PHYSICAL CHEMISTRY By: Shailendra Kumar

PHYSICAL CHEMISTRY
by: SHAILENDRA KR.
Meq. Approach
Classes at: -
SCIENCE TUTORIALS; Opp. Khuda Baksh Library, Ashok Rajpath, Patna
PIN POINT STUDY CIRCLE; House No. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna

Topic: Volumetric Analysis

1) 8 g NaOH are present in 200 mL solution. The 9) The weight of CuSO4.5H2O (mol.wt. 249.5)
normality of the solution is : present in 100 mL N/10 solution is :
(1) 1 (2) 2 (1) 2.495 g (2) 1.2475 g
(3) 3 (4) 4 (3) 3.475 g (4) 4.5 g
2) The normality of concentrated sulphuric acid of 10) 200 mL of 0.3 M-HCl were mixed with 100 mL of
specific gravity 1.80 and containing 98.0 percent 0.3 M-NaOH. The strength of the resulting
H2SO4 by weight is : solution in terms of normality is :
(1) 10 (2) 30 (1) 0.5 (2) 0.4
(3) 32 (4) 36 (3) 0.2 (4) 0.1
3) The normality of 0.5 M-H3PO4 solution is : 11) 25 mL of HCl liberates 10 mL of CO2 at S.T.P.
(1) 1 (2) 2.5 when reacting with excess of CaCO3. The
(3) 3.5 (4) 1.5 normality of HCl is :
4) 8 g of sodium hydroxide were dissolved in 100 (1) 0.03 (2) 0.0357
mL of water. The whole of this solution (3) 0.04 (4) 0.057
neutralises completely : 12) One molar 100 mL sodium hydroxide and 10
(1) 10 mL of 5 N-H2SO4 molar 10 mL of sulphuric acid are mixed together,
(2) 20 mL of 5 M-H2SO4 the resulting solution will be :
(3) 20 mL of 2.5 M-H2SO4 (1) Acidic (2) Basic
(4) 30 mL of 5 M-H2SO4 (3) Neutral (4) Alkaline
5) To 100 mL M/10 HCl is added 100 mL M/ 13) How much anhydrous sodium carbonate should
10Na2CO3. The resulting mixture will be : be weighed out for the preparetion of 500 mL of
(1) Acidic (2) Neutral 4 N-Na2CO3 solution ?
(3) Alkaline (4) None of these (1) 5.3 g (2) 10.6 g
6) 100 mL of 0.3 N-HCl was mixed with 200 mL of (3) 10.6 g (4) 106 g
0.6 N-H2SO4. The normality of the resulting 14) What is the normality of 7.3% (wt./vol.)
mixture was : hydrochloric acid solution (mol.wt. of HCl=36.5)?
(1) 0.5 (2) 1.0 (1) 1.5 (2) 3.0
(3) 1.5 (4) 2.0 (3) 2.0 (4) 4.0
7) One gram of a-metal carbonate neutralises 200 15) How much N/5 HCl solution would be required n
mL of 0.1 N-HCl. The equivalent weight of the react completely with 1 g of CaCO3 ?
