BUBBLE P

T= 100 C

Bahan 1 Bahan 2
Antoine
Benzene Toluen
A= 13.7819 13.932
B= 2726.81 3056.96 ln P = A - B/T+C
C= 217.572 217.625
D=

Komponen Psat (kPa) Xi P (kPa) Yi

Benzene 180.452793 0.33 0.544808
109.3034
Toluen 74.2597197 0.67 0.455192
Total 1 1

Chart Title
0.54481 109.3034337 12
0
0.1 10
0.2 8
0.3
P (kPa)

0.4 6

0.5 4
0.6
2
0.7
0.8 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
0.9
1 xi,yi

BUBBLE T

P= 120 kPa

Bahan 1 Bahan 2
Antoine
Benzene Toluen
A= 13.7819 13.932
B= 2726.81 3056.96
C= 217.572 217.625
D= 0 0

Komponen Tsat (C) xi P(kPa)

Benzene 85.5952481 0.33
106.4151
Toluene 116.66963 0.67
Total 1

Tebak T (°C) 70 105.3068512 103.1968 103.3129 103.3065 103.3068544984 103.3068

P1 sat 73.6790241 207.8041739 196.5748 197.1802 197.1467 197.1485827057 197.1485
P2 sat 27.2135945 86.98453056 81.73413 82.01629 82.00067 82.0015372899 82.00149
a1 1 1 1 1 1 1 1
a2 2.70743448 2.388978507 2.405052 2.404159 2.40421 2.40420594 2.404206
Psat 207.804174 196.5748165 197.1802 197.1467 197.1486 197.1484803903 197.1485
Tsat 105.306851 103.1968394 103.3129 103.3065 103.3069 103.3068349021 103.3068

Komponen yi yi yi yi yi yi yi
Benzene 0.20261732 0.571461478 0.540581 0.542246 0.542154 0.5421586024 0.542158
Toluen 0.15194257 0.485663629 0.456349 0.457924 0.457837 0.4578419165 0.457842
Total 0.35455989 1.057125107 0.99693 1.00017 0.999991 1.000000519 1

BUBBLE T

Sebelum dilakukan Goal Seek Sesudah dilakukan Goal Seek

diketahui xi 0.33 diketahui xi 0.33
P 120 kPa P 120
ditanya yi ditanya yi
T T

asumsi T 70 °C asumsi T 103.307

P1sat 73.67902408 P1sat 197.1492
P2sat 27.21359446 P2sat 82.00184
P 42.54718624 P 120.0005
yi 0.571461478 yi 0.542158
 DEW P

T= 100 C 318.15

Bahan 1 Bahan 2
Antoine
Benzene Toluen
A= 13.7819 13.932
B= 2726.81 3056.96
C= 217.572 217.625
D= 0 0

Komponen Psat (kPa) yi P (kPa)

Benzene 180.452793 0.33
92.15638
Toluen 74.2597197 0.67
1

Chart Title yi xi Ptotal (kPa)

0.16852942 92.15637652
0
0.1
0.2
0.3
P-xi
P-yi 0.4
0.5
0.6
0.7
0.8
0.5 0.6 0.7 0.8 0.9 1
0.9
xi,yi 1

DEW T

P= 120 kPa

Bahan 1 Bahan 2
Antoine
Benzene Toluen
A= 13.7819 13.932
B= 2726.81 3056.96
C= 217.572 217.625
D= 0 0

Komponen Tsat (C) yi P(kPa)

 Benzene 85.5952481 0.33
106.4151
Toluene 116.66963 0.67
Total 1

103.3068 Tebak T (°C) 70 113.6834493 108.6836

197.1485 P1 sat 73.6790241 257.2777325 226.7856
82.00149 P2 sat 27.2135945 110.5059767 95.93687
1 a1 1 1 1
2.404206 a2 2.70743448 2.328179345 2.363905
197.1485 Psat 257.277732 226.7856193 229.6579
103.3068 Tsat 113.683449 108.6836006 109.1756

yi Komponen xi xi xi
0.542158 Benzene 0.5374664 0.153919267 0.174614
0.457842 Toluen 2.95440575 0.727562457 0.838051
1 Total 3.49187215 0.881481724 1.012665

