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Hydrocracking Processes

Distillate hydrocracking is a refining process for conversion of heavy


gas oils and heavy diesels or similar boiling-range heavy distillates into
light distillates (naphtha, kerosene, diesel, etc.) or base stocks for lubri-
cating oil manufacture. The process consists of causing feed to react with
hydrogen in the presence of a catalyst under specified operating condi-
tions: temperature, pressure, and space velocity.

HYDROCRACKING REACTIONS

DESULFURIZATION

The feedstock is desulfurized by the hydrogenation of the sulfur con-


taining compounds to form hydrocarbon and hydrogen sulfide. The H2S is
removed from the reactor effluent leaving only the hydrocarbon product.
The heat of reaction for desulfurization is about 60 Btu/scf of hydrogen
consumed:

CATALYST

Thiophene Paraffin Hydrogen Sulphide

DENITRIFICATION

Nitrogen is removed from feedstock by the hydrogenation of nitrogen-


containing compounds to form ammonia and hydrocarbons. Ammonia is
later removed from the reactor effluent, leaving only the hydrocarbons in
the product. The heat of reaction of the denitrification reactions is about

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