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    GeneralOrganicChemistry Assignment

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    Aayush
    For IIT aspirants only

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    Vedantu, 1. The R/S configuration of following compound is (2016) com = {ox # a cus (@ QS, 3R) ©) @S, 38) (© GR 3R) @ R38) 2. The IUPAC name of the following compound is (2009) (@) 4-bromo-3-cyanophenol (b) 2-bromo-5-hydroxybenzonitrile (©) 2-cyano-4-hydroxybromobenzene (@ 6-bromo-3-hydroxybenzonitrile 3. The number of stereoisomers obtained by bromination of frans-2-buteneis (2007) @! 2 ©3 @4 4. The IUPAC name of CéHsCOCl is (2006) (@ benzoyl chloride (b) benzene chloro ketone (©) benzene carbonyl chloride (@ chloro phenyl Ketone 'cHs Ta Wea cH, Cais rotated anti-clockwise 120° about C2- C3 bond. The resulting conformer is (2004) (@ patially eclipsed () eclipsed (© gauche (@ staggered 6. Which of the following compounds exhibits, stereoisomerism? (2002) (@ 2-methylbutene-1 (b) 3-methylbutyne-1 (©) 3-methylbutanoic acid (@ 2-methylbutanoic acid 7. The number of isomers for the compound with molecular formula C2BrCIFlis (2001) @3 @)4 5 @s 8. Which of the following compounds will exhibit geometrical isomerism? (2000) (@ L-phenyl-2-butene (b) 3-pbenyl-I-butene (©) 2-phenyl-1-butene (@ 1, 1-diphenyl-1-propene Vedantu, 9. The optically active tartaric acid is named as D-(+)-tartaric acid because ithas a positive (4999) (@ optical rotation and is derived from D- glucose (b) pHin organic solvent (©) optical rotation and is derived from D-(+ }-glyceraldehydes (@ optical rotation when substituted by deuterium 10. How many optically active stereoisomers are possible for butane-2, 3- diol ? as97) @l @)2 ©3 @4 11, Isomers which can be interconverted through rotation around a single bond are (ag92) (@ conformers () diastereomers (©) enantiomers (@ positional isomers 12. The enolic form of acetone contains (ass) (@)9 sigma bonds, | pi bond and 2 lone pairs (b) 8 sigma bonds, 2 pi bonds and 2 lone pairs (©) 10 sigma bonds, 1 pi bond and I lone pair (@ 9 sigma bonds, 2 pi bonds and 1 lone pair 13. The number of isomers of Csthis is 987, 2007) @4 6 @)5 @7 14, Iftwo compounds have the same empirical formula but different molecular formulae, they must have 987) (@ different percentage composition () different molecular weight (©) same velocity (@ same vapour density 15, Which of the following will have least hindered rotation about carbon-carbon bond? a987) (@ Ethane (b) Ethylene (©) Acetylene (@) Hexachloroethane 16. The IUPAC name of the compound CH = CH-CH(CH): is ass7) (@ 1,1-dimethyl-2-butene (b) 3-methyl-1-butene (©) 2-vinyl propane (@ None of these Vedantu, 17. An isomer of ethanol is (1986) (@) methanol (©) diethyl ether (©) acetone @ dimethyl ether 18. The IUPAC name of the compound having the formulas assay CH, uc—¢—cH=cH, by (@ 3, 3, 3-trimethyl-1-propene (0) 1, 1, 1-trimethyl-2-propene (© 3, 3-dimethyl-1-butene (@ 2, 2-dimethyl-3-butene 19. Which of the following compounds will exhibit cis-trans (geometrical) isomerism ? (4983) (©) 2-butyne @ butanal (@ 2-butene (©) 2-butanol 20. The compound which is not isomeric with diethyl etheris asl) (@ n-propyl methyl ether () butane-1-ol (©) 2-methyl propane-2-o1 (@ butanone 21. The IUPAC name(s) of the following compound is (are) 2017) wth (@) 4-methylchlorobenzene (b) 3-chlorotoluene (©) 1 -chloro-4-methylbenzene (@) 1-methyl-4-chlorabenzene 22. The correct combination of names for isomeric alcohols with molecular formula Cat0O is/are 01) (@ tert-butanol and 2-methylpropan-2-0l () fert-butanol and 1, 1-dimethylethan-1-ol (©) n-butanal and butan-I-ol (@ iso-butyl alcohol and 2-methylpropan-3- ol 23. Which of the given statement(s) about N, O, P and Qwith respect to Mislare correct? 