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National Fertilizer Limited
National Fertilizer Limited
National Fertilizer Limited
ACKNOWLEDGEMENT
CONTENTS
1. INTRODUCTION
2. PROCESS DESCRIPTION
3. UREA PURIFICATION AND LOW PRESSURE RECOVERY
4. UREA CONCENTRATION
5. UREA PRILLING
6. SUSTAINABLE ENVIRONMENTAL POLLUTION
7. COOLING TOWER
8. WASTE WATER TREATMENT PROCESS AT NFL VIJAIPUR
9. NFL UNITS
10. REFERENCES
PROFILE OF THE COMPANY
National Fertilizers Limited, Vijaipur unit is one of the four units of M/S
National Fertilizers Limited, a Government of India undertaking with its
corporate office at New Delhi, The other units are located at Nangal and
Bhatinda in Punjab ant at Panipat in Haryana.
National Fertilizers Ltd, Vijaipur unit is one of the four units of M/S
National Fertilizers Limited. With the commencement of commercial
production of the Expansion project the gas based unit at Vijaipur now
comprises of two 1520 ton per day (tpd) Ammonia streams and four 1310
Ton per day Urea streams and related off-site facilities. The gas is being
received from the HBJ gas pipe line being operated by M/s Gas Authority
of India Ltd (GAIL) another government of India undertaking.
The line one plants (one stream of Ammonia and two streams of Urea)
were built with a total cost of Rs 533 Crores and the cost of the line two
(one stream of Ammonia and two streams of Urea) was Rs 1067 Crores.
For Both streams of Ammonia plants the consultant have been M/S
Haldor Topose of Den-Mark and M/S Projects Development India Ltd.
(PDIL), and for all other streams of Urea consultant have been PDIL and
M/S Snamprogetti of Italy.
The line one Plants had gone in Commercial Production w.e.f July 1988
and the Expansion Unit has started the Commercial Production w.e.f 31
March 1997.
The line one plant have been consistently operating at above 115% of the
rated capacity. The line two plant is also expected to perform similarly.
Vijaipur unit has won several prestigious awards like Best Implemented
Project award given by Ministry of Programme Implementation GOI,
National Safety awards given by National Safety Council GOI and by
National Safety Council(MP).
The main product of this industry is Kisan Urea. The total production
capacity of Kisan Urea is 6,261 Tonnes/day which is the second largest
production in the country.
INTRODUCTION
Process Description
The urea production process takes place through the following main
operations:
I) Urea synthesis and high pressure recovery
II) Urea purifications and medium pressure recovery
The total flow of liquid Ammonia coming directly from the battery limits
is measured by turbine flow meter and then diverted to 11/21 line1 unit
and 31/41 line2 unit. The flow of liquid ammonia going to each unit is
measured by and temperature and collected in the Ammonia receiver
tank . From Ammonia receiver tank, it is drawn and compressed at about
22.4 kg/cm2 pressure by means of centrifugal pump . Part of this
ammonia is sent to the Medium pressure absorber , the remaining part
enters the high pressure synthesis loop. The ammonia feeding the
synthesis loop is compressed by two low-speed, heavy duty reciprocating
pumps at a pressure of about 240 ata. Before entering the reactor the
Ammonia feed is used as motive fluid in the Carbamate Ejector, where
the carbamate coming from the Carbamate Separator is compressed up to
the synthesis pressure. The liquid mixture of NH3 and Carbamate enters
the reactor where NH3 reacts with the compressed carbon dioxide. The
CO2 drawn at Urea plant battery limits at about 1.5 ata and about 40°C
enters the centrifugal compressor and leaves at a pressure of about
160ata.The C02 at a pressure 160 ata and temp. 130°C is fed to Urea
reactor through Discharge Separator A small quantity of air is added to
the Carbon dioxide at the compressor suction in order to passivate the
stainless steel surfaces, thus protecting them for corrosion due to both
reagent and reaction product. The reaction products, leaving the reactor,
flow to the steam heated falling film type stripper , which operates at 146
kg/cm2 pressure. The mixture is heated up as it flows down the stripper.
