DKY Sir Hindi Final : 12-01-13

(JB-C)_Paper-1_MT(AIOT)-XI Sylla_20-01-13_Pg. No # 1

JB –(XI SYLLABUS) : (DLPD) TEST : MAJOR TEST (MT) (JEE ADVANCE)

TEST DATE : 20-01-2013 AJN SIR
PAPER-1
Paper-1
Q.No. Subject Nature of Questions No. of Questions Marks Negative Total
1 to 7 SCQ 7 3 0 21
8 to 10 Physics TTF (S1, S2, S3) 3 4 0 12
11 to 14 Comprehension (2 comp. × 2 Questions) 4 3 0 12
15 to 21 Integer (Double Digit) 7 4 –1 28
22 to 28 SCQ 7 3 0 21
29 to 31 TTF (S1, S2, S3) 3 4 0 12
Chemistry
32 to 35 Comprehension (2 comp. × 2 Questions) 4 3 0 12
36 to 42 Integer (Double Digit) 7 4 –1 28
43 to 49 SCQ 7 3 0 21
50 to 52 TTF (S1, S2, S3) 3 4 0 12
Maths
53 to 56 Comprehension (2 comp. × 2 Questions) 4 3 0 12
57 to 63 Integer (Double Digit) 7 4 –1 28
Total 63 Total 219
Paper-2

SECTION - I
Straight Objective Type
This section contains 7 questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONLY ONE is correct.
[k.M - I
lh/ksoLrqfu"B izd kj
bl [k.M esa7 iz'u gSaA izR;sd iz'u d s4 fod Yi (A), (B), (C) rFkk (D) gSa] ft uesalsflQ Z,d lgh gSA

1. Initially car A is 10.5 m ahead of car B. Both start moving at time t = 0 in the same direction along a straight
line. The velocity time graph of two cars is shown in figure. The time when the car B will catch the car A, will
be
çkjEHk esad kj A, d kj B ls10.5 m vkxsgSA nksaukst = 0 ij ,d ljy js[kk d svuqfn'k leku fn'kk esaxfr çkjEHk d jrh
gSA nksauksd kjksad k osx le; xzkQ fp=k esan'kkZ;k x;k gSA og le; t c d kj B, d kj A d ksid M+ysxh] gksxk &

(A*) t = 21 sec (B) t = 2 5 sec (C) 20 sec. (D) None of these bues
alsd ksbZugha
Ans. (A)
Hint : xA = xB
1 2
10.5 + 10t = at a = tan45° = 1
2

20  400  84
t2 – 20t – 21 = 0 t=
2
t = 21 sec.
 (JB-C)_Paper-1_MT(AIOT)-XI Sylla_20-01-13_Pg. No # 2
2. The velocity displacement graph of a particle moving along a straight line is shown in figure.
,d ljy js[kk esaxfr d jrsgq, ,d d .k d k osx&foLFkkiu oØ fp=k esafn[kk;k x;k gS%

Then the acceleration displacement graph is.

bld k Roj.k&foLFkkiu oØ gksxk &

(A) (B) (C*) (D)

Sol. From the graph, we can write

xzkQ l s] ge fy [k l d rsgSa
v=–x+2
dv dx
a= =–
dt dt
=–v
= – (– x + 2) =x–2

3. Figure shows five identical open–top container filled upto the brim with water. In figure(b), toy duck is
floating, in figure(c) a heavy toy duck sinks and touches the bottom, in figure (d) a heavy toy duck is
suspended from a string and in figure (e) a light toy duck is tied with a massless string. If all the five
containers are put on weighing machine, the correct order of their reading will be :
fp=k esaçnf'kZr ik¡p le: i [kqy sik=k Å ij rd ikuh lsHkjsgq, gSA fp=k (b) esaf[kykSuk cÙk[k rSj jgh gS] fp=k (c) esa
,d Hkkjh f[kykSuk cÙk[k ry d ksNwrh gqbZMwch gqbZgS] fp=k (d) esaHkkjh f[kykSuk cÙk[k jLlh lsyVd h gqbZgSrFkk fp=k
(e) es
agYd h f[ky kSuk cÙk[k nzO;ekujfgr jLlh }kjk c¡/kh gqbZgSA ;fn lHkh ik¡p ksaik=k Hkkj e'khu ij j[k fn;st k, rks
bud sikB;kad ksd k lgh Ø e gksxkA

(A) (a) = (b) = (c) = (d) = (e) (B*) (e) < (a) = (b) = (d) < (c)
(C) (e) < (d) < (a) = (b) < (c) (D) (a) = (b) = (d) = (e) < (c)
 (JB-C)_Paper-1_MT(AIOT)-XI Sylla_20-01-13_Pg. No # 3

Sol. (b) weight of the displaced water = weight of the duck

so, the weight of the system (b) will be equal to that of system (a)
(c) as the density of the duck is more that of water, the weight of system (c) is more than that of
system (a).
(d) The boyansive force transmitted from the duck to the water is equal to the weight of the displaced
water.
So, weight of system (d) = weight of system (a)
(e) As the density of the duck is less than that of water, so weight of system (e) is less that of system
(a).
Sol. (b) foLFkkfir ikuh d k Hkkj = cÙk[k d k Hkkj vr% fud k; b d k Hkkj fud k; a d scjkcj gks
xkA
(c) pwafd cÙk[k d k ?kuRo ikuh lsT;knk gSblfy, fud k; c d k Hkkj fud k; a lsT;knk gksxkA
(d) cÙk[k }kjk ikuh ij LFkkukUrfjr mRIykod cy foLFkkfir t y d sHkkj d scjkcj gks rk gSA vr% fud k; d d k Hkkj =
fud k; a d k HkkjA
(e) pw afd cÙk[k d k ?kuRo ikuh lsd e gSblfy , fud k; e d k Hkkj fud k; a lsd e gSA

4. A man can swim certain distance in still water up and down in time t1. If he swims to some distance down
stream the river and returns back to same point he takes time t2. Then :]
,d O;fDr fLFkj ikuh esarSjrsgq, fuf'pr nwjh rd t kd j okil vkusesat1 le; y srk gSA ;fn og ,d unh esaikuh
d scgko d h fn'kk esaleku nwjh rd t kd j okil izkjfEHkd fcUnqrd vkusesat2 le; ysrk gksrksA

(A) t1 = t2 (B*) t1 < t2

(C) t1 < t2 (D) t1 & t2 can't be compared
t1 rFkk t2 d h rq
y uk ugh d h t k ld rh gSA
2d d d 2vd 2d
Sol. t1 = t2 =  = =
v v u v u v  u2
2
u2
v2 
v

2d
t2 =
 u2 
v 1  2 
 v 
t2 > t1 .
5. If the fundamental frequency of a pipe closed at one end is 512Hz. The fundamental frequency of a
pipe of the same dimensions but open at both ends will be:
;fn ,d fl jsl scUn ,d ikbi d h ewy vkof̀Ùk 512 Hz gSA l eku foekvksaoky k ikbi t ksnksuksafl jksl s[kqy k gks]
d h ewy v kof̀Ùk gksxhA
(A*) 1024 Hz (B) 512Hz (C) 256 Hz (D) 128Hz
Sol. The fundamental modes of vibration of a pipe closed at one end and open at both ends (of same
length) are shown in figure.

The wavelength in figure (b) is half of that in figure (a). Hence the fundamental frequency in figure (b)
is double that in figure (a).
 f open = 2 × 512 = 1024 Hz

,d fljslscan rFkk nksuksafljksij [kqy s¼leku y ackbZd s½ ikbZi d sd aiu d h ewy fo/kk fp=k esaiznf'kZr gSA

fp=k (b) esarajxnS/;Zfp=k(a) esarjaxnS/;Zd h vk/khgksrh gSvr%fp=k(b) esaewy vkof̀Ùk fp=k (a) esaewy vkof̀Ùk d h nqxquh
gksrh gSA
 f [kqy k = 2 × 512 = 1024 Hz
 (JB-C)_Paper-1_MT(AIOT)-XI Sylla_20-01-13_Pg. No # 4

6. For an adiabatic process graph between PV and V for a monoatomic gas is :

: nks"e izØ e esa,d ijek.kqd xSl d sfy , PV rFkkV d se/; xzkQ gksxk %

PV PV PV PV

(A) (B*) (C) (D)

V V V V
Sol. PV = constant fu;rka
5/3
d
(PV) V2/3 = constant fu;rka
d

7. The length of the wire shown in figure between the pulleys is 1.5 m and its mass is 12.0 g. The frequency
of vibration with which the wire vibrates in three loops forming antinode at the mid point of the wire is -
(Take g = 9.8 m/s2)
fp=k esaiznf'kZr f?kjfu;ksad se/; rkj d h yEckbZ1.5 eh rFkk bld k nzO;eku 12.0 xzke gSA nksuksaf?kjfu;ksd schp d k rkj
e?; fcUnqij izLiUn cukrsgq, rhu y wiksaesad EiUu d j jgk gS] d EiUu d h vkof̀Ùk gSA (g = 9.8 m/s2)

9kg 9kg
(A) 210 Hz (B) 140 Hz (C) 70 Hz (D*) none of these
Sol. =1m

9  9.8  1.5
v= = 105 m/s
12  10 3

105  1
f= = 105 Hz
1

SECTION - II
True & False Statement Type
This Section Contains 3 questions. Each questions contains 3 or 4 statements S1, S2, S3 or S4. Each
statement is either true (T) or false (F). Each questions has 4 choices (A), (B), (C) and (D) each of
which contains whether S1, S2, S3 or S4 are true or false. Exactly one choice contains the correct order
of truthness or falseness of S1, S2, S3 or S4 respectively and is the correct choice.
[k.M - II
lR; o v lR; izd kj
bl [k.M esa3 iz'u gSA izR;sd iz'u d s3 ;k 4 d Fku S1, S2, S3 ;k S4 gSA izR;sd d Fku l R; (T) ;k vl R; (F) gks
l d rk gSA izR;sd iz'u d h 4 fod Yi (A), (B), (C) rFkk(D) gSizR;sd esal sd ksbZHkh S1, S2, S3 ;k S4 l R; ;k v l R;
gksl d rsgSA S1, S2, S3 ;k S4 d sl UnHkZesaØ e'k% ,d fod Yi l R; ;k vl R; gSvkSj t ksl gh fod Yi gSA

8. S1 : Net torque on a system due to all internal forces about any point is zero.
S2 : For a rigid body undergoing fixed axis rotation, the direction of its angular acceleration and angular
velocity are always same.
S3 : If net torque on a rigid body about its centre of mass is zero, the angular speed of the rigid body is
always zero.
S1 : fd lh Hkh fcUnqd slkis
{k fud k; ij lHkh vkUrfjd cyksad sd kj.k ifj.kkeh cy k?kw.kZ'kwU; gksrk gSA
S2 : ,d fLFkj t M+ or v{k d sifjr ?kw.kZu d jrh gqbZn`<+oLrqd sfy, d ks.kh; Roj.k rFkk d ks.kh; osx d h fn'kk ges'kk
leku gksxhA
S3 : ;fn n`<+oLrqd k nzO;eku d sUnzd slkis{k d qy cyk?kw.kZ'kwU; gS] rksn`<+oLrqd h d ks.kh; pky ges'kk 'kwU; gksxhA
(A) T F T (B) T T F (C) F F F (D*) T F F
 (JB-C)_Paper-1_MT(AIOT)-XI Sylla_20-01-13_Pg. No # 5

