MARSIC300

CUSTOMER TRAINING
MARSIC300 SERVICE TRAINING
SYSTEM DESCRIPTION

The MARSIC300 is a new developed measuring devices to

measure emissions aboard of ships according to MARPOL Annex VI and
MEPC.184(59)
Especially designed for maritime applications with a high level of availability
due to insensitivity against vibrations, fluctuation of power, etc.
High measurement performance and accuracy with proven technology ensure
today compliance with lower limits in the future
Up to two measurement points can be measured with only one analyzer which means
less amount of invest compared to “in-situ” solutions (one analyzer each measurement point)
Up to nine components at the same time for all maritime applications :
SO2, CO2, NO, NO2,O2, CO, CH4, NH3, H20
Easy to maintain & servicing (only changing defined modules) by on-board engineer

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MARSIC300
SYSTEM DESCRIPTION

Service concept included spare part hubs all over the world and 24/7
maritime Hotline
Less movable parts (e.g. ejector pump instead of membrane
pump) for less service and maintenance effort
Complete Type Approved by DNV GL according to MARPOL Annex VI and
MEPC.184(59)
MARSIC300 as successor of the well proven MCS100E,
which have been installed on more than 40 Vessels

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MARSIC300
TECHNOLOGY

Analyzer

Filter Sampling Unit

Sampling Probe heated/unheated

Bundle of pipes

Heated Sampling Line

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MARSIC300
PRINCIPLE ARRANGEMENT

1 2

Lmax=35m

Up to two measuring points with integrated switch (one is standard)

Max length for sample line 35 m
Controlled heated sample line (200°C) from sample probe to
analyzer means no condensation of H2O, H2SO4, HNO3, etc.
Bundled of pipes (with reduced halogen content) for easy
installation, for power and pneumatic

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 MARSIC300
CABINET

Second sample line to sampling probe #2

Heated sample line to sampling probe

Bundle of pipes #1 + #2

Instrument Air pressure regulation unit

Valve unit control of the

sampling filter and test gas

External Instrument Air conditioning

unit included

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 MARSIC300
ANALYZER

Sample inlet
O2 sensor (option)
(ZrOx)

Test gas inlet

Ejector pump
and pressure sensor

Control unit for

ejector pump located in
electronic unit Cuvette Inlet filter (sinter metal)

Exhaust line

Photometer

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MARSIC300
SAMPLING FILTER UNIT SFU

Stainless steel heated probe (0.5 or 0.8 m length) or

unheated probe (0.2 ; 0.5 or 0.8 m) length

Sampling Filter Unit SFU

reinforced design for maritime applications
Fine filter cartridge: glass fibre 0,1 µm
Back purge function
Main valve for sample point switching + standby
Flange (NW 65 / ND 6)

Vibration approved up to 4G
or 10 G (only 0.2m unheated)

Glass fibre filter 0,1µm

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MARSIC300
GAS FLOW
Ejector pump
Exhaust
All parts in contact with gas Ejector air
sample gas are heated

O2- Pressure regulation

Sample probe 2 Sensor and flow control

Heated
gas cell

Sample probe 1
Nozzle MARSIC Photometer

Sample gas line Filter

Test gas
Zero gas
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MARSIC300

Advantages of gas sampling using an ejector

▸ Wear-free
― Low maintenance cost and requirements
▸ Gas sampling without any moving parts
― No pulsation
▸ Internal cell pressure remains constant
― Internal cell pressure is independent of atmospheric or process variations
― Hence no distortion of measuring results by varying pressure conditions
▸ Intelligent indirect flow control via pressure sensors
― No moving parts
― Low maintenance requirements
― Within the heated area
▸ High gas flow results in short response times

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MARSIC300
SINGLE BEAM PHOTOMETER

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MARSIC300
SAMPLING FILTER UNIT SFU

Gas cell:
Integrated mirrors
Working temperature 200 °C
Gas filter in gas inlet
Corrosion resistant
Gold covered mirrors with special surface coating

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MARSIC300
MEASURING PRINCIPLES

Dual Wavelength Technique

▸ Measured Components:
SO2 high
CO2
NO2
CH4 high
NH3 high
H2O

Gas Filter Correlation

▸ Measured Components:
SO2 low
NO
CO
CH4 low
NH3 low

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MARSIC300
MEASUREMENT PRINCIPLE: DUAL WAVELENGTH TECHNIQUE

Measurement Principle: Dual Wavelength Technique

Example: Measuring of CO:

Measuring filter Reference filter

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MARSIC300
MEASUREMENT PRINCIPLE: DUAL WAVELENGTH TECHNIQUE

Measurement Principle: Dual Wavelength Technique

Example: Measuring of CO:

High CO concentration
=
High CO value

Reference unchangend

Measuring filter Reference filter

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MARSIC300
MEASUREMENT PRINCIPLE: GAS FILTER CORRELATION

Measurement Principle: Gas Filter Correlation

Example: Measuring of HCl
▸ Measuring at 1 optical wavelength
▸ Reference is a high concentration of this gas
stored in a gasfilter

Signal processing
▸ Absorbance = - log (Intensity Sample/Intensity
Referenz )
The gas filter overlays the HCl- Signal from sample HCl Spectrum
with a very high reference signal. The gas filter 100 %

correlation technique suppresses interferences,

90

80

because they will be measured on both signal 70

types (sample and reference signal).

60

50

▸ Typical components: HCl, NO, CO, NH3

40

30

20

10
Sample Filter
3 200 31 00 3 000 29 00 280 0 27 00 2 6 0 0 cm-1

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 MARSIC300
INTERNAL CALIBRATION

Cuvette

SO2 SO2 SO2

SO2 SO2
SO2
SO2
SO2 SO2 SO2
Light Source
Detector
SO2 SO2 SO2
Filter wheel Filter wheel
(component specific wavelength) (internal calibration filter)

Calibration curve for SO2

0. MARSIC300 in measurement mode
1. flushing the cuvette with instrument air
SO2 Concentration (ppm)

2. Setting signal zero (internal zero adjustment)

Measuring value
3. Swing in of specific calibration filter
4. Setting span point calibration
SO2 raw signal
5. Swing of specific calibration filter
6. Switch back to measurement

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 MARSIC300
INTERNAL CALIBRATION

Advantage of certified calibration filters on MARSIC300:

The optical path during calibration is exact the complete light path during the "normal" measurement
mode. Aging effects of all optical components are taken into account and are corrected accordingly
Checking with calibration gas only necessary after optical parts have been replaced!
No hazzle with expired calibration gas bottles (usually expired after 12months)
No costs for calibration gas (10l bottle of calibration gas (CO2/SO2) costs around 600€)
The operator of the vessel is always in the position to show compliance with the applied regulations
against flag state, class or PSC (port state control) without additional measures
The MARSIC300 is the only device with this feature available on the market!

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 MARSIC300
FLOW CONTROL

Operating pressure in cuvette is regulated to 750 mbar and operates up to sample pressure of 1150 mbar abs.
Flow at 1015 mbar ambient pressure is 290 l/h

0,4

0,9

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 MARSIC300
TECHNOLOGY OF MARSIC300

Technology
Hot/wet Technology
Well known technology from MCS100E
Instrument air conditioning unit included!
CO2, SO2 low(0-30ppm and SO2 high (0-2000ppm) included.
Internal calibration filters included
Optional measurement of NO, NO2, O2, H2O, CO, NH3, CH4
No condensation of H2SO4 or HNO3 at any point
No cooler needed, no sampling preparation
No doubt of losing SO2
Simple system, less movable parts
Only one box, very compact system

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 MARSIC300
TESTING AND VERIFICATION, DIMENSIONS

Leakage test and verification of calibration must be shown

to the administration / PSC

Testing and Verification

Zero point setting and check with I-Air
Easy leakage test with “build in method”
No calibration gas needed (certified internal filter included)
Calibration with calibration gas only after changing major
parts of optical measurement system

Dimensions
H: 1200 x B: 600 x T: 400
(approx. 130kg)

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 MARSIC300
INSTRUMENT AIR AND POWER SUPPLY

Instrument air and power supply

Sample flow ~200-300l/h
Needs instrument air for operating the ejector and purging sampling
probe in bypass modus (~1.300 l/h)
Content of oil max. 0,1 mg/m³
Particles max. 1 μm
Dew point max. -40 °C

This quality is usually not available aboard,

I-air conditioning is included!
Different quality is possible (two connections):
highest quality for zero setting and
lower quality for ejector operation