The C02 content is reduced by the stripping action of the Ammonia as it
boils out of the solution. For the bottom of bimetallic stripper, passivation
air is required in continuous way. For this passivation air compressor are
installed. The carbamate decomposition heat is supplied by 24 ata
saturated steam. The overhead gases and the recovered solution from M.P.
absorber , all flow to the high pressure Carbamate condensers where the
total mixture, except for a few inerts, is condensed and recycled to the
Reactor by means of ejector .The côndensation of gases at high pressure
and temperature permits the production of 4.5 ata steam in the high
pressure Carbamate condenser. In the Carbamate Separator the
incondensable gases, consisting of inert gases containing a little quantity
of NH3 and CO2 unreacted in the condenser, are separated from the
carbamate solution and sent to the Medium pressure decomposer .
UREA CONCENTRATION
Urea concentration in two stages (0.3 and 0.03 ata) Urea solution storage
& recovery Urea concentration section .As it is
necessary in order to prills urea, to concentrate the urea solution up to
99.7% a vacuum concentration section in two
stages is provided. The solution leaving the low pressure decomposer
bottom with about 71% urea is sent to the pre Concentrator this solution
having urea concentration is 83.5 % and vacuum 0.34 ata. This solution
sent to first vacuum concentrator operating at a pressure of 0.3 ata. Urea
concentration section the mixed phase coming out of enters the gas liquid
separator from where vapours are extracted by the first vacuum system
while the solution enters the second vacuum concentrator operating at a
pressure of 0.03 ata. The two concentrations are fed by saturated steam at
4.5 ata. Urea concentration section the mixed phase coming out of enters
the gas liquid separator from where vapours are extracted by the second
vacuum system.
Prill temp at the tower outlet 75°C max corresponding to maximum
ambient temp of 46°C. Relative humidity of ambient air is to be
considered 100% at 35° C.
UREA PRILLING
The melted urea leaving the second vacuum separator is sent to the
Prilling bucket by means of pump . The urea coming out of the bucket in
the form of drops along the Prilling tower and encounters a cold air
flow which causes its solidification. Urea Prilling. The solid prills falling
to the bottom of the Prilling
tower are sent into the belt conveyor by the rotary scrapper .From here
they are sent through lumps separator to retain lumps only and then to
the product belt conveyor which carries the product to the Urea storage
section. Urea lumps by means of Urea recycle belt conveyor are recycled
back to the underground Urea lumps dissolving tank where
they are dissolved. The Prills from prilling tower bottom sent to bulk
Flow cooler when the temp more than 65OC.
At a urea plant, the major sources of water pollution are the process
condensate generated from the urea section (containing urea, ammonia
and CO2) and oil-bearing effluent from pumps and compressors. A
substantial quantity of wastewater is also generated from plant utilities as
cooling tower blow-down, demineralised regeneration and water
treatment plant (WTP) back-washing. Typical end-of-pipe effluent
treatment plants are generally not seen in urea plants as they possess
in-house treatment facilities.
COOLING TOWER
A cooling tower is heat removal device that uses water to transfer process
waste heat into the atmosphere. All cooling towers operate on the
principle of removing heat from water be evaporating a small portion of
water that is recirculated through the unit. The mixing of warm water
and cooler air releases latent heat of vaporization, causing a cooling effect
to the water. They are a key component of many refrigeration systems
and can be found in industries such as power plants, chemical processing,
steel mills, and many manufacturing companies where process cooling is
necessary. Also, cooling towers can be used to provide comfort cooling
for large commercial buildings like airports, schools, hospitals, or hotels.
Cooling towers might be one of the most vital part of any industrial
process. These tall, open-topped, cylindrical structures are responsible for
cooling water generated from industrial or HVAC comfort cooling
process. They are classified by the type of draft (natural or mechanical)
and by the direction of air flow (counter or cross).
TYPES:
1. Natural Draft Cooling Towers are usually used for large power
plants and industries with infinite cooling water flow. The tower operates
by hot air in the tower rising removing waste heat and then releasing it
into the atmosphere. These towers are tall and have a hyperbolic shape to
induce proper air flow.
2. Induced Draft towers are typically mounted with a fan at the top of
the cooling tower, which allows hot air out and pulls air throughout. The
high exiting air velocities reduces the chance of re-circulation. To avoid
the entrapment of water droplets in the leaving stream air, drift
eliminators are used. Induced draft towers are more efficient as they use
30% to up to 75% less energy compared to forced draft designs.
