Mian Sharaf Al_Qadri (Govt.

College Peshawar) ETEA Engineering 2019

The Scholars Academy (TSA)

ETEA ENGINEERING 2019
“Paper-B” (Chemistry)
1. Pollutant which inhibit the synthesis of hemoglobin:
A) Mg B) Pb C) Ni D) Ag
2. Which of the following alkyl halide shows higher reactivity?
A) R-F B) R-Cl C) R-Br D) R-I
3. For a reversible reaction, the catalyst increases the speed of
A) Forward reaction B) backward reaction
C) Both forward and backward reactions equally
D) Forward reaction to larger extent than backward reaction
4. 2N2O5 → 4NO2 + O2, the reaction is an example of ____ order reaction.
A) 1st B) 2nd C) 3rd D) Zero
5. Diamond and graphite are
A) Isomers B) isomorphs C) allotropes D) both (B) and (C)
6. Metal sulphate that is comparatively more soluble in water is:
A) MgSO4 B) CaSO4 C) BaSO4 D) SrSO4
7. CO2 is a gas at room temperature but SiO2 is solid. The reason is that:
A) SiO2 is ionic B) bonds in SiO2 are very strong
C) SiO2 is polymeric D) Si makes double bond with oxygen
8. Which one of the following compounds produce lowest amount of beat on combustion?
A) 1-butene B) trans-2-butene C) cis-2-butene D) iso-butylene
2
9. During SN mechanism, the nucleophile attacks on the substrate:
A) When C-X bond has broken B) before C-X bond has broken
C) When C-H bond has broken D) after the formation of carbocation
10. Carat is the unit of purity of gold. 18 carat gold contains _______ % gold.
A) 50-60 B) 70-75 C) 90-95 D) 99
11. Which one of the following reagents is used to distinguish between the primary, secondary and tertiary
alcohols?
A) Baeyer’s reagent B) Tollen’s reagent C) Lucas reagent D) Nesseler’s reagent
12. As the attraction between the nucleus and electron increases, the potential energy of the system:
A) Increases B) un-effected C) decreases D) first decreases then start increase
13. The formation of but-2-ene always take place through:
A) Sp2 hybridization B) Sp3 hybridization C) Sp2, Sp3 both D) Sp, Sp3 both
14. Pentane C5H12 at room temperature does not obey:
A) Charles’s law B) Boyl’s law C) Avogadro’s law D) all of the above
3 3
15. 20 cm CH4 gas was burnt in 40 cm O2 gas to produce CO2 gas as:
CH4 + 2O2 → CO2 + 2H2O. The limiting reactant in this equation is:
A) O2 B) CH4 C) CO2 D) None of the above
16. NO2 gas shows maximum absorption at about________ nm.
A) 400 B) 700 C) 200 D) 170
17. Color of the hair dye is mainly due to:
A) Substituted alcohols B) stearalkonium hectorite
C) meta substituted aniline D) acetone
18. Which of the following produces an NMR spectrum with more than one peak?
A) Toluene B) methane C) butane D) cyclobutene
19. Which of the following gasses in the major contributor to greenhouse effect?
A) Ozone B) CO2 C) CN6 D) NO2
20. Oxidation number of nickel in tetracarbonyl nickel {Ni (CO)4} is:
A) +4 B) +3 C) 0 D) -2
21. Addition of HCN to acetone forms cyanohydrin. It is an example of
A) Electrophilic addition reaction B) nucleophilic addition reaction
C) Electrophilic substitution reaction D) nucleophilic substitution reaction
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22. In ice there are hydrogen bonds and covalent bonds. What type of solid is it?
A) Ionic B) covalent C) molecular D) metallic
23. Which one of the following liquids is more volatile?
A) Chloroform B) ethanol C) water D) glycerin
24. If the equilibrium constant Kc value for a certain reaction is very very small, then:
A) Reactants are in large amount B) products are in appreciable amount
B) Reactant and products both are in appreciable amount
C) In such a situation equilibrium cannot be obtained
25. Which one of the following forms acidic solutions when dissolved in water?
A) Na2CO3 B) CH3COONa C) NH4Cl D) K2CO3
26. Zinc and copper electrodes are connected for galvanic cell and salt bridge is also immersed in both the
half-cells; the salt bridge will give cation to:
A) Copper half-cell B) zinc half-cell C) both (A) and (B) D) none of the above
27. When K4[Fe (CN)6} is dissolved in water. It will furnish ________ ions per molecule.
A) 10 B) 2 C) 6 D) 5
28. Choose an alkyne that on catalytic hydrolysis form an aldehyde:
A) CH3− C ≡ CH B) C) CH3− C ≡ C – CH3 D) none of the above
29. The compound which you can say ester is:
O O
∥ ∥
A) CH3CONH2 B) CH3− C − O − COCH3 D} CH3O − C − O − COCH3 D) CH3OCOCH3
30. Which one is not endothermic process?
A) Atomization of I2 B) electrolysis of water
C) condensation of vapors D) both (B) and (C)
31. One mole of which of the following Bucky ball will have more molecules?
A) C20 B) C30 C) C60 D) All same
32. The possible peaks (chemical shift values) for 1-chloro-2-propanol molecules are:
A) 2 B) 3 C) 4 D) 7
33. A metallic carbide on treatment with water gives out a colorless gas, which burns in air readily and gives
red precipitate with Cu2Cl2 and NH4OH. Identify the gas:
A) CH4 B) C2H2 C) C2H4 D) C2H6
34. Acetamide on hydrolysis gives:
A) Acetaldehyde B) acetic acid C) ethyl amine D) ethanol
35. Which one of the following does not have a carboxylic acid group?
A) Benzoic acid B) ethanoic acid C) picric acid D) adipic acid
36. On chlorination benzene forms a single monochlorobenzene without any isomer. It proves that
A) Benzene is aromatic B) all C-C bonds in benzene are identical
C) All C-H bonds in benzene are identical
D) benzene sometimes behaves as non-aromatic
37. Avogadro’s constant is the number of:
A) atoms in 1g of He B) molecules in 35.5g of chlorine
C) electrons present in 2g H D) atoms in 24g Mg
38. A given sample of AlCl3 contains 6.02 x 10 Al+3 ions. The moles of Cl- ions will be:
20

