‘Access fo your success SHIMADZU Application News TOC May 2008 Total Organic Carbon In Soil Ghua A Ming, Tokura Takako Custer Support onto, Shiau (Asia Pace), Po. Li Introduction Slermic carbon $0), whichsa major component of Soil organi mater ts coneed pep the mow import ne Gy and preci A Frducon of hmm seid by eran amp, 2d ‘Shocqurn demotion of tread chromic sed by ‘aio with ferous ammonium spate" As here ‘owing latest to elimite the we of chromic acd Beene of fy an dips ses, he eto hat ‘il ey cota afro ccpounds tcc ‘opuit”Al,he dry combustion mehodmeasues a ‘zen (1) wheres th chrom ald mebod ders ‘only oxdaabe euboe. Carey. three any insets thar wise the dy combustion mee which uter simples te procedure and hoes th aml ‘Umetoabutveminuespe measurement ‘Thoratetwo1ypes of dey combustion astument-indet seeds Pau) i es gue: Indrectand distr combusionsrunents Inthe inst ey combustion instunen there are wo funaceetnbers sad thee ps are tvaied In the eesenen SO: 2)TC mewurement a samples cambustel in a Hak lempertire finace camer Whee all rms ‘stra converted to carbon dnd (©0,) whch = ‘henmessrd aly withan ned tet 5) serum cabs (1C) mesement be sample ‘eited wih aed in a separate furnace camber 6 ©) he terence betwen TC and IC is SOC, sich oknownasaalorancearton TOC), ‘The det dry combustion insrumen is equippd with Steps 1 in sample fit eve by reatng he sample withec 1) toate ample hen combustin a frsce ‘amber to release CO, which then etre wih tina detector tain TOC sl However the acracy of TOC eu may be fected the ICisnotsuiy moved for be same Hence, eke te adnan ope ‘Srtorate conten nao req. To onan IC ‘TC, Thedifference between TCand TOCis IC. ers, we desea met mente TOC ins ng tinge dy sombaton inser, the, Shins SSsoina’ ‘Methods & Results ‘Glucose (C,H,0,) and soiun carbon (Na.CO) were eda the TC and IC saan respecte For Imesuenont OF TC, each spe (about 100 a) wes pbcedin craic spe boa which asthe astoned Into» 960°C exacts of sol exe end pstioun oman shamter nie the SSMLSIIDA oxidised no CO, wih the sof omvgen(0) ee, The Covwsethencared yO, carergs inthe sacl on dare nae (NDIR) detecorin he TOC- Vet Scmenred. This was flowed by mensrementoFIC = ere, eth sample (ou 100 mp wea inet in ‘eae sample bet. The, 0.3m 85% phorpor hd {H1PO) was edad whe sample sing pense ore the sample bot was pte ne & 207 combustion ‘amber to rode CO, which saso measure using the [DIR dtetor in he TOC-Vcs. Preah sued td Sample themeasutenens wee eps at ease es to ehiove coefiet variation (CV) of 4c sand Akan (SD) of 0 The average els, S0CV aed SD ‘ercautomateal cuted esonvare SHIMADZU (la Pact) Pe,TheTCandICcairaioncureresutsareshowninFigue Ove gpod epebilty of witha 2% CV ot SD and Srspeively as achieved for al meaitemen Good itty wat slboachevedwitepesan omer 9590, Following htt did sl harap si samples TY ‘eremetsued with SSSA sad he TOC rae / Semple | Te |e | To=Te-1e | ssn | stwinn | "seem | weal | ass | ow | 096 | fo Pest Soil | 7.28 000, 728 J : ‘ile 1: TCs | fSygeona soca eon = aie CConetasons Bir itera Pena fpr The Sst5100 an eu odie TOC in si eS ‘pies nga shor nas ine compart he wet ‘ton method Unlike the det dry combusan ‘neument ht ony hve one combustion care a tear TC (and TOC ihe sap speed with tei he Shinde SOM: SO00A cn prove bath TC ad Te results conven. Analysis also easier spe eating the sample wih ace oremave I nt equ Prortanabsi References (2) nf on (2) Sol Surey Liberatory Medhods Manual (1996) ‘Unied ‘Stes ‘Departmen Stats of Agieutae ‘Nn Resoures Conservation Service, Nation SoiSuvey Cente (6) Recommended Sol Testing Procedures For The Nonteaseen Unie Sites (1995, None ‘Region PulcaioaNo433, Second Eden ‘Acknowledgements ‘The aus woul ie tank Dr Khai aon fom ‘Maia Puli Bos for kindly proving te so Fine 3:1Caliation re SHIMADZU (Asia Paci Pe Lid, prio 208 yas ae) a Canter Support Contre ‘Tamar pratt Te'Sience Park Drive 801-01, The Paster fen mres ot Singapore Scene Park, Singapore 18227 ear 65 6778280 Panes) 782080 ‘StHRADZY (Asis Pc) PL