DEW T

kukan Goal Seek Sebelum dilakukan Goal Seek

diketahui yi 0.33
kPa P 120 kPa
ditanya xi
P

asumsi T 70
P1sat 73.67902408
P2sat 27.21359446
P 34.36551933
xi 0.153919267

Metode Goalseek :
- Kalau yg dicari Bubble T, maka pakai rumus Bubble P
- Kalau yg dicari Dew T, maka pakai rumus Dew P
K

xi
0.168529
0.831471
1

12

10

8
P (kPa)

6
P-yi
4 P-xi

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
yi, xi
 109.1756 109.1264 109.1313 109.1308 109.1309 109.1309
229.6579 229.3694 229.3982 229.3953 229.3956 229.3956
97.29966 97.16267 97.17634 97.17498 97.17511 97.1751
1 1 1 1 1 1
2.360316 2.360674 2.360638 2.360642 2.360642 2.360642
229.3694 229.3982 229.3953 229.3956 229.3956 229.3956
109.1264 109.1313 109.1308 109.1309 109.1309 109.1309

xi xi xi xi xi xi
0.17243 0.172647 0.172626 0.172628 0.172628 0.172628
0.826313 0.827478 0.827362 0.827374 0.827372 0.827372
0.998744 1.000126 0.999987 1.000001 1 1

DEW T

Seek Sesudah dilakukan Goal Seek

diketahui yi 0.33
P 120
ditanya xi
P

asumsi T 109.1309
P1sat 229.3956
P2sat 97.17509
P 120
xi 0.172628

1
Flash Calculation
a. n-C5/n-C6/n-C7
T= 200 F 366.483 k 93.333 °C
P= 2 atm 202.65 kPa
Component zi T P A B C
n-C5 0.25 13.9778 2554.6 -36.2529
n-C6 0.45 366.4833 202.65 14.0568 2825.42 -42.7089
n-C7 0.3 13.9008 2932.72 -55.6356

V/F = 0.461883 L = 0.538117

Komponen Psat (kPa) Ki xi yi
n-C5 513.8799 2.5358 0.146254 0.37087
n-C6 206.4984 1.01899 0.446087 0.454559
n-C7 87.02652 0.429443 0.407349 0.174933
Total 0.99969 1.000361
b. Acetone/Acetonitrile/Nitromethane
T= 300 F
P= 6.8 atm
Component zi T P A B C
Acetone 0.45 14.3145 2756.22 228.06
Acetonitrile 0.35 148.8889 689.01 14.895 3413.1 250.523

V/F = 0.603818 L = 0.396182

Komponen Psat (kPa) Ki xi yi
Acetone 1099.466 1.595719 0.330954 0.528109
Acetonitrile 572.313 0.830631 0.389871 0.323839
Nitromethane 1 0.001451 0 0
Total 0.720825 0.851949
BUBBLE P

T= 45 C

Bahan 1 Bahan 2
Antoine
Met MA
A= 16.5785 14.2456
B= 3638.27 2662.78 ln P = A - B/T+C
C= 239.5 219.69
D=

KomponenPsat (kPa) Xi P (kPa) Yi

Benzene 44.26546 0.25 0.18332
60.36632
Toluen 65.73328 0.75 0.81668
Total 1 1

Chart Title
0.18332 60.36632 12
0
0.1 10
0.2 8
0.3
P (kPa)

6 P-xi
0.4 P-yi
0.5 4
0.6
2
0.7
0.8 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.9
1 xi,yi

BUBBLE T

P= 101.33 kPa

Bahan 1 Bahan 2
Antoine
Met MA
A= 16.5785 14.2456
B= 3638.27 2662.78
C= 239.5 219.69
D= 0 0

KomponenTsat (C) xi P(kPa)

Met 64.70019 0.85
63.52997
MA 56.89874 0.15
Total 1

Tebak T (°C) 100 64.48794 63.57017 63.54232 63.54147 63.5414462 63.54145 63.54145
P1 sat 351.4074 100.4874 96.91056 96.80369 96.80044 96.800338 96.80033 96.80033
P2 sat 371.0525 131.0377 127.1193 127.0018 126.9982 126.998106 126.9981 126.9981
a1 1 1 1 1 1 1 1 1
a2 0.947056 0.766858 0.762359 0.762223 0.76222 0.76221875 0.762219 0.762219
Psat 100.4874 96.91056 96.80369 96.80044 96.80034 96.8003349 96.80033 96.80033
Tsat 64.48794 63.57017 63.54232 63.54147 63.54145 63.5414454 63.54145 63.54145

Komponenyi yi yi yi yi yi yi yi
Benzene 2.947758 0.842932 0.812928 0.812031 0.812004 0.81200323 0.812003 0.812003
Toluen 0.549273 0.193977 0.188176 0.188002 0.187997 0.1879968 0.187997 0.187997
Total 3.497031 1.036908 1.001104 1.000034 1.000001 1 1 1

