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Trilon C Types TI en
Trilon C Types TI en
Trilon C Types TI en
TI/EVD 1153 e
January 2007 Page 1 of 11
Trilon® C types
® =R
egistered trademark of
BASF Aktiengesellschaft
Trilon CS
Trilon C Liquid
Trilon C Powder
Organic chelating agents used to control the concentration of metal
ions in aqueous systems
TI/EVD 1153 e January 2007 Page of 11 Trilon C types
Contents
Properties Page
Chemical nature 3
Chemical and physical data 4
Complex formation 5
Chemical stability 7
Corrosion 8
Applications
Laundry detergents 9
Cleaners 9
Soap 9
Textile processing 9
Pulp and paper 9
Other applications 10
Safety
Storage 10
Ecology and toxicology 11
Labelling 11
Note 11
TI/EVD 1153 e January 2007 Page of 11 Trilon C types
Properties
COOH
TI/EVD 1153 e January 2007 Page of 11 Trilon C types
Calcium binding capacity mg CaCO3/g t. q. approx. 285 approx. 100 approx. 210
(BASF method, pH 11)
The above information is correct at the time of going to press. It does not necessarily form part of the product
specification.
Viscosity mPa·s
250
150
100
50
0
-10 0 10 20 30
Temperature (°C)
Viscosity as a function of temperature
Complex formation he most important property of the Trilon C types is their ability to form
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water-soluble complexes with polyvalent ions (eg. calcium, magnesium,
lead, copper, zinc, cadmium, mercury, manganese, iron, aluminium) over
a wide pH range from 1 to 13.5. DTPA usually forms 1 : 1 complexes, i. e.
1 mol of DTPA chelates binds to 1 mol of metal ions. These complexes
remain stable, especially in alkali media and even at temperatures of up to
100 °C.
rom the law of mass action, we the equation for the stability constant K for
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1 : 1 complexes can be written as follows:
[MeZ(m-n)-]
K = ––––––––––––––
[Men+] [Zm-]
where
[MeZ(m-n)-] is the concentration of the chelate that is formed
[Men+] is the concentration of free, positively charged metal
ions
Fe3+ 27.9
Hg2+ 26.7
Cu2+ 21.5
Ni2+ 20.2
Co2+ 19.3
Cd2+ 19.3
Pb2+ 18.9
Zn2+ 18.6
Fe2+ 16.0
Mn2+ 15.6
Ca2+ 10.9
Mg2+ 9.0
In aqueous solutions, DTPA competes for metal ions with other anions such
as hydroxide, sulphate, sulphide, carbonate and oxalate that form sparingly
soluble metal salts. The formation of chelates reduces the concentration of
free metal ions [Men+] to such an extent that the solubility products of many
sparingly soluble metal salts are no longer exceeded. The result is that the
salts no longer precipitate or may even redissolve.
Conditional stability constants [log Kcond] take into account the stability
constant K as well as the acid base dissociation equilibria.
TI/EVD 1153 e January 2007 Page of 11 Trilon C types
log K cond
20
18
16
14
12
10
8
Ca2+
6
Cu2+
4 Fe3+
Mg2+
2
Mn2+
0
0 2 4 6 8 10 12 14
pH
Conditional stability constants for selected DTPA chelates
The Trilon C types are resistant to strong acids and bases. They are gradu-
ally broken down by chromic acid, potassium permanganate and other
strong oxidizing agents. Stability in the presence of hydrogen peroxide,
percarbonate and perborate is sufficient for joint application. Nevertheless,
we do not recommend combining Trilon C types and peroxides in liquid
formulations.
TI/EVD 1153 e January 2007 Page of 11 Trilon C types
Corrosion he Trilon C types stabilize polyvalent metal ions, which means that they can
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increase the rate at which metals dissolve. Nevertheless, with the exception
of aluminium, an oxidizing agent such as air always has to be present for
corrosion to take place. Unalloyed steel is prone to corrosion in media that
contain air, but corrosion can be reduced substantially if the pH is in the
alkaline range and can be eliminated almost completely if oxygen and other
oxidizing agents are excluded. With the exception of aluminium, metals that
are cleaned with Trilon C types in the slightly alkaline range, which is the
optimum pH range for the Trilon C types, are much less prone to corrosion
than if they are cleaned with acids.
The only type of corrosion that has been observed with the Trilon C types
is general corrosion: pitting or stress cracking have not been observed
in media with a low chloride content. One of the advantages of the
Trilon C types is that they can be supplied with very low chloride contents
(< 20 mg/kg).
ighly alloyed austenitic stainless steels such as AISI/SAE 321 are very
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effective for vessels that are used to store and transport the Trilon C types at
temperatures of up to 60 °C.
Applications
he Trilon C types are used sequester free metal ions in aqueous systems.
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They are used to soften water and to remove traces of alkaline earth and
heavy metals.
The Trilon C types are also very effective for stabilizing bleach.