metal will be : (1) 100 mL (2) 500 mL
(1) 50 (2) 40 (3) 25 mL (4) 200 mL
(3) 20 (4) 100 16) When 10 mL of 5% NaOH is mixed water . 5 mL
8) How much water should be added to 100 mL of of 5% HCl, the resulting solution is:
seminormal HCl solution to make it decinormal? (1) Acidic (2) Basic
(1) 100 mL (2) 200 mL (3) Neutral (4) None of the above
(3) 300 mL (4) 400 mL 17) The molecular weight of NaOH is 40, 25 mL of

1. Opp. Khuda Baksh Library, Ashok Rajpath, Patna - 4

Page No.: 1
2. House no. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna
PHYSICAL CHEMISTRY By: Shailendra Kumar
solution containing 4 g of NaOH in 500 mL will 26) 75 mL of HCl solution required 125 mL of N/25
require for complete neutralisation: NaOH solution for complete neutralisation. The
(1) 50 mL of N/10 HCl solution amount of HCl present in solution is given by :
(2) 20 mL of N/10 HCl solution (1) 18.25 g (2) 1.825 g
(3) 25 mL of N/10 HCl solution (3) 0.1825 g (4) 0.9125 g
(4) 10 mL of N/10 HCl solution 27) 250 mL of 0.1 N solution of HCl contains :
18) 1 g of pure calcium carbonate is mixed with 200 (1) 0.25 g-mole of HCl
mL of N/10 HCl. After the reaction is over : (2) 0.025 g-mole of HCl
(1) Excess of HCl is left (3) 9.12 g-mole of HCl
(2) Unreacted calcium carbonate is left (4) 0.912 g-mole of HCl
(3) Neither of calcium carbonate nor of 28) 250 mL of N/10 sulphuric acid solution contains
HCl is left (1) 1.225 g (2) 2.450 g
(4) None of these (3) 4.9 g (4) 9.8 g
19) 20 mL of N-HCl reacts completely with 0.4 g of 29) 10.0 mL of 0.1 M-H2SO4 will neutralise :
a metal. The equivalent weight of the metal is : (1) 10.0 mL of 0.1 M sodium hydroxide
(1) 4 (2) 8 (2) 10.0 mL of 0.1 M sodium carbonate
(3) 20 (4) 40 (3) 50. mL of 0.1 M sodium hydroxide
20) 100 mL of a dibasic acid solution contains 3.15 (4) 5.0 mL of 1.0 M sodium carbonate
g of the acid. 10 mL of this solution neutralises 30) 100 mL of 0.5 N-NaOH solution is added to 20
10 ml of 0.5 N-NaOH solution. The molecular mL of N-HCl solution and 10 ml of 3N-H2SO4
weight of acid is : solution. The solution will be :
(1) 63 (2) 126 (1) Strongly acidic (2) Alkaline
(3) 30 (4) 31.5 (3) Neutral (4) Faintly acidic
21) 6.3 g of hydrated oxalic acid (H2C2O4xH2O) is 31) 100 mL of 0.2 M-H2SO4 is added to 100 mL of
present in 100 mL normal solution of the acid. 0.2 M-NaOH. The resulting solution will be :
The number of mole of water of crystallisation is (1) Acidic (2) Basic
(1) 2 (2) 3 (3) Neutral (4) Slightly basic
(3) 5 (4) 4 (5) None of these
22) 0.82 g of metal was treated with 200 mL of N/2 32) What is the weight of sodium hydroxide required
H2SO4 till the metal dissolved completely. The to neutralise 100 mL of 0.1-N-HCl:
resulting solutio required 65 mL of (N) NaOH for (1) 4.0 g (2) 0.04 g
neutralisation. The equivalent weight of the metal (3) 0.4 g (4) 2.0 g
is :
(5) 0.2 g
(1) 9 (2) 12
33) 100 mL of 0.4 N-HCl is mixed with 100 mL of
(3) 24 (4) 18 0.6 N-H2SO4. What is the normality of the
23) Certain weight of calcium carbonate reacts with resulting solution ?
100 mL H2SO4 completely to give 224 mL CO2 (1) 0.5 (2) 0.2
at S.T.P. The normality of H2SO4
(3) 0.3 (4) 0.4
(1) N (2) N/3
(5) 1.0
(3) N/4 (4) N/5
34) The formula of metallic hydroxide (equivalent
24) 10.6 g of a mixture containing sodium chloride weight = 150 ) is M(OH)2.xH2O. If the atomic