Sol. S1 : The line of action of each action reaction pair is same. Therefore magnitude of couple of each such
pair is zero. Hence net torque of all internal forces is zero.
S2 : The direction of angular acceleration and angular velocity shall be opposite if the body is slowing
down.
S3 : If net torque on a rigid body is zero, its angular velocity will be constant. The constant may necessarily
not zero.
S1 : izR;sd fØ ;k&izfrfØ ;k ;qXe d h fØ ;k&js[kk l eku gSA bl fy ;sizR;sd ,sl s;qXe d scy &;qXe d k ifjek.k 'kwU;
gSA bl fy ;sl Hkh v kUrfjd cy ksad k usV vk?kw.kZ'kwU; gSA
S2 : d ks
.kh; Roj.k rFkk d ks.kh; osx d h fn'kk, foijhr gksxh ;fn fi.M d h xfr /kheh gksjgh gSA
S3 : ;fn ,d n` <+fi.M ij usV v k?kw.kZ'kwU; gS] rksbl d k d ks.kh; osx fu;r gksxkA ;g vko';d ugh gSfd og
'kwU; gksA
9. S1 : If the absolute temperature of a gas is doubled, the final rms-velocity of the gas particles becomes
2 times the initial value.
S2 : In isothermal process involving an ideal gas, whole of the heat energy supplied to the gas is
converted into internal energy.
S3 : In a perfectly inelastic collision, all the initial kinetic energy of the colliding bodies is converted to heat

S1 : ;fn ,d xSl d k ijerki nqxuk d j fn;k t k, rksxSl d sd .kksad k vfUre oxZek/; ewy osx izkjfEHkd eku
d k 2 xquk gkst krk gSA
S2 : fd l h vkn'kZxS l d sl erkih; izØ e esaxSl d ksiznku d h xbZiwjh Å "eh; Å t kZvkUrfjd Å t kZesa: ikUrfjr
gkst krh gSA
S3 : iw.kZr;kvizR;kLFkVDd j esa]VDd j d jusoky hlHkhoLrqv ksad hd qy izkjfEHkd xfrt Å t kZiw.kZr;kÅ "ekesaifjofrZr
gksrh gSA
(A*) T F F (B) T T F (C) T F T (D) F F T
Sol. S1 : If the absolute temperature T doubles, vrms must increase by sqrt(2) m and k are constants).

S2 : In isothermal process U = 0, Q = PV. Hence False,

S3 : In a perfectly inelastic collision, final momentum of system is equal to initial momentum of system. If
final momentum of system is nonzero, there will be some final kinetic energy of system. Hence all initial
kinetic energy of system cannot always be dissipated. Thus the statement is false.
S1 : ;fn ijerki T nq xuk d jsrksvrms Hkh 2 xquk gksxh pwafd k fu;rkad gSA
S2 : l erkih; iz Ø e esaU = 0, Q = PV. v r% oDrO; vlR; gSA
S3 : ,d iw .kZvizR;kLFk VDd j esa] fud k; d k vafre l aosx fud k; d sizkjfEHkd l aosx d scjkcj gksrk gSA ;fn fud k;
d k vafre l aosx v 'kwU; gS] rksfud k; d h d qN v afre xfrt Å t kZgksxhA bl fy ;sfud k; d h iwjh izkjfEHkd xfrt
Å t kZd k {k; ugh gksl d rk gSA bl izd kj ;g d Fku vl R; gSA
10. S1 : Two identical spheres undergo headon collision, then the kinetic energy of each sphere is least
at the same instant of time.
S2 : For a particle undergoing circular motion the angular velocity (considered non-zero) is always
perpendicular to acceleration of the particle.
S3 : The number of nodes and antinodes are equal in a standing sound wave in a pipe, then the pipe
has both ends open.
S1 : nks,d leku xks y slEeq[k izR;kLFk VDd j d jrsgSrksnksuksad h xfrt Å t kZ,d lkFk U;wure gksxhA
S2 : oÙ̀kh; xfr d jrsgq ;s,d d .k d k d ks.kh; osx ¼v'kwU;½ lnSo d .k d sRoj.k d syEcor~gksxkA
S3 : ;fn fd lhuyhes amRiUu vizxkeh/ofu rjax esaizLian ,oafuLian d hla[;kleku gSrksuyhnksuksafljksaij [kqy hgksxhA
(A) T T F (B) TFT (C) FFF (D*) F T F
Sol. S1 : The K.E. of each sphere may not be least at same instant. Hence false
S2 : Angular velocity is perpendicular to plane of circle whereas acceleration lies in plane of circle.
Hence true.
S3 : If number of nodes = number of antinodes then pipe must be open at one end only. Hence false.
gy S1 : leku le; ij nks uksaxksy ksad h xfrt Å t kZU;wure ugh gksld rh vr% vlR; gSA
S2 : d ks
.kh; osx oÙ̀k d sry d syEcor~gksrk gSt cfd Roj.k oÙ̀k d sry esagksrk gSA vr% lR; gSA
S3 : ;fn iz LiUn d h la[;k = fuLian d h la[;k gksrksikbi ,d fljsij gh [kqy k gksxkA vr% vlR; gSA
 (JB-C)_Paper-1_MT(AIOT)-XI Sylla_20-01-13_Pg. No # 6

SECTION - III
Comprehension Type
This section contains 2 paragraphs. Based upon each paragraph, there are 2 questions. Each question
has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

Paragraph for Question Nos. 11 to 12

, A bar of mass m is held as shown between 4 uniform discs , each of mass m & radius r = 75 mm. The
bar has been released from rest, knowing that the normal forces exerted on the discs by vertical
walls are sufficient to prevent any slipping. Answer the following questions assuming attachments
are massless and fixed to the bar. (Acceleration due to gravity is g)
m nzO;eku d h ,d NM+,oapkj ,d leku pd fr;kaçR;sd d k nzO;eku m o f=kT;k r = 75 mm gS]fp=kkuql kj j[kh gS
NM+d ksfojke lsNksM +usd srqjUr ckn ;g ekursgq, fd pd fr;ksaij nksuksaÅ /okZ/kj nhokjksa}kjk vkjksfir vfHkyEc cy
fd lh Hkh çd kj d h fQ lyu jksd usd sfy, i;kZIr gSA fuEu ç'uksad smÙkj nhft ,A ¼NM+rFkk pd rh d kst ksM +usoky k
la;qXed nzO;ekughu gSA½ & ¼xq: Ro d sd kj.k Roj.k g gS½

11. If m = 5 kg and m = 2 kg, then acceleration of the bar is

;fn m = 5 kg o m = 2 kg gksrksNM+d k Roj.k gksxk &
g
(A) g (B) 13g/7 (C*) 13g/17 (D)
17

12. If the mass m of the discs is negligible, then acceleration of the bar is
;fn pd fr;ksad k nzO;eku m' ux.; gSrksNM+d k Roj.k gksxk &
g
(A*) g (B) 2g/3 (C) 13g/17 (D)
17
Sol. 11 to 12
11. (Tough) F.B.D. of disc 
In horizontal direction N = Nx .....(1) Ng
In vertical direction m'g – f – Ny = m'a .....(2)
f
Torque due to friction ;
m' R 2 Nx
fR = 
2
As a = R
m'g
2
m' R a m' a
 fR =  f= put in (2)
2 R 2
3m' a
 m'g – Ny =
2
3m' a
Ny = m'g – ..... (3)
2
Now, F.B.D. of bar ; Ny Ny

4Ny + mg = ma
Put Ny from (3) Ny Ny
4m'g – 6m'a + mg = ma ..... (4)
mg
As m' = 2kg & m = 5 kg
 8g – 12a + 5g = 5a
13g
a= 
17
 (JB-C)_Paper-1_MT(AIOT)-XI Sylla_20-01-13_Pg. No # 7

12. (Easy) From equation (4) (neglecting m') a=g

Sol. 11 to 12
11. (Tough) pd rh d k eq ä oLrqfp=k &
{kSfrt fn'kk esa] N = Nx .....(1)
Ng
Å /okZ/kj fn'kk esa] m'g – f – Ny = m'a .....(2)
f
?k"kZ.k d sd kj.k vk?kw.kZ
m' R 2 Nx
fR = 
2
tc a = R m'g
2
m' R a m' a
 fR =  l eh- (2) esaf = j[kusij
2 R 2
3m' a
 m'g – Ny =
2
3m' a
Ny = m'g – ..... (3)
2
v c] N M+d k eqä oLrqfp=k Ny Ny
4Ny + mg = ma
Put Ny from (3)
4m'g – 6m'a + mg = ma ..... (4)
Ny Ny
tc m' = 2kg & m = 5 kg
 8g – 12a + 5g = 5a mg

13g
a= 
17
12. (Easy) m' d ksux.; ekursgq;sl eh- (4) l s] a=g

Paragraph for Question Nos. 13 to 14

iz'u 13 l s14 d sfy , v uqPN sn
5.3 COMPREHENSION
A sinusoidal wave is propagating in negative x–direction in a string stretched along x-axis. A particle of
string at x = 2m is found at its mean position and it is moving in positive y direction at t = 1 sec. The
amplitude of the wave, the wavelength and the angular frequency of the wave are 0.1meter, /4 meter and
4 rad/sec respectively.
x–v{k d svuqfn'k f[kap h gqbZ,d Mksjh esa,d T;k&oØ h; (sinusoidal) rjax _ .kkRed x-fn'kk esalap fjr gksrh gSA Mksjh
ij x = 2m d k ,d d .k le; t = 1 sec ij viuh ek/; fLFkfr ij ik;k t krk gSrFkk ;g /kukRed y-fn'kk d h vksj xfr
d jrk gSA rjax d k vk;ke] rjaxnS/;ZrFkk d ks.kh; vkof̀Ùk Ø e'k% 0.1 m, /4 m rFkk 4 rad/sec gSaA
13. The equation of the wave is
rjax d k lehd j.k gS&
(A*) y = 0.1 sin (4t –1)+ 8(x – 2)) (B) y = 0.1 sin (t–1)– (x – 2))
(C) y = 0.1 sin (4t –1)–8(x – 2)) (D) none of these bues a ls d ksbZ ugh
Sol. The equation of wave moving in negative x-direction, assuming origin of position at x = 2 and origin of time
(i.e. initial time) at t = 1 sec.
y = 0.1 sin (4t + 8x)
Shifting the origin of position to left by 2m, that is, to x = 0. Also shifting the origin of time backwards by 1
sec, that is to t = 0 sec.
y = 0.1 sin [(4t + 8(x – 2)]
gy % fLFkfr d k ewy fcUnqx = 2 ij rFkk le; d k ewy fcUnq(vFkkZr~çkjfEHkd le;) t = 1 sec. ij ekursgq,] _ .kkRed x–
fn'kk esaxfr d jrh gqbZrjax d k lehd j.k &
y = 0.1 sin (4t + 8x)
fLFkfr d sewy fcUnqd kscka;h vksj 2m, foLFkkfir d jusij]vFkkZr~x = 0 d sfy,A le; d sewy fcUnqd ksHkh 1 sec, ihNs
foLFkkfir d jusij] vFkkZr~t = 0 sec. d sfy, ]
y = 0.1 sin [(4t + 8(x – 2)]
 (JB-C)_Paper-1_MT(AIOT)-XI Sylla_20-01-13_Pg. No # 8

14. The speed of particle at x = 2 m and t = 1sec is

x = 2 m rFkkt = 1sec ij d .k d h pky gS a&
(A) 0.2 m/s (B) 0.6 m/s
(C*) 0.4 m/s (D) 0
Sol. As given the particle at x = 2 is at mean position at t = 1 sec.
 its velocity v = A = 4 × 0.1 = 0.4  m/s.
fn;k x;k d .k t = 2 sec. ij x = 2 ij ek/; fLFkfr ij gSA
 bld k os
x v = A = 4 × 0.1 = 0.4  m/s.