01) HO, q # a # 1 oi W0 a no. H “Fort H i &y u ic ° ay om, nM on Ho Pn WPA oP g g 2 (@ Mand N are non-mirror image diastereomers (0) Mand N are identical () Mand P are diastereomers (@ Mand Q are identical Vedantu, 24. The correct statement(s) about the compound is/are 2009) H3C(HO)HC ~ CH = CH - CH(QH)CHs (X) (@ The total number of stereoisomers possible for Xis 5 (b) The total number of diastereomers possible for Xis 3 (©) If the stereochemistry about the double bond in Xis trans, the number of enantiomers possible for Xis 4 (@) IE the stereochemistry about the double bond in Xis cis, the number of enantiomers possible for Xis 2 25. The correct statement(s) conceming the structures EE F and Gis/are Oe CHy HyC’ CH Ke (@ E, F and G are resonance structures (b) E, F and E, G are diastereomers (© F and G are geometrical isomers (@ F and G are tautomer 26. The correct statement(s) about the compound given below is/are 2008) cl Hy Hy H (@ the compound is optically active () the compound possesses centre of symmetry (©) the compound possesses plane of symmetry (@ the compound does not possess axis of symmetry 27. Tautomerism is not exhibited by (1998) @ - CH=CH—OH ®) 28, Which of the following compounds will show geometrical isomerism? ag98) (@) Ethene (b) propene (©) L-phenyl propene (@) 2-methyl-2-butene Vedantu, 29. Which of the following have asymmetric carbon atom? (ags9) 30. Keto-enol tautomerism is observed in (ass) @ ° Il CoHs—C—H ) ° ° I CH, —C—CH,—C—CH, t CoH — CG, ® ° GHy.—C—C — CH, 31. Only two isomeric mono-chloro derivatives are possible for (4986) (@ n-butane (b) 2, 4-dimethyl pentane (©) benzene (@ 2-methyl propane 32. Statement I: Molecules thet are non- superimposable on their mirror images are chiral Statement II: All chiral molecules have chiral centres. 2007) (@ Statement Iis correct; Statement ITis correct, Statement I is the correct, explanation of Statement I (b) Statement Lis correct, Statement Ilis correct, Statement Il is not the correct explanation of Statement I (o) Statement Iis correct; Statement ITis incorrect (@ Statement Lis incorrect; Statement ITis, correct, Vedantu, 33. The total number of stereoisomers that can exist for Mis 2015) HC ett if He MN @1 @)2 3 @4 34. The total number(s) of stable conformers with non-zero dipole moment for the following compound is/are 2014) a br——cn, tr—~cl Ch, @1 @)2 3 @4 35. The total number of cyclic structures as well as stereoisomers possible for a compound with the molecular formula CsHio islare (2009) @s @)2 (3 @ 36. Hage = Xs Where usis the dipole moment of stable conformer and x,is the mole fraction of that conformer. (D Write stable conformer for Z-CHa-CH-Z, in Newman's projection, (2005) If Usotwion = 1.0 D and mole fraction of anti form = 0.82, find Usmene @ 557D (b) 585D (2) 5.94D (@) 5.55D 37. Relatively less stability of the staggered form is due to (2004) (@ Torsional strain (b) van der Waals' strain (©) Combination of the above two (@ None of the above 