and sodium carbonate(anhydrous) reacts with weight of the metal is 176, then the value of x is
100 mL N-HCl. The percentage of sodium chloride
(1) 5 (2) 8
in the mixtureis :
(3) 4 (4) 10
(1) 40 (2) 50
35) 500 mL of a 0.1 N solution of AgNO3 are added
(3) 60 (4) 80
to 500 mL of 0.1 N solution of KCl. The
25) 100 mL of N/10 H2SO4 is completely neutralised concentration of nitrate ion in the resulting
by 0.20 g of an oxide of the metal M. The mixture is :
equivalent weight of the metal M is:
(1) 0.05 N (2) 0.01 N
(1) 12 (2) 24
(3) 0.2 N (4) 0.1 N
(3) 36 (4) 48
1. Opp. Khuda Baksh Library, Ashok Rajpath, Patna - 4
Page No.: 2
2. House no. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna
PHYSICAL CHEMISTRY By: Shailendra Kumar
36) A solution containing 98 g of H2SO4 (formula (3) 7.175 g (4) 3.65 g
weight = 98 ) per litre will be : 46) 2.5 g of sodium hydroxide was dissolved in water
(1) Normal (2) Molar and the volume was made to 50 mL. The volume
(3) Centi-normal (4) Deci-normal of 5 N-H2SO4 required to neutralise the above
37) One gram of a metal carbonate nutralise 200 alkali completely is :
mL of 0.1 N-HCl. The equivalent weight of the (1) 12.5 mL (2) 25 mL
metal will be : (3) 30 mL (4) 15 mL
(1) 50 (2) 40 (5) 10 mL
(3) 20 (4) 100 47) One mole of sulphuric acid will be exactly
38) 75 mL of N/5 H2SO4. 10 mL of N/2 HCl and 30 neutralised by :
mL of N/10 HNO3 are mixed togather. The (1) One mole of ammonia
strength of the resulting acid mixture is : (2) One mole of barium hydroxide
(1) 0.1 N (2) 0.2 N (3) Two moles of calcium hydroxide
(3) 0.3 N (4) 0.4 N (4) Two mole of barium hydroxide
39) What is the amount of NaOH required to (5) None of these
neutralise 100 mL of 0.1 N-H2SO4 ? 48) 30 mL of 0.2 N-NaOH solution is completely
(1) 5.0 g (2) 4.0 g neutralised by 60 mL of hydrochloric acid. the
(3) 0.4 g (4) 0.8 g normality of HCl is :
(5) 2.0 g (1) 0.8 N (2) 0.4 N
40) 40 mL of 0.1 N-HCl are mixed with 20 mL of 0.1 (3) 0.3 N (4) 0.2 N
M-H2SO4. The strength of the resulting solution (5) 0.1 N
will be : 49) The molarity of water in pure water is :
(1) 0.4 N (2) 0.3 N (1) 1 M (2) 18 M
(3) 2N/15 (4) 0.1 N (3) 55.5 M (4) 1000 M
41) The normality 0.5 M-H2SO4 solution will be : 50) The weight of H2SO4 in 2.5 litres of 2M H2SO4 is
(1) 0.5 (2) 1.0 (1) 400 g (2) 450 g
(3) 1.5 (4) 2.0 (3) 480 g (4) 490 g
(5) 2.5 (5) 500 g
42) How many millilitres of 0.02 M sodium hydroxide 51) 1.0 g of a mixture of sodium chloride and
solution are needed to react completely with 100 anhydrous sodium carbonate is exactly
mL of 0.01 M sulphuric acid ? neutralised by 50 mL of N/5 solution of an acid.
(1) 200 mL (2) 150 mL The percentage of sodium chloride in the mixture
(3) 100 mL (4) 50 mL is
(5) 250 mL (1) 53 (2) 47
43) Oxalic acid is a dibasic acid having molecular (3) 80 (4) 70
formula (COOH)2.2H2O. What weight of oxalic (5) 60
acid is required to prepare 500 mL of 0.1 M 52) 10 mL of (N) HCl reacts with 0.12 g of a metal.
solution ? The equivalent weight of metal is :
(1) 12.6 g (2) 6.3 g (1) 8 (2) 10
(3) 4.5 g (4) 9 g (3) 12 (4) 20
44) 4 g of solid sodium hydroxide was dissolved in (5) 23
100 mL of water. The whole of this solution 53) Which of the following is independent of
neutralises completely : temperature ?
