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Schematic Pre Lab 2
Schematic Pre Lab 2
Schematic Diagram
In this experiment, sulfate solution and BaCl 2 solution will be utilized in analyzing
the concentration of sulfate from a sample solution. Sulfate is quite common in nature
and may be present in natural water with concentrations ranging from a few to several
thousand milligrams/liter. These are of considerable concern because they are indirectly
held responsible for two serious problems in handling and treatment of wastewater:
odor and sewer corrosion. This is a result from the reduction of sulfates to hydrogen
sulfide under anaerobic conditions.
The experiment will start off when a constant mass of crucible is observed, followed
by the determination of the mass of the sample. Then, a pre-weighed sample of the
unknown sulfate will be dissolved in water. A 50% HCl solution is then added to the
solution with 4.5 to 5 pH to increase the solubility of the BaSO4, which will result to a
decrease in the rate of precipitation. After that, aqueous barium chloride is added to the
sulfate solution which will then result to the precipitation of sulfate ions as barium
sulfate. This will be digested for about one hour to minimize error from the spilling of
precipitate.
In an aqueous solution, sulfate ion undergoes the following reaction with barium:
Ba2+(aq) + SO42-(aq) → BaSO4 (s) Ksp = Ba2+SO42− = 1.1x10−10 at 25 C
This barium sulfate precipitate is gathered through filtration, dried and weighed.
In the procedure, barium chloride is added in excess and the precipitation reaction goes
to completion. With this being stated, it can be assumed that all of the sulfate is
transferred from the original sample to the precipitate. After reaching a constant weight,
determination of the concentration of the sulfate as % BaSO4 can now be performed
using stoichiometry. This also yields to the mass of sulfate in the original sample since:
Using the balanced chemical equation for the precipitation reaction, the moles of the
precipitate can be obtained by the equation:
Then, the moles of analyte can be calculated from the balanced chemical equation using
the mole ratio of analyte: precipitate. From this, the mass of the analyte can be obtained
by the equation:
mass analyte
by mass= x 100
mass of sample
To obtain the best results, collected BaSo 4 crystals should be as large as possible.
This is mainly because larger crystals do not generally pass through the filter paper and
it also minimizes the amount of impurities adsorbed onto the crystals due to smaller
surface area. These large crystals are achieved through decreasing the rate of
precipitation, which is done by the slow addition of BaCl 2 solution to the sulfate solution
while continuously stirring the solution. Addition of HCl solution also contributes to the
decrease in the rate of precipitation.
Formulas to be used:
d́=
∑ di
n
x́=
∑ xi
n
C. Data Blanks
I. CONSTANT MASS OF THE CRUCIBLE
Table 2.1 Taring of crucible and cover
Condition Trial 1 Trial 2
Volume of sample, mL
% Barium sulfate
x́ ± d́
% sulfate
x́ ± d́
References:
(n.d.). Retrieved from http://users.metu.edu.tr/chem223/Sulfate.pdf.
Libretexts. (2019, June 5). 7: Gravimetric Analysis (Experiment). Retrieved from
https://chem.libretexts.org/Bookshelves/Ancillary_Materials/Laboratory_Experi
ments/Wet_Lab_Experiments/General_Chemistry_Labs/Online_Chemistry_Lab_
Manual/Chem_11_Experiments/07:_Gravimetric_Analysis_(Experiment).
Stubbings, J. (n.d.). Gravimetric Analysis Tutorial. Retrieved from
https://www.ausetute.com.au/gravimetric.html.