BUBBLE T

Sebelum dilakukan Goal Seek Sesudah dilakukan Goal Seek

diketahui xi 0.85 diketahui xi 0.33
P 101.33 kPa P 120 kPa
ditanya yi ditanya yi
T T

asumsi T 70 °C asumsi T 103.307

P1sat 124.3605 P1sat 389.6802
P2sat 156.6124 P2sat 404.0837
P 129.1983 P 399.3305
yi 0.818172 yi 0.322025

Metode Goalseek :
- Kalau yg dicari Bubble T, maka pakai rum
- Kalau yg dicari Dew T, maka pakai rumus
 DEW P

T= 45 C 318.15 K

Bahan 1 Bahan 2
Antoine
Met MA
A= 16.5785 14.2456
B= 3638.27 2662.78
C= 239.5 219.69
D= 0 0

KomponenPsat (kPa) yi P (kPa) xi

Met 44.26546 0.6 0.69016
50.91706
MA 65.73328 0.4 0.30984
1 1

yi xi Ptotal (kPa) 12
0.69016 50.91706
10
0 0 74.25972
0.1 0.043725 78.90301
8
0.2 0.093283 84.16571
0.3 0.149924 90.18059 P (kPa)
6
P-xi
P-yi 0.4 0.215284 97.12136
0.5 0.291543 105.2196 4
0.6 0.381677 114.7912
0.7 0.489851 126.2785 2
0.8 0.622082 140.3205
0.8 0.9 1 0
0.9 0.7874 157.8761 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
1 1 180.4528 yi, xi

DEW T

P= 101.3 kPa

Bahan 1 Bahan 2
Antoine
Met MA
A= 16.5785 14.2456
B= 3638.27 2662.78
C= 239.5 219.69
 D= 0 0

KomponenTsat (C) yi P(kPa)

Met 64.69266 0.33
59.46504
MA 56.89024 0.67
Total 1

Tebak T (°C) 70 60.96282 60.09317 60.00905 60.00091 60.00012

P1 sat 124.3605 87.32302 84.30701 84.01993 83.99219 83.98951
P2 sat 156.6124 116.4885 113.1033 112.78 112.7487 112.7457
a1 1 1 1 1 1 1
a2 0.794066 0.749628 0.745398 0.74499 0.74495 0.744946
Psat 87.32302 84.30701 84.01993 83.99219 83.98951 83.98925
Tsat 60.96282 60.09317 60.00905 60.00091 60.00012 60.00005

Komponenxi xi xi xi xi xi
Met 0.268807 0.38282 0.396515 0.39787 0.398001 0.398014
MA 0.433369 0.582641 0.60008 0.6018 0.601967 0.601983
Total 0.702176 0.965461 0.996595 0.99967 0.999968 0.999997

DEW T

Sebelum dilakukan Goal Seek Sesudah dilakukan Goal Seek

diketahui yi 0.4 diketahui yi
P 101.33 kPa P
ditanya xi ditanya xi
T P

asumsi T 100 asumsi T

P1sat 351.4074 P1sat
P2sat 371.0525 P2sat
P 362.9366 P
xi 0.413124 xi

alseek :
cari Bubble T, maka pakai rumus Bubble P
cari Dew T, maka pakai rumus Dew P
 P-yi
P-xi

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

yi, xi
 60.00005 60.00004 60.00004
83.98925 83.98923 83.98922
112.7454 112.7454 112.7454
1 1 1
0.744946 0.744946 0.744946
83.98923 83.98922 83.98922
60.00004 60.00004 60.00004

xi xi xi
0.398015 0.398015 0.398015
0.601984 0.601985 0.601985
1 1 1

Sesudah dilakukan Goal Seek

0.33
120

60.00812
84.01677
112.7764
101.33
0.398003

1
Flash Calculation
a. Acetone / Acetronitile
T= F 340 k 66.850 °C
P= atm 115 kPa
Component zi T P A B C
Acetone 0.75 14.3145 2756.22 228.06
Acetronitile 0.25 340 115 14.895 3413.1 250.523

V/F = 0.999976 L = 2.36E-05

Komponen Psat (kPa) Ki xi yi
Acetone 143.8153 1.250568 0.59973 0.750004
Acetronitile 62.85164 0.546536 0.457417 0.249995

Total 1.057148 0.999999

b. Acetone/Acetonitrile/Nitromethane
T= 360 K 86.85 C
P= 0.8 atm
Component zi T P A B C
Ethanol 0.25 14.3145 2756.22 228.06
1-Propanol 0.75 86.85 81.06 14.895 3413.1 250.523

V/F = 0.999944 L = 5.57E-05

Komponen Psat (kPa) Ki xi yi
Ethanol 260.3676 3.212036 0.077835 0.25001
1-Propanol 118.9025 1.466846 0.51131 0.750013