A) 1.0 x 10-3 B) 3 x 10-3 C) 3 x 103 D) 0.33 x 10-3

39. The angular momentum of the Hydrogen atom in ground state is equal to:
A) h/2 B) 2h/2 C) /2h D) 2 /h
40. Which electronic level will allow the hydrogen atom to absorb a photon but not emit?
A) 1s B) 2s, 2p, 3d C) 2p, 3d D) 3d
41. Which statement about the following molecules is incorrect?
A) NH3 has pyramidal shape B) CO2 is linear
C) H2O is angular D) H2S is linear
42. The molecule having zero dipole moment among the following:
A) NH3 B) SnCl2 C) PH3 D) CCl4

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43. For a gas when volume and pressure are 1dm3 and 2atm respectively. What will be its new volume the
pressure is increased to 6 atm at constant temperature?
A) ½ dm3 B) 1/3 dm3 C) ¼ dm3 D) 2/3 dm3
44. Vapor pressure of a liquid does not depend upon:
A) Temperature B) intermolecular forces
C) amount of liquid D) amount of solid dissolved in the liquid
45. When NH4Cl is added to a solution of (NH4)2CO3. There will be?
A) Decrease in (NH4+) ions concentration B) decrease in CO3-2 ions concentration
C) No change in CO3-2 ions concentration D) No change in concentration of any specie
46. The strongest base among the following is
A) Cl- B) Br- C) I- D) CH3COO-
47. During the discharge of lead acid battery
A) Pb is dissolved at the cathode B) Pb is deposited at the cathode
C) PbSO4 is formed both at anode and cathode D) concentration of H2SO4 increases
48. Acidic KMnO4 can’t be used for estimation of:
A) Ferrous ions B) oxalic acid C) potassium iodide D) ferric ions
49. A compound X is orange in color, when KOH (aq) is added to it, lemon yellow coloration is obtained.
Compound X is:
A) K2CrO4 B) K2Cr2O7 C) KMnO4 D) PbS
50. Ozonolysis of 2-methyl-2-butene yields:
A) Only aldehyde B) only ketone
C) both aldehyde and ketone D) aldehyde and alcohol
51. Alkyl halides are reactive towards nucleophilic attacks because:
A) They are ionic in nature B) the C-X bond is non-polar
C) They have nucleophilic carbon and bad leaving group
D) They have electrophilic carbon and good leaving group
52. Methyl alcohol on oxidation with acidified K2Cr2O7 gives:
A) CH3COCH3 B) CH3CHO C) HCOOH D) CH3COOH
53. Aldehydes are reducing agents. In the reaction with Fehling’s solution they reduce
A) Cu+2 B) Ag+ C) NaOH D) Na
54. In ice the water molecules are bound by
A) Ionic bond B) hydrogen bond C) covalent bond D) metallic bond
55. The property of crystalline solids necessary to maintain habit of crystal is called
A) Crystal lattice B) lattice site C) geometrical shape D) polymorphism
56. The dispersion phase and dispersion medium for soap lather is respectively
A) Gas and solid B) gas and liquid C) liquid and liquid D) solid and liquid
57. Which one is not correct for the stability of colloidal solution?
A) Greater charge density on colloid B) Less solvation energy
C) More Brownian motion D) none of the above
58. Which one of the following has highest melting point?
A) NaCl B) MgCl2 C) AlCl3 D) SiCl4
59. The main product obtained when acetic acid reacts with PCl5 is:
A) CH3COCl B) CCl3CHO C) CH3CL D) CH3OH
60. hydrolysis of an ester in the presence of alkali is called
A) esterification B) transesterification C) saponification D) decarboxylation