(1) 10 mL of 5 N-H2SO4 (1) Molarity (2) Molality
(2) 20 mL of 2.5 M-H2SO4 (3) Formality (4) Normality
(3) 30 mL of 5 M-H2SO4 54) A substance has its molecular weight 342. The
(4) 40 mL of 10 M-H2SO4 molarity of a solution containing 6.84 g of a
45) 100 mL of 0.1 N-HCl is treated with excess of substance in 200 mL of solution is :
AgNO3. The weight of AgCl precipitated is : (1) 0.1 M (2) 0.2 M
(1) 1.435 g (2) 14.35 g (3) 0.3 M (4) 0.4 M

1. Opp. Khuda Baksh Library, Ashok Rajpath, Patna - 4

Page No.: 3
2. House no. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna
PHYSICAL CHEMISTRY By: Shailendra Kumar
NaOH solution for neutralisation. The molecular
55) Molarity is expressed as : weight of the dibasic acid is
(1) g/litre (2) litre/mole (1) 45 (2) 60
(3) mole/L (4) mole/1000 g (3) 70 (4) 80
56) One g-equivalent of potassium hydroxide is 56 (5) 90
g. Therefore, weight of KOH present is 500 mL
65) 0.84 g of metal carbonate reacts exactly with
of deci-normal solution is :
40 mL of N/2 H2SO4 solution. The equivalent
(1) 5.6 g (2) 2.8 g weight of the metal carbonate is :
(3) 28 g (4) 11.2 g (1) 21 (2) 30
57) 100 mL 0.3 N solution of NaOH was mixed with (3) 40 (4) 42
200 mL of 0.3 M-H2SO4 solution. The normality
(5) 60
of H2SO4 in the resulting solution is :
66) Increasing the temperature of an aqueous
(1) 0.9 N (2) 0.3 N
solution will cause :
(3) 0.67 N (4) 0.4 N
(1) Decrease in molality
(5) 0.45 N
(2) Decrease in molarity
58) The volume of N/5 HCl solution required to
(3) Decrease in mole fraction
neutralise 2 g of CaCO3 is (Ca = 40, C = 12)
(4) Decrease in % (w/w)
(1) 100 mL (2) 200 mL
67) The amount of HCl required to neutralise 20 mL
(3) 50 mL (4) 90 mL of 0.5 N-NaOH is :
(5) 25 mL (1) 20 mL of 1.0 N-HCl
59) 5.3 g of pure and anhydrous sodium carbonate (2) 10 mL of 1.0 N-HCl
is treated with 100 mL N/10 HCl. After the
(3) 40 mL of 0.5 N-HCl
reaction is over :
(4) 10 mL of 0.1 N-HCl
(1) Excess of HCl is left
(5) None of these
(2) Unreacted sodium carbonate is left
68) 20 mL of a solution containing 6.5 g of a dibasic
(3) Neither of HCl nor of sodium carbonate
acid per litre neutralised 22.18 mL of a solution
is left
of NaOH. The same volume (20 mL) of N/10 HCl
(4) None of these neutralised 21.5 mL of the same sodium
60) The normality of 73% HCl (density 1.2 g/mL) by hydroxide solution. The molecular weight of the
weight would be : acid is :
(1) 12 (2) 18 (1) 120 (2) 126.0
(3) 24 (4) 36 (3) 128.02 (4) 100.32
(5) 48 (5) 140.02
61) When 10 ml of 1 M-KOH solution is mixed with 69) 2 N-NaOH solution means that :
10 mL of M-H2SO4 solution, the resulting mixture (1) 2 g of NaOH is dissolved in 100 mL of water
will be :
(2) 2 g of NaOH is dissolved in 100 mL of solution
(1) Acidic (2) Alkaline
(3) 4 g of NaOH is dissolved in 100 mL of water
(3) Neutral (4) Strongly alkaline
(4) 8 g of NaOH is dissolved in 100 mL of solution
(5) None of these
70) 1.0 g of a piece of metal was allowed to react
62) Which of the following should be done in order with 25 mL of 4 N-HCl. When the reaction was
to prepare 0.40 M-NaCl starting with 100 mL of over, 100 mg of the metal remained unreacted.
0.30 M-NaCl (mol.wt. of NaCl = 58.5) ? The equivalent weight of the metal is :
(1) Add 5.85 g NaCl (1) 9 (2) 12
(2) Add 20.0 mL water (3) 18 (4) 24
(3) Add 0.01 mole NaCl (5) 30
(4) Evaporate 10 mL water 71) A sample of Na2CO3.H2O weighing 0.62 g is
63) The concentration of an aqueous solution of 0.01 added to 100 mL of 0.1 N-H2SO4 solution. The
M-CH3OH solution is very nearly equal to : resulting solution is :
(1) 0.01 % CH3OH (2) 0.01 M-CH3OH (1) Acidic (2) Basic
(3) XCH OH = 0.01 (4) 0.99 M-H2O (3) Neutral (4) Slightly acidic
3
64) 0.45 g of a dibasic acid required 200 mL of N/20 (5) Slightly basic
1. Opp. Khuda Baksh Library, Ashok Rajpath, Patna - 4
Page No.: 4
2. House no. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna
PHYSICAL CHEMISTRY By: Shailendra Kumar
72) Two litres of ammonia at 30ºC and 0.20 atm (1) 0.2 litre (2) 0.5 litre
pressure neutralised 134 mL of a solution of (3) 2.5 litres (4) 5 litres
sulphuric acid. The normality of the acid is : 81) Hydrochloric acid solution A and B have
(1) 0.1 N (2) 0.11 N concentrations of 0.5 N and 0.1 N, respectively.