38. Glycerin contains hydroxy group 2004) (@ Territory (b) Secondary (© Both (@) and (6) (@ None of the above 39, Identify the pairs of enantiomers and diastereomers from the following (2000) om 2 ee non woe to Hon o—f—# #0 om % ° (@ 1+ I= Enantiomers and I+ IIT = Diastereomers (b) I+ I and I+ I= Diastereomers Vedantu, 1+ and 11+ IL Il = Enantiomers (@ I+ I= Enantiomers and 1+ I= Diastereomers Diastereomers, 1+ 40. The decreasing order of acidic character of the following is ( CrssH (UD Fro @I>u>m>iv @)Iv>m>m>1 (© ul> nv (i) CHaOH (I) EXOH (@Ul>1>u>1V 41, The decreasing basic character of the following is: 1 Pho® Il CH3S® IIL. OPH IV. MeO® (b) I> IV>1>1 @>ueivem @I>u>m>iv (@veme>m>1 42. The decreasing nucleophilicity of the following is: LCH3S° —ILCH30° MLOH® IV. Et0® ()IV>Ml>m>1 @)1> > mI IV (@Iv>m>1>n @)u>1>m>1V 43, Arrange the following in their decreasing order of basic character Me. oo 1 >=0 o AO HN ‘Me’ iH ‘Me Me mk IV.NK, Me/ NH @Ul>Iv>i>n @)I> n> M> Iv (IV>m>m>1 @U>mI>1>I1V 44, Which of the following carbocations is least stable? (@ PhCH, () CH=CH, (©) Me,CH @ CH, =CH-cH, 45, Which of the following is a soft base? @NE &) os () Cur @ ho 46, Which of the following is a soft base? (aco (b) CO;* jar (@ Po 47. Which of the following molecules is least resonance stabilized? 017) @ Vedantu, 48. The distillation technique most suited for separating glycerol from spent lye in the soap industry is (@ fractional distillation () steam distillation (© distillation under reduced pressure (@ simple distillation 49. The correct order of acidity for the following compounds is 2016) con COnH (@I> I> mv @)MI> I> 1>N (mr Ive net @I> > 1vem 50. For the estimation of nitrogen, 1 4 g of an organic compound was digested by Kjeldahl's method and the evolved ammonia was absorbed in 60 mL of M110 sulphuric acid. The unreacted acid required 20 mL of ‘MI\0 sodium hydroxide for complete neutralisation, The percentage of nitrogen in the compound is 014) @e% (b) 10% 3% @s% 51. A gaseous hydrocarbon gives upon combustion 0.72 g of water and 3.08 g of COs, The empirical formula of the hydrocarbon is (2013) (@ Cath (b) Cate (©) Colts @ CrHe 52. The order of stability of the following carbocations (2013) ® e (CH=CH Cy ; CHy—CH CH o a Vedantu, @UP>I>1 ® I> ml>I (lene m @uern 53, Arrange the following compounds in the order of decreasing acidity (2013) OH OH OOH 58:8 ci CH; NO, OCH; o a any (ly) @U>Iv> Pil (I> > m>1V (QUl> I> n> Iv @Wvem>ir>n 54. A solution of (-1) 1 -chloro-1- phenylethane in toluene racemises slowly in the presence of a small amount of SbCls, due to the formation of 2013) (b) carbene @ free radical (@ carbanion (© carbocation 55. In allene (CsHs), the type(s) of hybridisation of the carbon atoms, is (are) 012) (b) sp and sp? @ sp’ and sy? (sp and sp? (© only sp? 56. Among the following compounds, the most acidic is (2011) (@ p-nitrophenol (b) p-hydroxybenzoic acid (© o-hydroxybenzoic acid (@ ptoluic acid 57. The correct stability order of the following resonance structure is (2009) z ) H,C-N=N N () H,CoN=N () C= (ai HC @@>a>a> ay ©) > a) > Gy > ay) ©@> o> ayn> a) @an>@>ay>a@ 58. In the following carbocation, HICHs that is most likely to migrate to the positively charged carbon is (2009) H H wipe pb OH HCH, (@ CH at C-4 () Hat C-4 (©) CH at C-2 @Hac-2 59, The correct acidity order of the following is (2009) oH OH HH COOH eS SS 2 LZ o ag a cy ay aw) @ap>™>@>o@ @) av) > GID > @> @ © aD > D> @> Cy) @ a> ay>avy>@ 60. Hyperconjugation involves overlap of the following orbitals 2008) @o-o @)o-p ©p-p @a-n 61. The correct stability order for the following species is (2008) Aon AA ap AA aa (up @ @)> (vy) > > aD (b) @ > (I) > Al) > (y) © >> dvy)> ap @@> (p> a) > dy) 62. Among the following, the least stable resonance structure is (2007) @ A 7 ¥ 20—% 63, When benzene sulphonic acid and p- nitrophenol are treated -with NaHCO, the gases released respectively are (2006) (@ S02, NO; (©) $02, NO (c) SOn, COr (@) COn, COr 64, Which of the following is obtained when 4-methylbenzene sulphonic acid is hydrolysed with excess of sodium acetate? (2005) @ aos eC +s, © Vedantu, 65. For 1 -methoxy- 1, 3-butadiene, which of the following resonating structure is least stable? (2005) @ eo ¢ CH, —CH—CH=CH—O—CH) ) 2 ° CH, —CH=CH—CH=0—CH, © e 6 CH, =CH—CH=CH—O—CH, @ 2 2 CH,=CH—CH—CH=0—CH, 66. HN’ iu b 7 Y COOH x Asrange in order of increasing acidic strength (2004) @X>Z>¥ )Z¥ (xX>¥oz @z>x>¥ 67, Among the following, the molecule with the highest dipole momentis 2003) (@ CHBCL (b) CHCl: (© CHaCh @cch 68, Which of the following represent the given mode of hybridisation sp? - sp? - sp - sp from left to right? (2003) (@ HC =CH-C=N () HC=C-C=CH (©) hC=C=C=Chh The product A will be 2003) @ om ) Vedantu, © mee no AY “oN @® nooe. On. 70. Which of the following acids has the smallest dissociation constant? (2002) (@ CHBCHFCOOH (® FCH:CH:COOH (© BrCFhCHaCOOH @ CH3CHBrCOOH 71. Identify the correct order of boiling points of the following compounds CH3CH:CH,CH,OH (1) CHsCH:CH2CHO (2) CHsCH,CH,COOH (3) ()3>1>2 @3>2>1 @1>2>3 (1>3>2 72. Which of the following hydrocarbons has the lowest dipole moment? 2002) (@ cis-2-butene (b) 2-butyne (©) 1 -butyne (@ HC =CH-C=CH 73, The correct order of basicities of the following compounds is gun WCCO CH,CH,NH, 2 Q) wo (CHy ),NH ‘CH,CONH, (3) (4) (2>1>3>4 — @)l>3>2>4 (a> 1>2>4 @1>2>3>4 74, Among the following, the strongest base is 2000) @ CoHsNEb (b) p-NO2CoHiNED (© m-NO2-Coti NED (@ CeHsCHLNHe 75, Which of the following, has the most acidic hydrogen? 2000) (@ 3-hexanone (&) 2, 4-hexanedione (©)2, S-hexanedione (@ 2, 3-hexanedione Vedantu, 76. The most unlikely representation of resonance structures of p-nitro phenoxide ionis (a999) @ oo 4 77, Among the following compounds, the strongest acid is (ag98) (@ HC=CH (0) Colts CaHs (d) CH30H 78. Inthe following compounds (1997) AO A qao0cka V4 Sy hr. ee ‘The order of acidity is @lUP>Iv>pu @)I> Ive men (QU> I> mv @Ivem>i>1 79, What is the decreasing order of strength of the bases? a997) OH-,NH,,H -C=C" and CH, -CH; @ CH, CH; > NH, > H-C=C” >OH™ ) H-C=C" >CH, -CH; > NH, > OH- © OH” > NH; > H.-C =C” > CH,-CH; @ NH, > H-C=C> > OH” > CH, -CH; 80, The hybridisation of carbon atoms in C- C single bond H-C =C-CH=CH, is sol) (@ sp>—sp* O sp -y Vedantu, ©) sp @) sp’ -sp 81. Amongst the following, the most basic compound is (a990) (@ benzylamine () aniline (© acetanilide @ pritroaniline 82, The number of sigma and pi-bonds in 1 - butene 3-yne are (ags9) (@) 5 sigma and 5 pi (b) 7 sigma and 3 pi (©)8 sigma and 2 pi (@ 6 sigma and 4 pi 83. The compound which gives the most stable carbonium ion is a9s9 @ CHly—FH—CH, OH CHy ) f "on CH, (©) CH - CH - CH - CH:0H @ OH CH;—CH—CH,—CH, 84, Polarisation of electrons in acrolein may be wnitten as agss) @ o . I H,C=CH—C—H oe ) be 0 & H,C=CH—C—H © ° se | H,C=CH—C—H @ & 9 ue I H,C=CH—C—H 85. The bond between carbon atom (1) and carbon atom (2) in compound 987) N=C—CH=CH, 12 Involves the hybridisation as (©) sp? and sp (@ sp? and sp? (@ sp? and sp? (©) sp and sp? 86. Among P, Q Rand S aromatic compounds, how many have the 2 number of pi electron? 