Safety Data Sheet

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SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier Solvent CORPS the distillation residue of butyl alcohols HScode 3814009000

1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
Product Categories [PC]
PC9 - Coatings and paints, fillers, putties, thinners
PC35 - Washing and cleaning products (including solvent based products)
as a solvent for obtaining a fuel composition, in the production of corrosion inhibitors, graffiti removals
1.3 Details of the supplier of the safety data sheet
Supplier (manufacturer/importer/only representative/downstream
user/distributor) STS LLC, STS Group Chemicals

Street: prospect Mira, 106, office 342

Postal code/city: 129626 Moscow
Product Name: Platinum Herbicide
Telephone: +7 495 640 9420 Page: 1 of 6
This version issued: July, 2016
E-mail (competent person): vmachulski@stschemical.ru info@stschemical.ru
Section 1 - Identification of The Material and Supplier
1.4 Emergency telephone number +7 495 640 9420
Adama Australia Pty Ltd, Telephone (02)9431 7800 (office hours)
Suite 1, Level 4, Building B Emergency 1800 024 973 (24 hours)
Fax (02)9431 7700
207 Pacific Highway St Leonards, NSW 2065
SECTION 2: Hazards identification
ACN 050 328 973
Chemical nature: Active ingredient is a cyclohexanedioneoxime derivative.
Trade Name: Platinum Herbicide
2.1 Classification
APVMA Code: of the59904
substance or mixture
Classification according herbicide
Product Use: Agricultural to Regulation
for use as described(EC)
on theNo.1272/2008
product label. [CLP]
Flammable liquids Category 4

Creation Date: December, 2005
This version issued: July, 2016 and is valid for 5 years from this date.
Aspiration Hazard Category 2

Poisons Information Centre: Phone 13 1126 from anywhere in Australia
Section 2 - Hazards Identification
Skin Irritation Category 2

Statement of Hazardous Nature
This product is classified as: Xn, Harmful. Xi, Irritating. N, Dangerous to the environment. Hazardous according to
Eye irritation Category 2B

the criteria of SWA.
This product does not meet the criteria of the Australian Dangerous Goods (ADG) Code. However, this is a C1
Hazardous to aquatic environment Short term/Chronic Category 3
Combustible Liquid so must be stored and handled as specified in AS 1940 “The storage and handling of flammable
and combustible liquids.”
SUSMP Classification: S5
2.1 Label elementsNone allocated. Not a Dangerous Good under the ADG Code.
ADG Classification:
UN Number: None allocated

GHS Signal word: WARNING.

Flammable liquids Category 4
Hazard Statements:
Aspiration Hazard Category H227:
2 Combustible liquid.
H305: May be harmful if swallowed and
Skin Irritation Category 2
enters airways.
Eye irritation H315: Causes skin irritation.
H320: Causes eye irritation.
H412: Harmful
Category 2B
Hazardous to aquatic environment Short term/Chronic Category 3
to aquaticH227:
lifeCombustible
with long
HAZARD STATEMENT:
liquid. lasting effects.
H305: May be harmful if swallowed and enters airways.
H315: Causes skin irritation.
2.2 Other H320:
hazards
Causes eye irritation.
H412: Harmful to aquatic life with long lasting effects.
None
PREVENTION
P102: Keep out of reach of children.
P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash contacted areas thoroughly after handling.
P273: Avoid release to the environment.
P280: Wear protective gloves, protective clothing and eye or face protection.
RESPONSE
P362: Take off contaminated clothing and wash before reuse.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor. 00 p. 1 of 6
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.

SAFETY DATA SHEET

Issued by: Adama Australia Pty Ltd Phone: (02)9431 7800 (office hours)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
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SECTION 3: Composition / information on ingredients

Mixtures
Hazardous ingredients
exposure limits
ingredient Wt, % TWA CAS № EC №
3
mg\m
category

2-Ethylhexanol C8H18O < 35 10 3 104-76-7 203-243-3

C8 alcohols fraction 31,2 – 58,2 10 3 104-76-7 203-243-3
fractions low C8 9,3 – 45,58 10 3 n.a. n.a.
alcohols
fractions high alcohols 23,0 – 39,3 10 3 n.a. n.a.
C8, C12 acetals included
1-butanol C4H12O 0,43– 4,46 30\10 3 71-36-3 200-751-6
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for
a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and
should not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The
term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

