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5.

2 Production Facilities

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GENERAL DIAGRAM OF
SURFACE PROCESS
Gas injector Gas Manifold
Well

DRY GAS
C
GAS FOR ARTIFICIAL LIFT
DRY GAS U
Producing RICH GAS LNG
S
Well
Gas Plant
T
OIL + WATER + GAS
Flow O
Station
M
Water injector OIL
Well STEAM WATER OIL E
R
WATER
Water Treatment S

Gathering Separation Treatment Storage Transportation

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SURFACE PROCESSES

GATHERING

SEPARATION

TREATMENT

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SURFACE PROCESSES

GATHERING

SEPARATION

TREATMENT

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Gathering
From the wellhead to the separator

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Gathering
To General
Flowline Separator

Wellhead TT

PT

Flow Station

Test line
 To Test Separator, Tank
or MFM

TT
PT

Wells
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Gathering System
CONVENTIONAL PRODUCTION MANIFOLD

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Surface Gathering System
Manifold-center gathering system (radial
gathering system)

Wells

Gathering Center
& Flow Station

Production
Manifold
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Surface Gathering System
Trunk-line gathering system (axial
gathering system) Gathering Center
Wells & Flow Station
Main trunk line

Well trunk line

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Surface Gathering System

Pipelines in series Parallel pipelines


LA LB LC A

B
A B C C

Looped
pipelines
LA LC
A
C
B
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Gathering System
NON CONVENTIONAL PRODUCTION MANIFOLD

MULTIPHASE
METER
MULTIPORT
VALVE

PIPELINES

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GATHERING SYSTEM

NON CONVENTIONAL PRODUCTION MANIFOLD WITH A


MULTIPORT VALVE

• Easy to maintain
• Inexpensive
• Simplify automation

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GATHERING SYSTEM

NON CONVENTIONAL PRODUCTION MANIFOLD WITH A


MULTIPORT VALVE

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GATHERING SYSTEM

GATHERING SYSTEM ENDS AT THE FLOW STATION

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Phase Separation

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Two-phase Oil and Gas Separation
INTRODUCTION

 The produced fluids from the wellhead are a


complex mixture of different compounds of
hydrogen and carbon, generally in presence of
water and solids
 The physical separation of these phases is one of
the basic operations in the processing, and
treatment of oil and gas
 Separator as classified as
Vertical
- Two-phase Horizontal

- Three-phase Vertical
Horizontal

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Two-phase Oil and Gas Separation
FACTORS AFFECTING SEPARATION
Characteristics of the flow stream will greatly affect the design and operation of a
separator. The following factors must be determined before separator design.
 Gas and liquid flow rates (minimum, average, and peak)
 Operating and design pressure and temperature
 Surging or slugging tendencies of the feed stream
 Physical properties of the fluids such as density and compressibility
 Designed degree of separation (e.g., removing 100% of particles greater than
10 microns)
 Presence of impurities (paraffin, sand, scale, etc.)
 Foaming tendencies of the liquids or gas
 Corrosive tendencies of the liquids or gas

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Two-phase Oil and Gas Separation

EQUIPMENT DESCRIPTION
Horizontal Separators
PRESSURE CONTROL VALVE

MIST EXTRACTOR
GAS OUT

INLET GRAVITY SETTLING SECTION

GAS-LIQUID INTERFACE

LIQUID COLLECTION SECTION

INLET DIVERTER LIQUID OUT

LEVEL CONTROL VALVE

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TWO-PHASE OIL AND GAS
SEPARATION
EQUIPMENT DESCRIPTION
Horizontal Separators

A. INLET C. DIVERTER E. MIST EXTRACTOR G. DRAINAGE

B. IMPACT ANGLE D. WAVE BREAKER F. GAS OUTLET H. LIQUID OUTLET

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TWO-PHASE OIL AND GAS
SEPARATION
EQUIPMENT DESCRIPTION
PRESSURE CONTROL VALVE
Vertical Separators
MIST GAS OUT
EXTRACTOR