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SOLUTION:

1. B) Pb (lead) from paints, gasoline and solder enters water reservoirs which causes anemia and inhibits the
enzyme involved in the biosynthesis of hemoglobin. (textbook II: page # 409).
2. D) The strength and bond energy of C-X bond is in the order HF > HCl > HBr > HI, so the reactivity order
will be HI > HBr > HCl > HF. (Textbook-II page # 193).
3. C) A catalyst speeds up the rate of Both forward and backward reactions equally to the same extent but
don’t affect equilibrium constant and position of equilibrium. (Textbook-I page # 200).
4. A) The given reaction for one mole of N2O5 is: N2O5 → NO2 + ½O2. It is a first order reaction. Order of reaction
is experimental and don’t change with change in concentration of all reactants and products. (Textbook-I
page # 238).
5. C) Diamond, graphite and Bucky balls are allotropic forms of carbon which have different crystalline shapes.
(Textbook-II page # 173). {Coke, soot and charcoal are not allotropes because they are amorphous (not
crystalline)}.
6. A) The solubility of group-IIA sulphates decrease down the group i.e. BeSO4 > MgSO4 > CaSO4 > SrSO4 >
BaSO4. This is because of decrease in hydration energy of metal cations down the group. (Textbook-II page
# 27).
7. C) SiO2 is a high melting covalent solid (network solid) in which one Si atom is bonded to four oxygen atoms.
The p-orbital of Si cannot sidewise overlap with that of Oxygen atom to form pi-bond. (Textbook-II page #
32).
8. D) Stability ∝ The relative order of decreasing stability of different isomers of butene is as: iso-butylene
∆ °
> trans-2-butene > cis-2-butene > 1-butene. So iso-butylene, the most stable of all isomers, will release least
amount of heat on combustion. (Textbook-II page # 129).
9. B) During SN2 mechanism, the nucleophile attacks the electrophilic carbon atom of the substrate before the
leaving group departs as it is a single step mechanism. (Textbook-II page # 129).
10. B) Carat is the unit of mass equals 200mg (0.2g) used for measuring gemstones and pearl. 18 carat gold
contain 74% gold and 26% copper while 24 carat gold is pure gold. (Textbook-II page # 54).
11. C) Lucas reagent (HCl + Anhydrous ZnCl2) is used to distinguish between primary, secondary and tertiary
alcohols. ROH + HCl → RCl + HOH, The 3° ROH form alkyl chloride (Cloudy appearance/ turbidity) immediately
while 2° ROH form RCl after 3 to 5 minutes. 1° ROH don’t react at room temperature although at high
temperature it takes 25-30 minutes.
12. C) P.E ∝ , as the distance b/w nucleus and electron decreases, attraction increases and P.E of the system
decreases.
13. C) but-2-ene has both sp2 and sp3 hybridized carbons. CH3 – CH = CH − CH3. Carbon no. 1 and 4 are sp3
hybridized while carbon no. 2 and 3 are sp2 hybridized.
14. D) Pentane is liquid at room temperature and gas laws are not applicable to liquids. (Textbook-II page # 118).
15. D) According to balanced chemical equation, 1 mole of CH4 requires 2 moles of O2, so 20cm3 of CH4 needs
40cm3 of O2. When stoichiometric amounts are reacted together, there will be no reactant left at the end of
reaction i.e. there will be no limiting or excess reagent. (Textbook-I page # 16).
16. A) NO2, the component of photochemical smog has a brown color due to its maximum absorption at a region
of about 400 nm. It is the only common atmospheric molecule capable of absorbing light near the ground
level. (Textbook-II page # 397).
17. C) The couplers or coupling agents which are meta substituted derivatives of aniline define the color of the
hair dye. (Textbook-II page # 379).
18. C) Butane molecule has two types of protons i.e. CH3 and CH2., while all others have only one type of identical
protons. Butane will give two peaks in NMR spectrum.
19. B) The major gas contributing 50% to greenhouse effect is CO2. Other greenhouse gasses contributing the
remaining 50% are CH4, CFCs, SOx, NOx, and water vapors. (Textbook-II page # 400).
20. C) The oxidation state of nickel in the given compound is zero. Since CO is a neutral ligand, so Ni + 4 CO = 0,
Ni + 4 (0) = 0, thus Ni = 0.
21. B) Aldehydes and ketones undergo nucleophilic addition reactions. When HCN is added to carbonyl
compounds under base catalyzed mechanism, a cyanohydrin (compound containing both OH and CN
functional groups attached to same carbon) is formed. (Textbook-II page # 275).