(3) 0.12 N (4) 0.14 N The volumes of solutions A and B required to
(5) 0.15 N make 2.0 litres of 0.2 N-HCl are :
73) One gram of a solid tribasic acid was dissolved (1) 0.5 L A + 1.5 L B
in water and the solution was made to 250 mL. (2) 1.5 L A + 0.5 L B
19.2 mL of this solution required 10 mL of N/10 (3) 1.0 L A + 1.0 L B
NaOH solution for complete neutralisation. The (4) 0.75 L A + 1.25 L B
Mol. wt. of the acid is 82) The equivalent weight of an unknown compound
(1) 210 (2) 310 is 53. If 1.325 g of it be dissolved to make 250
(3) 420 (4) 220 mL of an aqueous solution of the compound,
(5) 850 the normality of the solution is :
74) The normality of a 26 % wt./mol. solution of (1) 0.1 N (2) 0.2 N
ammonia is approximately : (3) 0.3 N (4) 0.4 N
(1) 1.5 (2) 4.0 (5) 0.5 N
(3) 0.4 (4) 15.3 83) 0.12 g of pure Mg ribbon completely reacts with
75) 4 g of NaOH (mol. wt. = 40) were dissolved in 100 mL H2SO4. The normality of H2SO4 is :
water and the solution was made to 1000 mL. (1) N/10 (2) N/15
The whole of this will neutralize completely : (3) N/20 (4) N/25
(1) 100 mL of M-H2SO4 84) Suppose that 0.099 mole of solid sodium
(2) 50 mL of 10 M-H2SO4 hydroxide is added to 100 mL of 1.0 M-HCl. The
(3) 20 mL of 2.5 M-H2SO4 excess of mole of HCl present in solution than
(4) 30 mL of 5 M-H2SO4 NaOH is :
76) Commercial hydrochloric acid is 12 N. If 8.3 mL (1) 0.1 mole (2) 0.01 mole
of this acid is dissolved in 991.7mL of water, the (3) 0.001 mole (4) 0.02 mole
normality of the resulting solution will be about : (5) 0.0001 mole
(1) 0.05 (2) 0.5 85) The mole fraction of water in a
(3) 0.1 (4) 0.45 20 % (w/w) aqueous solution of H2O2 is
77) On dissolving 1.0 mole each of the following (1) 77 / 68 (2) 68 / 77
acids in 1.0 litre water, the acid that does not (3) 20 / 80 (4) 80 / 20
give a solution of strength 1.0 N is : 86) If 5.85 g of NaCl is dissolved in 90 g of water, the
(1) HCl (2) Perchloric acid mole fraction of NaCl is :
(3) HNO3 (4) Phosphoric acid (1) 0.1 (2) 0.2
78) The volume of water which must be added to 40 (3) 0.3 (4) 0.01
mL of 0.25 N oxalic acid solution in order to (5) 0.0196
make it exactly decinormal is : 87) What volume of CO2 at S.T.P. will be liberated
(1) 40 mL (2) 30 mL by the action of 100 mL of 0.2N-HCl on CaCO3 ?
(3) 20 mL (4) 25 mL (1) 112 mL (2) 224 mL
(5) 60 mL (3) 448 mL (4) 1120 mL
79) 25 mL of N solution of an acid was diluted to 88) To 1000 mL N/10 BaCl2 solution is added 0.1
250 mL. 10 mL of the solution was titrated with mole of AgNO3. The molarity of chloride ions in
0.05 N alkali solution. The volume of alkali the resulting solution is :
solution required for complete neutralisation (1) 0 (2) 0.05
would be : (3) 0.1 (4) 0.2
(1) 100 mL (2) 20 mL 89) 1 g of the carbonate of a metal was dissolved in
(3) 5 mL (4) 10 mL 25 mL of N-HCl. The resulting liquid required 5
80) What volume of 0.2 N oxalic solution can be mL of N-NaOH for neutralisation. The eq.wt. of
prepared from 63 g of oxalic acid ? metal carbonate is :

1. Opp. Khuda Baksh Library, Ashok Rajpath, Patna - 4

Page No.: 5
2. House no. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna
PHYSICAL CHEMISTRY By: Shailendra Kumar
(1) 5 (2) 30 98) A solution is prepared by dissolved 0.5 mole
(3) 20 (4) 40 KCl and 0.5 mole BaCl2 in 1000 mL solution.