2013) Vedantu, a my \ ACh,» (he 7 ik ae o 0 @l @)2 3 @4 87. The hyperconjugative stabilities of tert- ‘butyl cation and 2-butene, respectively, are due to (2013) @o—p (empty) and o > n* electron delocalisation (0) 6 + nt and om electron delocalisations (op (Billed) and o — m electron delocalisations (@)p (filled) S of and o x* electron delocalisations 88. Amongst the given options, the compound(s) in which all the atoms are in one plane in all the possible conformations Gf any), is/are 2011) @ HY A uc7 “Sou, ) H-C= cc © @ hhC=C=Ch 89. In the Newman's projection for dimethylbutane x HC CH rt H Y Xand Yon Ci —C2 axis, can respectively be 2010) (@HandH (b) Hand CHs (© CoHs and H (@) CH and CHs 90. The molecules that will have dipole moment are as92) (@ 2, 2-dimethyl propane () trans-2-pentene (©) trans-3-hexene @22 , 3-tetramethyl butane 91. The compound in which C uses its sp? - hybrid orbitals for bond formation is 2000) (@ HCOOH (b) GaN)2co (2 (CHB)sCOH (®N=C-CH=Chh Vedantu, 92. Phenol is less acidic than 4986) (@ acetic acid (b) p-methoxy phenol (© Glyoxal @ ethanol 93, Statement I: p-hydroxybenzoic acid has a lower boiling point than o-hydroxybenzoic acid. Statement II: o-hydroxybenzoic acid has intramolecular hydrogen bonding. (@ Statement Iis correct; Statement ITis correct; Statement II is the correct, explanation of Statement I (b) Statement Lis correct; Statement IT is correct; Statement Il is not the correct explanation of Statement I (©) Statement Iis correct; Statement ITis incorrect (@ Statement Lis incorrect, Statement ITis correct 94, Statement I: p-nitrophenol is a stronger acid than o-nitrophenol Statement I: Intramolecular hydrogen bonding make the o-isomer weaker acid than p-isomer (@ Statement Iis correct; Statement ITis correct; Statement II is the correct, explanation of Statement I (b) Statement Lis correct; Statement Il is correct; Statement Il is not the correct explanation of Statement I (o) Statement Iis correct; Statement ITis incorrect (@ Statement Lis incorrect; Statement ITis, correct, 95. Match the reactions in Column I with appropriate types of stepsireactive intermediate involved in these reactions as given in Column IL ol) i 4 8 » hen « ‘ oo ach : Toa ; me oy ain @A13,4Bp,s; ConssDoqr (W)A>rGBop.s; Cons; Dogr @A>rtBops; Cors;Doqns @A>r 4 Bop; Cons, Dogr 96. Match the reaction in Column I wit appropriate options in Column Il 2010) econ sts erp statin ei sian . er wjeane , Oo s @A>n Bot Cop.q Dor WA4s Boy Cop.g Dor (ASK Bos; Copq Dor @MASr Bot Cop Dog 97. The total number of contributing structures showing hyperconjugation Gavolving C - H bonds) for the following carbocation is 2011) HC. @ -CH,CH, @s 7 3 @s 98. Amongst the following, the total number of compounds soluble in aqueous NaOH is 2010) WC cts Sy coo Noy om 0 Hyc“*ScH, Vedantu, orci OH HHACHs “" Ayia LU SS coon ws CO @s 7 (4 @s8 99. The kind of delocalisation involving sigma bond orbitals is called? 