Laundry detergents ike the Trilon B types, the Trilon C types can be used to stabilize perborate
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and percarbonate in powder detergents. Small amounts of complexing
agents, as little as 0.5 – 1.0 % expressed as the active substance, can be
added to prevent traces of heavy metals form catalyzing the decomposition
of hydrogen peroxide and other types of bleach. These heavy metals, which
mainly consist of iron, copper and manganese, originate from the walls of
pipes, the soil contained in the laundry and the other ingredients of the
detergent. Peroxide bleach can break down fluorescent whitening agents,
cause coloured laundry to change shade and damage fabrics in the pres-
ence of heavy metal ions. The Trilon C types protect fabrics by sequestering
heavy metals.
Cleaners he Trilon C types can be employed in all types of cleaner and degreaser
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formulations for industrial and institutional applications. They prevent hard-
ness ions and heavy metal ions from precipitating. Inorganic solids of this
type can form scale and deposits in tanks, pipes, and nozzles and on hard
surfaces. The Trilon C types boost the performance of the surfactants con-
tained in cleaner formulations and ensure that their performance remains
undiminished during the whole cleaning process.
Soap he Trilon C types can be added to curd soap, toilet soap and shaving
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soap at rates of between 0.3 % and 1 % to prevent it becoming rancid and
discoloured. The heavy metals responsible for this are usually contained in
the tallow, fatty acids and other raw materials, but soap can also be con-
taminated with metallic particles during drying, milling, plodding or stamping.
Textile processing he Trilon C types are employed in the textile industry in pretreatment,
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aftertreatment and dyeing processes to prevent insoluble substances such
as boiler scale and lime soaps from precipitating. They ensure that the
treatment process remains effective over the whole working life of the bath.
In bleaching processes, the disruptive heavy metal ions that are washed
out of cotton, wool and blended fabrics have to be sequestered with
Trilon C types to prevent them from catalysing the decomposition of
peroxide bleach. The bleach would otherwise decompose very quickly.
The Trilon C types enable bleaching costs to be reduced substantially.
he Trilon C types can also be used to stabilize dyes. They protect fabrics
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from incrustation and prevent dyes from being precipitated by calcium or
magnesium salts.
Pulp and paper he Trilon C types and Trilon B types are used to stabilize peroxide and
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hydrosulphite bleach by sequestering disruptive metal ions, especially Fe3+,
Mn2+ and Cu2+. These metals are washed out of the pulp in the form of their
complexes.
TI/EVD 1153 e January 2007 Page 10 of 11 Trilon C types
In reductive bleaching processes with sodium dithionite, the Trilon C types
and Trilon B types are used to sequester Fe3+ ions that would otherwise
react with phenolic compounds to form strongly coloured complexes.
The Trilon C types and Trilon B types have also been shown to perform
well in two-stage bleaching processes with peroxide and hydrosulphite or
peroxide and peroxide.
echnological advances in the field of paper production have had the effect
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that paper machine white water circuits are operated at a higher degree of
closure. This has resulted in the increased formation of scale and deposits in
pipes and evaporators, etc., and on the pulp itself. The Trilon C types offer a
simple means of softening the water. The Trilon C types are also capable of
dissolving scale that consists of calcium carbonate, calcium sulphate or
calcium oxalate in the 9 – 12 pH range.
Other applications he Trilon C types can be employed very effectively as setting retarders in
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the production of plaster.
he Trilon C types are very strong complexing agents, which makes them
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very effective for removing scale formed by substances such as barium
sulphate.
rilon CS is a very pure grade of the free acid of DTPA. It is very effective for
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complexing metals that are used as micronutrients for plants.
Safety
e know of no ill effects that could have resulted from using the
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Trilon C types for the purpose for which they are intended and from
processing them in accordance with current practice.
ccording to the experience we have gained over many years and other
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information at our disposal, the Trilon C types do not exert any harmful
effects on health, provided that they are used properly, due attention is
given to the precautions necessary for handling chemicals, and the
information and advice given in our Safety Data Sheets are observed.
Storage rilon C Liquid should not be stored at temperatures below 0 °C, because
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this can cause it to precipitate. It can be reconstituted by heating it briefly to
40 – 50 °C and stirring.
rilon CS has a shelf life of two years, provided it is stored in its original
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packaging and kept tightly sealed.
he Trilon C Liquid has a shelf life of one year in its tightly sealed original
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packaging.
Tests are still being performed to assess the shelf life of Trilon C Powder.
We would recommend storing the Trilon C liquid in tanks made from
AISI 316 Ti or AISI 321 stainless steel.
Ecology and toxicology lease refer to the latest Safety Data Sheets for ecological and toxicological
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information.
Labelling lease refer to the latest Safety Data Sheets for detailed, up-to-date
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information on classification, labelling and product safety.
Note
The data contained in this publication are based on our current knowledge
and experience. In view of the many factors that may affect processing
and application of our product, these data do not relieve processors from
carrying out their own investigations and tests; neither do these data imply
any guarantee of certain properties, nor the suitability of the product for
a specific purpose. Any descriptions, drawings, photographs, data, pro-
portions, weights etc. given herein may change without prior information
and do not constitute the agreed contractual quality of the product. It is
the responsibility of the recipient of our products to ensure that any
proprietary rights and existing laws and legislation are observed.
January 2007
BASF Aktiengesellschaft
Performance Chemicals for
Detergents and Formulators
67056 Ludwigshafen, Germany
www.basf.com/detergents-formulators