The urea waste stream from line-I & line-II plant is collected in concrete
Buffer tank; the system comprises three concrete tanks in series having
weir for increasing residence time. The ammonia is removed in air
stripping tower and bottom waste stream is sent to urea hydrolyser
through buffer tank. The waste feed in Biohydrolizer is subjected to 4-5
hrs residence time. The treated waste goes to cleaned pond B, if ammonia
content is more than recycle to stripper.
Advantages of Biohydrolizer
1. No chemical required for urea waste stream.
2. Low installation cost & no running cost.
3. Low space required compared to conventional clarifier.
Process Flow diagram of Urea Biohydrolizer
NFL UNITS
There Are mainly four units are working in INDIA for NATIONAL
FERTILIZERS LIMITED
1. Vijaipur, GUNA, MADHYA PRADESH
2. Panipat, HARYANA
3. Nangal, PUNJAB
4. Bathinda, PUNJAB
With the four units working in INDIA, NFL has become the 2nd Largest
Producer of UREA in INDIA after IFFCO With the share of near about
15-16% in urea.
Let us now study about these four plants in little detail.
PANIPAT UNIT
BATHINDA, PUNJAB
Bathinda district in Punjab is one of the oldest and ninth largest district of
Punjab situated in the heart of Malwa region. It is said that Bhatinda was
build by rulers of Punjab 'Bhatti Rao' in 6th century AD and then the city
was called by the name of 'Bhatti Vinda' after their surname and 1516
now it is called as Bathinda. The district has three sub divisions -
Bathinda, Rampura Phul, and Talwandi Sabo. Bathinda is also known as
"The city of Lakes" for its five artificial lakes in the city. The district is
bounded by Sirsa and Fatehabad of Haryana State in the South, Sangrur
and Mansa district in the East, Faridkot in the North and Muktsar on the
West. Bathinda is well known for cotton and agricultural production, also
boasting a rapid development in industrialisation with thermal power
plants Guru Nanak Dev Thermal Plant and Guru Hargobind Thermal
Plant, Fertilizer Unit National Fertilizers Limited and a large oil refinery
and these give boost to the city's economic growth. Bathinda railway
station is one of the biggest rail junctions in India. The Sirhind canal from
which the minor branch canal, Bathinda branch and Kotla branch canal
take off solves the irrigation purpose of Bathinda District. The
neighbouring districts of Bathinda are Ludhiana (136km), Faridkot
(63km), Chandigarh (210km), Ferozpur (103km) and Delhi (370km).
NANGAL UNIT
Nangal is situated at a distance of 100 kms from Chandigarh – the joint
capital of Punjab and Haryana. It has a township at a stone‟s throw from
a fertilizer unit often referred to as Nangal Unit of National Fertilizers
Limited. Places of religious importance like Shri Anandpur Sahib, Mata
Naina Devi Shrine, Shri Bhabour Sahib lie within 20 kms radius of Naya
Nangal. Places of tourist attraction like Manali and Dharamshala in
Himachal Pradesh can also be visited en-route a trip to Naya Nangal. A
rail head connection to „Nangal Dam‟ station is on the electrified track
with two daily trains to national capital Delhi. Soon after independence of
our country the need to develop the infrastructure in the country was hard
felt. As a result of the motivation by the policy makers of the nation at
that time, sites and locations were shortlisted on priority basis for hydro
projects, core sector industry, research and development,defence
establishments etc. In an endeavour towards this, a small villagenestled in
the midst of Shivalik Hills on the banks of the river Sutlej was considered
to be an ideal location for a Hydro power project. This idea mooted by a
foreigner and proposed to the then Prime Minister gave birth to Bhakra
Dam – often referred to as one of the „temples of modern India‟. The
artificial lake created upstream of the dam christened „Gobind Sagar‟ is
still considered as the biggest man-made lake in the world. With the
coming up of Bhakra Dam and surplus power available from the hydel
project, Govt. of India decided to set up Fertilizer Factory at Naya Nangal,
which went on stream in 1961.
REFERENCES