AIR- 2, 4 , 6 , 9 (NEET)

Ashwani Tyagi AIR - 3, 4, 9 (AIIMS)

AIR - 10, 14 (JEE Adv.)
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 Advanced
Problems on
Physical
Chemistry
In the reaction COCl2 (g) ⇌ CO(g) + Cl2(g) at 5500 when the initial
pressure of CO & CI2 are 250 and 280 mm of Hg respectively.
The equilibrium pressure is found to be 380mm of Hg. Calculate
the degree of dissociation COCl2 at 1 atm. What will be the
extent of dissociation, when N2 at the pressure of 0.4m atm is
present and the total pressure is 1 atm.

A. 0.32 & no change B. 0.32 and 0.4

C. 0.4 and 0.3 D. In pressure of N2

dissociation cannot takes
place
The molecular diameters of A and B are 4nm and 8nm
respectively. The pressure of A and B are 10 atm and 5 atm
respectively. The temperature of A and B are 300 K and 400 K
respectively. The ratio of molecular mass of A and B are 30 :
40. What will be the ratio of binary collisions among A
molecules to that of B molecules.
A. 50/57 B. 29/21 C. 16/9 D. 49/36
Find the mean free path of a molecule of a vander waal gas
at 360K (the Boyle’s temperature for the given gas) & 1 atm.
Given the excluded volume for the gas is 9.6 x 10-3 dm3 mol-1
[use π = 3, NA = 6 x 1023 2 = 3/2, boltzmann constant k = 1 x
10-23 J/K, 1 atm = 103 Pa]

A. 2 x 10-7 m B. 3 x 10-7 m C. 4 x 10-7 m D. 5 x 10-7 m

The ratio of coefficient of thermal expansion and the isothermal
compressibility for an ideal gas is:

A. -P/T B. P/T C. T/P D. -T/P

‘n’ moles of helium gas are placed in a vessel of volume ‘V’ litre
atT K. if Vr is the ideal volume of helium, the diameter of He
atom is:

A. B. C. D.
0.5 mole each of two ideal gas

are taken into a container and expanded reversibly and

adiabatically from V = 1 litre to V = 4 litres started from initial
temperatures T = 300K, ΔH for the process (in cal/mol) is

A. -500 cal B. -900 cal C. -450 cal D. -600 cal

For an ideal diatomic gas, during any process T = KV, find out
the molar heat capacity of the gas during process (neglecting
vibrational degree of freedom.
A. 3R/2 B. 5R/2 C. 7R/2 D. 2R
Br2 and Cl2 react to form Brcl according to the equation
Br2 + Cl2 ⇌ 2BrCl, at 270 C. [Kp = 1 atm]. Initially 1 mole of Cl2
was taken and at equilibrium partial pressure of BrCl was
found to be 0.1 atm. If vapour pressure of Br2 was equal to
that of BrCl. find the minimum number of moles of Br2
require to attain this equilibrium.

A. 5/6 B. 10/6 C. 15/6 D. 16/6

Ammonium carbonate dissociates according to the equation
NH2COONH4 ⇌ 2NH3 + CO2
At initial equilibrium pressure was found to be P1 atm. Now
NH3 was added to this container till partial pressure of NH3
was thrice of initial equilibrium pressure. At this point
pressure was found to be P2. Find P2/P1 = ?

A. 243/733 B. 733/243 C. 729/243 D. 243/729

 11th Grade
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Tuesday
Wednesday

Subjects Timings
Physics 7 PM
Chemistry 8 PM
Mathematics 9 PM
 12th Grade
Friday
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Subjects Timings
Physics 7 PM
Chemistry 8 PM
Mathematics 9 PM
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