1.

The standard ________________ is the change in enthalpy or a

process in which the initial and final substances are in their
standard states.
a) Enthalpy change
b) Reversible change
c) Adiabatic change
d) None of the above
2. The standard enthalpy of ___________ is the standard reaction enthalpy for complete
oxidation of an organic compound to CO2 gas and liquid H2O if the compound contains
C, H,and O, and to N2 gas if N is also present.
a) Decomposition
b) Combustion
c) Single Replacement
d) Enthalpy Change
3. Calculate the final pressure of a sample of water vapor that expands reversibly and
adiabatically from 87.3 Torr and 500 cm3 to a final volume of 3.0 dm3. Take γ = 1.37
a) 0.75 Torr
b) 0.36 Torr
c) 0.85 Torr
d) 90 Torr
4. A vapor at 22 atm and 5°C was allowed to expand adiabatically to a final pressure of 1.00
atm; the temperature fell by 10 K. Calculate the Joule–Thomson coefficient, µ, at 5°C,
assuming it remains constant over this temperature range.
𝐾
a) 0.5 𝑎𝑡𝑚
𝐾
b) 0.45𝑎𝑡𝑚
𝐾
c) 0.78𝑎𝑡𝑚
𝐾
d) 0.48𝑎𝑡𝑚*
5. Calculate the final temperature of a sample of carbon dioxide of mass 16.0 g that is
expanded reversibly and adiabatically from 500 cm3 at 298.15 K to 2.00 dm3.
a) 199.85 K
b) 199.79 K
c) 459.6 K 2.9
d) 165.23 K
ANSWER KEY
1.A
2.B
3.C
4.D
5.B

SOLUTION
𝑉𝑖 0.5 𝑑𝑚3
3. PfVf = PiViy so Pf = P(i𝑉𝑓 )y = (8.73 Torr) (3.0 𝑑𝑚 3) = 𝟎. 𝟖𝟓 𝐓𝐨𝐫𝐫

0.001 𝑑𝑚3
500 cm3 x = 0.5 dm3
1 𝑐𝑚3

𝜕𝑇 ∆𝑇 −10 𝐾 𝑲
4. 𝜇 = (𝜕𝑃)H = ∆𝑃 = (1.00−22)𝑎𝑡𝑚
= 𝟎. 𝟒𝟖 𝒂𝒕𝒎

𝐽
𝐶𝑣𝑚 𝐶𝑝𝑚−𝑅 (37.11−8.3145 )
𝐾−𝑚𝑜𝑙
5. c= = = 𝐽 = 𝟑. 𝟒𝟔𝟑
𝑅 𝑅 8.3145
𝐾−𝑚𝑜𝑙

0.001 𝑑𝑚3
Formula for final temperature; 500 cm3 x = 0.5 dm3
1 𝑐𝑚3

𝑉𝑖 0.5 𝑑𝑚3
Tf= Ti( 𝑉𝑓)1/c = Tf= (298.15K)(2.00𝑑𝑚3)1/3.463 = 199.79 K