GRAVITY SETTLING
SECTION

LIQUID-GAS
INLET INTERFACE

INLET DIVERTER
LEVEL CONTROL
VALVE

LIQUID COLLECTION LIQUID OUT


SECTION

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TWO-PHASE OIL AND GAS
SEPARATION
VERTICAL SEPARATORS
STANDARD Mist Extractor
• Removes smallest particles of liquid
• Utilizes collision forces
Primary Separation Section
• Removes the main volume of liquid
INLET • Brakes oil batches and
minimizes
Gravitational Separation Section
turbulencesmall particles of liquid
• Removes
• Efficiency depends on gas-liquid
properties and turbulence.
Liquid Settle Section
• Receives and disposes liquid
• Minimizes turbulence
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TWO-PHASE OIL AND GAS
SEPARATION
VERTICAL VS. HORIZONTAL SELECTION

Uses: Uses:
• Sand, paraffin, or wax production • Large volume of liquid
• Plot space is limited • High-to- medium GOR streams
• Ease of level control is desired • Foaming crudes
• Small flow rates • Three-phase separation
• Very low or very high GOR streams
Advantages:
Advantages: • Cheap than vertical
• More versatile than horizontal • Less diameter for a same gas capacity
• Liquid level control is not critical • Skid mounting and shipping
• Good bottom-drain and clean-out facilities • No counter flow (gas flow does not
• Can handle more sand, mud, paraffin, wax oppose drainage of mist extractor
without plugging • Large liquid surface area for foam
• Less tendency to re-entrainment dispersion generally reduces turbulence
• Full diameter for gas flow at top and oil flow • Large surge volume capacity
at bottom
• Occupies smaller area
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TWO-PHASE OIL AND GAS
SEPARATION
VERTICAL VS. HORIZONTAL SELECTION

Disadvantages: Disadvantages:

• More expensive than horizontal • Only part of shell available for


• Require larger diameter for a pasage of gas
• Given gas capacity, therefore, more • Occupy more space unless “stack”
• Competitive for very low GOR or mounted
• Very high GOR o scrubber application • Lquid-level control is more critical
• More difficult to skid mount and ship • More difficult to clean produced
• More difficult to reach and service sand, mud, wax, paraffin, etc
• Top-mounted instruments and safety
devices

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TWO-PHASE OIL AND GAS
SEPARATION
VESSEL INTERNALS
1) Inlet Diverters

A. Baffle plates

Tangential Baffle

Diverter Baffle

Cone Baffle
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TWO-PHASE OIL AND GAS
SEPARATION
VESSEL INTERNALS
1) Inlet Diverters

B. Centrifugal diverters

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TWO-PHASE OIL AND GAS
SEPARATION
VESSEL INTERNALS
1) Inlet Diverters

B. Centrifugal
diverters

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TWO-PHASE OIL AND GAS
SEPARATION
VESSEL INTERNALS
2) Wave Breakers
Wave
Breakers

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TWO-PHASE OIL AND GAS
SEPARATION
VESSEL INTERNALS
3) Defoaming Plates
Foam at the interface may occur when gas bubbles are liberated
from the liquid. This foam can be stabilized with the addition of
chemicals at the inlet. Many times a more effective solution is to
force the foam to pass through a series of inclined parallel plates
or tubes so as to aid in coalescence of the foam bubbles.

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TWO-PHASE OIL AND GAS
SEPARATION
VESSEL INTERNALS
4) Vortex Breaker

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TWO-PHASE OIL AND GAS
SEPARATION
VESSEL INTERNALS
5) Mist Extractor

Momentum change throws liquid Gas


to outside

Velocity decreased on inside


Gas/Liquid Inlet Coalesced Liquid fall
of turn

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TWO-PHASE OIL AND GAS
SEPARATION
VESSEL INTERNALS
5) Mist Extractor

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TWO-PHASE OIL AND GAS
SEPARATION
VESSEL INTERNALS
5) Mist Extractor

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TWO-PHASE OIL AND GAS
SEPARATION
VESSEL INTERNALS
5) Mist Extractor

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TWO-PHASE OIL AND GAS SEPARATION

VESSEL INTERNALS
5) Mist Extractor

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TWO-PHASE OIL AND GAS SEPARATION

CYCLONIC

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TWO-PHASE OIL AND GAS SEPARATOR OPERATION

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THREE-PHASE OIL AND GAS SEPARATOR OPERATION

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THREE-STAGE SEPARATION SCHEME

G
A
2000 PSIA S
HIGH PRESSURE
SEPARATOR

MIDDLE PRESSURE
W 1000 PSIA
SEPARATION

E SEDIMENTS
L
LOW PRESSURE
L SEPARATION
500 PSIA
S
SEDIMENTS 100 PSIA

OIL
SEDIMENTS
WATER

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RUTINARY OPERATION OF SEPARATORS

• Check pressure and level control instruments as much as possible.


