Ionisation Energy – Revision

Definition of FIRST ionization energy: The energy required to remove 1 mole of

electrons from 1 mole of gaseous atoms to form 1 mole of gaseous ions.

e.g. Na(g) – e-  Na+(g)

Definition of SECOND ionization energy: The energy required to remove 1 mole

of electrons from 1 mole of gaseous 1+ ions to form 1 mole of gaseous 2+ ions.

e.g. Na+(g) – e-  Na2+(g)

Summary:

Ionisation energy INCREASES across a period because…

 Nuclear charge increases

 Electron is being removed from same quantum shell (same amount of
shielding)
 Atomic radius decreases
 Greater attraction between outermost electron and nucleus
Ionisation energy DECREASES down
a group because…

 Electron is being removed

from same quantum shell
that is further from the
nucleus (more shielding)
 Atomic radius increases
 Weaker attraction between
outermost electron and
nucleus
The graph below shows the pattern in the first ionization energies of
the first 18 elements.

Explain why there is a general increase in the first ionization energies

from lithium to neon. (3)

 The number of protons increases i.e. the nuclear charge increases as

you go from Li to Ne.
 For each element, Li – Ne, the electron is being removed from the
same quantum shell (the second quantum shell) so there is the same
amount of shielding.
 Across the period the atomic radius decreases, this causes a greater
attraction between the nucleus and the outermost electron.
Explain why the first ionization energy of aluminium (Z = 13) is less
than that of magnesium (Z = 12). (2)

For aluminium, the electron is removed from a p-orbital which has a higher
energy as it is slightly further from the nucleus and it experiences slightly
more shielding.

(note this is the same explanation for the I.E. of Boron being lower than
Beryllium)

Explain why the first ionization energy of sulfur (Z = 16) is less than
that of phosphorus (Z = 15). (2)

For sulfur, the electron is removed from an orbital with spin-paired

electrons.

This increases the electron-electron repulsion which increases the energy

of the electron, making it easier to remove the electron.

(note this is the same explanation for the I.E. of Oxygen being lower than
Nitrogen)
The graph below shows the successive ionisation energies of
potassium.

Estimate the 1st ionisation energy and the 19th ionisation energy of
potassium. Use data from the graph and your calculator. (1)
Explain why the logarithm of the ionisation energy is used in plotting
this graph rather than the ionisation energy. (1)

The large range of numbers is too big to fit onto the graph.

Explain why there is a general rise in the value of the successive

ionisation energies. (3)

 The electrons are being removed from a more positive ion each time.
The electron:proton ration increases e.g.

Na(g) – e-  Na+(g)

Na+(g) – e-  Na2+(g)

Na2+(g) – e-  Na3+(g)

Na3+(g) – e-  Na4+(g) and so on…

 This causes the ionic radius to decrease as there are fewer electrons
and less electron-electron repulsion
 There is a greater attraction between the outermost electron and the
nucleus
Explain each of the three sharp rises in the graph.
You should include details of the subshell from which the electron is
removed at each sharp rise. (4)
(Hint: Start by writing out the electronic configuration for potassium)

 Each sharp rise is caused by the removal of an electron from a quantum

shell that is closer to the nucleus
 The first sharp increase is when the first 3p electron is removed
 The second sharp increase is when the first 2p electron is removed
 The third sharp increase is when the first 1s electron is removed
 Exam Question Practice
Q1.

The first ionization energies, in kJ mol-1, of four elements with consecutive atomic
numbers are shown below.
A 1680
B 2080
C 496
D 738
(a) Which element could be an inert gas?
(1)
A
B
C
D

(b) Which element could be X in a covalent compound with formula HX?

(1)
A
B
C
D

(c) Which element could be Y in an ionic compound with formula YH2?

(1)
A
B
C
D
(Total for question = 3 marks)
Q2.

The first five successive ionization energies for an element J, in kJ mol−1, are

The formula of the compound of chlorine with element J is

A JCl
B JCl2
C JCl3
D J2Cl3

(Total for question = 1 mark)

Q3.