SECTION 4: First aid measures

4.1 Description of first aid measures General information

When in doubt or if symptoms are observed, get medical advice.
Following inhalation
Remove casualty to fresh air and keep warm and at rest.
In case of skin contact
Change contaminated, saturated clothing. Subsequently wash off with: Water and soap
After eye contact
Rinse immediately carefully and thoroughly with eye-bath or water. In case of eye irritation consult an
ophthalmologist.
After ingestion
Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water.
4.2 Most important symptoms and effects, both acute and delayed
No information available.
4.3 Indication of any immediate medical attention and special treatment needed
None

SECTION 5: Firefighting measures

The product itself does not burn. Co-ordinate fire-fighting measures to the fire surroundings.
5.1 Extinguishing media
Suitable extinguishing media
alcohol resistant foam Carbon dioxide (CO2) Extinguishing powder Water spray
Unsuitable extinguishing media
Full water jet
5.2 Special hazards arising from the substance or mixture
None
5.3 Advice for firefighters
In case of fire: Wear self-contained breathing apparatus. Protective clothing.
5.4 Additional information

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Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Move
undamaged containers from immediate hazard area if it can be done safely.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protection equipment. Provide adequate ventilation. See protective measures under point 7 and
8.
6.2 Environmental precautions
No special environmental measures are necessary.
6.3 Methods and material for containment and cleaning up
Take up mechanically. Wipe up with absorbent material (eg. cloth, fleece). Clean with detergents. Avoid solvent
cleaners.
6.4 Reference to other sections
See sections 8 &13

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Wear personal protection equipment (refer to section 8). Working places should be designed to allow cleaning at
any time.
Protective measures
No special handling advices are necessary.
Measures to prevent fire
Usual measures for fire prevention.
Measures to prevent aerosol and dust generation
Vapours/aerosols should be exhausted directly at the point of origin.
Environmental precautions
Shafts and sewers must be protected from entry of the product.
7.2 Conditions for safe storage, including any incompatibilities
Hints on joint storage
Storage class: 10
Storage class (TRGS 510): 10
7.3 Specific end use(s)
None

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

None
8.2 Exposure controls

Personal protection equipment

Eye/face protection
Eye glasses with side protection
Skin protection
Hand protection
There is no one glove material or combination of materials that will give unlimited resistance to any individual or
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combination of chemicals. The breakthrough time must be greater than the end use time of the product. The instructions
and information provided by the glove manufacturer on use, storage, maintenance and replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove material. Always ensure that gloves
are free from defects and that they are stored and used correctly. The performance or effectiveness of the glove may be
reduced by physical/ chemical damage and poor maintenance. Barrier creams may help to protect the exposed areas of
the skin, they should however not be applied once exposure has occurred.
Suitable gloves type : Gloves with long cuffs
Suitable material : NBR (Nitrile rubber)
Breakthrough time (maximum wearing time) : 480 min
Thickness of the glove material : 0,5 mm
Recommended glove articles : DIN EN 374
Additional hand protection measures : Check leak tightness/impermeability prior to use. Do not wear gloves near rotary
machines and tools. In the case of wanting to use the gloves again, clean them before taking off and air them well.
Remark : The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working
place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the
resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.
Body protection
Lab coat. Overall Only wear fitting, comfortable and clean protective clothing.
Recommended material: Natural fibres (e.g. cotton) heat-resistant synthetic fibres
Respiratory protection
Usually no personal respirative protection necessary.
Remark
The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that
may arise when handling the product. If the concentration is exceeded, self-contained breathing apparatus must be used.
General health and safety measures
Wash hands before breaks and after work. Apply skin care products after work.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

9.2 Odour: Characteristic aromaic
Appearance: Clear yellowich liquid
Safety relevant basis data
Physical state : Clear yellowich liquid
Boiling point / range : 120 - 320 °c 3
Density : 0,84 – 0,88 g/cm
Solubility in water : 0,07 wt%

9.3 Other information
None

SECTION 10: Stability and reactivity

10.1 Reactivity
No information available.
10.2 Chemical stability
Stable under recommended storage and handling conditions (see section 7).
10.З Possibility of hazardous reactions
None Acid
10.4 Conditions to avoid
No information available.
10.5 Incompatible materials
None Oxidising agent.
10.6 Hazardous decomposition products
Thermal decomposition can lead to the escape of irritating gases and vapours. No information available.

Carbon dioxide. Nitrogen oxides (NOx).