• Actuated control valves must be frequently checked to assure that
they can open and close .
• Liquid in glass sights must be drained from time to time.
Safety Flare
valve Gas
outlet

Inlet
Liquid
outlet

Drainage

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SHUTDOWN OF PHASE SEPARATORS

4. Check that the flare valve


is open 3. Close the gas outlet valve

Safety Flare
valve Gas
outlet
2a. If vessel will be drained, adjust the
control level to drain the separator.
1. Close the inlet
valve

Inlet
Liquid
outlet

2b. If it is not necessary to drain the


Drainage separator, proceed to close the
liquid outlet valve.

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STARTING UP OF PHASE SEPARATORS

2. Set operating pressure in the


pressure control

Safety Flare
valve Gas
outlet
6. Adjust the pressure and level controls
until operation is stabilized

Inlet
4. Open the inlet
valve slowly
Liquid outlet

1. Check that the liquid outlet


Drainage valve is closed
3. Deactivate control of low level if
liquid level is below that point 5. When operating level is normal, open the outlet
liquid valve and re-activate the low level control.

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TWO-PHASE OIL AND GAS SEPARATION

POTENTIAL OPERATING PROBLEMS


1) Foamy Crudes
- Mechanical control of liquid is aggravated
- Foam has a large volume-to-weight ratio
- Uncontrolled foam bank
2) Paraffin
- Plugging of coalescing plates and mesh pad mist extractors
2) Sand
- Cutout of valve trim
- Plugging of separator internals
- Accumulation in the bottom of the separator
4) Liquid carryover and Gas Blowy
‐ Free liquid escapes with the gas phase: high liquid level, damage to
vessel internals, foam, improper design, plugged liquid outlets, or higher
flow rates that exceeds the vessel’s design rate
‐ Free gas escapes with the liquid phase: low liquid level, vortexing, or
level control failure

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OIL - WATER
SEPARATION

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OIL AND WATER SEPARATION

INTRODUCTION

Growth of water layer with


time
% Water in sample
ho

Oil
hw/h
he

Emulsion
h

hw

Water

Time

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OIL AND WATER SEPARATION

EQUIPMENT DESCRIPTION
Horizontal Separators
Horizontal Three Phase PRESSURE CONTROL VALVE

Separator
MIST EXTRACTOR
GAS OUT

INLET
GRAVITY SETTLING SECTION

INLET DIVERTER OIL AND EMULSION

WATER

WATER OUT OIL OUT

LEVEL CONTROL VALVE LEVEL CONTROL VALVE

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OIL AND WATER SEPARATION

EQUIPMENT DESCRIPTION
Horizontal Separators
Horizontal Three Phase Separator: Bucket and Weir
design

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OIL AND WATER SEPARATION

EQUIPMENT DESCRIPTION
Horizontal Separators

Horizontal Three Phase Separator: Bucket and weir design

h = ho [ 1 – (o/  w)]
Where: h = distance below the oil weir, in.
ho = desired oil pad height, in.
 o,  w = oil and water densities, lbm/ft3

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OIL AND WATER SEPARATION

EQUIPMENT DESCRIPTION
Horizontal Separators
Horizontal Three Phase Separator: Free – water
knockout (FWKO)

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OIL AND WATER SEPARATION

EQUIPMENT DESCRIPTION
Horizontal Separators
Horizontal Three Phase Separator:
Operation

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OIL AND WATER SEPARATION

EQUIPMENT DESCRIPTION
Vertical Separators

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OIL AND WATER SEPARATION

EQUIPMENT DESCRIPTION
OIL WEIR
Vertical Separators

LC LC

OIL OIL
OUT OUT
OIL

OIL OIL
LC LC

WATER
WATER WATER WATER
OUT OUT

INTERFACE LEVEL CONTROL


INTERFACE LEVEL CONTROL WITH OIL CHAMBER

Liquid level control schems


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OIL AND WATER SEPARATION

EQUIPMENT DESCRIPTION GAS EQUALIZING LINE

Vertical Separators

LC ADJUSTABLE
HEIGHT
OIL
OUT

OIL
LC

WATER

WATER
WATER
OUT
WATER LEG WITH OR WITHOUT OIL CHAMBER

Liquid level control schems


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OIL AND WATER SEPARATION

EQUIPMENT DESCRIPTION
Horizontal vs. Vertical Selection
Process related aspects:
1. Horizontal separators are not as good as vertical separators in
handling solids
2. Horizontal vessels required more plan area to perform the same
separation as vertical vessels
3. Smaller, horizontal vessels can have less liquid surge capacity than
vertical vessels sized for the same steady-state flow rate
Non-process related aspects:
1. The relief valve and some of the controls may be difficult to service
without special ladders and platforms
2. The vessels may have to be removed from a skid for trucking due
to height restrictions