SECTION - IV
Integer Answer Type

This section contains 7 questions. The answer to each of the questions is

a double digit integer, ranging from 00 to 99. The appropriate bubble
below the respective question number in the ORS have to be darkened.

15. One mole of an ideal gas ( = 1.4) at 500 K, is filled in an adiabatic cylinder. The piston is free to move
against atmospheric pressure. A non–conducting fan is inserted into the gas space and rotated vigorously,
so that the gas expands slowly, till its volume is doubled. Find work done by the fan in kJ.
(Take R = 8 J/mole.K, neglect heat capacity of the cylinder, piston and the fan).
,d : ) ks"e ik=k esa,d eksy vkn'kZxSl ( = 1.4) d ks500 K rki ij j[kk x;k gSA fiLVu ok;qe.Myh; nkc d sfo: )
xfr d jusd sfy, LorU=k gSA ,d vpkyd ia[ksd ksxSl d svUnj j[kd j rst h ls?kqek;k t krk gS] rkfd xSl /khjs& /khjs
nqxquk vk;ru gksusrd çlkfjr gksrh gSA bl nkSjku ia[ks}kjk fd ;k x;k d k;ZkJ esaKkr d jksA
(R = 8 J/mole.K, ik=k, fiLVu vkS
j ia[ksd h Å "ek /kkfjrk d ksux.; ekusa)

Ans. 14 kJ
Sol. Using 1st law of TD Å "ekxfrd h d sçFke fu;e ls
Q = W + U

f
0 = (  Wfan )  Pv   n RT
2
f
W fan = n RT + n RT
2
W fan = n Cp T
 f 
W fan = (1)  R  R  (500 k)
 2 
(as the gas is expending slowly so p = constant, so T  v)
(pw
afd xSl /khjs& /khjsçlkfjr gksrh gSvr% p = fu;r]vr%T  v)
W fan = 14 kJ

16. 4th harmonic of an organ pipe has frequency 33 Hz lesser than 5th harmonic of same organ pipe. Find
difference of wavelength (in cm) in the given two cases (Assume velocity of sound in air = 330 m/s).
Neglect end correction.
,d vkWxZu ikbZi d h4th lauknhd hvkof̀Ùkblh ikbZi d h5th lauknhd h vkof̀Ùkls33 Hz U;wu gSA fn, x, nksuksaçd j.kksa
esrjaxnS/;ksZ(lseh esa) d k vUrj Kkr d hft ,A (ok;qesa/ofu osx = 330 m/s ekfu,) fljk la'kks/ku ux.; gSA
 (JB-C)_Paper-1_MT(AIOT)-XI Sylla_20-01-13_Pg. No # 9
Ans. 50
Sol. Clearly it is open organ pipe Li"Vr% ;g [kqy k vkWxZu ikbZi gS
4v 5v
= – 33
2 2
v
= 33
2
2 = 10
 = 5m.

17. A bus is moving with a constant acceleration a = 3g/4 towards right. In the bus, a ball is tied with a
rope and is rotated in vertical circle as shown. The tension in the rope will be minimum, when the rope
makes an angle  with horizontal. Find  in degree.
,d cl a = 3g/4 fu;r Roj.k lsnka;h rjQ xfr d j jgh gSA cl esa,d xsan t ksjLlh lst qM +h gS] m/okZ/kj ry esa
fp=kkuql kj oÙ̀kh; xfr d j jgh gSA jLlh esaruko U;wure gksxk t c jLlh  d ks.k cukrh gS] rks d k eku fMxzh esaKkr
d jksA

 a=3g/4

Ans. 53

B Tmin
inertial force
M(3g/4) 530
Sol. 530

A
Tmax
Fnet mg

Fnet is shown in the figure. So, tension will be max. at point A and will be min. at point B.
Fnet fp=kkuq
l kj iznf'kZr gS] vr% fcUnqA ij ruko vf/kd re~gksxkA rFkk fcUnqB ij U;wure~gksxkA

18 In a cyclic process ABCA for an ideal gas. In AB, BC and CA process 50 J, 20 J and 5 J heat is supplied to
an ideal gas. In process AB internal energy of gas increases by 60 J and in process BC work done by gas
is 30 J. The decrease in internal energy of gas in process CA in joule is :
,d vkn'kZxSl d sfy , pØ h; çØ e ABCA esaAB, BC o CA çØ e esavkn'kZxSl d ks50 J, 20 J o 5 J Å "ek nh t krh
gSA çØ e AB esaxSl d h vkUrfjd Å t kZ60 J lsc<+rh gS,oaçØ e BC esaxSl }kjk fd ;k x;k d k;Z30 J gSA çØ eCAesa
xSl d h vkUrfjd Å t kZesad eh t wy esagksxh :
Ans. 50

Sol.
 (JB-C)_Paper-1_MT(AIOT)-XI Sylla_20-01-13_Pg. No # 10

2
19. One end of a very long chain of linear mass density  is fixed to a cube of mass m and specific density
3
while the other end of chain is free. The cube attached with chain is immersed in deep water container. If
specific density of chain is 6, then find the height h (in mtres) above the surface of container at which cube
m
will float in equilibrium. (Given = 50 metre)

2
js[kh; nzO;eku ?kuRo  d h ,d y Ech t at hj d k ,d fl jk nzO;eku m rFkk fof'k"V ?kuRo d s,d ?ku l st qM +k
3
gS]rFkk nwl jk fl jk eqDr gSA t at hj l st qM +k ?ku t y d sxgjsik=k esaMqcks;k t krk gSA ;fn t at hj d k fof'k"V ?kuRo
6 gS, rks?ku d sl kE;koLFkk esarSjrsl e; bl d h ik=k d h ry h l sÅ ¡p kbZh (ehVj ek=kd esa) K kr d hft ,A (fn;k x;k
m
gS = 50 metre)


Ans. 30
Sol. Weight of cube + straight chain = (m + h) g
 3m h 
Buoyant force =    g
 2 6 
at equilibrium, weight = Buoyant force
3m h
m + h = 
2 6

m 5h 3m
=  h=
2 6 5
Sol. ?ku + Jà[ky k d k Hkkj = (m + h) g
 3m h 
mRIykou cy =  2  6  g
 
lkE;koLFkk esa, Hkkj = mRIy kou cy
3m h
m + h = 
2 6

m 5h 3m
=  h=
2 6 5

20. A standing wave  = (5 mm) sin x.cos (200t) is maintained in a homogeneous rod with cross-sectional
area 0.04 m2 and density 1000 kg/m3. Find the total mechanical-energy in joule confined between the
sections corresponding to the adjacent displacement nodes.
,d vizxkeh rjax  = (5mm) sin x.cos (200 t) ,d leku NM+ft ld k vuqizLFk d kV {ks=kQ y 0.04 m2 rFkk ?kuRo
1000 kg/m3 gSesalap kfjr gSA nksfud VLFk fuLianksd schp lafpr d qy ;kaf=kd Å t kZ¼t wy esa½ Kkr d jks&

Ans. 10
 (JB-C)_Paper-1_MT(AIOT)-XI Sylla_20-01-13_Pg. No # 11

1 2
Sol. Total mechanical energy of vibration =  2 dm v
1 2
d EiUu d h d qy ;kfU=kd Å t kZ=  2 dm v
dm =  dx,  = 103 kg/m3 (0.04) m2
 = 40 kg/m
ds
v(x) = = 5 mm sin x (– sin (200 t)
dt
1
Total mechanical energy d qy ;kfU=kd Å t kZ=  v 2 ( x )dx = 10 joules.

2

21. In the pulley system shown in figure, at an instant if block A is going down at 5 m/s, find speed of block B (in
m/s).In step pulley the ratio of radii is 1 : 2. There is no slipping between step pulley and string. Other
pulleys are frictionless.
fp=k esan'kkZ;sf?kjuh fud k; esafd lh {k.k ;fn Cy kWd A, 5 m/s lsuhpsd h vksj t k jgk gS, rc CykWd B d h pky ¼m/s
esa½ Kkr d hft , (LVsi f?kjuh esaf=kT;kvksad k vuqikr 1 : 2 gSA) LVSi f?kjuh rFkk Mksjh d se/; d ksbZfQ ly u ughagSA vU;
f?kjfu;kW?k"kZ.kjghr gSA

Sol.
Ans. 40
From constrain motion
caf/kr xfr ls
vB = 10 + r
vB
= r – 10
2

vB
= 20
2
vB = 40 m/s
 TEST PATTERN
TEST : MAJOR TEST (MT) (JEE ADVANCE)
TEST DATE : 20-01-2013
TARGET DATE : 10.01.2013 (AIOT)
BATCH : B (DLPD) | (XI SYLLABUS)
Faculty Name : VIJ Sir
Pattern Sent Date : 01.01.2013
Paper Submit Date : 08.01.2013 Paper Final Date : 09-01-2013

Faculty Name : DRM Mam

Pattern Sent Date : 01.01.2013
Paper Submit Date : 07.01.2013 Paper Final Date : 09.01.2013

BATCH : B (DLPD) | (XI SYLLABUS)

Sent to Sm sir and skv sir and asw sir for paper finalisation : 10.01.2013
Physical/Inorganic and Organic chemistry

Correction submit by SKV Sir : and correction done by NKB Sir : 12.01.2013

P a p e r-1
Q .N o . S u b je c t N a t u r e o f Q u e s t io n s N o . o f Q u e s t io n s M a rk s N e g a t iv e T o ta l
1 to 7 SCQ 7 3 0 21
8 to 1 0 P h y s ic s T T F (S 1 , S 2 , S 3 ) 3 4 0 12
1 1 to 1 4 C o m p r e h e n s io n ( 2 c o m p . × 2 Q u e s t io n s ) 4 3 0 12
1 5 to 2 1 In te g e r ( D o u b le D ig it) 7 4 –1 28
2 2 to 2 8 SCQ 7 3 0 21
2 9 to 3 1 T T F (S 1 , S 2 , S 3 ) 3 4 0 12
C h e m is t r y
3 2 to 3 5 C o m p r e h e n s io n ( 2 c o m p . × 2 Q u e s t io n s ) 4 3 0 12
3 6 to 4 2 In te g e r ( D o u b le D ig it) 7 4 –1 28
4 3 to 4 9 SCQ 7 3 0 21
5 0 to 5 2 T T F (S 1 , S 2 , S 3 ) 3 4 0 12
M a th s
5 3 to 5 6 C o m p r e h e n s io n ( 2 c o m p . × 2 Q u e s t io n s ) 4 3 0 12
5 7 to 6 3 In te g e r ( D o u b le D ig it) 7 4 –1 28
T o ta l 63 T o ta l 219
P a p e r-2
Q .N o . S u b je c t N a t u r e o f Q u e s t io n s N o . o f Q u e s t io n s M a rk s N e g a t iv e T o ta l
1 to 8 SCQ 8 3 0 24
9 to 1 6 MCQ 8 4 0 32
P h y s ic s
1 7 to 1 9 A s s e r tio n /R e a s o n in g 3 4 0 12
2 0 to 2 4 In te g e r T y p e ( S in g le d ig it) 5 4 –1 20
2 5 to 3 2 SCQ 8 3 0 24
3 3 to 4 0 MCQ 8 4 0 32
C h e m is t r y
4 1 to 4 3 A s s e r tio n /R e a s o n in g 3 4 0 12
4 4 to 4 8 In te g e r T y p e ( S in g le d ig it) 5 4 –1 20
4 9 to 5 6 SCQ 8 3 0 24
5 7 to 6 4 MCQ 8 4 0 32
M a th s
6 5 to 6 7 A s s e r tio n /R e a s o n in g 3 4 0 12
6 8 to 7 2 In te g e r T y p e ( S in g le d ig it) 5 4 –1 20
T o ta l 72 T o ta l 264