(5) 50 the molarity of chloride ions in the solution is :
90) 0.1 mole of NaCl is added to 200 mL of M/10 (1) 1.5 (2) 1.0
AgNO3 solution. The molarity of nitrate ions in (3) 0.5 (4) 0.2
the solution will be : 99) A sample of metal carbonate was neutralised
(1) 0.2 (2) 0.1 by 10 mL of 0.1 N-HCl and the resulting metal
(3) 1.0 (4) 2.0 chloride gave 0.0517 g of metal phosphate. The
91) 5 mL of N-HCl. 20 mL of N/2 H2SO4 and 30 mL equivalent weight of the metal is :
of N/3 HNO3 are mixed together and the volume (1) 12 (2) 20
made to 1 litre. The weight of pure sodium (3) 23 (4) 39
hydroxide required to neutralise the acid mixture 100) 100 mL of an N/10 acid will exactly neutralise :
is : (1) 40 mL of N/4 alkali
(1) 10 g (2) 2 g (2) 50 mL of N/10 alkali
(3) 1 g (4) 2.5 g (3) 20 mL of N/5 alkali
92) 1 g of pure magnesium ribbon reacts with 100 (4) 30 mL of N/6 alkali
mL N/10 HCl. After the reaction is over: 101) The weight of BaCl2 that must be dissolved in
(1) Excess of HCl left 200 mL solution to produce chloride ion
(2) Excess of magnesium is left concentration as that present in solution
(3) Neither of magnesium nor of HCl is left containing 5.85 g NaCl per 100 mL is (Ba =137)
(4) None of these (1) 20.8 g (2) 10.4 g
93) 1 g of a mixture of calcium carbonate and sodium (3) 41.6 g (4) 15.4 g
chloride reacts completely with 100 mL N/10 102) 100 mL 10% NaOH is mixed with 100 mL 10%
HCl. The percentage of CaCO3 in the mixture is H2SO4. The resulting solution is :
(1) 40% (2) 50% (1) Acidic (2) Basic
(3) 60% (4) 80% (3) Neutral (4) Slightly acidic
(5) 90% 103) The volume of water that should be added to
94) 200 mL M-NaNO3 and 200 mL M-Al(NO3)3 400 mL of N/8 HCl to make it exactly N/12 is :
solution are mixed. The molarity of nitrate ions (1) 100 mL (2) 200 mL
in the mixture is : (3) 300 mL (4) 400 mL
(1) 4 (2) 3 104) The mass of magnesium that must be added to
(3) 2 (4) 1 250 mL 1.2 M-HCl to reduce it to exactly 1.0 M-
95) If 200 mL of N/10 HCl were added to 1g of HCl is :
calcium carbonate. What would remain after the (1) 1.2 g (2) 1.0 g
reaction? (3) 0.6g (4) 0.4 g
(1) CaCO3 (2) HCl 105) Equal volumes of 0.80 M-HCl, 0.50 M-KOH and
(3) Neither of two (4) Part of the both 0.5 M-KCl are mixed. The molarity of resulting
(5) 100 mL N/10 HCl solution with regard to KCl is :
96) Certain weight of zinc reacts with 100 mL HCl (1) 1/2 M (2) 1/3 M
to give 112 mL of H2 at S.T.P. The normality of (3) 1/4 M (4) 1.0 M
HCl is : 106) The volume of 0.25 M-MgCl2 that must be added
(1) N (2) N/5 to 320 mL of 0.25 M-NaCl to produce 0.3 M-Cl–
(3) N/10 (4) N/15 in the mixture is :
(5) N/20 (1) 80 mL (2) 90 mL
97) The normality of 200 mL H2SO4 solution that (3) 100 mL (4) 120 mL
precipitates 2.33 g of BaSO4 when treated with 107) 20 mL of NaOH solution converts 0.240 g
excess of BaCl2 solution is : NaH2PO4 in a solution to produce monohydrogen
(1) 1 (2) 0.5 phosphate. The concentration of NaOH solution
(3) 0.2 (4) 0.1 is :
(5) None of these (1) 1 (2) 0.5
(3) 0.2 (4) 0.1
1. Opp. Khuda Baksh Library, Ashok Rajpath, Patna - 4
Page No.: 6
2. House no. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna
PHYSICAL CHEMISTRY By: Shailendra Kumar
108) What volume of 0.5 N-HCl is required for the 119) A solution is called normal if one gram equivalent