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OIL AND WATER SEPARATION

VESSEL INTERNALS
• Most of the vessel internals were discussed. Two common internals not
discussed are coalescing plate and sand jets. It is possible to use
various plate or pipe coalescer designs to aid in the coalescing of oil
droplets in the water and water droplets in the oil
1) Plate Coalescers
Are skim tanks or vessels that use internal plates to improve the gravity
separation process
a) Parallel Plate Interceptor (PPI)
b) Corrugated Plate Interceptor (CPI)
2) Sand Jets and Drains

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OIL AND WATER SEPARATION

VESSEL INTERNALS
1) Plate Coalescers
a) Parallel Plate Interceptor (PPI)
Section A-A

Large Droplet Rise to Oil


Collection Surface
Water
Oil Sheet
Coalescing Plate Velocity

Oil
u
Oil Out
o Oil Droplet
 Inlet Water
Water
Out
A

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OIL AND WATER SEPARATION

VESSEL INTERNALS
b) Corrugated Plate Interceptor (CPI)
Gas
Out
Gas Out
Adjustable
Oil Out
Adjustable Oil Weir
Water Weir Oil
Flow Distribution
Baffle
Inlet
Water
Out

Drain

Drain

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OIL AND WATER SEPARATION

VESSEL INTERNALS
b) Corrugated Plate Interceptor (CPI)

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OIL & WATER TREATMENT

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CRUDE OIL TREATING SYSTEMS

Removing water from crude oil often requires additional processing


beyond gravitational separation. In selecting a treating system, several
aspect should be considered:

1. Tightness of the emulsion.


2. Specific gravity of the oil and produced water.
3. Corrosiveness of the produced crude oil, water and gas.
4. Scaling tendencies of the produced water.
5. Total volume of fluid to be treated and water percent in the fluid.
6. Paraffin-forming tendencies of the crude oil.
7. Desirable operating pressure for equipment.

Other factors or design considerations:

- Temperature, time, viscosity and vessels’ dimensions


- Laboratory analysis and field experience

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CRUDE OIL TREATING SYSTEMS

EMULSION TREATING THEORY


Forming Emulsions
Two mutually immiscible liquids
An emulsifying agent
Sufficient mechanical energy (agitation)
The difficulty of separating the emulsified water from oil depends on
the stability of the emulsion. The stability of the emulsion depends
on several factors:
1) The difference in density between the water and oil phases.
2) The size of dispersed water particles.
3) Viscosity
4) Interfacial tension
5) The presence and concentration of emulsifying agents
60 Copyright ©2012 NExT. All rights reserved
CRUDE OIL TREATING SYSTEMS

EMULSION TREATING THEORY

Forming Emulsions

Photomicrograph of normal emulsion Photomicrograph of emulsifying agent Photomicrograph of emulsifying agent


sorrounding a water droplet preventing two droplets from coalescing

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CRUDE OIL TREATING SYSTEMS

EMULSION TREATING THEORY

Emulsifying Agent
- Preference for the oil
- Preference for the water

An emulsifier tends to be insoluble in one of the liquid phases. The


emulsifying agent’s action can be visualized as one or more of the
following:
1) It decreases the interfacial tension of the water droplet
2) It forms a viscous coating on the droplets that keeps them from
coalescing into larger droplets when they collide
3) They may be polar molecules, which align themselves in such a
manner as to cause an electrical charge on the surface of the
droplets.

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CRUDE OIL TREATING SYSTEMS

EMULSION TREATING THEORY

Emulsifying Agent Solid stabilizer agent

Emulsified
Water
Droplet

Molecules stabilizer agent


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CRUDE OIL TREATING SYSTEMS

EMULSION TREATING THEORY


Demulsifiers
There are four important actions required of a demulsifier:
1. Strong attraction to the oil-water interface
2. Flocculation
3. Coalescence
4. Solid wetting

It would be unusual if one chemical structure could produce


all four desirable actions. In selecting a demulsifiers one
should keep in mind:
- Process system
- Bottle tests
- Field tests
64 Copyright ©2012 NExT. All rights reserved
CRUDE OIL TREATING SYSTEMS

GRAVITY SEPARATION

1.78 x 10-6 () Stokes’


ut = d 2 
m Law
Where ut = downward velocity of the water droplet relative to the oil
continuous phase, ft/s
dm = diameter of the water droplet, micron
 = difference in specific gravity between the oil and water
 = dynamic viscosity of the oil continuous phase, cp
Several conclusions can be drawn from Stokes’ Law:
1) The larger the size of a water droplet, the larger the square of its
diameter, and thus, the greater its downward velocity
2) The greater the difference in density between the water droplet and
the oil phase, the greater the downward velocity
3) The higher the temperature, the lower the viscosity of the oil, and
thus the greater the downward velocity.

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CRUDE OIL TREATING SYSTEMS

GRAVITY SEPARATION
Coalescence
d j – (d o) j
t= 
6  Ks

Where do = initial droplet size


d = final droplet size
 = volume fraction of the dispersed phase
Ks = empirical parameter for the particular system
j = an empirical parameter always larger than 3 and
dependent on the probability that the droplets will
bounce apart before coalescence occurs

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CRUDE OIL TREATING SYSTEMS

GRAVITY SEPARATION
Coalescence
When the energy of the oscillations is very low so that bouncing of
droplets approaches zero, j approaches 3. Assuming a value of 4, the
minimum time required to obtain a desired particle diameter can be
expressed.
 d 4 – (do) 4
t= 6  Ks
Assuming do is small relative to the droplet size we wish
to grow by coalescence in our gravity settler, the equation
can be approximated:
d4
t=
2 Ks

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CRUDE OIL TREATING SYSTEMS

GRAVITY SEPARATION

Coalescence
The following qualitative conclusions for coalescence in a gravity settler
can be drawn from this relationship:
1) A doubling of residence time increases the maximum size drop
grown in a gravity settler less than 19 %. If the value of “j” is greater
than 4 the growth in droplet diameter will be even slower.
2) The more dilute de dispersed phase, the greater the residence time
needed to “grow” a given particle size. That is, coalescence occurs
more rapidly in concentrated dispersions. This is the reason that oil
is “water washed” by entering the treating vessel below the oil-water
interface in most gunbarrels and treaters. Floculation and
coalescence therefore occur most effectively at the interface zone
between oil and water
68 Copyright ©2012 NExT. All rights reserved
CRUDE OIL TREATING SYSTEMS
GRAVITY SEPARATION
Viscosity
1) Laboratory tests at various temperatures
2) ASTM D 341
3) Beggs and Robinson Equation
 = 10x – 1
Where:  is the oil viscosity, cp
T = oil temperature, ºF
x = y (T)-1.163
y = 10z
z = 3.0324 – 0.02023 o
o = oil gravity, º API
4) eff / c = 1 + 2.5  + 10 2 (modified Vand’s equation)
Where: eff = effective viscosity, cp
c = viscosity of the continuous phase, cp
 = volume fraction of the disconinuous phase
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CRUDE OIL TREATING SYSTEMS

GRAVITY SEPARATION

Viscosity

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CRUDE OIL TREATING SYSTEMS

GRAVITY SEPARATION

Viscosity
4) The viscosity of the produced water depends on the amount of
dissolved solids in water as well as the temperature, but for most
practical applications it varies from:
1.5 to 2.0 cp at 50 ºF
0.7 to 1.0 cp at 100 ºF
0.4 to 0.6 cp at 150 ºF
When an emulsion of oil and water is formed, the viscosity of the
mixture may be substantially higher than either the viscosity of the oil
or that of the water taken by themselves

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CRUDE OIL TREATING SYSTEMS

GRAVITY SEPARATION
Viscosity

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CRUDE OIL TREATING SYSTEMS

GRAVITY SEPARATION
Temperature Effects
Adding heat to the incoming oil/water stream is the traditional method of
separating the phases.