SECTION 11: Toxicological information

Toxicity: LD50 (Oral), Rat >2000mg/kg LD50 (Dermal), Rabbit >5000mg/kg
LC50 Inhal, 4hr Rat >2.09mg/L
An
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information profile for Clethodim is available at http://extoxnet.orst.edu/pips/ghindex.html
Acute Toxicity: Clethodim

is harmful by ingestion. The reported oral LD50 is 1,630mg/kg and 1,360mg/kg in male and female rats, respectively.
Clethodim is practically non-toxic by dermal absorption. The reported dermal LD50 is greater than 5,000 mg/kg. The
technical product did not cause skin irritation in the rabbit, but formulation caused moderate skin as well as eye
irritation in the rabbit. Eye irritation was reversible within 8-21 days. No data regarding skin sensitization or eye
irritation were available for the technical product. Clethodim is practically non-toxic by the inhalation route. The
reported rodent 4-hour inhalation LC50 for Clethodim technical is greater than 3.9 mg/L. Effects of acute exposure to
Clethodim or formulated products may include eye or skin irritation or central nervous system effects, e.g., salivation,
decreased motor activity, incoordination, unsteady gait and hyperactivity. These latter effects may be in large measure
due to the aromatic constituents of the formulation, as these effects commonly occur upon exposure to such
compounds.
Chronic Toxicity: In a one-year feeding study of dogs, doses of 75 mg/kg/day resulted in increased
relative and absolute liver weights, with anaemia-like alterations in blood chemistry such as reduced haemoglobin,
erythrocyte and hematocrit counts. In a two-year chronic study of rats, no compound-related effects on the structure
and function of the liver were observed, and no changes in liver weights were observed at the highest dose tested,
approximately 100 mg/kg/day. Reduced body weight gain was observed in another study on rats at 350 mg/kg/day,
but not at 100 mg/kg/day, over an unspecified period.
Reproductive Effects: No effects on fertility, length of
gestation or growth and development of offspring were observed at doses up to and including the highest dose tested,
263 mg/kg/day.
Teratogenic Effects: Data suggests that while there have been documented teratological effects in
animal studies, such effects are unlikely in humans under normal conditions of exposure.
Mutagenic Effects: The
available data for mutagenicity and genotoxicity yield no evidence for mutagenic or genotoxic activity.
Carcinogenic
Effects: No carcinogenic effects were observed in mice administered Clethodim at doses of 24 mg/kg/day over an 18
month period. Based on the available data, it appears that Clethodim is not carcinogenic. Organ Toxicity: The liver
was the primary organ affected in chronic animal studies. Although potential effects associated with acute exposure
are reported to include central nervous system effects, no available chronic data pointed to such effects.

SECTION 12: Ecological information

12.1 Toxicity
No information available.
12.2 Persistence and degradability
Biodegradable.
12.3 Bioaccumulative potential
No information available.
12.4 Mobility in soil
No information available.
12.5 Results of PBT and vPvB assessment
No information available.
12.6 Other adverse effects
No information available.
12.7 Additional ecotoxicological information
None

SECTION 13: Disposal considerations

Dispose according to legislation.

13.1 Waste treatment methods
Product/Packaging disposal
Waste codes/waste designations according to EWC/AW
Waste code (91/689/EEC): 07 07 99
13.2 Additional information
None

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SECTION 14: Transport information

14.1 UN number
No dangerous goods in sense of this transport regulation.
14.2 UN proper shipping name
No dangerous goods in sense of this transport regulation.
14.3 Transport hazard class(es)
No dangerous goods in sense of this transport regulation.
14.4 Packing group
No dangerous goods in sense of this transport regulation.
14.5 Environmental hazards
No dangerous goods in sense of this transport regulation.
14.6 Special precautions for user
None

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
Water hazard class (WGK)
Class : nwg (Non-hazardous to water) Classification according to VwVwS
International regulatory information
This product contains max.: 0 g/l VOC
15.2 Chemical Safety Assessment
No information available.

SECTION 16: Other information

16.1 Indication of changes

02. Classification of the substance or mixture • 02. Label elements
16.2 Abbreviations and acronyms
For abbreviations and acronyms, see: ECHA Guidance on information requirements and chemical safety
assessment, chapter R.20 (Table of terms and abbreviations).
16.3 Key literature references and sources for data
None
16.5 Relevant H- and EUH-phrases (Number and full text)
None
16.6 Training advice
None

16.7 Additional information

We have no knowledge or control over the user's working conditions however. The user is responsible for the observance of all required
statutory provisions. These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific
product feature and shall not establish a legally valid contractual relationship.

The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The
information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing,
transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the
case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material.

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