Total 0.589145 1.000023

Multicomponent Distillation

Fungsi

Data yagdiketahui
P enriching section = 2 atm
P feed = 1 atm
P reboiler = 2 atm
Feed
Komponen BM Massa (kg) Mol (kmol) Xf

C2H5OH (LK) 46 136.38 2.9647826087 0.060388503

H2O (HK) 18 773.08 42.948888889 0.874809204
CH3COOH 60 63.63 1.0605 0.021600912
C3H8O3 92 195.13 2.1209782609 0.043201381
49.095149758 1

Konstanta Antoine
Boiling
Komponen A B C
Ponit (K)
C2H5OH (LK) 351.5 18.9119 3803.98 -41.68
H2O (HK) 373.2 18.3036 3816.44 -46.13
CH3COOH 391.1 16.808 3405.57 -56.34
C3H8O3 563 17.2392 4487.04 -140.2

Penyelesaian :

A. Mencari kondisi operasi feed, D & B

FEED Mencari temperatur umpan

P feed 1 atm 760

Ttebak 372.549384 K 99.399383672
Komponen Xf Pi (mmHg) Ki ai ai.Xf yF

C2H5OH (LK) 0.0604 1660.6701 2.1851 2.2327 0.1348 0.1320

H2O (HK) 0.8748 743.7982 0.9787 1.0000 0.8748 0.8562
CH3COOH 0.0216 419.0608 0.5514 0.5634 0.0122 0.0119
C3H8O3 0.0432 0.1259 0.0002 0.0002 0.0000 0.0000
Jumlah 1.0000 3.7963 1.0218 1.0000

Asumsi distribusi distilat dan bottom

1. Etanol (LK) di overhead 95% feed
2. Air (HK) di Bottom 95% feed ,maka :

Komponen mol D mol B mol (D/B) log (D/B) log a

C2H5OH (LK) 2.8165 0.1482 19.0000 1.2788 0.3488
H2O (HK) 2.1474 40.8014 0.0526 -1.2788 0.0000
 -3.105655194
-28.93022393

m= 7.3317 slope
c= -1.2788 intercept

Komponen log ai log (D/B) (D/B) kmol D xD

C2H5OH (LK) 0.34882822 1.2787536 19.0000 2.8165 0.5673

H2O (HK) 0 -1.2787536 0.0526 2.1474 0.4325
CH3COOH -0.2491781 -3.1056552 0.0008 0.0008 0.0002
C3H8O3 -3.7714901 -28.930224 0.0000 0.0000 0.0000
4.9648 1.0000

Pengecekan pemilihan Light dan Heavy Key

LK = C2H5OH HK = H2O
Penentuan Pendistribuan komponen
D X xD
Komponen Xf xD Keterangan
F X xF
C2H5OH (LK) 0.0603885 0.56730036 0.95 Terdistribusi
H2O (HK) 0.8748092 0.43253229 0.05 Terdistribusi
CH3COOH 0.02160091 0.00016734 0.0007834376 Terdistribusi
C3H8O3 0.04320138 5.0166E-30 1.174292E-29 Terdistribusi
Jumlah 1 1

Bubble Point Distilat

P enrich 2 atm 1520 mmHg
T tebak 377.903584 K
Komponen xD Pi Ki yD

C2H5OH (LK) 0.5673 1994.3222 1.3121 0.7443

H2O (HK) 0.4325 898.2549 0.5910 0.2556
CH3COOH 0.0002 501.3687 0.3298 0.0001
C3H8O3 0.0000 0.1945 0.0001 0.0000
Jumlah 1.0000

Dew Point Distilat

P enrich 2 atm 1520 mmHg
T tebak 382.4129 K
Komponen yD Pi Ki xD

C2H5OH (LK) 0.5673 2316.4445 1.5240 0.8646

H2O (HK) 0.4325 1048.0672 0.6895 0.2982
CH3COOH 0.0002 580.4489 0.3819 0.0001
C3H8O3 0.0000 0.2764 0.0002 0.0000
1.1629
Jumlah

BOTTOM mencari temperatur bubble dan dew point

Komponen kmol B xB

C2H5OH (LK) 0.1482 0.0034

H2O (HK) 40.8014 0.9246
CH3COOH 1.0597 0.0240
C3H8O3 2.1210 0.0481
Jumlah 44.1303 1.0000