Page NO. # 1
 Paper-1
SECTION - I
Straight Objective Type
This section contains 7 questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONLY ONE is correct.
[k.M - I
lh/ksoLrqfu"B izd kj
bl [k.M esa7 iz'u gSaA izR;sd iz'u d s4 fod Yi (A), (B), (C) rFkk (D) gSa]ft uesalsflQ Z,d l gh gSA

Physical SCQ (4)

22. In what ratio should a 15% solution of acetic acid be mixed with a 3% solution of the acid to prepare a 10%
solution(all percentages are mass/mass percentages) :
3% vEy d sfoy ;u d slkFk 15% ,flfVd vEy d sfoy;u d ksfd l vuq ikr esafefJr d juk pkfg, fd 10% foy ;u
(lHkh izfr'kr nzO;eku@nzO;eku izfr'kr esagSa) cu ld sA
(A) 7 : 3 (B) 5 : 7 (C*) 7 : 5 (D) 7 : 10
15 1000 3 1000
 V1   V2 10 1000
Sol. 60 100 60 100 = 
V1  V2 60 100

or
1 1 1
V1  V2 = ( V1  V2 )
4 20 6
or
V1 V1 V2 V2
 = 
4 6 6 20
or
6 V1  4 V1 10 V2  3 V2
=
24 60
or
2V1 7 V2 V1
= or  7/5
24 60 V2

23. The wave motion of electron in a Bohr's orbit of hydrogen is as shown in diagram. The potential energy of
electron in the given orbit of hydrogen atom is :
gkbMª
kts u ijek.kqd h,d d {kkes abysDVª
kuW d hrjax xfr d ksfuEu fp=k}kjkiz
nf'kZr fd ;kt krkgS
]bl nhxbZd {kes
agkbMªkst u
ijek.kqd sbysDVªkWu d h fLFkfrt Å t kZgksxh %

(A) –3.4 eV (B) + 3.4 eV (C*) –3.02 eV (D) –1.51 eV

Sol. n=3

Z2
PE = – 27.2 × eV
n2

12
PE = – 27.2 × = – 3.02 eV
32

Page NO. # 2
24. In context with the industrial preparation of hydrogen from water gas (CO + H2), which of the following is
the correct statement ?
t y xSl (CO +H2) lsgkbMªkst u d svkS| ksfxd fuekZ.k d slUnHkZesafuEu esalsd kSulk d Fku lgh gS?
(A) CO is removed by absorption in aqueous Cu2Cl2 Solution.
(A) t yh; Cu2Cl2 foy ;u es avo'kks"k.k}kjk CO d ksgVk;k t krkgSA
(B) H2 is removed through occlusion with Pd.
(B) Pd d slkFkvf/k/kkj.k ¼lek;ks t u½ d s}kjkH2 d ksnwj fd ;kt krkgSA
(C*) CO is oxidized to CO2 with steam in the presence of a catalyst followed by absorption of CO2 in alkali.
(C*) mRizsjd d hmifLFkfr esaHkki }kjkCO d ksCO2 esavkWDlhd r̀ fd ;kt krkgSrRi'pkr~CO2 d k{kkjh; vo'kks"k.kgksrkgSA
(D) CO and H2 are fractionally separated using differences in their densities.
(D) mud s?kuRoksaesavUrj d k mi;ksx d jrsgq, CO vkSj H2 d k izHkkt h iFkDd j.k fd ;k t krk gSA
673 K 673 K
Sol. CO + H2O (g)      CO2 + H2 ; CO2 + 2KOH  K2CO3 + H2O
catalyst mRçsjd

25. A(s) 2B(g) + C(g)

The above equilibrium was established by initially taking A(s) only. At equilibrium, B is removed so that its
partial pressure at new equilibrium becomes 1/3rd of original total pressure. Ratio of total pressure at new
equilibrium and at initial equilibrium will be :
A(s) 2B(g) + C(g)
mDr lkE; d ks]izkjEHkesad soy A(s) ysd j LFkkfir fd ;kx;kA lkE; ij]B d ksbl izd kj iF̀kd fd ;kt krkgSfd u;slkE;
ij bld kvkaf'kd nkc]okLrfod ¼ewy ½d qy nkc d k1/3rd gkst krkgSA rc]u;slkE; ij d qy nkc rFkkizkjfEHkd lkE; ij
d qy nkc d k vuqikr gksxk %
(A) 2/3 (B) 14/13 (C*) 5/3 (D) 17/19
Sol. A(s) 2B(g) + C(g)
eq.1 2p p
eq.2 p p'
PT1 = 3p, Kp = 4p3, (p)2 p' = 4p3

p' = 4p, PT2 = p + 4p = 5p

PT2 5p
PT1 = 3p = 5/3

Organic SCQ (3)

26 . The IUPAC name of the following compound is :
fuEufy f[kr ;kSfxd d k vkbZ;wih , lh (IUPAC) uke gS%

(A) 4-Bromo-3-cyanophenol (B*) 2-Bromo-5-hydroxybenzonitrile

(C) 2-Cyano-4-hydroxybromobenzene (D) 6-Bromo-3-hydroxybenzonitrile

(A) 4-cz
kesks-3-lk,ukQs hukWy (B*) 2-cz
kesks-5-gkbMªkWDlhcs
Ut ksukbVª
kbWy
(C) 2-lk,uk-s4-gkbMª
kDWlhcz
ksekcsUst hu (D) 6-cz
ksek-s3-gkbMªkWDlhcs
Ut kuskbVªkWby

Page NO. # 3
Sol.

2-Bromo-5-hydroxybenzonitrile (–CN group gets higher priority over –OH and –Br)
2-cz
kseks-5-gkbMªkWDlhcsUt ksukbVªkWby (–CN lewg –OH rFkk–Br d hrqy ukesaeq[; izkf;d rkj[krkgSA)

27. What is the decreasing order of C–N bond lenth in the given compounds :
fn;sx;s;kSfxd ksaesaC–N cU/k yEckbZd k ?kVrk gqv k Ø e D;k gS%

(A*) x > y > w > z (B) z > y > w > x (C) x > z > y > w (D) y > z > w > x

28. The most stable resonating structure of p-nitroso nitrobenzene is :

p-ukbVª
ksl ksukbVªkscsUt hu d hfuEu vuquknhlajpukvksaesalclsvf/kd LFkk;hgS%

(A) (B) (C*) (D)

Sol. 

–N=O show + m & –effects.

–N=O lew
g + m o –izHkko n'kkZrk gSA

SECTION - II
True & False Statement Type
This Section Contains 3 questions. Each questions contains 3 or 4 statements S1, S2, S3 or S4. Each
statement is either true (T) or false (F). Each questions has 4 choices (A), (B), (C) and (D) each of
which contains whether S1, S2, S3 or S4 are true or false. Exactly one choice contains the correct order
of truthness or falseness of S1, S2, S3 or S4 respectively and is the correct choice.
[k.M - II
lR; o v lR; izd kj
bl [k.M esa3 iz'u gSA izR;sd iz'u d s3 ;k4 d Fku S1, S2, S3 ;k S4 gSA izR;sd d Fku lR; (T) ;kvl R; (F) gksl d rk
gSA izR;sd iz'u d h 4 fod Yi (A), (B), (C) rFkk(D) gSizR;sd esal sd ksbZHkh S1, S2, S3 ;k S4 l R; ;k vl R; gksl d rs
gSA S1, S2, S3 ;k S4 d sl UnHkZesaØ e'k% ,d fod Yi l R; ;k vl R; gSv kSj t ksl gh fod Yi gSA

Page NO. # 4
Physical TTF (S1, S2, S3) (2)
29. S1 : In modern periodic table each block contains a number of columns equal to the number of electrons that
can occupy that sub-shell.
S2 : The greatest increase in ionization enthalpy is experienced on removal of electron from core noble gas
configuration.
S3 : The size of the isoelectronic species is effected by electron-electron interaction in the outer orbitals.
S1 : ,d vk/kqfud vkorZlkj.khesaizR;sd CykWd esaLrEHkd hla[;kbysDVªkWuksad hla[;kd scjkcj gksrhgSat ksml mid ks'k
esaHkjst k ld rsgSaA
S2 : vkUrfjd (core) mRd ` "V xSl foU;kl lsbysDVªkWuksad ksfud kyusij vk;uu ,UFkSYihesavf/kd re of̀) gksrh gSA
S3 : leby s DVªkWfud izt kfr d k vkd kj cká d {kd esabysDVªkWu&bysDVªkWu vUrZfØ ;k }kjk izHkkfor gksrk gSA
(A) FFT (B*) TTF (C) FTF (D) TTT
Sol. (B)
S3 : The size of the isoelectronic species is not effected by electron-electron inter action in the outer orbitals
but is effected by the nuclear charge.
S1 and S2 are correct statements.
gy % (B)
S3 : lebys DVªkWfud izt kfr d k vkd kj cká re d {kd esabysDVªkWu&bysDVªkWu vUrZfØ ;k }kjk izHkkfor ughagksrk gS]ysfd u
ukfHkd h; vkos'k}kjkizHkkfor gksrkgSA
S1 rFkkS2 lgh d Fku gS aA

30. S1: Carbon has allotropic forms due to its property of catenation
S2: Carbon has allotropic forms due to its ability to form p-d bond
S3: Carbon has allotropic forms due to its non-metallic character
fuEu esalsfd l d kj.k lsd kcZu d svij: i gS%
S1: bld h Jà
[kyu d h çof̀r d sd kj.k lsd kcZu d svij: i gS
S2: bld hp-d ca /k cukusd h lkeF;Zd sd kj.k lsd kcZu d svij: i gS
S3: bld sv/kkfRod vfHky{k.kd sd kj.klsd kcZ u d svij: i gS
(A) FFT (B*) TTF (C) FTF (D) TTT

Organic
TTF (S1, S2, S3) (1)
31. S1 : The energy of resonance hybrid is always less than that of any resonating structure.
S2 :The resonance energy is the difference between the enthalpies of formation of the molecule and the
resonating structure having maximum energy.
S3 : The resonance structures are hypothetical structure and they do not represent any real molecule.
S1 : fd lh Hkh vuq
uknh lajpuk d h rqy uk esavuquknh lad j d h Å t kZd e gksrh gSA
S2 : v.kqd sfuekZ
.k d h ,UFkSYih vkSj mPpre Å t kZj[kusokyh lajpuk d h Å t kZd k vUrj vuquknh Å t kZd gykrh gSA
S3 : vuq
uknh lajpuk;sad kYifud lajpuk;sagSrFkk ;sokLrfod lajpuk d ksiznf'kZr ughad jrh gSA
(A) F T F (B*) T F T (C) F F F (D) T T T

