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02 Aldehydes & Ketones Que. Final E
02 Aldehydes & Ketones Que. Final E
02 Aldehydes & Ketones Que. Final E
(c) C 6 H 5 CH 2 OH (d) C 6 H 5 CH CHCHO 133. Acetal is obtained by reacting in the presence of dry HCl and alcohol
with [MP PET 1996]
123. Grignard's reagent reacts with ethanal (acetaldehyde) and propanone to (a) Aldehyde (b) Ketone
give
(c) Ether (d) Carboxylic acid
(a) Higher aldehydes with ethanal and higher ketones with
propanone 134. The reagent with which both aldehyde and acetone react easily is[CPMT 1973, 74
(b) Primary alcohols with ethanal and secondary alcohols with (a) Fehling's reagent (b) Grignard reagent
propanone (c) Schiff's reagent (d) Tollen's reagent
(c) Ethers with ethanal and alcohols with propanone 135. Phenylmethanol can be prepared by reducing the benzaldehyde with
(d) Secondary alcohols with ethanal and tertiary alcohols with
(a) CH 3 Br (b) Zn and HCl
propanone
124. Base catalysed aldol condensation occurs with (c) CH 3 Br and Na (d) CH 3 I and Mg
[IIT-JEE 1991]
136. Which of the following is used in the manufacture of thermosetting
(a) Benzaldehyde plastics
(b) 2, 2-dimethyl propionaldehyde (a) Formaldehyde (b) Acetaldehyde
(c) Acetaldehyde (b) Acetone (d) Benzaldehyde
(d) Formaldehyde 137. Which compound undergoes iodoform reaction
125. Benzaldehyde reacts with ammonia to form [DPMT 1984; CPMT 1989]
[CPMT 1989; AFMC 1998]
(a) HCHO (b) CH 3 CHO
(a) Benzaldehyde ammonia
(b) Urotropine (c) CH 3 OH (d) CH 3 COOH
(c) Hydrobenzamide 138. Which does not react with Fehling solution [MNR 1983, 93]
(d) Aniline (a) Acetaldehyde (b) Benzaldehyde
126. Glucose + Tollen's reagent Silver mirror shows (c) Glucose (d) Formic acid
[CPMT 1997] 139. Which of the following compound will react with ethanolic KCN
(a) Presence of acidic group (a) Ethane (b) Acetyl chloride
(b) Presence of alkaline group (c) Chlorobenzene (d) Benzaldehyde
(c) Presence of ketonic group 140. Schiff's reagent gives pink colour with
(d) Presence of aldehyde group [EAMCET 1980; MP PMT 2000]
127. Fehling solution is [MP PMT 1989] (a) Aldehydes (b) Ethers
(a) Ammoniacal cuprous chloride solution (c) Ketones (d) Carboxylic acid
(b) Acidified copper sulphate solution 141. Acetaldehyde reacts with Cl 2 (in excess) to give
(c) Copper sulphate and sodium hydroxide + Rochelle salt
[MP PMT 1997]
(d) None of these
(a) Chloral (b) Chloroform
128. Reduction of an aldehyde produces
(c) Acetic acid (d) Trichloroacetic acid
[MP PMT 1994; MP PET 2001]
142. The compound which reacts with Fehling solution is
(a) Primary alcohol (b) Monocarboxylic acid
[CPMT 1989]
(c) Secondary alcohol (d) Tertiary alcohol
129. Which of the following on reaction with conc. NaOH gives an (a) C6 H 5 COOH (b) HCOOH