4994) (@ Hyperconjugation () Inductive (©) Electromertic (@ Mesomeric 100. The bond dissociation energy needed to form the benzyl radical from toluene is than the formation of the methyl radical from methane. a994) (@ more (less (© equal (@ None of the above 101. The structure of the enol form of CH —CO~CHp — CO-CHs with intermolecular hydrogen bonding is 4993) @ cyclic () acyclic (©) polar (@ None of the above 102. The IUPAC name of succinic acid is__ as90) (@pentancic acid —_(b) heptanoic acid Vedantu, )nonanoic acid (4) butanedioic acid 103. The shape of (CHs)* is a990) (®) square planar (b) trangular planar (©) tetrahedral (@ None of the above 104..A___ diol has two hydroxyl groups on _ carbon atoms. (agss) (@ geminal, different (b) geminal, same (©) geminal, infinity (@ None of these 105. The terminal carbon atom in butane is _ hybridized ass) @s* ©) sp Op @ spd 106.___ringis most strained (1981) (@ cyclopropane —_(b) cyclobutene (© cyclopentane (4) None of these 107. The compound having both sp and sp? -hybridised carbon atoms is 981) (@ propane (©) propene (©) propadiene (@ None of these 108. In acidic medium, behaves as the strongest base ssi) (@ nitrobenzene () aniline (© phenol (@ None of these 109. Among the given cations, __is most stable ssi) (@ sec-butyl carbonium ion () tert-butyl carbonium ion (©) n-butyl carbonium ion (@ None of these 110. Which of the following compounds will be suitable for Kjeldahl’s method for nitrogen estimation? 27 Vedantu, 111. Which of the following will not exist in zwitter ionic form at pH=7? NH oA, (a) Cre (b) 4, OH H NH2 NH © Cx @ ‘SO3H_ ‘SO3H 112. The increasing order of nitration of the following compounds is 0 db o 3 @) ©) © @ @ac are @o ®1 ©2 @4 126. Identify the compound and find the relation between them. OH 00H 4. COOH H. CH, H ‘ChHe H ‘CH, cH, OH (@ Conformational isomers or identical (b) Configurational diastereomer (c)Configurational enantiomers (@ Constitutional isomers 127. Correct IUPAC name of the compound is NHp —CH—CH—CHO i HOOC COOH (@)2-Formyl-3-aminobutane dioic acid (b) 2-Amino-3-formylbutane dioic acid ()3-Aminc (@ None of the above -dicarboxypropanal 128. How many structural isomers containing a benzene ring are possible for CeHio (@)2 @)3 @)4 @s5 129. Which of the following statement is incorrect ? (@ Ameso compound has chiral centres but does not exhibit optical activity. (b) Ifa molecule is dissymmetic, it rotate the plane of plane polarized light (©) Ameso compound is optically inactive because the rotation caused by any molecule is cancelled by an equal and opposite rotation caused by another molecule that is the misvor image of the first. (@ The two diastereomers have same structure formula but different physical and chemical properties Vedantu, 130. Which of the following species can not exhibit geometrical isomerism? Me @® Mo ve Me ZL Ni Mee 131, The stereochemical formula of diastereomer 'Y” of optically active compound 'X'is, (EX = 2,3-Dihydroxybutanedioic acid.) @ H—Lcoon HOoc—}—H on ) 132. Which is correctly matched with IUPAC Name? Oe” sanatteen acimnc _ o Se on OQ : 133. Which compound racemises (ooses optical activity) due to tautomerisation? ° 2.4@-romocycchexypropaneninis @) oa cH, Vedantu, cr es H ° i 1 (C) CH3 -C-CH, ~C-CHg t Br ° a (8) CHy-C-CHy-C-0r 134. In which compound D-exchange is possible in presence of OD/D20 ? ? g (2) CHy-C-Pn (b) CH = CH-C-Pn 1 © (6) CHy-C-cH- HCHO Colts 135. Compound CsHio (A) spl Saco B +c Compound B and C both gives iodoform test and B also gives silver mirror with ammonical silver nitrate ‘The structure of compound Ais ra) ows oOo nN oA, 136. Correct name of the following compound is aoe CI-CH, -C-0-C-CHp -CI (@ Bis (Chloroacetic anhydride) (@ Bis (Chloroethanoic anhydride) (©) Chloroethanoic anhydride (@ 1-Chloroethanoyloxy-2-chloroethanone 137. Which is the suitable reagent for the following conversion Acetone "5 Acetic acid (@ NaHCOs (b) Tollen's reagent (© NaOl followed by HY (@ NaOH 138. Which statement is correct for the given reaction cH, cH, HR C—ACHOH 1.5 Hm Ca COOH CH, He (3+2-Methy-1-butanol (+)-2-Methylbutanoie acid (@ The reactant and the product in the above reaction have (8) configuration () In this reaction no bond to the chiral centre is broken so there is retention of configuration in the product (©) Reactant and product both can be distinguished by NaHCO or Lucas reagent. (ALL are correct. 139. Aresearch scholar get a mixture of three product during an experiment with ammonia. In product I only one H of ammoniais replaced by ethyl group and in II two H atoms of ammonia are replaced by ethyl groups and in Ill all the H-atoms are replaced by ethyl groups. Which test he should use to distinguish or separate the products (@ Corbyl amine test (&) Iodoform test (© Fehling solution test (@ Hinsberg test 140. When a nitrogen containing organic compound is strongly heated with conc HaSOy, the product is- (@ HNOs (b) (NH)s0 (NHs @ Nr gas 141. The lower boiling isomer of the W is W —alic> Acetophenone @ PhHC\ Me C=C: Me Nc -Ph Ph-H, CH.-Ph Deeg Han @® Vedantu, 142. Which of the following compound has non superimposable mirror image — @ OOH COOH cH, H Me 7 © >1 (0) > 1> (m> m1 @piem 163. The correct order of C—N bond lengths for the following compounds is NH, NH, oy wy CHO NH: NH, O } (@wrx>y>z @y>x>wez (@w>y>z>x @x>y>2>w 164. Which compound give CO:with NaHCO3? (@ Phenol (b)Glyceral ()n—butanol (@ Acetic acid 165. Correct order of basic nature is (@ NH > CH3NHb > CsHsNEa (b) CoHsNEb > NH3> CHaNHz (QCHRNER > NHa> CoHsNHa (@ None of these 166. In HCO’, the two carbon-oxygen bonds are found to be of equal length. What is the reason for this ? (@ The anion is obtained by the removal of a proton from the acid molecule (b) Electronic orbitals of carbon atoms are hybridised. Vedantu, (©The bond. ‘bond is weaker than C—O (@ The anion HCOO has two equally stable resonating structures 167. Which of the following orders of acidic strength is correct ? (a) RCOOH > CH=CH > HOH >ROH, (b) RCOOH > ROH > HOH > CH=CH (©) RCOOH > HOH > ROH>CH=CH (@ RCOOH> HOH > CH=CH> ROH 168. CoHsOH —* > CoHsCl X can be expect @ SOCh (&) PCls (© PCls @Nacl 169.The conversion of Cl— CH= CH — Cl to CHCh—CHCl can be carried out with (@HCI (excess) (© Ch coh ©) Ch/hy @ ChiNeoH 170. In which of the following rate of Sxl is very fast ? @ a Hy -CH-CHy ) a r Ph-CH-CHy (2) CHsCH2 —O- CF -Cl @ Cb -CH=CH-Cl 171. Whichis the correct order for basicity ? @rm>m ()U> lat ()Ul> > 1 @u> 1m 174. Which order is correct for both nucleophilicity and basicity ? 