SECTION - III
Comprehension Type
This section contains 2 paragraphs. Based upon each paragraph, there are 2 questions. Each question has
4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
[k.M - III
cks/ku çd kj
bl [k.M esa 2 vuqPNsn (paragraphs) gSA çR;sd vuqPNsn ij vk/kkfjr 2 ç'u gSA çR;sd ç'u d s 4 fod Yi
(A), (B), (C) rFkk(D) gS, ft ues
alsflQ Z,d lgh gSA

Page NO. # 5
Physical Comp. (1 × 2) (1)
Paragraph for Question Nos. 32 to 33
iz'u 32 l s33 d sfy , v uqPN sn
The approximate shape of a molecule can often be predicted by using what is called the valence-shell
electron-pair repulsion (VSEPR) model. Electrons in bonds and in lone pairs can be thought of an “ charge
cloud” that repel one another and stay as far apart possible, thus causing molecules to assume specific
shapes.
The repulsive interactions of electron pairs decrease in the order :
lone pair - lone pair > lone pair - bond pair > bond pair - bond pair.
These repulsions effect result in deviations from idealised shapes and alteration in bond angles in
molecules.
,d v.kqd hlaHkkfor vkd f̀r d ksla;kst h&d ks'kbysDVªkWu&;qXe izfrd "kZ.k(VSEPR) ekWM y d ksiz;qDr d j crk;kt kld rk
gS
A cU/kksarFkk,d kd h;q XeksaesabysDVªkWukasd ks,d ^^vkos
f'kr vHk^z^(charge cloud) ekukt kld rkgSt ks,d nwl jsd ksiz
frd f"kZr
d jrsgSarFkk;s,d nwl jslsvf/kd re nwjhij jgrsgSaA bl izd kj ;sv.kqd ks,d fof'k"V vkd f̀r nsusd k d kj.k cursgSaA
fuEu vojksgh Ø e esabysDVªkWu ;qXeksad h izfrd "khZvUrZfØ ;k gksrh gSA
,d kd h ;qXe - ,d kd h ;qXe > ,d kd h ;qXe - cU/k ;qXe > cU/k ;qXe - cU/k ;qXe
;sizfrd "kZ.k v.kqesacU/k d ks.k esaifjorZu rFkk vkn'kZvkd f̀r d ksfod r̀ d jrsgSaA
32. Which of the following statement is correct with respect to bond angle ?
cU/k d ks.k d slanHkZesafuEu esalsd kSulk d Fku lR; gS?
(A) The F - S - F angle in SF2 is more than 109o 28’.
(A) SF2 es aF - S - F d ks.k109o 28’ lsvf/kd gksrk gSA
(B) The H - N - N angle in N2 H2 is approximately 180o .
(B) N2H2 es aH - N - N d ks.k yxHkx 180o gksrk gSA
(C*) The F -Kr - F angle in KrF4 is 90o .
(C*) KrF4 es aF -Kr - F d ks.k 90o gksrk gSA
(D) The Cl - N - O angle in NOCl is more than 120o.
(D) NOCl es aCl - N - O d ks.k 120o lsvf/kd gksrk gSA
Sol. (C)
(A) Bond angle is less than 109º28' because of lp-lp repulsion because bond pairs are more close to fluorine
atoms.
(A) lp-lp çfrd "kZ.kd sd kj.kca/kd ks.k109º28' lsd e gksrkgSD;ksafd ca/k;qXe ¶yksjhu ijek.kqv ksad svf/kd fud V gksrsgSaA

(B) Bond angle is close to 120º because of sp2 hybridisation.

(B) sp2 la
d j.k d sd kj.kca/k d ks.k120º d sfud V gksrkgSaA

(C) KrF4 has square planar shape.

(C) KrF4 d h oxZlery h; vkd f̀r gks
rh gSaA

(D) Bond angle is less than 120º because of repulsion between double bond and lone pair. -electrons of
double bond create more repulsion than single covalent bond.
(D) ca
/k d ks.k120º lsd e gksrk gS] D;kasfd f}ca/k o ,ad kd h ;qXe d se/; çfrd "kZ.k gksrk gSA f}ca/k d s-bysDVªkWu ,d y

Page NO. # 6
 lgla;kst h ca/k d hrqy ukesavf/kd çfrd "kZ.k mRiUu d jrsgSaA

33. Molecular shape of XeF3+, SF3+ and CF3+ are :

(A) the same with 2,1 and 0 lone pairs of electrons respectively.
(B*) different with 2 , 1 and 0 lone pairs of electrons respectively.
(C) different with 0, 1 and 2 lone pairs of electrons respectively.
(D) the same with 2, 0 and 1 lone pairs of electrons respectively.
XeF3+, SF3+ rFkkCF3+ d hvkf.od vkd f̀r;k¡%
(A) leku gSrFkk buesa,d kd h bysDVªkWu ;qXeksad h la[;k Ø e'k%2, 1 rFkk 0 gSA
(B*) fHkUu gSrFkk buesa,d kd h bysDVªkWu ;qXeksad h la[;k Ø e'k%2, 1 rFkk 0 gSA
(C) fHkUu gSrFkk bues
a,d kd h by sDVªkWu ;qXeksad h la[;k Ø e'k%0, 1 rFkk 2 gSA
(D) leku gSrFkk bues a,d kd h bysDVªkWu ;qXeksad h la[;k Ø e'k%2, 0 rFkk 1 gSA
Sol. (B)

(i) (ii) (iii)

sp3d sp3 sp2

(T-shape) (T-vkd f̀r) (trigonal pyramidal) ¼f=kd ks
.kh; fijSfeMh;½ (trigonal planar) ¼f=kd ks
.kh; leryh;½

Comp. (1 × 2) (1)
Paragraph for Question Nos. 34 to 35
iz'u 34 l s35 d sfy , v uqPN sn
Identification of +m & –m groups : If the first atom of the group has lone pair or negative charge shows +m
effect. If the group has vacant p-orbital or vacant d-orbital on first atom. Also a multiple bonded group in which
second atom is more electronegative than the first then it shows –m effect.
+m vkS
j –m lewg d higpku : ;fn lewg d sizFke ijek.kqij ,d kd hbysDVªkWu ;qXe ;k _ .kkRed vkos'k mifLFkr gksrks
og +m izHkko iznf'kZr d jrkgSA ;fn lewg d sizFke ijek.kqij fjDr p-d {kd ;kfjDr d-d {kd mifLFkr gksvkSj cgqcaf/kr
lewg ft lesaf}rh; ijek.kqd h fo|qr_ .krkizFke ijek.kqlsvf/kd gksrksog –m izHkko iznf'kZr d jrk gSA

34. Identify which of the following does not show + m effect.

fuEu esalsd kSulk lewg + m izHkko iznf'kZr ughad jrk gSmlsigpkuksaA
O
||
(A) –NH –
(B)  NH  C  CH (C) –O (D*) –B(CH3)2
3

35. Identify which of the following cannot show – m effect.

fuEu esalsd kSulk lewg – m izHkko iznf'kZr ughad jrk gSmlsigpkuksaA

(A*) –F (B)  P(CH ) (C) –CH = O (D) –NO2
3 3

Sol. Flourine has lone pair of electron so it shows +m effect.

Sol. ¶y ksjhu esa,d kd h bysDVªkWu ;qXe mifLFkr gSvr%+m izHkko iznf'kZr d jrk gSA

Page NO. # 7
 SECTION - IV
Integer Answer Type

This section contains 7 questions. The answer to each of the questions is

a double digit integer, ranging from 00 to 99. The appropriate bubble
below the respective question number in the ORS have to be darkened.

Physical Integer (Double Digit) (4)

36. Spin only magnetic moment (in unit of Bohr magneton) of Co3+ is x then value of x is ________.

Co3+ d s¼d s
oy pØ .k½ pqEcd h; vk?kw.kZ¼cksj esXusVksu d sinksaesa½ x gksrksx d k eku ______ gksxkA
Ans. 24
Sol. Co3+  1s2 2s2 2p6 3s2 3p6 3d6  Number of unpaired electrons = 4.
 Magnetic moment (spin only) = n (n  2) = 24 B.M.

Co3+  1s2 2s2 2p6 3s2 3p6 3d6  v;qfXer bysDVªkWuksad h la[;k= 4.
 pqEcd h; vk?kw.kZ(d soy pØ .k) = n (n  2) = 24 B.M

37. Give the atomic number of the inert gas atom in which the total number of d-electrons is equal to the
difference in the number of total p- and s-electrons.
ml vfØ ; xSl d k ijek.kqØ ekad crkb;sft lesad-bysDVªkWuksad h d qy la[;k p- ,oas-bysDVªkWuksad h d qy la[;k d svUrj
d scjkcj gksrhgSA
Ans. 36
Sol. First gas which contains d-electron is Kr.
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6
Total number of d-electrons = 10
Total number of p-electrons = 6 + 6 + 6 = 18
Total number of s-electrons = 2 + 2 + 2 + 2 = 8
Difference in total number of p- and s - electrons = 18 – 8 = 10
So inert gas is 36Kr.
d-by sDVªkWu ;qDr izFke vfØ ; xSl Kr gSA
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6
d-by sDVªkWuksad h d qy la[;k = 10
p-by s
DVªkWuksad h d qyla[;k = 6 + 6 + 6 = 18
s-by s
DVªkWuksad h d qyla[;k= 2 + 2 + 2 + 2 = 8
p- rFkks - bys
DVªkWuksad h d qy la[;k esavUrj = 18 – 8 = 10
blfy , mijksDr vfØ ; xSl 36Kr gh gSA

38. NH3 is heated initially at 15 atm from 27ºC to 127ºC at constant volume. At 127ºC equilibrium is established.
The new pressue at equilibrium at 127ºC becomes 30 atm for the reaction 2NH3(g) N2(g) + 3H2(g) . Then
find the % of moles of NH3 actually decomposed.
fu;r vk;ru ij NH3 d ksizkjEHkesa15atm ij 27ºC ls127ºC rd xeZfd ;kt krkgSaA 127ºC ij lkE; LFkkfir gkst krk
gSA vfHkfØ ;k 2NH3(g) N2(g) + 3H2(g) d sfy,, 127ºC ij]lkE; ij u;k nkc 30 atm gkst krk gS
]rc]NH3 d s
okLro esafo;ksft r gksusokyseksy ksad k % Kkr d hft ,A
.