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22. C) Solids having Vander Waal’s forces b/w their molecules are molecular solids. In ice water molecules are
held together by hydrogen bonding, so it is an example of polar molecular solids. (Textbook-II page # 180).
23. A) Ethanol, water and glycerin all have hydrogen bonding b/w their molecules while chloroform has Vander
Waal’s forces. Chloroform has lowest boiling point and is more volatile. [volatilty ∝ ].
[Products]
24. A) Equilibrium constant, Kc, is the ratio of products to reactants concentration. [ =
[Reactants]
], so ∝ .
[ ]
When Kc is very very small it means that the reactants are present in large amount at equilibrium because
the reaction proceeds very little in the forward direction. (Textbook-I page # 196).
25. C) Na2CO3, CH3COONa and K2CO3 are basic salts i.e. they are formed from strong base and weak acid. NH4Cl
is formed form NH4OH and HCl, a strong acid and weak base, so it will form acidic solution when dissolved
in water.
26. A) In Daniel cell, Cu acts as cathode and Zn acts as anode. Cu=2 ions are deposited at cathode and Zn=2 ions are released
into the solution. A salt bridge is an ionic compound like KCl, NaCl or KNO3 used to maintain the ion balance of the
cell. Cations are given to Copper half-cell because it is short in cations. [TTR for Daniel cell: Cu ----- Cathode,
ziNc ----- aNode]
27. D) The species outside the Square brackets in coordination complexes are ionizable and precipitable. The
species inside the square brackets are non-ionizable and non-precipitable. K4[Fe (CN)6] → 4K+ + [Fe (CN)6]-4.
It will give 5 ions per molecule.
28. D) Only acetylene (HC ≡ CH) on catalytic hydrolysis (hydration) forms aldehyde after enol as intermediate.
Other alkynes produce enols which on rearrangement form ketones. None of the given compounds can form
aldehydes on catalytic hydrolysis.
29. D) Esters have the general formula RCOOR. The compound CH3OCOCH3 (methyl acetate) is an ester.
30. C) Generally, the conversions: solid → liquid → gas → plasma, are endothermic while the reverse are
exothermic. Condensation of vapors is exothermic, while atomization of I2 and electrolysis of water are
endothermic processes.
31. D) One mole of any molecule contains Avogadro’s number of molecules. One mole of all Bucky balls will have same
no. of molecules; however, no. of atoms will be different.
32. C) The possible peaks (chemical shift values) in NMR spectrum for 1-chloro-2-propanol molecules will be
four b/c it contains four types of identical protons.