Power Supply 115-230V, 50/60 Hz

Power needed for one Sampling Point
incl. 10m heated tube ~2.700W

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MARSIC200 + MARSIC300
5. DIFFERENTIATION MARSIC200 AND MARSIC300

Component MARSIC300 MARSIC200 MARSIC300

DeSOx (2077255) DeNOx (1074309) DeNOx (2077257)
0 … 30 ppm 0 … 100 ppm 0 … 30 ppm
SO2 0 … 2.000 ppm 0 … 500 ppm 0 … 2.000 ppm

CO2 0 … 25 Vol.% 0 … 25 Vol.%

0 … 25 Vol.%

O2 0 ... 21 Vol.-% 0 ... 21 Vol.-% 0 ... 21 Vol.-%

0 ... 300 ppm 0 ... 300 ppm 0 ... 300 ppm

NO 0 ... 2000 ppm 0 ... 1.500 ppm 0 ... 2000 ppm
0 ... 300 ppm 0 ... 300 ppm 0 ... 300 ppm
NO2 0 ... 2000 ppm 0 ... 1.500 ppm 0 ... 2000 ppm
0 ... 200 ppm 0 ... 200 ppm
CO 0 ... 2000 ppm 0 ... 2000 ppm
0 ... 500 ppm 0 ... 500 ppm
CH4 0 ... 10 000 ppm 0 ... 10 000 ppm
0 … 50 ppm 0 … 50 ppm
NH3 0 … 500 ppm 0 … 500 ppm

H2 O 0 … 40 Vol.% 0 … 40 Vol.%

Inclusive Optional Not available

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MARSIC300
5. DIFFERENTIATION MARSIC200 AND MARSIC300

Component MARSIC200 MARSIC300

Measurement Principle Cold dry Hot wet

Design 3 Boxes, Modular 1 Box, Compact

No of standard sampling points 4 2

Fully Type Approved by DNV GL Yes Yes

Nox Before SCR Yes Yes

Nox After SCR Yes Yes

SOX After Scrubber Yes Yes

Measurement of
Yes Yes
CO2, SO2, O2, NO and NO2

SOx Before Scrubber No Yes

(SO2 max =500ppm)

Measurement of
No Yes
CH4, CO, NH3 and H2O

Integrated Calibration filters No Yes

(calibration interval= 3 months)

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 MARSIC300
6. USER INTERFACE CONCEPT AND CONNECTIVITY

GSM or
Satellite

SICK Meeting Point Router

Ethernet Connection; Direct or via network SOPAS-ET

(SICK Engineering Tool)
Remote diagnosis
Remote maintenance
Remote operation

Connectivity to customers devices

Routine operation via Control Unit
All required routine functions via instrument display
Multilingual: English, German, French, Spanish
Logbook function for status and alarms
Password protected operating levels
I/O signals (digital* & analog*), Modbus, OPC
Control via SICK solution MEAC
Control of the MARSIC via customers SPS
Data Recording on external devices
Prepared to embed the MARSICin customers
overall solution

*optional

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MARSIC300
7. MARITIME SERVICE CONCEPT & SICK MARITIME HOTLINE

Complete new service concept for MARSIC

MARSIC is designed that the service can be done by on-board engineer
In case of failures, only modules are to be exchanged by on-board engineer
Easy to understand description within operating instructions
Spare parts available via world wide network

SICK Maritime Hotline

Worldwide accessibility for customers of MARSIC on ships
Acceptance for parts orders or technical support – 24/7 worldwide availability to take the call
Feedback latest next business day from SICK logistics or SICK Service
Due to global SICK service availability fast response time can be achieved if needed

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MARSIC300
REPLACEABLE MODULES

Gas Sampling System

Housing Fan 6054075
Sample Gas Line
O2 Sensor 2081837
Span Gas Valve 6058571
Measuring Cell 2081438
Pressure Reducer Unit 5329115
Pressure Control Module 2081835
Valve Block incl. Span Gas Valve 6054600
Display 2081834
Electronics Unit 2081463

Complete Analyzer Module

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MARSIC300
PREVENTIVE MAINTENANCE
Maintenance Interval Maintenance Work
Every 1 week • Check pending messages
• Check external instrument air conditioning (optional)
• Check filter pad for housing fan (replace if necessary)
Every 1 month • Check system
• Check gas sampling system
• Glass fiber filter and seals
• Clean or replace if necessary
Every 6 months • Perform a leak tightness check
Every 1 year • Gas sampling system
• Replace the glass fiber filter and seals
• Replace the non return valve
• Remove soiling inside and outside
• Check the H2O interferience
Every 2 yeras • Replace on the cell:
• Non return valve
• Sample gas inlet filter
Every 3 years • Replace IR source
• Replace Drying Agent