Page NO. # 8
Sol. 2NH3 N2 + 3H2
a 0 0
a - 2x x 3x
P1 P2 15 P2
  =  P2 = 20 atm.
T1 T2 300 400

a  2x 30
Now 
a 20
2a + 4x = 3a
1
 x= a.
4
2x
 % of NH3 decomposed = × 100 = 50%
a

2x
 NH3 d k iz
fr'kr fo;kst u = × 100 = 50%
a
Ans. 50

39. The pressure of 11 gm of a gas which is placed in a 4 litres container at 127°C is 2 atm, then the
molecular weight of gas would be ?
(Take R = 0.08 ltr. atm/mol K)
11 xz ke xSl ft l sfd 127°C ij 0.04 y hVj ik=k esaj[kk x;k gS]d k nkc 2 atm gS, rc xSl d k v .kqHkkj fuEu gksxk%
(y hft , R = 0.08 ltr. atm/mol K)
Ans. 44
W
Sol. PV = RT
M
WRT 11 x 0.08 x 400
M= = = 44
PV 2x4

Organic Integer (Double Digit) (3)

40. Give the sum of aromatic and antiaromatic compounds in the following :
fn;sx;s;kSfxd ksaesa,jksesfVd rFkk,UVh,sjksesfVd d k;ksx ¼t ksM+½ fyf[k,

(a) (b) (c) (d) (e)

(f) (g) (h) (i) (j)

(k) (l) (m) (n)

Ans. 13
Sol. Aromatic (,jks
esfVd ) : (a), (b), (c), (d), (e), (f), (h), (l), (m)
Antiaromatic (,UVh,s
jksesfVd ) : (g), (i), (j), (n)
Nonaromatic (ukW
u,sjksesfVd ) : (k)

Page NO. # 9
41. What is the moleculer mass of conjugated diene (X) :

l;qfXer MkbZbu (X) d kv.kqHkkj D;k gS%

Ans. 80

42. Number of  electrons in resonance in the following structure is.

fuEufy f[kr ;kSfxd d svuqukn esafd rusbysDVªkWu Hkkx ysrsgSA \

Ans. 10 e–

Page NO. # 10
 TEST : MAJOR TEST (MT) (JEE ADVANCE)
TEST DATE : 20-01-2013
BATCH : B (DLPD) | (XI SYLLABUS)
Paper-1
Q.No. Subject Nature of Questions No. of Questions Marks Negative Total
1 to 7 SCQ 7 3 0 21
8 to 10 Physics TTF (S1, S2, S3) 3 4 0 12
11 to 14 Comprehension (2 comp. × 2 Questions) 4 3 0 12
15 to 21 Integer (Double Digit) 7 4 –1 28
22 to 28 SCQ 7 3 0 21
29 to 31 TTF (S1, S2, S3) 3 4 0 12
Chemistry
32 to 35 Comprehension (2 comp. × 2 Questions) 4 3 0 12
36 to 42 Integer (Double Digit) 7 4 –1 28
43 to 49 SCQ 7 3 0 21
50 to 52 TTF (S1, S2, S3) 3 4 0 12
Maths
53 to 56 Comprehension (2 comp. × 2 Questions) 4 3 0 12
57 to 63 Integer (Double Digit) 7 4 –1 28
Total 63 Total 219
Paper-2

SECTION - I
Straight Objective Type
This section contains 7 questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONLY ONE is correct.
[k.M - I
lh/ksoLrqfu"B izd kj
bl [k.M esa7 iz'u gSaA izR;sd iz'u d s4 fod Yi (A), (B), (C) rFkk (D) gSa] ft uesalsflQ Z,d l gh gSA

43. A value of a for which one root of quadratic equation (a2 – 5a + 3) x 2 + (2a – 3) x + 2 = 0 is twice as
large as other is
a d k eku ft ld sfy , f}?kkr lehd j.k (a2 – 5a + 3) x 2 + (2a – 3) x + 2 = 0 d k ,d ew
y ] nwl jsd sewy lsnqxuk
gS&
1 3 3 1
(A) – (B*) (C) – (D)
3 5 5 3

2a  3 2
Sol. Let the roots be  and 2, then  + 2 = – 2
and 22 = 2
a  5a  3 a  5a  3

2a  3 2
ekuk  vkSj 2nksewy gSrc  + 2 = – 2
vkSj 22 = 2
a  5a  3 a  5a  3
2
 2a  3  9
i.e  2   2
 a  5a  3  a  5a  3
i.e 4a – 12a + 9 = 9a2 – 45a + 27
2

i.e 5a2 – 33a + 18 = 0

33  1089  360 3
i.e a= = 6,
10 5

Page # 1
44. If a, a1, a2, a3 , ......, a100 , b are in A.P. and a, g1, g2, ...., g100b , are in G.P. and h is harmonic mean of a and
g1g 2 g3 ....g100 g 2 g3 g 4 ....g99 g3 g 4 g5 ....g98 g50 g51
b, then + + + ...+ is equal to
(a1  a100 ) 50
(a 2  a 99 ) 49 (a 3  a 98 ) 48 (a 50  a 51 )
;fn a, a1, a2, a3 , ......, a100 , b lekUrj Js.kh esagSvkSj a, g1, g2, ...., g100b xq.kksÙkj Js.kh esagSrFkk a vkSj b d k gjkRed
g1g 2 g3 ....g100 g 2 g3 g 4 ....g99 g3 g 4 g5 ....g98 g50 g51
ek/; h gS] rc 50 + 49 + + ...+ cjkcj gS&
(a1  a100 ) (a 2  a 99 ) (a 3  a 98 ) 48 (a 50  a 51 )

h(h50  1) h(h50  250 ) h(h50  2 50 ) 2(h50  2 50 )

(A) (B) (C*) (D)
h 1 h2 250 (h  2) h 50 (h  2)
Sol. Using property xq.k/keZlsg1g100 = g2 g99 = g3 g98 = .... = g50 g51 = ab
andvkS
j a1 + a100 = a2 + a99 = a3 + a98 = .... = a50 + a51 = a + b
(ab)50 (ab) 49 ab
given expression fn;k x;k O;a
td = 50 + 49 + ..... +
(a  b ) (a  b ) ab

  h  50 
    1
50 49
h  2  h(h50  250 )
h h h  

=   +   + ..... +   = =
2 2 2 2 h  250 (h  2)
  1
2 

45. The sum of the coefficient of all the terms in the expansion of (2x – y + z)20 in which y do not appear at all
while x appears in even powers and z appears in odd powers is
(2x – y + z)20 d siz
l kj esa,sl slHkh inksa]ft uesay d h ?kkr 'kwU; gS]x d h ?kkr le gSvkSj z d h ?kkr fo"ke gS]d sxq.kkad ks
d k ;ksx gS&

2 20  1 3 20  1
(A*) 0 (B) (C) 219 (D)
2 2
20 ! 20 !
p q r p q p q r
Sol. p ! q! r ! (2x) (– y) (z) = p ! q! r ! 2 (–1) x y z
p + q + r = 20 q=0
p + r = 20 p is even and r is odd
even + odd = even (never possible)
Coefficient of such power never occur
 coefficient is zero
20 ! 20 !
p q r p q p q r
Hindi. p ! q! r ! (2x) (– y) (z) = p ! q! r ! 2 (–1) x y z
p + q + r = 20 q=0
p + r = 20 p le vkS j r fo"ke gSA
le + fo"ke = le (d Hkh ughagksld rk gS)
 xq.kkad 'kwU; gSA

46. The number of six letter words, each consisting of three consonants and 3 vowels, that can be formed
using the letters of the word "CIRCUMFERENCE" is
'kCn "CIRCUMFERENCE" l scuusoky sN % v{kjksad sos'kCn ft uesal sizR;sd esarhu O;at d rFkk rhu Loj gSa
d h l a[;k gS&
(A*) 22100 (B) 22150 (C) 22101 (D) 21200

Page # 2
Sol. CIRCUMFERENCE
CRMFN IUE
3 211 1 113
Number of places for consonants = 6C3 = 20
3 consonants can be arranged in 1 + 2C1 . 4C1 . 3 + 5C3 . 6 = 85
3 vowels can be arranged in 1 + 2 . 3 + 6 = 13
 Total number of ways = 20 . 85 . 13 = 22100
Hindi. C I R C U M F E R E N C E
CRMFN IUE
3 211 1 113
O;at d ksad h fy , LFkkuksad h l a[;k = 6C3 = 20
3 O;at d 1 + 2C1 . 4C1 . 3 + 5C3 . 6 = 85 rjhd ksal sO;ofLFkr fd ;st k l d rsgSaA
3 Loj 1 + 2 . 3 + 6 = 13 rjhd ks al sO;ofLFkr fd ;st k l d rsgSaA
 d qy rjhd ksad h l a[;k = 20 . 85 . 13 = 22100

47. If in a ABC the equation of angle bisector of angle B is y = x and angle C is y = –x.
The equation of line BC if the coordiates of A are (5, 7) is
,d f=kHkqt ABC esad ks.kB vkSj d ks.k C d sd ks.k l ef}Hkkt d ksad sl ehd j.k Ø e'k%
y = x vkSj y = –x gSA ;fn 'kh"kZA d sfunsZ'kkad (5, 7) gS] rksjs[kk BC d k l ehd j.k gS&
(A) x + y + 1 = 0 (B) 7y + 5x – 3 = 0
(C*) 7y = 5x (D) none of these bues al sd ksbZugh
Sol.  y = x and y = –x are angle bisectors of B & C respectively
 Image of A about y = x and y = –x i.e. (7, 5) and (–7, –5) must lie on line joining
B and C
 equation of BC is
10
(y + 5) = (x + 7)  7y = 5x
14

(A) x + y + 1 = 0 (B) 7y + 5x – 3 = 0
(C*) 7y = 5x (D) buesal sd ksbZugh
Hindi  y=x rFkk y = –x Ø e'k% B & C d sd ks.k l ef}Hkkt d gSaA
 y = x v kS
j y = –x d sl kis{k A d sizfrfcEc vFkkZr~(7, 5) vkSj (–7, –5) js[kk BC ij fLFkr gksaxsA
 BC d k l ehd j.k
10
(y + 5) = (x + 7)  7y = 5x
14

48. If two distinct chords of a parabola y2 = 4ax passing through the point (a, 2a) are bisected by the line
x + y = 1, then length of the latus rectum can be
;fn ijoy; y2 = 4ax d sfcUnq(a, 2a) lsxqt jusokyh nksfofHkUu t hok,a] js[kk x + y = 1 d kslef) Hkkft r d jrh gS]
rc ukfHkyEc d h yEckbZgksld rh gS&
(A*) 2 (B) 7 (C) 4 (D) 5
Sol. The chord with mid point (, 1 – ) is T = S1
t hok d k e/; fcUnq(, 1 – ) gS] rc T = S1
y(1 – ) – 2a(x + ) = (1 – )2 – 4a
it passes through (a, 2a)
;g (a, 2a) lsxqt jrh gSA
(1 – )2 = 2a (1 – a) > 0  a  (0, 1)
4a  (0, 4)

49. The number of solutions of the equation 1 cos x = sin x which lie in the interval [, 5], are

v Urjky [, 5] esafLFkr l ehd j.k 1 cos x = sin x d sgy ksad h l a[;k gSa&
(A) 6 (B) 5 (C*) 4 (D) 3

Page # 3
Sol. 1 cos x = sinx
1 – cos x = sin2x
i.e. cos 2x – cos x = 0
i.e. cos x = 0 or cos x = 1
and rFkk sinx  0
5 9
 The solutions are 2, , 4 ,
2 2
5 9
gy 2, , 4 , gSaA
2 2
 There are four solutions
 ;gk¡pkj gy gSaA

SECTION - II
True & False Statement Type
This Section Contains 3 questions. Each questions contains 3 or 4 statements S1, S2, S3 or S4. Each
statement is either true (T) or false (F). Each questions has 4 choices (A), (B), (C) and (D) each of
which contains whether S1, S2, S3 or S4 are true or false. Exactly one choice contains the correct order
of truthness or falseness of S1, S2, S3 or S4 respectively and is the correct choice.