1. Reduces the viscosity of the oil phase. This results in a more rapid
settling velocity
2. Causes a significant loss of the lower boiling point hydrocarbons
(light ends). This results in a “shrinkage” of the oil
3. Increasing treating temperature also has the disadvantage of making
the crude oil that is recovered in the storage tank heavier and thus
decreasing its value.
4. Increasing the temperature may lower the specific gravity at treater
operating pressure of both the oil and the water. In most cases, if
treating temperature  200 ºF this change can be negleted.
5. The less heat that is used, the better. Economic effect.
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CRUDE OIL TREATING SYSTEMS

GRAVITY SEPARATION

Temperature Effects

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CRUDE OIL TREATING SYSTEMS

GRAVITY SEPARATION
Heat Input Equations

The heat input and thus the fuel required for treating depend on:
- The temperature
- The amount of water in the oil
- The flow rate

It requires about twice as much energy to heat water as it does to heat


oil.

For this reason, it is beneficial to separate any free water from the
emulsion to be treated with either a free-water knockout located
upstream of the treater or an inlet free-water knockout system in the
treater itself.
Q = 16 qo T (0.5 o + 0.1)

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CRUDE OIL TREATING SYSTEMS

GRAVITY SEPARATION

Heat Input Equations


Where: Q = heat input, Btu/hr
qo = oil flow rate, bpod
T = increase in temperature, ºF
o = specific gravity of oil relative to water

And assuming that the free water has been separated from
the emulsion,
the water remaining is less than 10% of the oil, and the
treater is insulated to minimize heat losses.

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CRUDE OIL TREATING SYSTEMS

GRAVITY SEPARATION
Water Droplet Size and Retention Time
The droplet diameter is the most important single parameter to control
to aid in water settling since this term is squared in the settling equation.
A small increase in diameter will create a much larger increase in
settling rate.
Qualitatively, droplet size is expected to:
- Increase with the retention time in the coalescing section
- Increase with the heat input
- Decrease with the oil viscosity

Increasing retention time in the crude oil treating system may not be
very cost effective. Water droplet should be allowed to grow of
sufficient size to settle in the vessel.

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CRUDE OIL TREATING SYSTEMS

GRAVITY SEPARATION
Coalescing Media
Promote the coalescence of the water droplets by creating
an obstruction to the flow of the small water droplets,
promoting random collision of these droplets for
coalescence. When the droplets are large enough, they
will fall out of the flow stream by gravity.

This may allow lower treating temperatures. However, these


media have a tendency to clog with time and are difficult to
remove. They are no longer in common use.

The most common coalescing media is wood excelsior,


which is referred to as a “hay section”.

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CRUDE OIL TREATING SYSTEMS

GRAVITY SEPARATION
Electrostatic Coalescers
Coalescing of the small water drops dispersed in the crude can be
accomplished by subjecting the water-in-oil emulsion to a high-voltage
electrical field. When a non-conductive liquid (oil) containing a
dispersed conductive liquid (water) is subjected to an electrostatic field,
the conductive particles or droplets are caused to combine by one of
three physical phenomena:
1) The droplets become polarized and tend to align themselves with the
lines of electrical force.
2) Droplets are attracted to an electrode due to an induced charge
3) The electrical field tends to distort and thus weaken the film of
emulsifier sorrounding the water droplet

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CRUDE OIL TREATING SYSTEMS

GRAVITY SEPARATION

Electrostatic Coalescers
The attraction between the droplets in an electric field is
given by:
Ks 2 (dm)6
F= 4
(with S ≥ dm)
S

Where: F = attractive force between droplets


Ks = constant for system
 = voltage gradient
dm = diameter of droplets
S = distance between droplets
80 Copyright ©2012 NExT. All rights reserved
CRUDE OIL TREATING SYSTEMS

TREATING EQUIPMENT
Vertical Treaters
Vertical treater
schematic

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CRUDE OIL TREATING SYSTEMS

TREATING EQUIPMENT

Horizontal Treaters

Horizontal heater-
treater schematic

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OIL DEHYDRATION

GUN BARREL TANK


Gas
Emulsion + Gas

Water
Oil
Water Hot Water

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OIL DEHYDRATION

Heating efect in heavy crude oil viscosity


(11 °API)

g D (dw – do)2
Vs =
o

where:

Vs = Sedimentation Speed
g = Gravity acceleration
D = Water droop diameter
dw = Water density
do = Oil density
o =oil viscosity

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OIL DEHYDRATION

Combine efect of temperature increase and dilute salt in water with


specific gravity

g D (dw – do)2
Vs =
18o

Where:

