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339 1757 1 PB PDF
339 1757 1 PB PDF
CAUSTICIZING SE FABRICS
G OF VISCOS
M. İ. Bahtiyari,
B K. Duran,
D A. E. Körlü,
K M. Bahhar, A. Özerddem, S. Perinccek
Egge University, Department of Textile Enngineering, Izmmir, Turkey
aysegul.ekkmekci@ege..edu.tr
AB
BSTRACT
Viscose treatment needs high carec and know w-how. Becauuse viscose faabrics are moore susceptiblle
to thee chemical prrocesses. In thhis study, cauusticizing whiich is generallly found to bee dangerous in
i
the prretreatment off viscose fabrrics was appliied to viscosee fabrics. It was
w found thaat the usage of o
caustiic-soda in prretreatment of o viscose fabrics ensuredd considerabble advantagees in terms of o
pillingg degree and
d color efficienncy in textile printing and dyeing. Afterr causticizingg the surface of
o
the faabrics became smoother, fuzzyf of the fabric decreased and thee crystallinityy of the fabriic
increaased. In add dition, perforrming a caussticizing befo fore dyeing anda printing with reactivve
dyestuuffs caused ann increase in the color efficiency.
1. INT
TRODUCTIION the pilling
p problem m of viscose fabrics. It waas
reporrted that fibrills on the surfaace of the fiberrs
The demand
d for viscose
v fibers is increasingg are stripped,
s solveed by causticizzing, thus fibeer
day byb day becau use of their natural
n originn smooothens and sw wells. Swolleen fibers causse
and high
h comfortt in wear. Thanks to thee the fabric
f to gain more
m compactt structure, thuus
recentt productionn techniques, today it iss reduce pilling formmation [14, 166].
possibble to prov vide all kindds of usagee
expecctations by the
t regeneratted cellulosee Besiides the inncrease in the swellinng
fiberss. Unfortunaately, some prroblems suchh tendency, with the aid off causticizinng
as hiigh fibrillatioon/pilling teendency, low w proccess, color efficiency of o the fabriic
repeattability andd low unifo formity afterr signiificantly increeases in the further
f printinng
dyeinng and prin nting can occuro duringg and dyeing proceesses. Since dye uptake of o
processing of viscoose fabrics. [11, 2, 14, 18]. the viscose fabrric increasess and dyeinng
becoomes more evven after the treatment
t witth
Cellullases are useed to removee the fuzz orr 4-6 % caustic-sooda, it is reccommended to t
pills on
o the fiber or
o fabric surfaace for a longg applyy 6-8 Bé cauustic-soda. Buut this increasse
time. There are a lot
l of studies on the use off in coolor efficienccy in the printting of viscosse
cellulases and some other parameterss mateerials causedd by causticizing changees
affectted the bio-ppolishing [3-113]. But thee accoording to the dyestuff used u and thhe
pillingg and fuzz of the visccose fabric’ss darkkness of the prrint [2, 17, 18].
surfacce did not decrease
d suffficiently withh
comm mercial cellullases [14, 155]. Moreover,, On the
t other handd, it is well known
k that anny
caustiicizing processs has been seeen to restrictt kindd of textile pretreatment
p c
conventionallly
2. EXPERIMEN
E NT Thenn, printed fabrics
f weree dried in a
laborratory type drying
d machiine (Rapid) at a
For the
t experimeents, 30/1 single
s jerseyy 100 0C for 3 minutes andd fixed on a
Lycraa/viscose knittted fabric with
w 310 g/m2 laborratory type steamer
s (Mathhis) at 102 0C
weighht was used inn accordancee with the testt for 10
1 minutes. Afterwards,
A washing-off waas
plan (Figure
( 1). perfoormed for both dyed and printed fabriccs
with cold waterr then a hot rinsing waas
All prretreatment and
a dyeing prrocesses weree perfoormed it was repeated
r till thhe rinsing wateer
realized on an overflow macchine with a will be clean andd finally a coold rinsing waas
capaccity of 50 kg and
a a stenter. Fabrics weree manaaged. During the treatment processes, sooft
printeed at 20 m/miin at 3 bars of
o pressure onn mill water (permuutit-water) was used.
a J. Zimmer
Z MDK K laboratory--type printingg
machiine with 70 Nr
N PES gauzee and a doctorr
Table 1. Process
P Condditions
1°C/min
SALT
T DYES
20 min
25°C
2 Dyeing Proocess
Figure 2.
In orrder to evalu uate the resuults obtained,, Moreeover, strenggth loss was measured on o
pillingg tests were realized accoording to thee Jamees J Heal burrsting strengthh measuremennt
ASTM M 3512 and K/S values of dyed andd devicce (7.5 cm² arrea and 30.5 mmm diaphragm m
printeed fabrics were
w determiined with a diam
meter) and FT T-IR analysis of fabrics waas
Minollta CM
M 3600dd Modell carrieed out with Peerkin Elmer Sppectrum 100.
Specttralphotometeer. Surface modificationn
was evvaluated by taaking fabric phhotographs onn 3. RESULTS
R A
AND DISCUSSION
Moticc trade mark microprojection
m n device.
3.1. Pilling Valu
ues
Figure 3. Microscopic
M v
views of caustticized and noot causticizedd fabrics after dyeing
K/S
Not Causticcized Dyed
N d 23.28
Fabric
C
Causticized Dyed
D Fabric 33.17
a b
Wavenumberr (cm-1) A
Assignment
3326 -OHH stretching
2890 -CH
H stretching
1650 -OHH of water abssorbed from cellulose
1420 CH
H2 symmetric bending
b
1365 C-H
H bending
1336 C-O
OH in plane beending
1316 CH
H2 wagging
1278 C-H
H bending
1235 C-O
OH in plane beending
1227 C-O
OH in plane beending
1200 OHH in plane bendding
1155 C-O
O-C asymmetrric stretching
894 Grooup C1 frequenncy
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