50. Consider the following statements :

fuEu d Fkuksaij /;ku nhft ,&
S1 : If two quadratic expressions f(x) = ax2 + bx + c and g(x) = ax2 + px + q, have equal discreminants
and f(x) = g(x) has a root x = , then arithematic mean of roots of f(x) + g(x) = 0 is 
;fn nksf}?kkr O;at d ksaf(x) = ax2 + bx + c vkSj g(x) = ax2 + px + q d sfoosp d cjkcj gSv kSj f(x) = g(x) d k
,d ewy x = gS] rksf(x) + g(x) = 0 d sewy ksad k l ekUrj ek/; gSA
1 a bc 1 a a2
S2 : The determinants D1 = 1 b ca , D2 = 1 b b 2 , then D1 = D2
1 c ab 1 c c2

1 a bc 1 a a2
l kjf.kd D1 = 1 b ca , D2 = 1 b b 2 gks] rks D1 = D2.
1 c ab 1 c c2

S3 : cos 1° > cos 1

State, in order, whether S1, S2, S3 are true or false
Ø e esacrk,¡fd S1, S2, S3 l R; ;k vl R; gSA
(A*) T T T (B) F T T (C) T F T (D) F F F
Sol. S1 : discriminants of f(x) & g(x) are equal
f(x) vkS
j g(x) d sfoosp d cjkcj gSA
 b2 – 4ac = p2 – 4aq
(b  p) (c  q)
 – = ..... (i)
4a (p  b )
f(x) = g(x) has a root 
 p + q = b + c
(c  q) (b  p)
 = =  by (i)
(p  b ) 4a
also f(x) + g(x) = 0
 2ax 2 + (p + b) x + (c + q) = 0
(b  p)
A.M. of its roots is  =
4a
(b  p)
bl d sewy ksad k l ekUrj ek/;  = gS
A
4a
Page # 4
  true
1 a bc
S2 : D1 = 1 b ca
1 c ab

a a2 abc a a2 1
1 2 abc
= b b abc = b b 2 1 = D2 True
abc 2 abc
c c abc c c2 1

S3 :  1c  57° and cos x decreases in first quadrant

1c  57° vkS
j izFke prqFkk±'k esacos x Ðkl eku gSA
 cos 1° > cos 1 true

51. Consider the following statements :

S1 : If x + y = k is a normal to y2 = 12x, then k = 9
S2 : The centre of ellipse 4x2 + 9y2 – 16x – 54y + 61 = 0 is (2, 3)
S3 : If in a triangle (a + b + c) (– a + b + c) = kbc, then k  [0, 3]
State, in order, whether S1, S2, S3 are true or false
fuEufy f[kr d Fkuksaij fopkj d hft , %
S1 : ;fn y2 = 12x d k vfHky Ec x + y = k gS] rc k = 9
S2 : nh?kZoÙ̀k 4x2 + 9y2 – 16x – 54y + 61 = 0 d k d sUnz(2, 3) gS
S3 : f=kHkqt esa;fn (a + b + c) (– a + b + c) = kbc gks] rksk  [0, 3]
S1, S2, S3 d sl R; (T) ;k vl R; (F) gks usd k l gh Ø e gS&
(A*) T T F (B) T F T (C) F T F (D) F F T

(A*) T T F (B) T F T (C) F T F (D) F F T

Sol. S1 : x + y = k is a normal to y2 = 12x
 k = – 2.3.(– 1) – 3(– 1)3 (c = – 2am – am3)
 k=6+3=9  S1 is true.
S2 : 4x2 + 9y2 – 16x – 54y + 61 = 0
 4(x2 – 4x) + 9 (y2 – 6y) = – 61
 4(x – 2)2 + 9(y – 3)2 = – 61 + 16 + 81 = 36
( x – 2) 2 ( y – 3 ) 2
  1
9 4
 centre is (2, 3)
S2 is true.
S3 : (a + b + c) (– a + b + c) = kbc
 (b + c)2 – a2 = kbc
 b2 + c2 + 2bc – a2 = kbc
 b2 + c2 – a2 = (k – 2) bc
b2  c 2 – a2 k – 2
 
2bc 2
k–2
 cosA =
2
in a triangle 0 < A <   cos < cosA < cos0
k–2
 –1< <1  –2<k–2<2
2
 0<k<4  k  (0, 4)
 S3 is false

Page # 5
Hindi. S1 : x + y = k is a normal to y2 = 12x
 k = – 2.3.(– 1) – 3(– 1)3 (c = – 2am – am3)
 k=6+3=9  S1 lR; gSA
S2 : 2 2
4x + 9y – 16x – 54y + 61 = 0
 4(x2 – 4x) + 9 (y2 – 6y) = – 61
 4(x – 2)2 + 9(y – 3)2 = – 61 + 16 + 81 = 36
( x – 2) 2 ( y – 3 ) 2
  1
9 4
 d sUnz(2, 3)
S2 lR; gSA
S3 : (a + b + c) (– a + b + c) = kbc
 (b + c)2 – a2 = kbc
 b2 + c2 + 2bc – a2 = kbc
 b2 + c2 – a2 = (k – 2) bc
b2  c 2 – a2 k – 2
 
2bc 2
k–2
 cosA =
2
f=kHkqt 0 < A <  cos < cosA < cos0
k–2
 –1< <1  –2<k–2<2
2
 0<k<4  k  (0, 4)
 S3 vlR; gS
A

52. Consider the following statements

S1 : If r and s are non negative integers and r + s = 2n + 1, then r! s! is least when value of |r – s| is 2.
 1  x sin x – cos 2x 
S2 : xlim
 
0  tan 2
( x / 2 )  = 6.
 
S3 : Number of values of ‘’ in [0, 4] satisfying the equation cos3 = 3cos, are 4
State, in order, whether S1, S2, S3 are true or false
fuEufy f[kr d Fkuksaij fopkj d hft , %
S1 : ;fn r rFkk s v_ .kkRed iw .kk±d gSrFkk r + s = 2n + 1 gS] rksr! s! U;wure gS] t c |r – s| d k eku 2 gSA
 1  x sin x – cos 2x 
S2 : xlim
 
0  tan2 ( x / 2)  = 6.
 
S3 : vUrjky [0, 4] esa‘’ d seku t ksfd l ehd j.k cos3 = 3cosd ksl Urq"V d jrsgS]d h l a[;k 4 gSA
S1, S2, S3 d sl R; (T) ;k v l R; (F) gksusd k l gh Ø e gS&
(A) T F T (B) F T F (C) F F T (D*) F T T

Page # 6
 (2n  1)!
Sol. S1 : Since r! s! is minimum ,  r ! s ! is greatest.
 |r – s| = 1
 S1 is false.

1  x sin x  cos 2x
S2 : lim =
x 0 x
tan 2  
2

lim (1  cos 2x )  x sin x sin x(2 sin x  x )

x 0
= xlim0
x  x
tan 2  ( 1  x sin x  cos 2 x ) 2 tan 2  
2
  2

 sin x  sin x 
  2  1
x x
= xlim
  
0 2 = 2(1)(3) = 6
 x
tan 
2  2
.
4 x 
 
 2 

S3 : cos3 = 3cos
4cos 3 – 3cos = 3cos
cos(4cos 2 – 6) = 0
cos = 0

 3 5 7
  = , , , .
2 2 2 2

SECTION - III
Comprehension Type
This section contains 2 paragraphs. Based upon each paragraph, there are 2 questions. Each question
has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

Paragraph for Question Nos. 53 to 54

iz'u 53 l s54 d sfy , v uqPN sn
Let (x, y)  x2 + y2 + 2gx + 2fy + c = 0 be a circle of radius k passing through the points (, 0) and
(0, ),   0. If (, 0) = 0 has equal roots and (1, 1) = – 2 ,then

53. Value of k is
(A) 1 (B*) 2 (C) 4 (D) 8
Sol. Since the circle passes through (, 0) and (0, )
 2 + 2g + c = 0 ..... (i)
and 2 + 2f + c = 0 ..... (ii)
 g=f
Since the roots equation (i) are equal
 g2 = c
 equation of circle is
x2 + y2 + 2gx + 2gy + g2 = 0
Now by (1, 1) = – 2
1 + 1 + 2g + 2g + g2 = – 2
g2 + 4 g + 4 = 0
 f = g = – 2 and c = 4
 (x, y)  x2 + y2 – 4x – 4y + 4 = 0
 k=2

Page # 7
54. Let the equation of tangent to the circle x2 + y2 – 2kx = 0 which is perpendicular to the normal drawn through
the origin be x + by = c, (where c  0 and k is obtained by Q.No. 53) then c =
(A*) 4 (B) 3 (C) 2 (D) 1
Sol. Since k = 2
 the equation of the circle is x2 + y2 – 4x = 0
(x – 2)2 + y2 = 4
 equation of normal through origin is y = 0
 equation of tangent perpendicular to this normal is x = 4
 c=4

iz'u 53 l s54 d sfy , v uqPN sn

ekukfd (x, y)  x2 + y2 + 2gx + 2fy + c = 0 ,d oÙ̀k gS ft l d h f=kT;k k gS vkSj ;g fcUnqv ksa(, 0) v kSj
(0, ),   0 l sxq
t jrk gSA ;fn (, 0) = 0 d sewy cjkcj gSvkSj (1, 1) = – 2 gks] rks&

53. k d k eku gS&

(A) 1 (B*) 2 (C) 4 (D) 8
Sol. pwafd oÙ̀k (, 0) v kSj (0, ) l sxqt jrk gSA
 2 + 2g + c = 0 ..... (i)
and 2 + 2f + c = 0 ..... (ii)
 g=f
pwafd l ehd j.k (i) d sewy cjkcj gSA
 g2 = c
 oÙ̀k d k l ehd j.k x2 + y2 + 2gx + 2gy + g2 = 0 gSA
Now by (1, 1) = – 2
1 + 1 + 2g + 2g + g2 = – 2
g2 + 4 g + 4 = 0
 f = g = – 2 and c = 4
 (x, y)  x2 + y2 – 4x – 4y + 4 = 0
 k=2

54. ekukfd oÙ̀k x2 + y2 – 2kx = 0 ij ewy fcUnq l s [khap s x;s vfHky Ec d s y Ecor~ Li'kZ js[kk d k l ehd j.k
x + by = c gS
](t gk¡c  0 ,oak iz'u l a- 53 l sizkIr gksxk) rksc =
(A*) 4 (B) 3 (C) 2 (D) 1
Sol. Since k=2 [Circle, M]
 oÙ̀k d k l ehd j.k x2 + y2 – 4x = 0
(x – 2)2 + y2 = 4
 ewy fcUnql svfHky Ec d k l ehd j.k y = 0
 bl vfHky Ec d sy Ecor~Li'kZjs[kk d k l ehd j.k x = 4
 c=4
Paragraph for Question Nos. 55 to 56
iz'u 55 l s56 d sfy , v uqPN sn
Consider f(x) = | logax – 4 | – | loga2 x  4 |

ekukfd f(x) = | logax – 4 | – | loga2 x  4 |

55. If f(x) = 4 has n solutions and product of these solutions is k, then k =

;fn f(x) = 4 d sn gy gSrFkk bu gy ksad k xq.kuQ y k gS, rc k =
n
(A*) (B) n (C) 2n (D) 3n
2