Vs = Sedimentation speed
G = Gravity acceleration
D = Water droop diameter
dw = Water density
do = Oil density
o= Oil viscocity

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CRUDE OIL TREATING SYSTEMS

TREATING EQUIPMENT

Electrostatic Treaters

Horizontal
electrostatic treater
schematic

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OIL DEHYDRATION

ELECTROSTATIC DEHYDRATOR

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OIL DEHYDRATION

ELECTROSTATIC DEHYDRATION

(-) (-)
OIL
++ + +++ +
++ +
++ +
d1 ++++ +
__ __ _
___
OIL d2
++ + +++ + __ _ _
++ + _ __ _
d1
__ __ _
___

(+) (+)
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OIL DEHYDRATION

ELECTROSTATIC DEHYDRATOR

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CRUDE OIL TREATING SYSTEMS

EQUIPMENT SIZING AND THEORY


Settling Equations

Horizontal Vessels Vertical Vessels


qo  qo  1/2
d Leff = 438 d = 81.8
( ) dm2 ( ) dm2

Where d = diameter of vessel, in.


Gunbarrels qo = oil flow rate, bpod
 = oil viscosity, cp
F qo  1/2 Leff = length of coalenscing section, ft
d = 81.8  = difference in specific gravity
( ) dm2 between oil and water (relative
to water)
F = short-circuiting factor
= 1 for d < 48 inches
> 1 for d > 48 inches
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CRUDE OIL TREATING SYSTEMS

EQUIPMENT SIZING AND THEORY

Residence Time Equations

Horizontal Vessels Vertical Vessels


qo (tr)o qo (tr)o
d2 Leff = d2 h=
1.05 0.12

Where tr = retention time, min


Gunbarrels
qo = oil flow rate, bopd
F qo (tr)o h = height of the coalescing section, in.
d2 h=
0.12
F = short-circuiting factor
= 1 for d < 48 inches
> 1 for d > 48 inches
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CRUDE OIL TREATING SYSTEMS

EQUIPMENT SIZING AND THEORY


Water Droplet Size
In order to develop a treater design procedure, the water droplet size to be use
in the settling equation to achieve a given outlet water cut must be determined.
Qualitatively, it is to be expected that the minimum droplet size that must be
removed for a given water cut to:

1) Increase with retention time in the coalescing section


2) Increase with temperature, which tend to excite the system, leading to more
collisions of small droplets
3) Increase with oil viscosity, which tend to inhibit the formatiion of small
droplets from shearing that occurs in the system

Assuming that the minimum droplet size of droplets that must be settled is a
function only of oil viscosity, the following correlation was developed:

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CRUDE OIL TREATING SYSTEMS

EQUIPMENT SIZING AND THEORY


Water Droplet Size
dm1% = 200 μ0.25 for μo < 80 cp

Where dm1% = diameter of water droplet to be settled from the oil to


achieve 1% water cut, microns
μ = viscosity of the oil phase, cp
And
For electrostatic treaters
dm1% = 170 μ0.4 for 3 cp < μo < 80 cp

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CRUDE OIL TREATING SYSTEMS

EQUIPMENT SIZING AND THEORY

Water Droplet Size


For μo < 3cp
Note: The two equations intersect at 3 cp, and
qo  1/2 electrostatic treaters would not be expected to
operate less efficiently at this range.
d = 81.8 Additionally, the data from which the
( ) dm2 electrostatic treater droplet size correlation was
developed did not include oil viscosities < 7 cp

For the minimum droplet size


dm / dm1% = wc0..33
Where:
dm = diameter of water droplet to be settled from the oil to achieve a
given water cut (wc), microns
wc = water cut, percent
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CRUDE OIL TREATING SYSTEMS

EQUIPMENT SIZING AND THEORY

Water Droplet Size


Flow rate vs. treating
temperature for
convencional and
electrostatic treaters
Note: This figure represents an approximated
relationship derived from the two equations for
dm1% in terms of the flow rate of emulsion (given
in bpd) flowing vertically through a horizontal
cross-section area of 1 ft2. For a horizontal
treater with vertical flow through the coalescing
section, the flow area can be approximated as
the diameter of the vessel times the length of
the coalescing section.

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CRUDE OIL TREATING SYSTEMS

DESIGN PROCEDURE

Choose a treating temperature.