33. B) By adding carbides of Metal such as Ca, Sr and Ba to water, Acetylene (C2H2) is released as smoke which is
inflammable.
CaCO3(s) CaO(s) + CO2(s) CaC2(s) + CO(s) C2H2(g) + Ca(OH)2(s).
CaC2(s) + H2O C2H2(g) + Ca(OH)2(s).
It is differentiated form other non-terminal alkynes, alkenes and alkanes by giving positive tests with Tollen’s reagent,
ammonical cuprous chloride and sodium amide in liquid ammonia. With Cu2Cl2 + NH4OH acetylene gives red
precipitates of copper (I) acetylide.
34. B) Amides on hydrolysis in the presence of acid catalyst give carboxylic acids.
CH3CONH2 + H2O CH3COOH + NH3
However alkaline hydrolysis is a useful test for amides. If sodium hydroxide solution is added to an unknown organic
compound and it gives off ammonia on heating, then it is an amide. CH3CONH2 + NaOH CH3COONa + NH3.
Ammonia is recognized by smell and also it turns red litmus blue. (Textbook-II page # 308).
35. C) Picric acid is 2,4,6-trinitrophenol which has no -COOH group. (Textbook-II page # 240).
36. C) If benzene was alkene it would give two addition products on chlorination. Benzene undergoes
electrophilic substitution. As all C−H bonds in benzene are identical, so on chlorination, benzene give single
mono-substituted product.
37. D) Avogadro’s number is the number of particles in mole of a substance. 24g of Mg atoms contains 1 mole, so there
are 6.023 X 1023 Mg atoms in 24g. 1g of He is ¼ moles, 35.5g of Cl2 is its ½ mole and 2g H contains 2 moles of H atoms.
38. B) When AlCl3 is dissolved, one mole of Al+3 and 3 moles of Cl- ions are formed. AlCl3 Al+3 + 3 Cl-. The
sample containing 6.02 x 1020 ions of Al+3 ions will contain 3 (6.02 x 1020) Cl- ions. For no. of moles we have:
( . )
= = = 3 x 10-3 moles of Cl- ions.
( . )

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39. A) According to Bohr’s postulate “Angular momentum of electron is the integral multiple of h/2 .”
mvr = nh/2 , for ground state n = 1, so angular momentum for ground state is h/2 .
40. A) The electron in 1s orbital can absorb photon for excitation to high energy level. However, the electron of
1s cannot be de-excited to any lower energy level because it is lowest possible energy level.
41. D) H2S has angular structure like water and cannot be linear.

42. D) CCl4 has zero dipole moment b/c it has no lone pair and its molecular geometry is similar to electron pair
geometry. Other molecules I.e. NH3, PH3 and SnCl2 are polar as they have lone pair in their structures.
(Textbook-I page # 98).
43. B) As P1V1 = P2V2, V2 = P1V1/P2, Putting values, V2 = 1 x 2/6 = 1/3. (Textbook-I page # 134, 106).
44. C) . ∝ , and also . ∝ . Vapor pressure of a pure liquid decreases by adding impurities
(colligative effect). Although V.P don’t depend upon amount of liquid as it is a constitutive property.
(Textbook-I page # 161).
45. B) When NH4Cl is added to a solution of (NH4)2CO3, there will be decrease in CO3-2 ions concentration due to
common ion effect. This is because NH4Cl is a stronger electrolyte than (NH4)2CO3. Due to increase in NH4+
ions concentration, equilibrium will shift in backward direction for (NH4)2CO3. The NH4)2CO3 precipitates out
to balance NH4+ ions and keep the Ksp value constant. (Textbook-I page # 204).
46. D) CH3COO- ion is the conjugate base of CH3COOH which is a weak acid while Cl-, Br- and I- ions are conjugate
bases of strong acids HCl, HBr and HI respectively. CH3COO- ion is comparatively the strongest base because
weak acid has strong conjugate base. (Textbook-I page # 215).
47. C) During the discharge of lead acid battery PbSO4 is formed both at anode and cathode.
At cathode 2H+ ions gain electrons to form two H atoms which attack on PbO2 and convert it into PbO
(lead peroxide) and water. PbO reacts with H2SO4 to form PbSO4 and water.
PbO2 + 2H PbO + H2O,
PbO + H2SO4 PbSO4 + H2O
-----------------------------------------------
PbO2 + 2H + H2SO4 PbSO4 + 2H2O
-2
At anode SO4 ions lose electrons to form SO4 radicals which attack on Pb to form PbSO4. (Textbook-I page # 345).
SO4-2 SO4 + 2e-
SO4 + Pb PbSO4
48. D) Acidified KMnO4 is a strong oxidizing agent which oxidizes other substances. It can oxidize I - to I2, H2S to
S, (COOH)2 to CO2, NO2- to NO3- and Fe+2 (Ferrous ions) to Fe+3 (Ferric ions). Ferric ions cannot be oxidized
further to higher oxidation state by KMnO4. (Textbook-II page # 69).
49. B) When K2Cr2O7 is dissolved in water, it gives an orange color. It is in equilibrium with K2CrO4. By adding
KOH, it converts to K2CrO4 which is yellow in color. (Textbook-II page # 64).
Cr2O7-2 + OH- ⇌ CrO4-2.
50 C) Ozonolysis of alkenes produces carbonyl compounds (aldehydes and ketones), while that of alkynes gives
carboxylic acids. Straight chain alkenes on reaction with ozone yield aldehydes while alkenes with branching at one
carbon of the double bond give ketone and aldehyde. When both doubly bonded carbons have branches on them,
they upon ozonolysis produce ketones only. So, ozonolysis of 2-methyl-2-butene yields both aldehyde and
ketone i.e. acetone and acetaldehyde.
51 D) Alkyl halides are reactive towards nucleophilic attacks because they have electrophilic carbon and good
leaving group. Carbon of the alkyl group has a partial positive charge (electrophilic) as it is attached to
halogen atom which is partial negative (nucleophilic).
Halogens are good leaving groups as they are easily replaced by other nucleophiles like OH-etc. (Textbook-I
page # 195).
52 C) Methanol on oxidation with strong oxidizing agent like acidified K2Cr2O7 gives formaldehyde (HCHO),
which in the presence of excess oxidizing agent converts to formic acid (HCOOH). The final product of
oxidation of primary alcohols with strong oxidizing agent is carboxylic acid if aldehyde is not removed from
the reaction mixture. (Textbook-II page # 237, 295).