7 Vedantu, @crF (0) FhO < FaS. (@EO < OF 175. Which one of the following is least acidic? Arrange pH of the given compounds in decreasing order (@ Phenol (W)Ethyl alcohol (© Formic acid (@)Benzoic acid 176. Maximum enol content is in “Lo LL wk J 177. Consider the Sl solvolysis of the following halides in aqueous formic acid CHa, Br Br, CH, | CH-CH-CH, tp CHy 8 (OH GH-CH, (yy oO br Which one of the following is correct sequence of the halides given above in the decreasing order of their reactivity? (@Ul>Iv> >t @)N>Iv>1> mr (I> >> Iv @m>1>m>1V 178. Consider the following groups @-OAc (ii) -O-SOx-Me (i) —OMe (Gv) -O-SO2-CF3 ‘The order of leaving power is (@iriirii>iv — @)iv>i>i>ii (ii>H>iriv @ii>ii>iv>i 179. The chemical system that is non- aa "GO » “A 180. Which of the following is least stable carbanion? a) ont 8 (b) (C,Hy) e (acre? (Hc? 181, Arrange stability of the given carbocations in decreasing order ox, ea, oa, ° O o 9 o o “ 9 Tne oO mH OG @I>M>M>Iv @)M>n>1>1v (Weteu>m @m>ml>1>1Vv Vedantu, 182, Which ofthe following compound give ] 186. The correct increasing order ofthe solvolysis reaction with slowest rate ? reactivity of halides for Sw reaction is (@p-NR, - Colle CH -Br 0H,-CH-X < (CHLCH-X < CHLRCH-CH.-X < PrOH xX () P—CCh — Cath Ci -Br (CAYCH-K < CH=CHL=K < CH= CH-CHX —< PhOH,-X (© p-NeC-Coll-Cl -Br (OPIOHAX —< (CH)OHAK < CH=CH «CH =CH-CH -K © Calis Cit -Br (MOHHOHK < PheCh-X < (HJCH-K ——< OH-,-X 187. Reaction intermediate of El cB 183. The most reactive nucleophile among reaction is the following is (@Carbocation —_—_(b) Carbanion (@ CHO (©) CoO (© Benzyne (@ Free radical (© (CHa). CHO @) (CH) CO 188. Select false statement from the 184. Which is the correct matched for the following ? following reactions (@ Formation of dichlorocarbene from o Oper sims, Padres CHCIs is an elimination reaction ° (b) Carbocations and free radicals are planar chemical species. 6 Ops 25 enn (©) Inthe rearrangement of carbocation, 0 Opowon mse. awraneatinan | | caboston may canver int 2— carbocation ” . ai @ CCl; group is o, p-directing because it * HOH, Nucteophitc substtstion exhibit hyperconjugation with benzene ring %, 185. Which is correctly matched 48 correctly matches 189. Which of the following Is not —, ran tmean | » Op fener ome Py jon or © OK oor x, e xr @alcl, \ 9 190. Which statement is incorrect 0 10 he @ fou ° ; ° o ‘a) logens are deactivating groups but peveatae fog 8 group have ortho-para directing nature Vedantu, (©) Nitrobenzene, gives metanitrotoluene on reaction with CH3Cl/AICIs. (©) Nitro group is meta directing (@ Aniline does not give Friedel Craft reaction directly 191. The correct leaving group ability order is A (2) BH >H,0 (b) 8H> 8 oy Ages a &>P 192. Which statement Is Incorrect tor the above reaction: cane te CH, -CH, -O-CH,-Cl (2) CHs — CHa — 0 - CH - Cl react faster than cH, cx, ocx, when treated with CHaMgBr (b) Resonance stabilised carbonium ion is formed in the above reaction. (©) Product of the reaction is diethyl ether (@ Reaction is proceed through Sw2 mechanism. 193, Which of the following is not a nucleophile? (@ CHsONa (©) PhLi (© PHs @ NH, 194, Select the correct option Si: Catechol is less acidic than resorcinol Sy Ortho-nitrophenol is less acidic then para- nitrophenol. $3 Ortho-cresol is less acidic than its meta and paraisomers Sq Generally ortho substituted phenols are less acidic than their corresponding meta & pare isomers (@ All are correct (b) Only Si S2 & $3 are correct (©) Only 1 and $2 are correct (@) Only $1 and $3 are correct 195. The reaction is CHsCHBr —CH»Br+ 2KOH (alc) 2 CH3—C=CH + 2KBr + 2720 (@ Dehalogenation (b) Dehydrohalogenation (©) Decarboxylation (@ Dehydration 196. For the following the increasing order of nucleophilicity would be or @ cr Gi) Br @r

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