(a) Define the term first ionization energy.

(2)
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*(b) Explain why the first ionization energy of the elements down Group 1 decreases even
though the atomic number increases.
(2)
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 (c) The eleven successive ionization energies for sodium are given below.

(i) Explain why the successive ionization energies increase.

(1)
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*(ii) Explain how these ionization energies give evidence for the electronic structure of
sodium. You may use a sketch graph if you wish.
(2)

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(d) The first ionization energy of aluminium (element 13) is lower than that of magnesium
(element 12).
(i) Give the electronic structures of magnesium and of aluminium in s, p and d notation.
(1)
Magnesium
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Aluminium
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*(ii) Explain the difference in the first ionization energies of the two metals.
(1)
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(Total for question = 9 marks)
Q4.

The first ionization energy of each of the elements from neon to argon is shown on the graph
below. The first ionization energy of potassium has been omitted.

(a) Define the term first ionization energy.

(3)
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(b) Explain why, in moving from Na to Ar, the general trend is for the first ionization energy to
increase.
(3)
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 (c) Explain why the first ionization energy decreases from P to S.
(2)
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(d) Estimate the value of the first ionization energy of potassium, K, and write your answer
below.
(1)
−1
................................................ kJ mol
(Total for Question = 9 marks)

Q5.

This question is about elements in Period 3 of the Periodic Table.

(a) Write the equation, including state symbols, which represents the first ionization energy of
magnesium.
(2)

(b) Complete the electronic configuration for aluminium using s, p notation.

(1)
1s2 .......................................................................................................................................
(c) The sketch graph below shows the first ionization energies of some of the elements in
Period 3.
 *(i) Explain why the values shown on the graph go down from magnesium to aluminium, and
then rise again going from aluminium to silicon.
(3)
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(ii) Complete the sketch graph for the elements from phosphorus to argon.
Explain why one of these elements does not follow the general trend.
(3)
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(Total for question = 9 marks)

Q6.

(a) Define the term first ionization energy.

(3)
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(b) Write an equation, with state symbols, to illustrate the process occurring when the
second ionization energy of sodium is measured.
(2)

(c) The graph below shows the variation in the first ionization energies of some of the
elements in Period 3.
 (i) On the graph, use crosses to show the approximate values of the first ionization
energies for the elements Na, P and S.

Join the crosses to complete your graph.

(3)

*(ii) Explain why the first ionization energies generally increase across the period
sodium to argon (Na to Ar).
(3)
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*(iii) Explain why the first ionization energy of aluminium is less than that of
magnesium.
(2)
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(d) Place the following species

in order of increasing first ionization energy, starting with the lowest.

(1)

(Total for question = 14 marks)

Q7.
The first five ionization energies of an element, X, are

578, 1817, 2745, 11578 and 14831 kJ mol−1, respectively.

In which group of the Periodic Table is X found?

A 1
B 2
C 3
D 4

(Total for Question = 1 mark)

Q8.
Which of the following equations represents the second ionization energy of chlorine?

A Cl+(g) → Cl2+(g) + e−
B Cl(g) → Cl2+(g) + 2e−
C Cl(g) → Cl2−(g) − 2e−
D Cl−(g) → Cl2−(g) − e−

(Total for Question = 1 mark)

Q9.
This question is about the elements arsenic to rubidium which have atomic numbers 33 to 37.

The first ionization energies, Em1, of these elements are given in the table.

(a) Write the equation, with state symbols, which represents the first ionization energy of
arsenic.
(2)

(b) Suggest the formulae of the hydrides of arsenic and selenium.

(2)

(c) (i) Complete the electronic configuration for an arsenic and a selenium atom using the
electrons-in-boxes notation.
(2)
*(ii) Explain why the first ionization energy of selenium is lower than that of arsenic.
(2)
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*(d) Explain why the first ionization energy of krypton is higher than that of selenium.
(2)
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*(e) Explain why the first ionization energy of rubidium is lower than that of krypton.
(2)
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(f) Which of the elements, arsenic to rubidium, is likely to have atoms with the smallest atomic
radius?
(1)
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(Total for Question = 13 marks)

Q10.
In atoms, electrons fill up the sub-shells in order of increasing energy.