Bubble Point Bottom

P enrich 2 atm 1520 mmHg
T tebak 395.605522 K

Komponen xB Pi (mmHg) Ki yB
C2H5OH (LK) 0.0034 3511.9704 2.3105 0.0078
H2O (HK) 0.9246 1608.6029 1.0583 0.9785
CH3COOH 0.0240 871.2536 0.5732 0.0138
C3H8O3 0.0481 0.7196 0.0005 0.0000
1.0000 1.0000

Dew Point Bottom

P enrich 2 1520
T tebak 395.626692 K
Komponen yB Pi (mmHg) Ki xB

C2H5OH (LK) 0.0034 3514.2288 2.3120 0.0078

H2O (HK) 0.9246 1609.6673 1.0590 0.9791
CH3COOH 0.0240 871.7995 0.5736 0.0138
C3H8O3 0.0481 0.7206 0.0005 0.0000
1.0000 1.0007

Komposisi vapor, cair Distilat dan Bottom berdasarkan VLE

Feed Distilat Bottom
Komponen
xF yF xD yD xB yB
C2H5OH (LK) 0.0604 0.1320 0.8646 0.7443 0.0078 0.0078
H2O (HK) 0.8748 0.8562 0.2982 0.2556 0.9791 0.9785
CH3COOH 0.0216 0.0119 0.0001 0.0001 0.0138 0.0138
C3H8O3 0.0432 0.0000 0.0000 0.0000 0.0000 0.0000
Jumlah 1.0000 1.0000 1.1629 1.0000 1.0007 1.0000

Mol Feed 49.0951498

Mol Distilat 4.9648
Mol Bottom 44.1303
 Feed Distilat Bottom
Komponen
xF nF xD nD xB nB
C2H5OH (LK) 0.0604 2.9648 0.8646 2.8165 0.0078 0.1482
H2O (HK) 0.8748 42.9489 0.2982 2.1474 0.9791 40.8014
CH3COOH 0.0216 1.0605 0.0001 0.0008 0.0138 1.0597
C3H8O3 0.0432 2.1210 0.0000 0.0000 0.0000 2.1210
1.0000 49.0951 1.1629 4.9648 1.0007 44.1303

Neraca Massa
Komponen BM mF mD mB

C2H5OH (LK) 46 136.3800 129.5610 6.8190

H2O (HK) 18 773.0800 38.6540 734.4260
CH3COOH 60 63.6300 0.0499 63.5801
C3H8O3 92 195.1300 0.0000 195.1300
Jumlah 168.2649 999.9551
1168.2200 1168.2200

Stage(𝑋𝑙𝑘⁡𝑑𝑖𝑠𝑡𝑖𝑙𝑎𝑡/𝑋ℎ𝑘⁡𝑑𝑖𝑠𝑡𝑖𝑙𝑎𝑡)(𝑋ℎ𝑘⁡𝐵𝑜𝑡𝑡𝑜𝑚/𝑋𝑙𝑘⁡𝑏𝑜𝑡𝑡𝑜𝑚) 〗 /(log⁡(α𝐿𝑎𝑣))
log⁡〖
B. Menghitung Jumlah
NM =

Xlkd 0.5673 Xlkb 0.0034

Xhkd 0.4325 Xhkb 0.9246
Alfa lkd 2.2202 Alfa lkb 2.1832
Alfa av 2.2017 Nm 7.4614
jumlah tray teoritis 6.4614

C. Menentukan Reflukx minimum

Tdewpoint distilat 382.4129
Tbibble point botttom 395.605522
389.009211
Tfeed avg
115.859211 asumsi,q = 1
Teta tebak 2
0.56885566

Komponen Pi(mmHg) Ki ai xf aixf/ai-teta xd

C2H5OH (LK) 0.0000

H2O (HK) 0.0000
CH3COOH 0.0000
C3H8O3 0.0000
0.0000
 log ai

0.3488
0.0000
-0.2492
-3.7715
0.579356

1.5000

f(x) = 7.3317096334x - 1.278753601

1.0000 R² = 1

0.5000

0.0000
0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000
1.5000

f(x) = 7.3317096334x - 1.278753601

1.0000 R² = 1

0.5000

0.0000
0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000

-0.5000

-1.0000

-1.5000
Col umn E Li nea r (Col umn E)
 Komponen Pi(mmHg) Ki ai xf aixf/ai-teta xd

C2H5OH (LK) 2863.535271 1.883904783 2.196311 0.0604 0.675621

H2O (HK) 1303.793144 0.857758648 1 0.8748 2.02904
CH3COOH 714.0078347 0.469741996 0.547639 0.0216 0.021601
C3H8O3 0.451644904 0.000297135 0.000346 0.0432 #VALUE!

aixd/ai-teta
aixd/ai-teta