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53 A) In Fehling’s test, aldehydes are oxidized to carboxylate anion and Cupric (Cu+2) ions of Fehling’s reagent
are reduced to Cuprous (Cu+) ions. Fehling’s reagent is a weak oxidizing agent which is a mixture of Fehling’s
solution A (CuSO4 .5H2O) and Fehling’s solution B (Aqueous Potassium Sodium Tartrate, also known as
Rochelle salt). The net reaction is:
RCHO + 2 Cu+2 + 5 OH- RCOO- + Cu2O + 3H2O (Textbook-II page # 279).
54 B) Crystalline Solids having Vander Waal’s forces b/w their molecules are molecular solids. Ice is an example
of molecular solids in which water molecules are held together by hydrogen bonding. (Textbook-I page #
181).
55 A) When minerals are free to grow without constraint, they form 3 dimensional solid forms
which are bounded by surfaces (crystal faces) arranged in a regular and repetitive way. The
shape/habit of a crystal is determined by the arrangement of atoms in its structure and this
structure is known as the crystal lattice. Unit cell is repetitive structural unit of a crystal. Crystal
lattice is the three-dimensional arrangement of unit cells. When crystal lattice grows in a
specific pattern in three dimensions this is what we call habit of a crystal. (Textbook-I page # 174).
56 B) In foams, the dispersed phase is gas while the dispersion medium is liquid. Soap lather is a form of foam
in which air is trapped between soap solution resulting in the formation of bubbles. (Textbook-I page # 288).
57 B) Stability of colloid depends upon charge, solvation and Brownian motion. A high charge, greater solvation
and Brownian motion makes the colloid stable. If greater amount of energy is released in solvation, the
colloid will be more stable and vice versa. (Textbook-I page # 291).
58 A) Covalent character increases and ionic character decreases across the period. Greater the covalent
character, lower will be the boiling point. So, the melting points of the given compounds are in the order:
NaCl > MgCL2 > AlCl3 > SiCL4. (Textbook-II page # 14).
59 A) Solid Phosphorous (V) chloride reacts with carboxylic acids to form fumes of hydrogen chloride gas and a
liquid mixture of the acyl chloride and phosphorous oxytrichloride (POCl3). The acyl chloride (CH3COCl) can
be separated by fractional distillation. (Textbook-II page # 299).
CH3COOH + PCl5 CH3COCl + POCl3 + HCl
60 C) Saponification is a process in which fat or oil (ester) is converted into soap (salt) and alcohol by the action
of heat in the presence of aqueous alkali e.g. KOH. The number of milligrams of KOH required to neutralize
the fatty acids resulting from the complete hydrolysis of 1 gram of fat is called saponification number.
(Textbook-II page # 306).
RCOOR + KOH RCOO-K+ + ROH

Chemistry Question numbers in ETEA engineering paper “B” 2019

1 1 13 35 25 76 37 130 49 145
2 2 14 36 26 77 38 131 50 146
3 3 15 37 27 78 39 132 51 147
4 4 16 45 28 79 40 133 52 148
5 5 17 46 29 80 41 134 53a 174
6 6 18 55 30 88 42 135 54b 175
7 7 19 56 31 89 43 136 55a 176
8 30 20 57 32 90 44 137 56b 177
3 31 21 58 33 100 45 141 57b 178
10 32 22 59 34 120 46 142 58 198
11 33 23 74 35 121 47 143 59 199
12 34 24 75 36 129 48 144 60 200

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