Page # 8
 1
Sol. Let logax = t, then f(x) = |t – 4| – t4
2
1
f(x) = 4  |t – 4| – t4 =4
2
case- when t < 4, the equation becomes

 t
4 – t – 4   = 4 i.e. t = – 8 i.e.x = a–8 is a solution
 2 
case- when 4  t < 8, the equation becomes

 t
t – 4 – 4   = 4 i.e. t = 8 (not possible)
 2 
case- when t  8, the equation becomes
1 
t – 4 –  t  4 = 4 i.e. t=8 i.e.x = a8 is a solution
2 
n
product of the solutions = k = 1 =
2

1
ekukfd logax = t gks] rksf(x) = |t – 4| – t4
2

1
f(x) = 4  |t – 4| – t4 =4
2

case- t c t < 4, rkslehd j.k fuEu gks

xh
 t
4 – t – 4  2  = 4 vFkkZr~ t = – 8 vFkkZr~ x = a–8 ,d gy gSSA
 
case- t c 4  t < 8, rkslehd j.k fuEu gks
xh
 t
t – 4 – 4  2  = 4 vFkkZr~ t = 8 (lEHko ughagS)
 
case- t c t  8, rkslehd j.k fuEu gks
xh
1 
t – 4 –  t  4 = 4 vFkkZr~ t = 8 vFkkZr~ x = a8 ,d gy gSA
2 

n
gy ksad k xq.kuQ y = k = 1 =
2
56. If a = 2, then the greater solution of f(x) = 4 is
;fn a = 2 gks] rksf(x) = 4 d k cM+k gy gS
(A) 22k (B) 24k (C*) 28k (D) 1
1
Sol. Let logax = t, then f(x) = |t – 4| – t4
2
1
f(x) = 4  |t – 4| – t4 =4
2
case- when t < 4, the equation becomes

 t
4 – t – 4   = 4 i.e. t = – 8 i.e. x = a–8 is a solution
 2 
case- when 4  t < 8, the equation becomes

 t
t – 4 – 4   = 4 i.e. t = 8 (not possible)
 2

Page # 9
case- when t  8, the equation becomes
1 
t – 4 –  t  4 = 4 i.e. t=8 i.e. x = a8 is a solution
2 
Since a = 2  greater solution is 28 = 28k

1
ekukfd logax = t gks] rksf(x) = |t – 4| – t4
2

1
f(x) = 4  |t – 4| – t4 =4
2

case- t c t < 4, rkslehd j.k fuEu gks

xh
 t
4 – t – 4  2  = 4 vFkkZr~ t = – 8 vFkkZr~ x = a–8 ,d gy gSSA
 
case- t c 4  t < 8, rkslehd j.k fuEu gks
xh
 t
t – 4 – 4  2  = 4 vFkkZr~ t = 8 (lEHko ughagS)
 
case- t c t  8, rkslehd j.k fuEu gks
xh
1 
t – 4 –  t  4 = 4 vFkkZr~ t = 8 vFkkZr~ x = a8 ,d gy gSA
2 

pwafd a = 2  vf/kd re gy 28 = 28k gSA

SECTION - IV
Integer Answer Type

This section contains 7 questions. The answer to each of the questions is

a double digit integer, ranging from 00 to 99. The appropriate bubble
below the respective question number in the ORS have to be darkened.

[k.M - IV
iw.kk±d mÙkj izd kj
bl [k.M esa7 iz'u gSaA izR;sd iz'u d kmÙkj 00 ls99 rd iw.kk±d gSA ORS esaiz'u
la[;k d slaxr uhpsfn;sx;scqYyksaesalslgh mÙkj okyscqYyksad ksd kyk fd ;k t kuk
gSA

( 2a  1)x 2  2(a  1)x  ( 2a  1)

57. If set of all real value of a such that f(x) = always negative is (– , p),
x 2  2x  40
then find the value of p.
( 2a  1)x 2  2(a  1)x  ( 2a  1)
;fn a d sl Hkh okLrfod ekuksad k l eqPp; ft l d sfy , f(x) = l nSo _ .kkRed
x 2  2x  40
gks] (– , p) gS] rksp d k eku K kr d hft ,A

Ans. 00

Page # 10
 ( 2a  1)x 2  2(a  1)x  ( 2a  1)
Sol. < 0, for all x  R
x 2  2 x  40

 (2a – 1) x 2 + 2(a + 1) x + (2a – 1) < 0, for all x  R

 2a – 1 < 0 and rFkk4(a +1)2 – 4(2a – 1)2 < 0
1
 a< and rFkk3a(–a + 2) < 0
2

1
 a< and rFkk a(a – 2) > 0
2

1
 a< and rFkk {a < 0 or a > 2}
2

Thus vr% a < 0

58. Find the least positive integer n such that

1 1 1 1
  .......  
sin 45 º sin 46º sin 47 º sin 48 º sin 133 º sin 134 º sin nº .
U;wure /kukRed iw.kk±d n Kkr d hft ;sft ld sfy;s
1 1 1 1
  .......  
sin 45 º sin 46º sin 47 º sin 48 º sin 133 º sin 134 º sin nº .
Ans. 01
1 1 1
Sol.   ....... 
sin 45 º sin 46 º sin 47 º sin 48 º sin133 º sin134 º

1  sin1º sin1º sin1º 

=    ....... 
sin 1º  sin 45 º sin 46 º sin 47 º sin 48 º sin133 º sin134 º 

1  sin( 46 º 45 º ) sin(134 º 133 º ) 

=  .......... . 
sin 1º  sin 45 º sin 46 º sin133 º sin134 º 

1
= [cot45º – cot46º + cot47º – cot48º + ........ + cot131º – cot132º + cot 133º – cot134º]
sin 1º
Using, cot134º = cot(180º – 46º) = –cot 46º
cot133º = cot(180º – 47º) = –cot 47º So on
1
=  n = 1.
sin 1º

x2 x3 x5

59. If x4 x6 x9 = kx 2 + x + m, then find the value of 2 – 5(k +  + m).
x  8 x  11 x  15

x2 x3 x5

;fn x4 x6 x9 = kx 2 + x + m gS] rks2 – 5(k +  + m) d k eku K kr d hft ,A
x  8 x  11 x  15

Ans. 12

x2 x3 x5 x2 1 2 x2 1 2

Sol. x4 x6 x9 = x4 2 3 = 2 1 1 =–2
x  8 x  11 x  15 x8 3 4 4 1 1

 k = 0,  = 0, m = – 2,  2 – 5(k +  + m) = 12
Page # 11
60. T he s um of the s quar es of the r ecipr oc als of two per pendic ular diam eter s of the
ellipse 5x 2 + 4y2 = 1 is equal to k, then find the value of 8k.
nh?kZoÙ̀k 5x2 + 4y2 = 1 d snksijLij y Ecor~O;kl d sO;qRØ eksad soxksZd k ;ksxQ y k d scjkcj gS]rc 8k d k eku cjkcj
gSA
Ans. 18

1  m2
Sol. Length of the diameter with slope m is = 2
5  4m 2

1 1  m2
Length of the diameter with slope – is = 2
m 4  5m 2
9
 sum of the squares of the reciprocals = =k
4
 4k = 9

1  m2
Hindi. izo.krk m d k O;kl d h yEckbZ= 2
5  4m 2

1 1  m2
izo.krk – d k O;kl d h y EckbZ= 2
m 4  5m 2
9
 O;qRØ eksad soxZd k ;ksxQ y = =k
4
 4k = 9

x2 y2
61. If PQ is a double ordinate and e is eccentricity of the hyperbola  1 such that OPQ is an –
a2 b2
equilateral triangle, O being the centre of the hyperbola, then find the least possible integral value of 3e2.
x2 y2
;fn vfrijoy; – 1 d h f}d ksfV PQ rFkk mRd sUnzrk e bl izd kj gSfd OPQ ,d leckgqf=kHkqt gSA O
a2 b2
vfrijoy ; d k d sUnzgS] rks3e2 d k U;wure laHkkfor iw.kk±d eku Kkr d hft ,A
Ans. 05
Sol. Let co-ordinate of P be (, ),

Then PQ = 2 and OP =  2  2
Since OPQ is an equilateral triangle OP = PQ
 2 +  2 = 4 2
 2 = 3 2
Also since (, ) lies on the given hyperbola
2 2 3 2 2 3 1 1
2
– 2
1  2
– 1  –  0
a b a b2 a 2
b 2
2
b2 1 1
 2
  e2 – 1 >  3e2 > 4
a 3 3
Hindi ekuk P d sfunsZ'kkad (, ) gSA
rc PQ = 2 vkSj OP =  2  2
pawfd OPQ ,d leckgqf=kHkqt gSOP = PQ
 2 +  2 = 4 2
 2 = 3 2
rFkk (, ) fn;sx;svfrijoy; ij fLFkr gSA
2 2 3 2 2 3 1 1
– 1  – 1  –  0
a2 b2 a2 b2 a 2
b 2
2
b2 1 1
 2
  e2 – 1 >  3e2 > 4
a 3 3

Page # 12
62. PN is an ordinate of the parabola y2 = 4ax. A straight line is drawn parallel to the axis to bisect NP and
meets the curve in Q. NQ meets the tangent at the vertex in a point T such that AT = kNP, then find
the value of 30k. (Where A is the vertex)
ijoy ; y2 = 4ax d h d ksfV PN gSt gk¡P ijoy ; ij fLFkr gSA v{k d sl ekUrj ,d l jy js[kkNP d ksl ef}Hkkft r
d jrh gSrFkk oØ d ksQ ij fey rh gSA NQ 'kh"kZij [khap h xbZLi'kZjs[kk d ksfcUnq T ij bl izd kj fey rh gSfd
AT = kNP gks ] rks30k d k eku gS(t gk¡A 'kh"kZgSA)
Ans. 20
Sol. Let ekuk P (at2, 2at)
NP = 2at ... (i)
Equation of L, y = at js[kk L d k lehd j.ky = at
Co-ordinate of Q Q d k funsZ'kkad
2
y = 4ax
a2t2 = 4ax
at 2
 x=
4
 at 2 
Q  , at 
 4


equation of NQ NQ d k lehd j.k

at
y–0= (x – at2)
3 2
– at
4
4at
y= (x – at2)
– 3at 2
for point T, put x = 0 in equation of NQ fcUnqT d sfy, , x = 0 ij NQ d k lehd j.k
4 4at 4at
y=+ (at2) =  AT = ... (ii)
3t 3 3

AT 4at 2
by (i) & (ii) =K= 
NP 3(2at ) 3

63. The number of different necklaces formed by using 30 identical diamonds and 3 different jewels when
exactly two jewels are always together is 10x + y, where 0  x, y  9, then find the value of |x – y|.
30 loZl e ghjsrFkk 3 fofHkUu Lo.kZlscuusokysfofHkUu gkjksa(necklaces) d h la[;k10x + y gSt cfd Bhd nksLo.kZ
lkFk lkFk gks] t gk¡0  x, y  9 rc |x – y| d k eku Kkr d hft ,A
Ans. 09
(3 1)!  2 !
Sol. Required number of ways Ø ep; = 3C2 × 2! (30 ! )! – 3 = 90
x = 9, y = 0 |x – y| = | 9 – 0| = 9

Page # 13