(a) Fill in the last two boxes in the table below to show the order in which the next two sub-
shells are filled.

(2)
(b) Electrons in atoms occupy orbitals.

(i) Explain the term orbital.

(1)
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(ii) Draw diagrams below to show the shape of an s-orbital and of a p-orbital.
(2)

(c) State the total number of electrons occupying all the p-orbitals in one atom of chlorine.
(1)
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(d) State the number of electrons present in an ion of calcium, Ca2+.

(1)
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*(e) Define the term first ionization energy.
(3)
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(f) The ionization energies of sodium, Na, are shown in the table below.

Show with a tick ( ), in the third row of the table below, all the ionization numbers that involve
the removal of an electron from an s-orbital.
(2)

(Total for Question = 12 marks)

Q11.

Magnesium is in Group 2 of the Periodic Table. It has a number of naturally occurring isotopes,
including 24Mg and 26Mg.
(i) Give the electronic structure of a magnesium atom, using the s, p, d notation.
(1)
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(ii) Write the equation for the first ionization energy of magnesium.
Include state symbols.
(1)

* (iii) Explain why the first ionization energy of magnesium is higher than the first ionization
energy of sodium.
(2)
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(iv) Explain why the first ionization energy of magnesium is higher than the first ionization
energy of aluminium.
(2)
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(Total for question = 6 marks)

Q12.

The electronic configurations of the atoms of four different elements are given below.
For which element would you expect the value of the first ionization energy to be the
largest?
A 1s1
B 1s2
C 1s2 2s1
D 1s2 2s2
(Total for question = 1 mark)
Q13.

The sketch graph below shows the trend in first ionization energies for some elements in
Periods two and three.

Select, from the elements A to D, the one that

(a) has atoms with five p electrons.

(1)
A
B
C
D
(b) is a member of Group 3.
(1)
A
B
C
D
(c) is likely to be very unreactive.
(1)
A
B
C
D
 (d) normally forms four covalent bonds per atom.
(1)
A
B
C
D
(Total for question = 4 marks)

Q14.

Which of these equations represents the electron affinity of chlorine?

A Mg+(g) → Mg2+(g) + e-
B Mg(g) → Mg2+(g) + 2e-
C Mg+(g) + e- → Mg2+(g)
D Mg(g) + 2e- → Mg2+(g)
(Total for question = 1 mark)

Q15.
The first eight ionization energies of an element are (in kJ mol−1):
789, 1577, 3232, 4356, 16091, 19785, 23787, 29253.
A Group 1
B Group 2
C Group 3
D Group 4
(Total for question = 1 mark)
Q16.

The graph below represents the successive ionization energies of an element X plotted
against the number of the electron removed. X is not the symbol for the element.

(a) From this graph it is possible to deduce the group in the Periodic Table to which X
belongs. X is in
(1)
A Group 1
B Group 3
C Group 5
D Group 7

(b) From the graph it is possible to deduce that the most stable ion of X will be
(1)
A X3+
B X+
C X−
D X3−
(Total for question = 2 marks)
Q17.

The first five ionization energies of an element, Z, are:

790, 1600, 3200, 4400, 16100 kJ mol−1

In which group of the Periodic Table is Z found?

A 2
B 3
C 4
D 5
(Total for question = 1 mark)

Q18.

The first five successive ionization energies of an element, X, are shown in the table
below.

Which ion is X most likely to form when it reacts with chlorine?

A X+
B X2+
C X3+
D X4+
(Total for question = 1 mark)
Mark Scheme
Q1.

Q2.
Q3.
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Q5.
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Q7.

Q8.
Q9.
Q10.
Q11.
Q12.

Q13.
Q14.

Q15.

Q16.
Q17.

Q18.