alcohol [MP PET 1996] (c) C6 H 5 CHO (d) CH 2ClCH 3
(a) Methanal (b) Ethanal
Aldehydes and Ketones 1287
143. Which one of the following undergoes reaction with 50% sodium (a) 1° > 3° > 2° (b) 1° > 2° > 3°
hydroxide solution to give the corresponding alcohol and acid (c) 3° [AIEEE
> 2° > 2004]
1° (d) 2° > 3° > 1°
(a) Butanal (b) Benzaldehyde 156. In Wolf-Kishner reduction, the carbonyl group of aldehydes and
(c) Phenol (d) Benzoic acid ketones is converted into [Pb. CET 2000]
144. Which one of the following is reduced with zinc and hydrochloric (a) CH 2 group (b) CH 3 group
acid to give the corresponding hydrocarbon
[AIEEE 2004]
(c) CH 2 OH group (d) CHOH group
(a) Acetamide (b) Acetic acid 157. Which of the following react with NaHSO 3
(c) Ethyl acetate (d) Butan–2–one [Pb. CET 2003]
145. Three molecules of acetone in the presence of dry HCl form (a) CH 3 COCH 3 (b) CH 3 CHO
[MP PET 2004]
(a) Mesitylene (b) Phorone (c) HCHO (d) All of these
(c) Glyoxal (d) Mesityl oxide 158. Fehling solution is [Pb. CET 2003]
146. Aldehydes and ketones can be reduced to corresponding (a) CuSO 4 + lime (b) CuSO 4 NaOH(aq)
hydrocarbons by [Kerala PMT 2004]
(c) CuSO 4 Na 2 CO 3 (d) None of these
(a) Refluxing with water
(b) Refluxing with strong acids 159. Wolf kishner reduction, reduces [Pb. CET 2003]
(c) Refluxing with soda amalgam and water (a) COOH group (b) C C – group
(d) Refluxing with zinc amalgam and concentrated HCl (c) CHO group (d) O group
(e) Passing the vapour under heated PbO2 160. A compound has a vapour density of 29. On warming an aqueous
147. Acetone reacts with iodine to form iodoform in the presence of solution of alkali, it[BHU
gives2004;
a yellow
CPMTprecipitate.
2004] The compound is
(a) CaCO 3 (b) NaOH (a) CH 3 CH 2 CHO (b) CH 3 CHOHCH 3
2
(c) HNO 2 (d) I2
173. Ketones react with Mg-Hg over water gives [AFMC 2005]
3. Which of the following will react with water [IIT 1998]
(a) Pinacolone (b) Pinacols
(c) Alcohols (d) None of these (a) CHCl 3 (b) Cl 3 CCHO
174. Which of the following will form two isomers with semi carbazide[Orissa JEE 2005] (c) CCl 4 (d) ClCH 2 CH 2 Cl
(a) Benzaldehyde (b) Acetone
4. An organic compound ‘A’ has the molecular formula C 3 H 6 O, it
(c) Benzoquinone (d) Benzophenone
undergoes iodoform test. When saturated with dil. HCl is gives ‘B’
175. A compound A C 5 H 10 Cl 2 on hydrolysis gives C 5 H 10 O of molecular formula C9 H 14 O . A and B respectively are [Tamil Nadu CET 2002
which reacts with NH 2 OH , forms iodoform but does not give (a) Propanal and mesitylene
fehling test. A is [DPMT 2005] (b) Propanone and mesityl oxide
Cl (c) Propanone and 2,6–dimethyl –2, 5-heptadien–4–one
|
(a) CH 3 C CH 2 CH 2 CH 3 (d) Propanone and mesitylene oxide
| 5. Which alkene is formed from the following reaction
Cl
CH 3 CH 2 CH 2 CH PPh3 2 Butanone [Manipal 2001]
Cl
| (a) 3- Methyl-3-heptene
(b) CH 3 CH 2 C CH 2 CH 3 (b) 4-Methyl-3-heptene
|
Cl (c) 5-Methyl-3-heptene
Cl (d) 1-Methyl-5- methane
|
6. Compound ‘A’ (molecular formula C3 H 8 O) is treated with
(c) CH 3 CH 2 CH 2 CH 2 CH
| acidified potassium dichromate to form a product ‘B’ (molecular
Cl
formula C 3 H 6 O). ‘B’ forms a shining silver mirror on warming
Cl Cl with ammoniacal silver nitrate. ‘B’ when treated with an aqueous
| |
(d) CH 3 CH CH CH 2 CH 3 solution of H 2 NCONHNH 2 .HCl and sodium acetate gives a
product ‘C’. Identify the structure of ‘C’ [IIT-JEE (Screening) 2002]
176. CH 3 CHO HCN A ; Compound A on hydrolysis gives[Kerala CET 2005]
(a) CH 3CH 2CH NNHCONH 2
(a) CH 3 CH 2 COOH
(b) CH 3 CH NNH CONH 2
(b) CH 3 CH 2 CH 2 NH 2 |
CH 3
(c) CH 3 CO COOH
(c) CH 3 CH NCO NHNH 2
(d) CH 3 CO CH NOH |
CH 3
(e) CH 3 CH COOH
|
OH (d) CH 3CH 2CH NCONHNH 2
177. Which one does not give cannizzaro's reaction 7. Which is not true about acetophenone [Manipal 2002]
[Kerala CET 2005] (a) Reacts to form 2, 4-dinitorphenyl hydrazine
(a) Benzaldehyde (b) Reacts with Tollen’s reagent to form silver mirror
Aldehydes and Ketones 1289
(c) Reacts with I2 / NaOH to form iodoform
(c) H 2 / Ni (d) NaBH 4 15. The product of acid hydrolysis of P and Q can be distinguished by [
OH OH
(c) O (d) O | |
(a) CH 3 C CH CH 2 CH 3
|
CH 3
OH OH
12. CHO OHC CH 3
(i) NaOH / 100 o C (b) CHCO 2 H CH 3 COOH
(ii) H / H 2 O
CH 3
CHO OHC CH 3
Major Product is [IIT-JEE (Screening) 2003] (c) CHOH CH 3 CH 2 CH 2 OH
COOH HOOC CH 3
(a) CH 3
(d) C O CH 3 CH 2 COOH
CH 3
COOH HOOC
HO HOOC 17. Which of the following reactions give benzo phenone
[Roorkee Qualifying 1998]
(b)
(a) 2C6 H 6 CCl 4
(i) AlCl3
(ii)H 2 O
COOH HO
(b) C6 H 6 C6 H 5 COCl
AlCl3
O
O
(c) o CH 3 C 6 H 4 COC 6 H 5
Heat
(c)
(d) o HOOC C 6 H 4 COC 6 H 5
Cu
260 o C
O 18. Aldehyde and ketones can decolourize by [CPMT 2003]
O (a) Bromine water (b) Quick lime
CH OH HOH 2C
2
CH OH 2 HOH 2C
1290 Aldehydes and Ketones
(c) dil. H 2 SO 4 (d) None of these
19. Which of the following statements regarding chemical properties of H
acetophenone are wrong NCH 3
(a) (b)
(1) It is reduced to methyl phenyl carbinol by sodium and ethanol OH NCH 3
(2) It is oxidised to benzoic acid with acidified KMnO4 H
(3) It does not undergo iodoform electrophilic substitution like O.NHCH 3 H
nitration at meta position (c) (d) NCH 3
(4) It does not undergo iodoform reaction with iodine and alkali [Tamil Nadu CET 2001]
(a) 1 and 2 (b) 2 and 4 29. Products of the following reaction OH
(c) 3 and 4 (d) 1 and 3
CH 3 C C CH 2 CH 3 ... are
(1) O 3
[CBSE PMT 2005]
20. The product(s) obtained via oxymercuration (HgSO4 H 2 SO 4 ) (2) Hydrolysis
O. –
Introduction
1 a 2 b 3 a 4 c 5 a
6 c 7 b 8 b 9 a 10 b
11 b 12 d 13 d 14 b 15 a
16 c 17 c 18 c