1. Determine oil viscosity at treating temperature.

2. Determine the diameter of the water droplet that must be removed


from the oil at treating temperature.

3. Determine the treater geometry necessary to satisfy settling


criteria for horizontal vessels, vertical vessels or gunbarrels.

4. Check the geometry to assure it provides sufficient retention time


for horizontal vessel, vertical vessels or gunbarrels.

5. Repeat to procedure for different assumed treating temperatures.

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EMULSIONS

Mixes of two liquids non miscible where one is dispersed, constituting


the internal phase and the other is the dispersant environment or
external phase.

Emulsion W/O Emulsion O/W Emulsion O/W/O


DIRECT REVERSE MULTIPLE

Water Water Water


Water Water Water Oil Oil Oil
Oil Oil Water Water Oil Oil
Water Oil Oil
Water Water Oil
Water Water Water

- Two non miscible liquids: oil and water


- Stabilizing agent: surfactant, soap, fines, paraffin, asphaltene
- Mix energy: agitation, pump, orifices
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SURFACTANTS

Molecules constituted by not polar part, without load, a


hydrocarbon and a polar part, with load of hetheroatoms
carbonates, sulfates and they have superficial activity, that it is
located in the interface oil / water

Water
O
CH3-CH2-CH2-(CH2)n-C
O Na
NO POLAR
POLAR

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OIL DEHYDRATION

Definition: process to separate water from oil until levels of bottom


sediment and water (BS&W) below the market specifications, typically
less than 1%.
GAS

Emulsion W/O Emulsion


O/W

OIL + WATER
WATER

GAS
OIL
WATER
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OIL DEHYDRATION

TO DESTABILIZE EMULSION IS REQUIRED:


- Destabilizing agent that reduce the external cast: surfactant, temperature, magnetic
field, salts
- Mix energy: promote effective collides
- Coalescence: union of small drops to form big drops
-
-
Water -
+
+ - +
- +
-+ +-
+ +-

- + + -+ - - + Water + -+ -

+-+- +-+-
+ +
- -
+ +
- -
+
-

+
-
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OIL DEHYDRATION
Floculation

Water Water Water Agua


Oil
Oil Oil
Temp., Dem. ,Mix.
Water Water Agua Agua Oil

Oil
Oil

Water Water

Water

Separation Coalescence

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OIL DEHYDRATION

OPERATIONAL PROCEDURE
-SETTLING TANKS
- FREE WATER KNOCKOUT
- MECHANICAL SEPARATORS
- HEATER / TREATERS
- GUN BARREL TANK
- ELECTROSTATIC
- CENTRIFUGAL
- CYCLONICS SEPARATORS

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DEHYDRATION BY SETTLING

1. Chemical Injection

2. Filled tank and


retention time

3. Water Separation
and Drainage

Water to Treatment
System

4. Oil treated
Oil to Refinery or ship

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WATER TREATMENT

USES OF PRODUCTION WASTE WATER

Recycling: Disposal:
• Steam Genaeration • Aquiefers
• Watering • River and Lake
• Enhanced Recovery • Ocean
• Animal Consumption • Re-injection
• Domestic Comsumption

Depending of final use water will have specific quality


requirements

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WATER TREATMENT

CHEMIST
- Destabilize oil/water emulsión with polymers and/or surfactants
- Solid separation with floculants and/or coagulants selected by each kind of emulsion
and solids
SEPARATOR EQUIPMENTS
- API Separator , not use by standards environment
- Surge Tanks, replace API Separator
- Coalescence Tubing
- Flotation by disolved air. DAS
- Flotation by forced air. IAF o IGF
- Plate Seaparators
- Floculators
- Sand Filters /gravel, special filler

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WATER TREATMENT

API SEPARATOR API

Water
Water
+ Oil

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WATER TREATMENT

Oil

Water + Oil

Water
Surge Tanks

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WATER TREATMENT

FLOTATION BY DISOLVED AIR

Air Oil

Water to PRESSURE
be treated Water
Water

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WATER TREATMENT
FLOTATION BY FORCED AIR

Engine

Air Inlet

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WATER TREATMENT

Gas

Part. > 150 mu and oil. < 100 ppm

Part. < 20 mu F
< 20 ppm I
L
T
E
R

Chem. Part. < 5 mu


and < 5 ppm oil

Secondary recovery purpose

Disposal Injection

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