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 MARSIC200 + MARSIC300
APPENDIX MARSIC300 - TECHNICAL SPECIFICATION

Parameter
Gas Components DeSOx: SO2 , CO2, H2O
DeNOx: NO, NO2, H2O
Optional: SO2 , CO2, O2, NO, NO2, CO, CH4, NH3
Max. numbers of gas components 9
Measurement principle NDIR-Photometer, Zirconiumdioxide (O2)
Technology Hot-wet
Spectral range 2000 – 11000 nm
Measurement path length 8,5 m
Sample flow 200 - 300 l/h
Measuring ranges SO2 0... 30ppm / 0... 2000 ppm
CO2 0 ... 25 Vol.-%
O2 0 ... 21 Vol.-%
NO 0 ... 300 ppm; 0 ... 2000 ppm
NO2 0 ... 200 ppm; 0 ... 500 ppm
CO 0 ... 200 ppm; 0 ... 2000 ppm
CH4 0 ... 500 ppm; 0 ... 10 000 ppm
H2O 0 – 40 Vol%
NH3 0 – 50 ppm, 0 – 500 ppm
t90-time < 140 sec total length from sampling point
Max numbers of sampling points 2 per analyzer
Accuracy, Drift, etc.
Accuracy < 2% of measuring range
Drift (zero) < 2% of measuring range per week
* In evaluation
Drift (span) < 2% of measuring range per week
Detection Limit < 2% of measuring range

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 MARSIC200 + MARSIC300
APPENDIX MARSIC300 - TECHNICAL SPECIFICATION

Ambient Conditions
Temperature (operation) +5 °C ... +45 °C acc. to environment category „A“
Temperature (storage) -20 °C ... +70 °C
Pressure 900 hPa ... 1.100 hPa
Rel. Humidity ≤ 90 % (not condensing)
Conformities
Conformities -MARPOL Annex VI and NTC 2008 - MEPC.177(58)
-Guidelines for exhaust gas cleaning systems - MEPC.184(59)
-DNV GL Rules for Classification and Construction, Part VI Additional Rules and Guidelines chapter 7,
Guidelines for the Performance of Type Approvals, Test Requirements for Electrical / Electronic
Equipment and Systems (2012)
Electrical safety CE, DNV GL Rules
Process conditions
Temperature 10…550°C
Pressure -20…+200 hPa relative
Inlet Pressure 20…+200 hPa relative
Dust load ≤ 200 mg/m³
Dimensions
Design Wall mounted cabinet
Dimensions (W x H x D) 600mm x 1200mm x 400mm
Weight App. 120 kg
Material in contact with gas Stainless steel 1.4571, PTFE, Aluminium (coated)
Material generally steel, cast aluminium

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 MARSIC200 + MARSIC300
APPENDIX MARSIC300 - TECHNICAL SPECIFICATION

Operating supplies
Instrument air Flow: ≤ 1.300 l/h; 5 ... 7 bar
Instrument air quality Oil content max. 0,1 mg/m³;
Particle size max. 1 μm
Dew point max. -40 °C
Connections
Sampling gas Swagelok DN 4/6
Instrument air Instrument air: DN 6/8 and 8/10, Calibration gas:DN 6/8
Calibration
Adjustment functions Certified drift correction with internal measures or calibration gas
Zero point adjustment Automatic with instrument air
Connectivity
Connectors Ethernet (TCP / IP)
Data bus Modbus TCP, OPC, PROFIBUS (Option)
Visualisiation LC-Display, Status-LEDs „Power“, „Failure“ und „Maintenance request“
Operation With LC-Display or Software SOPAS ET, password protected.
Power Supply
Power 3-Phase: 115V, 50/60Hz
3-Phase: 208V, 50/60Hz
3-Phase: 230V, 50/60Hz
Other configurations possible on request (e.g. 1~230V for minimaly equipped system)
Frequency 50 / 60 Hz
Current Max. 14A (at 230VAC)
Power consumption -Analyzer: 1000W
-Heated sampling tube (90W/m): 1350W
-Sampling Probe, heated: 750W
Protection class IP 44 , others on request

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