complete decomposition of 10 g of CaCO3 ? of solute is present in :
(1) 50 mL (2) 400 mL (1) 1000 g water (2) 1000 mL water
(3) 500 mL (4) 1000 mL (3) 1000 mL solution (4) 1000 g solution
109) The weight of iodine liberated when 100 mL 2 M 120) The molarity of phosphoric acid is 0.5. Its reacts
CuSO4 solution is treated with excess of K1 with Ca(OH)2 as
solution is : Ca(OH) 2 + H 3PO 4 → CaHPO 4 + 2H 2O Its
(1) 12.7 g (2) 25.4 g strength is :
(3) 1.27 g (4) 2.54 g (1) 0.5 N (2) 1 N
110) 25 mL of 0.5 M-H2SO4 is mixed with 30 mL of M- (3) 1.5 N (4) 3 N
NaOH solution. The volume of N/10 H2SO4 which (5) 2 N
will just neutralise the excess of alkali will be : 121) To 100 mL M/10 HCl, 100 mL M/10 NaCO3 was
(1) 5 mL (2) 50 mL added. The solution after the reaction is :
(3) 10 mL (4) 20 mL (1) Acidic (2) Basic
111) Which of these solutions has the highest (3) Neutral (4) None of these
normality ? 122) 4 g of NaOH was dissolved in 50 mL water. The
(1) 8 g of KOH per 100 mL volume of (N) H2SO4 required for its complete
(2) 0.5 M-H2SO4 (3) N-phosphoric acid neutralisation is :
(4) 6 g of NaOH per 100 mL (1) 100 mL (2) 50 mL
112) The strength of NaOH solution is 5.1%(w/v), (3) 200 mL (4) 10 mL
density 1.02 g/mL. Its strength in w/w is : (5) 500 mL
(1) 4% (2) 4.8% 123) The volume of HCl having concentration 18.25%
(3) 5% (4) 5.1% by weight and specific gravity 1.2 for the
113) 100 mL of N/10 ( f = 1.08) HCl is diluted with preparation of 100 mL (N) solution is :
distilled water to produce exactly decinormal (1) 18.25 mL (2) 33.3 mL
solution. The volume of water required for the (3) 21.6 mL (4) 16.66 mL
same is : (5) 20.66 mL
(1) 108 mL (2) 100 mL 124) 10 g of a mixture of CaCO3 and MgCO3 (3%
(3) 80 mL (4) 8.0 mL CaCO3 and 7% MgCO3) is allowed to react
(5) 120 mL completely with 2.0 M-HCl. The volume of the
114) The strength of a sodium hydroxide solution is acid required is :
10% by wt. The mole fraction of water is : (1) 113.3 mL (2) 213.3 mL
(1) 16/21 (2) 19/21 (3) 225 mL (4) 233 mL
(3) 20/21 (4) None 125) 1 g marble when reacted with (N) HCl acid
115) 100 mL 10% KOH is mixed with 100 mL 10% required 19 mL for complete reaction leaving
H2SO4. The resulting solution is : behind some sandy materials. The percentage
(1) Acidic (2) Basic purity of CaCO3 in the marble is :
(3) Neutral (4) None (1) 0.95 (2) 95
116) 100 mL M-CH3COOH is mixed with 100 mL (3) 5 (4) 19
M-NaOH. The resulting solution is : (5) 20
(1) Acidic (2) Slightly basic 126) 10 mL N/10 solution of a dibasic acid will
(3) Neutral (4) Basic completely neutralise N/10 solution of a
117) The volume of 0.50 M BaCl2 that will contain 3.0 monoacidic base if its volume added is :
mole of chloride ions is : (1) 10 mL (2) 20 mL
(1) 1.0 L (2) 2.0 L (3) 30 mL (4) 50 mL
(3) 3.0 L (4) 1.5 L (5) 5 mL
118) The volume of 0.5 (N) sulphuric acid required to 127) When excess of zinc reacts with 10 mL of
neutralise 200 mL of 0.2 N sodium carbonate is H2SO4, 224 ml H2 is liberated at S.T.P. The
(1) 23 mL (2) 40 mL strength of H2SO4 is :
(3) 80 mL (4) 100 mL (1) 10 N (2) 1 N
(5) 60 mL (3) 2 N (4) 4 N
1. Opp. Khuda Baksh Library, Ashok Rajpath, Patna - 4
Page No.: 7
2. House no. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna