500–14000
Film Properties
Gloss (100 µm, on glass):
Gloss 20°: 2–3
Gloss 60°: 4–5
Sheen 85°: 4–5
Contrast ratio:
CR at 150 µm wet: 99.6%

®TM Trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow
PRIMAL™ SF-016 ER Acrylic Polymer / Dow Coating Materials
843-02005-1111-EN
Page 7 of 8 04/2016, Rev.2
 Handling Precautions Before using this product, consult the Material Safety Data Sheet (MSDS)/Safety Data
Sheet (SDS) for details on product hazards, recommended handling precautions and
product storage.

Storage Store products in tightly closed original containers at temperatures recommended on the
product label.

Disposal Dispose in accordance with all, local or national regulations. Empty containers may
Considerations contain hazardous residues. This material and its container must be disposed in a safe
and legal manner.

It is the user's responsibility to verify that treatment and disposal procedures comply with
local or national regulations. Contact your Dow Coating Materials Technical
Representative for more information.

Chemical Registration
Many countries within EMEAI require the registration of chemicals, either imported or
produced locally, prior to their commercial use. Violation of these regulations may lead to
substantial penalties imposed upon the user, the importer or manufacturer, and/or
cessation of supply. It is in your interests to ensure that all chemicals used by you are
registered. Dow does not supply unregistered products unless permitted under limited
sampling procedures as a precursor to registration.

Note on EMEA Product availability and grades vary throughout the countries in the EMEA area. Please
Product Line contact your local Dow Coating Materials representative for further information and
samples.

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Customer Notice Dow strongly encourages its customers to review both their manufacturing processes
and their applications of Dow products from the standpoint of human health and
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